Performance Chemical Co
Product: Bleach
Issue Date: August-20-2014
Bleach
From:
Page 1 of 5
GHS
Safety Data Sheet
24 Hour Emergency Telephone
CHEM-TEL, INC. 1-800-255-3924
Performance Chemical Company
9105 W Interstate 20
Midland, TX 79706
Phone: (432) 332-3059
Fax:
(432) 332-3097
All non-emergency questions should be directed to (432) 332-3059 for
assistance.
NOTE: CHEM-TEL emergency number to be
used only in the event of chemical emergencies
involving a spill, leak, fire, exposure, or accident
involving chemicals.
1. Product Identification
Bleach
Product Name:
Chemical Family:
CLASS 5.1: Oxidizing material.
2. Hazards Identification
Hazard Classification: Oxidizing Liquid-Category 3
Acute Toxicity-Category 5
Skin Irritant-Category 2
Eye Irritant-Category 2
Respiratory Sensitizer
Aspiration Hazard-Category 2
DANGER
Hazard Statement:
Eye Irritant
Skin Irritant
Ingestion Hazard
Precautionary Statement:
Very hazardous in case of skin contact (irritant), of eye contact (irritant). Hazardous in case of ingestion, of inhalation. Slightly
hazardous in case of skin contact (sensitizer). Prolonged exposure may result in skin burns and ulcerations. Over-exposure
by inhalation may cause respiratory irritation. Inflammation of the eye is characterized by redness, watering, and itching. Skin
inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.
Performance Chemical Co
Product: Bleach
Issue Date: August-20-2014
Page 2 of 5
3. Composition / Information on Ingredients
Component Name
Sodium hypochlorite (NaClO)
CAS Registry No.
7681-52-9
Concentration % (Wt.)
12.5%
4. First Aid Measures
Eye Contact:
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids
open. Cold water may be used. Do not use an eye ointment. Seek medical attention.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running
water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is
difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform
mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards:
Do not allow water to enter container because of violent reaction. Keep container tightly closed. Powerful oxidizing agent; may
ignite oxidizable materials.
Special Remarks on Explosion Hazards: Not available.
6. Accidental Release Measures
Adequately ventilate area of leak or spill. Wear appropriate personal protective equipment (PPE), as specified in Section 8.
Isolate hazard area to keep unprotected personnel from entering. Stop the leak if possible. Contain and recover liquid when
possible. Absorb spilled liquid with an inert material, such as vermiculite, sand, or earth and place recovered material in an
approved, compatible chemical waste container. Do not use combustible materials such as cardboard or saw dust as an
absorbent. Do not flush spilled liquid to the sewer. EPA regulations require reporting spills and releases to the soil, air and
water, in excess of the reportable quantity (100 lbs of solution), to the National Response Center, telephone number 1-800424-8802. Reporting to the State Emergency Response Commission (SERC) warning point and local authorities (911) is also
Performance Chemical Co
Product: Bleach
Issue Date: August-20-2014
Page 3 of 5
required. Notify CHEMTREC, for specific information, in the event of any transportation related spills or leaks. (1-800-4249300)
7. Handling and Storage
Precautions:
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material Do not ingest. Do
In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice
immediately and show the container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as
reducing agents, organic materials, metals, acids, moisture.
Storage: Oxidizing materials should be stored in a separate safety storage cabinet or room.
8. Exposure Controls and Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits: Not available.
9. Physical and Chemical Properties
Physical state and appearance: Liquid
Odor: Pungent
Taste: Acrid. (Slight.)
Color: Colorless, sometimes green
pH (1% soln/water): 10 [Basic.]
Boiling Point: 180 F.
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 1.17 g/mL.
Vapor Pressure: 17.5 @ 68 F.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Dispersion Properties: See solubility in water.
Solubility: Soluble in water.
10.Stability and Reactivity
Chemical Stability
Hazardous Polymerization
Hazardous Decomposition
Materials Incompatibility
Slowly decomposes on contact with air. Decomposition rate increases with concentration and
temperature. Exposure to sunlight accelerates decomposition. Sodium hypochlorite solutions
become less toxic with age.
No
When heated to decomposition, emits toxic chlorine fumes and will react with water or steam to
produce heat and toxic, corrosive fumes. Thermal decomposition results in the emission of
chlorine oxides.
Ammonia (chloramines gas may evolve), amines, ammonium salts, acids,
methanol, cellulose, reducing agents, oxidizable metals, and bisulfates.
Performance Chemical Co
Product: Bleach
Issue Date: August-20-2014
Page 4 of 5
11. Toxicological Information
Routes of Entry: Eye contact. Inhalation. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 8.91 g/kg [Mouse].
Chronic Effects on Humans: Not available.
Other Toxic Effects on Humans:
Very hazardous in case of skin contact (irritant). Hazardous in case of ingestion, of inhalation. Slightly hazardous in case of
skin contact (sensitizer).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Material is irritating to mucous membranes and upper respiratory tract.
12. Ecological Information
Ecotoxicity: Highly toxic to aquatic organisms.
Products of Biodegradation:
Decomposes in air and light to release chlorine gas, oxygen and sodium chloride solution (salt water).
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
13. Disposal Considerations
Small leaks and spills may be flushed away with plenty of water. Whatever cannot be recovered
or recycled should be handled as hazardous waste and sent to a RCRA approved waste facility.
State and local disposal regulations may differ from federal regulations. Dispose of container and
contents in accordance with federal, state and local laws.
14. Transport Information
DOT Classification: UN 1791, hypochlorite solution, 8, PG III, ER 154
Identification: Special Provisions for Transport: Not available.
Placards Required
15. Regulatory Information
TOXIC SUBSTANCES CONTROL ACT This substance is listed on the Toxic Substances Control Act
mentoq
NSF LIMITS NSF Maximum Dndang Water Usage Concentrahon - 250 mgll as s&um hypochlonte
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT TITLE M. None Established
HAZARD CATEGORmS, PER 40 CFR 370.2
HEALTH Immediate (Acute)
Delayed (Chronic)
PHYSICAL:
FIRE:
REACTIVITY:
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW, PER 40 CFR 355, APP.A
EXTREMELY HAZARDOUS SUBSTANCE
THRESHOLD PLANNING QUANTITY None Established
SUPPLIER NOTIRICATLON REQUIREMENTS, PER 40 CFR 37245: None Established
Performance Chemical Co
Product: Bleach
Issue Date: August-20-2014
Page 5 of 5
16. Other Information
Disclaimer of Liability:
The information in this msds was obtained from sources which we believe are reliable. However, the information is
provided without any warranty, expressed or implied regarding its correctness. Some information presented and
conclusions drawn herein are from sources other than direct test data on the substance itself. This msds was prepared
and is to be used only for this product.
The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be
beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for
loss, damage or expense arising out of or in any way connected with handling, storage, use or disposal of the product.
Abbreviations:
App. = Approximately
NE = Not Established
EQ = Equal
> = Greater Than
< = Less Than
ACGIH = American Conference of Governmental Industrial Hygienists
IARC = International Agency for Research on Cancer
NIOSH = National Institute of Occupational Safety and Health
NPCA = National Paint and Coating Manufacturers Association
NFPA = National Fire Protection Association
HMIS®
N/AP = Not Applicable
ND = No Data
AIHA = American Industrial Hygiene Association
NTP = National Toxicology Program
OSHA = Occupational Safety and Health Administration
HMIS = Hazardous Materials Information System
EPA = Environmental Protection Agency
Explanation of the HMIS® Ratings
III - HEALTH HAZARD RATINGS
* Chronic Hazard Chronic (long-term) health effects may result from repeated overexposure
0 Minimal Hazard No significant risk to health
1 Slight Hazard Irritation or minor reversible injury possible
2 Moderate Hazard Temporary or minor injury may occur
3 Serious Hazard Major injury likely unless prompt action is taken and medical treatment is given
4 Severe Hazard Life-threatening, major or permanent damage may result from single or repeated overexposures
HMIS® III - FLAMMABILITY RATINGS
0 Minimal Hazard Materials that will not burn
1 Slight Hazard Materials that must be preheated before ignition will occur. Includes liquids, solids and semi solids having a
flash point above 200 F. (Class IIIB)
2 Moderate Hazard Materials which must be moderately heated or exposed to high ambient temperatures before ignition will
occur. Includes liquids having a flash point at or above 100 F but below 200 F. (Classes II & IIIA)
3 Serious Hazard Materials capable of ignition under almost all normal temperature conditions. Includes flammable liquids with
flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F.
(Classes IB & IC)
4 Severe Hazard Flammable gases, or very volatile flammable liquids with flash points below 73 F, and boiling points below 100
F. Materials may ignite spontaneously with air. (Class IA)
HMIS® III - PHYSICAL HAZARD RATINGS
0 Minimal Hazard Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize,
decompose, condense, or self-react. Non-Explosives.
1 Slight Hazard Materials that are normally stable but can become unstable (self-react) at high temperatures and pressures.
Materials may react non-violently with water or undergo hazardous polymerization in the absence of inhibitors.
2 Moderate Hazard Materials that are unstable and may undergo violent chemical changes at normal temperature and pressure
with low risk for explosion. Materials may react violently with water or form peroxides upon exposure to air.
3 Serious Hazard Materials that may form explosive mixtures with water and are capable of detonation or explosive reaction in
the presence of a strong initiating source. Materials may polymerize, decompose, self-react, or undergo other chemical
change at normal temperature and pressure with moderate risk of explosion.
4 Severe Hazard Materials that are readily capable of explosive water reaction, detonation or explosive decomposition,
polymerization, or self-reaction at normal temperature and pressure.