Water Quality Survey of the Sevilleta Kameron Ortiz Devin Belt 8/8/1013 Abstract: The objective of the study was to collect, analyze, and report water quality of a variety of wells, drinkers, springs, and the Rio Grande located inside of Sevilleta Wildlife Refuge. The study was completed in several steps. First, water samples were collected in the field. The samples were then taken into the lab for analysis. Finally data was derived from lab tests. This data was then interpreted and compared to previous data collected in 2008-2009. The study found that 29% of waters in the region had disappeared from 2008. The water sources that remained declined in quality but were still relatively healthy. Introduction The American Southwest has long been known for its semi-arid climate, the sparse desert brush that its inhabitants have for shelter, and the scarce resource of a very limited state of water availability. In severe cases harsh droughts occur which further impair the life cycles, ecology, and geological features of the affected region (http://pmep.cce.cornell.edu). Throughout history numerous and extensive examples of such droughts have been recorded, including the long lasting drought we are experiencing today (http://www.ncdc.noaa.gov). Prolonged drought can have a more long term damaging effect on environmental and life sustaining communities, locally and globally, including increased wildfires, dust storms, scarce water resources, higher pollution levels, crop failure leading to famine, and in extreme case even violence and war (http://drought.unl.edu). Consecutive monitoring of drought conditions and water quality are essential for providing insight and direction toward sustainability (http://water.epa.gov). With climate change happening in current and rapid succession, recording data can provide a better understanding of hydrogeologic and hydrochemical processes, and insight into what that information means to the scientific and human community (http://water.epa.gov). Serving as a long term case study in water management and availability The Rio Grande Rift, extending from central Colorado into Mexico, has provided insight to potential water reflux based on observing the Rio Grande river (http://academic.emporia.edu). By continuing the tradition of detailed observance of the naturally occurring phenomena present in this great valley, we hope to not only expand on the knowledge compiled of the area, but to offer our own insights regarding the current and future states if the water resources available from this river body. Through careful and accurate measurements, realistic projection models based on the data collected, and a sincere and responsible scientific method we hope to offer an unbiased and accurate appraisal of not only the current condition of our scarcest resource, but guidance for future generations of scientists and student to preserve and celebrate our subject. Methods We collected water samples from several sites around the Sevilleta National Wildlife Refuge (SNWR; Table 1). We focused on collecting water from both drinkers and tanks maintained by the United States Fish and Wildlife Service, as well as open water sources found in the Middle Rio Grande Valley. We followed standard protocols already established by the Hydrogeochemistry Lab at the University of New Mexico. Our goals were to test for alkalinity, pH, conductivity, temperature, ppm (dissolved solids), and cation/anion ratios. To collect water samples, we used at each test site 2 plastic bottles (125ml and 60ml), a syringe with a filter on the end, nitric acid (HNO3; cation/anion analysis), and a water quality probe used on site. All of the sampling bottles had to be rinsed three times with water from the drinker/tank/water source that we were testing. After rinsing water samples could be collected. The 125 ml bottle was dipped directly into the sampling source and had to be filled completely to the top to ensure no air pockets remained in the bottle that could affect future tests. The 60 ml bottle was filled with filtered water from the source using the filtration syringe. Four drops (approximately 4ml) of nitric acid was then added to the water in order to prep it for cation/anion analysis. Final steps included collecting data with the water quality probe. Within two days we tested our water samples for alkalinity with water collected in the 125ml bottle. The water sample in the 60ml bottle was placed into test tubes and was processed at the Hydrogeochemistry Lab at the University of New Mexico for cation/anion analyses. Results and Discussion There have been numerous influences directed toward water quality in the Sevilleta National Wildlife Refuge and surrounding area. This study compares and contrasts data collected in 2008-2009 to present data analysis. Higher elevations of major cations/anions were present in almost all testing sites although non significant at most. Major cations (figure 1.a, 1.b, 1.c, 1.d) exhibit relative influxes with the Esquivel drinker site being the most significant in these elements. Sodium Content 700 600 500 400 300 200 100 0 Na 2008 Na 2013 Rio Grande Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Fig. 1.a Potassium 30 25 20 15 K 2008 10 K 2013 5 0 Rio Grande Fig. 1.b Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Calcium 250 200 150 Ca 2008 100 Ca 2013 50 0 Rio Grande Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Fig. 1.c Magnesium 90 80 70 60 50 40 Mg 2008 30 Mg 2013 20 10 0 Rio Grande Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Fig. 1.d Anion analysis showed an overall decrease in chlorine at 4.2% and bromide at 58.6% with an increase of sulfate at 10.5% shown in figures (2.a, 2.b, 2.c) Chlorine 1000 900 800 700 600 500 400 300 200 100 0 Cl 2008 Cl 2013 Rio Grande Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Fig. 2.a Bromide 1.4 1.2 1 0.8 Br 2008 0.6 Br 2013 0.4 0.2 0 Rio Grande Fig. 2.b Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Sulfate 800 700 600 500 400 SO4 2008 300 SO4 2013 200 100 0 Rio Grande Esquival Well West Mesa Well San Lorenzo Spring Goat Draw Well Data (2.b) is possibly insignificant given insufficient number of comparison sites of water sampling. Conclusion With the general trend showing an increase in major elements since 2008-2009 we can conclude that drought has had a negative effect on water quality in the Sevilleta Region. Our study provides strong evidence that shows further decline of water quality in the Sevilleta region if drought-like conditions persist. Conservation of current water resources will likely help prolong the quality of Sevilleta region waters but without the addition of new waters water quality will continue to decline. Citations http://pmep.cce.cornell.edu/profiles/extoxnet/TIB/ecological.html http://www.ncdc.noaa.gov/paleo/drought/drght_history.html http://drought.unl.edu/DroughtBasics/TypesofDrought.aspx http://water.epa.gov/type/watersheds/monitoring/monintr.cfm http://academic.emporia.edu/schulmem/hydro/TERM%20PROJECTS/Ware/571%20TermP aper.htm