HO 6 LIMITING REAGENT ICF (Initial Change Final ) Chart 1. Consider the following reaction: NH4NO3 + Na3PO4 (NH4)3PO4 + NaNO3 Which reactant is limiting, assuming we started with 30.0 grams of ammonium nitrate and 50.0 grams of sodium phosphate. What is the mass of each product that can be formed? What mass of the excess reactant(s) is left over? Initial moles Which is the Limiting reactant? 3 NH4 NO3 0.3747 Na 3PO4 0.3049 Comes from 30.0/80.052 Comes from 50.0/163.94 0.3747/3 = 0.1249 0.3049/1 =0.3049 (NH4 )3 PO4 Zero 3 Na NO3 Zero Smaller than 0.3049, Hence Na 3PO4 is in excess DO NOT USE THESE answers in the division in any subsequent calculations !!!!!!! They are only to be used to determine the LR. NH4 NO3 is LR In all the following steps use initial moles of LR and mole ratios to find the desired moles Changed moles (used or produced) -0.3747 (all of initial LR) Final moles Zero - 0.1249 (calculate from initial moles of LR and the mole ratio) 0.30490.1249= 0.180 + 0.1249 +0.3747 0.1249 0.3747 Changed moles: 0.3747 moles (LR) NH4 NO3 used x 1mol Na 3PO4 used 3mole NH4 NO3 used 0.3747 moles (LR) NH4 NO3 used x 1mol (NH4 )3 PO4 formed 3mole NH4 NO3 used 0.3747 moles (LR) NH4 NO3 used x 3mol Na NO3formed 3mole NH4 NO3 used = 0.1249 mol Na 3PO4 used = 0.1249 mol (NH4 )3 PO4 formed = 0.3747 mol Na NO3formed Products: (NH4 )3 PO4 : 0.1249 (149.09) = 18.6 g ; Na NO3 : 0.3747 (84.99) = 31.8 g Left over excess reactant Na 3PO4 = 0.180 (163.94) = 29.5 g Page 1 of 3 HO 6 LIMITING REAGENT ICF (Initial Change Final ) Chart 2. In this reaction: CaCO3 + FePO4 Ca3(PO4)2 + Fe2(CO3)3 Which reactant is limiting, assuming we start with 100. grams of calcium carbonate and 45.0 grams of iron (III) phosphate. What is the mass of each product that can be formed? What mass of the excess reactant(s) is left over? ? 2 Fe(PO4) ? ? ? ? ? 3 CaCO3 + Initial moles Ca 3(PO4) 2 Zero Fe2(CO3)3 Zero Which is the Limiting reactant? Changed moles (used or produced) Final moles Ca 3(PO4) 2 46. 3 g ; Fe2(CO3)3 = 43.8 g 3) In the balanced reaction : Page 2 of 3 ? CaCO3 = 54.0 g left at the end of reaction CuCl2 + NaNO3 Cu(NO3)2 + NaCl HO 6 LIMITING REAGENT ICF (Initial Change Final ) Chart a) If 15 grams of copper (II) chloride react with 20. grams of sodium nitrate, how much sodium chloride can be formed? b) What is the name of the limiting reagent? c) How much of the excess reagent is left over in this reaction? Page 3 of 3