Thursday, Feb. 10 SEC 4 FORMATIVE QUIZ 7 Name: SOLUTION KEY Mega Quiz! 100 100 1. Combine the following atoms to form compounds, state whether they’re ionic or covalent, acid, base, salt or nothing and give the name of the compound that forms. 24 pts. Atoms Compound formed Ionic or covalent Acid, base, salt or nothing Name a. Ca and P Ca3P2 Ionic Salt Calcium Phosphide b. Li and C Li4C Ionic Salt Lithium Crabide c. P2O3 Covalent Nothing Diphosphourous trioxide d. N and I NI3 Covalent Nothing Nitrogen triidiode e. Li and S Li2S Ionic Salt Lithium sulphide f. CaO Ionic Salt Calcium oxide g. N and O N2O3 Covalent Nothing Dinitrogen trioxide h. C and F CF4 Covalent Nothing Carbon tetrafluoride P and O Ca and O 2. Combine the following. 60 pts. Atoms and radicals a. sodium b. Magnesium c. Ammonium NH4+1 d. Aluminium nitrate NO3-1 sulfate SO4-2 Carbonate CO3-2 Phosphate PO4-3 Hydroxide OH-1 Chromate CrO4-2 NaNO3 Na2SO4 Na2CO3 Na3PO4 NaOH Na2CrO4 Mg(NO3)2 MgSO4 MgCO3 Mg3(PO4)2 Mg(OH)2 MgCrO4 NH4NO3 (NH4)2SO4 (NH4)2CO3 (NH4)3PO4 NH4OH (NH4)2CrO4 Al(NO3)3 Al2(SO4)3 Al2(CO3)3 AlPO4 Al(OH)3 Al2(CrO4)3 1 nitrate NO3-1 sulfate SO4-2 Carbonate CO3-2 Phosphate PO4-3 Hydroxide OH-1 Chromate CrO4-2 e. Boron B(NO3)3 B2(SO4)3 B2(CO3)3 BPO4 B(OH)3 B2(CrO4)3 f. Si(NO3)4 Si(SO4)2 Si(CO3)2 Si3(PO4)4 Si(OH)4 Si(CrO4)2 g. Cu+2 Cu(NO3)2 CuSO4 CuCO3 Cu3(PO4)2 Cu(OH)2 CuCrO4 h. Lead+3 Pb(NO3)3 Pb2(SO4)3 Pb2(CO3)3 PbPO4 Pb(OH)3 Pb2(CrO4)3 KNO3 K2SO4 K2CO3 K3PO4 KOH K2CrO4 Ca(NO3)2 CaSO4 CaCO3 Ca3(PO4)2 Ca(OH)2 CaCrO4 Atoms and radicals Silicon i. Potassium j. Calcium 3. Which substance has only covalent bonding? Circle the correct answer. 1 pt. a) KCl c) SO2 b) MgO d) Na2O Answer: c 4. Which substance has only ionic bonding? Circle the correct answer. 1 pt. a) H2O c)P4O10 b) Na2O d)CO2 Answer: b 5. Which of the following is a polyatomic ion? Circle the correct answer. 1 pt. a) H+ c) H2O Answer: b b) OH- d) CO2 2 6. Which is the correct formula for the compound formed by the Al+³ and SO4-2 ions? Circle the correct answer. 1 pt. a) AlSO4 c) Al2(SO4)3 b) Al3(SO4)2 d) Al(SO4)3 Answer: c 7. What would be the correct formula for ammonium (NH4+1) and a phosphate ion (PO4-3)? Circle the correct answer. 1 pt. a) NH4PO4 c) (NH4)3PO4 Answer: c b) NH4(PO4)3 d) PO4(NH4)3 8. The formula for aluminum oxalate is Al2(C2O4)3. What is the charge of the oxalate ion,C2O4 ? Circle the correct answer. 1 pt. a) -1 c) -6 b) -3 d) -2 Answer: d 9. Calculate the molecular molar mass for the following: 4 pts. Al2(SO4)3 342 CH3ClO 66.45 (Remember that chlorine’s mass does not get rounded, you have to use 34.45 g/mol) C2H8N2 60 C3H9O3P 124 10. What is the mass of 0.25 mol of potassium nitrate, KNO3? Circle the correct answer. 1 pt. a) 17.3 g c) 69.0 g b) 25.3 g d) 101.0 g Answer: b 3 11. 12. 13. 14. What is the mass of 0.45 mol of 3-aminobutane-1,2,4-triol, C4H11NO3? Circle the correct answer. 1 pt. a) 54.45 g c) 99.0 g b) 20.3 g d) 161.0 g Answer: a What is the mass of 1.25 mol of butan-1-amine C4H11N? Circle the correct answer. 1 pt. a) 91.25 g c) 199.0 g b) 300.3 g d) 71.0 g Answer: a What is the mass of 2.35 mol of adenine C5H5N5? Circle the correct answer. 1 pt. a) 491.25 g c) 199.0 g b) 245.31 g d) 317.25 g Answer: d How many moles are present in 100 g of (NH4)2SO4? Circle the correct answer. 1 pt. a) 1.32 mol c) 1.14 mol Answer: b b) 0.76 mol 15. d) 0.88 mol How many moles are present in 150g of CH5O3P? Circle the correct answer. 1 pt. a) 2.32 mol c) 1.24 mol Answer: b b) 1.56 mol 16. d) 1.78 mol How many moles are present in 113 g of hexane-2,3,4-triol (C6H14O3) ? Circle the correct answer. 1 pt. a) 0.84 mol c) 0.64 mol b) 0.56 mol d) 0.78 mol Answer: a 4 17. 18. How many moles are present in 234g of 2-(dimethylamino) pentan-3-ol (C7H17NO)? Circle the correct answer. 1 pt. a) 1.79 mol c) 2.64 mol b) 0.56 mol d) 1.68 mol Answer: a You are to prepare 300 mL of an aqueous solution of sodium hydroxide, NaOH that will have a concentration of 0.8 mol/L. What mass of NaOH do you need? Circle the correct answer. 1 pt. a) 0.24 g c) 9.6 g b) 6.0 g d) 32 g Answer: c 19. You are to prepare 150 mL of an aqueous solution of triphenylphosphine C18H15P that will have a concentration of 1.25 mol/L. What mass of C18H15P do you need? Circle the correct answer. 1 pt. a) 32.24 g c) 49.13 g b) 26.02 g d) 31.71 g Answer: c 20. 21. You are to prepare 75 mL of an aqueous solution of diethyl phosphonite C4H11O2P that will have a concentration of 0.735 mol/L. What mass of C4H11O2P do you need? Circle the correct answer. 1 pt. a) 2.24 g c) 9.13 g b) 6.73 g d) 5.71 g Answer: b You are to prepare 1.2 L of an aqueous solution of uracil C4H4N2O2 that will have a concentration of 1.86 mol/L. What mass of C4H4N2O2 do you need in kilograms? Circle the correct answer. 1 pt. a) 0.25 Kg c) 1.13 Kg Answer: a b) 0.73 Kg d) 0.81 Kg 5 22. What is the concentration of a solution of MgSO4 when 125 g of MgSO4 are dissolved to form 2.5 L of solution? 1 pt. a) 0.38 mol/L c) 2.40 mol/L Answer: b b) 0.42 mol/L 23. 24. d) 2.60 mol/L What is the concentration of a solution of CHKO2 when 200 g of CHKO2 are dissolved to form 0.85 L of solution? 1 pt. a) 2.38 mol/L c) 3.45 mol/L b) 5.02 mol/L d) 2.80 mol/L Answer: d 500 mL of a 4 mol/L solution are diluted to form a 1 mol/L solution. What volume of water is added to the original solution? 2 pts. Step1 : Given Step2 : Step3 : C1 : 4 mol/L C1V1 = C2V2 Water = V2 – V1 V1 : 0.5 L 4 x 0.5 = 1 x V2 = 2 – 0.5 C2 : 1 mol/L V2 = 2 L = 1.5 L V2 ? Water ? 6 25. 250 mL of a 3.13 mol/L solution are diluted to form a 2.25 mol/L solution. What volume of water is added to the original solution? 2 pts. Step1 : Given Step2 : Step3 : C1 : 3.13 mol/L C1V1 = C2V2 Water = V2 – V1 V1 : 0.25 L 3.13 x 0.25 = 2.25 x V2 = 0.348 – 0.24 C2 : 2.25 V2 = 0.348 L = 0.098 L V2 ? Water ? 26. The lab technician is asked to prepare 2 L of 0.3 mol/L HNO3 solution. He has a stock supply of 12 mol/L HNO3 solution. How much of the stock solution does he need? 2 pts. Step1 : Given Step2 : C1 : 12 mol/L C1V1 = C2V2 V1 : ? 12 x V1 = 0.3 x 2 C2 : 0.3 mol/L V2 = 0.05 L V2 : 2 L 27. What is the mass (g) of 0.45 mol of each of the following compounds? 6 pts. a. H4Al2O4 c. AlCl3 e. AlNaO2 54.9 60 36.9 b. Al2O3 d. H2Fe2O3 f. CaCO3 45.9 72.9 45 7 28. How many moles are present in 200 g of each of the following compounds? 6 pts. a. SnF4 c. AlCl3 f. PbO2 0.94 1.41 1.41 0.84 You are to prepare 150 mL of an aqueous solution with the following compounds. Each solution will have a concentration of 3.45 mol/L. What mass (g) of each of the following compounds do you need? 6 pts. a. H4Al2O4 b. Al2O3 63.14 c. AlCl3 d. H2Fe2O3 69.01 e. AlNaO2 30. d. P2O5 1.50 e. CrBr2 29. b. Na2O4S 1.03 f. CaCO3 42.44 52.79 83.84 51.75 What will be the concentration (mol/L) of the following solutions when 120 g of each compound is dissolved in 1.29 mL? 6 pts. a. Baking Soda: NaHCO3 1107.42 b. Liquid bleach: NaClO 1249.47 c. Solid bleach: NaBHO3 1120.76 d. Borax: Na2B4O7 • H2O 422.83 e. Chloroform: CHCl3 779.42 f. Laughing gas: N2O 31. 2114.16 Give the formula to the following names. 4 pts. a) Magnesium nitride Mg3N2 b) Carbon tetrachloride CCl4 c) Aluminium sulphide Al2S3 d) Calcium phosphide Ca3P2 8 32. You are given 35 g of MgF2 dissolved in water at a concentration of 2.5 mol/L. Calculate the volume of water used. 2 pts. Step1 : Given Step2 : Step3 : m: 35 g n: m/mMm V = n /C mMm: 62 g/mol : 35 g / 62 g/mol = 0.56 mol / 2.5 mol/L C: 2.5 mol/L : 0.56 mol = 0.224 L V?L ___m____ n x mMm n ? mol 33. ___n___ _C x V Find the solution concentration in g/mL of dissolving 0.256 mol of Na2S in 0.4 L of water. 2 pts. Step1 : Given Step2 : Step3 : C ? g/mL m = n x mMm C=m/V n= 0.256 mol = 0.256 mol x 78 g/mol = 19.97 g / 400 mL m? g = 19.97 g = 0.050 g /mL ___m____ n x mMm V: 0.4 L mMm: 78 g/mol ___m___ _C x V 9 34. What is the final concentration in mol/L of a solution if initially it had 500 mL concentrated at 2 mol/L and you added 2.5 L to that solution? 2 pts. Step1 : Given Step2 : C2? C1V1 = C2V2 V1: 0.5 L 2 x 0.5 = C2 x 3 C2: 2 mol/L C2 = 0.3 mol/L V2: 2.5 L + 0.5 L :3L 35. What volume of distilled water must be added to 200 mL of an NaOH solution concentrated at 1.5 mol/L to dilute it to 0.4 mol/L? 2 pts. Step1 : Given Step2 : Step3 : Water ? C1V1 = C2V2 Water = V2 – V1 V1: 0.2 L 1.5 x 0.2 = 0.4 x V2 = 0.75- 0.2 C1: 2 mol/L V2 = 0.75 L = 0.55 L C2: 0.4 mol/L V2 ? 36. Find the concentration in g/mL of dissolving 2.5 mol of NaBr in 3 L of water. 2 Step1 : Given Step2 : Step3 : C ? g /mL m = n x mMm C = m/V pts. n: 2.5 mol = 2.5 mol x 103 g/mol = 257.5 / 3000 V: 3 L: 3000 mL = 257.5 g = 0.0857 g /mL ___m___ _C x V m? mMm: 103 g/mol ___m____ n x mMm 10 37. You are given 60 g of CaCl2 dissolved in water at a concentration of 1.8 mol/L. Calculate the volume of water used. 2 pts. Step1 : Given Step2 : Step3 : m: 60 g n = m/mMm V = n /C mMm: 110.9 g/mol = 60/110.9 = 0.541/1.8 C: 1.8 mol/L = 0.541 mol = 0.301 L ___m____ n x mMm V? n? 38. ___n___ _C x V Find the solution concentration in g/mL of dissolving 0.345 mol of Li2O in 0.6 L of water. Step1 : Given Step2 : Step3 : C ? g/mL m = n x mMm C = m/V n: 0.345 mol = 0.345 x 30 = 10.35/600 mMm: 30 g/mol = 10.35 g = 0.0173 g/mL V: 600 mL 39. 2 pts. ___m____ n x mMm ___m___ _C x V What is the final concentration in mol/L of a solution if initially it had 400 mL concentrated at 3 mol/L and you added 4.5 L to that solution? 2 pts. Step1 : Given Step2 : C2 ? C1V1=C2V2 V1: 400 mL: 0.4 L 3 x 0.4 = C2 x 4.9 C1: 3 mol/L C2 = 0.24 mol/L V2: 0.4+4.5: 4.9 L 11 40. What volume of distilled water must be added to 150 mL of an CaCO3 solution concentrated at 0.250 g/mL to dilute it to 0.5 mol/L? 2 pts. Step1 : Given Step2 : Step3 : Water ? Convert C2 into g/mL C1V1=C2V2 V1: 150 mL m = n x mMm 0.25 x 150 = 0.05 x V2 C1: 0.25 g/mL = 0.5 x 100 = 50 g C2: 0.5 mol/L C2 = 50 g / 1000 mL V2 ? 41. = 0.05 g /mL ___m___ _C x V V2 = 750 mL ___m____ n x mMm Water = V2 – V1 = 750 – 150 = 600 mL Find the mass in grams in 75 mL of Al2O3 solution knowing that the concentration of this solution is 2.67 g/ L? pts. Step1 : Given Step2 : m?g m=CxV V: 75 mL: 0.075 L = 2.67 x 0.075 C: 2.67 g/L = 0.200 g ___m___ _C x V 12 2 42. 43. 2 pts. If you were given 24 mg of CHCl3 in 175 mL, what is the concentration in g/L? Step1 : Given Step2 : m: 24 mg: 0.024 g C = m/V V: 175 mL: 0.175 L = 0.024/0.175 C? = 0.137 g/L ___m___ _C x V Which of the following is the mass in grams in 75 mL of Al2O3 solution knowing that the concentration of this solution is 2.67 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : C: 2.67 mol/L n=CxV m = n x mMm V: 0.075 L = 2.67 mol/L x 0.075 L = 0.200 x 102 m? = 0.200 mol = 20.43 g ___n___ _C x V n? mMm: 102 g/mol ___m____ n x mMm 13 44. If you were given 24 g of CHCl3 in 175 mL, what is the molarity (molar concentration, mol/ L) of this solution? pts. Step1 : Given Step2 : Step3 : m: 24 g n = m / mMm C=n/V V: 0.175 L = 24 / 119.35 = 0.201 / 0.175 C? = 0.201 mol = 1.15 mol/L ___n___ _C x V n? ___m____ n x mMm mMm: 119.35 g/mol 45. Convert 25 % (25g/100mL) of Mg(OH)2 (aq) into molarity (mol/ L). 2 pts. Step1 : Given Step2 : Step3 : m: 25 g n = m / mMm C=n/V V: 0.1 L = 25 / 58 = 0.43 / 0.1 n? = 0.43 mol = 4.3 mol/L ___n___ _C x V mMm: 58 g ___m____ n x mMm 14 2 46. What is the final concentration of a solution if initially it had 2L concentrated at 8 mol/L and you added 3 L to that solution? 2 pts. Step1 : Given Step2 : C2 ? C1V1 = C2V2 V1: 2 L 8 x 2 = C2 x 5 C1: 8 mol/L C2 = 3.2 mol/L V2: 3+2: 5L 47. What volume of distilled water must be added to 100 mL of an NaOH solution concentrated at 3 mol/L to dilute it to 1 mol/L? 2 pts. Step1 : Given Step2 : Step3 : Water ? C1V1 = C2V2 Water = V2-V1 V1: 100 mL: 0.1L 3 x 0.1 = 1 x V2 = 0.3 – 0.1 C1: 3 mol/L V2 = 0.3 L = 0.2 L V2 ? C2: 1 mol/L 15 48. When drawing the Newton-Lewis diagram for the combination of Oxygen and Nitrogen, how many electrons are being shared in total? 1 pt. Covalent bond formed by two non-metals that SHARE electrons. N3 O2 N2O3 Double bonds N O N O Single bond O Single bond O N O N O Answer: 12 electrons are being shared. Double bonds 16 49. Which of the following are covalent compound(s)? Circle the correct answer. 1 pts. a. H2O b. NaCl Answer: a and d c. MgF2 d. NI3 50. Draw the Newton-Lewis structure for Mg3P2. 2 pts. Ionic bond formed by a metal with a non-metal where there is a transfer of electrons. Mg+2 P-3 P Mg Mg3P2 P Mg Mg Mg P Mg P Mg 17 51. Draw the Newton-Lewis diagram for the compound formed between Ca and C. 2 pts. Ionic bond formed by a metal with a non-metal where there is a transfer of electrons. Ca+2 C-4 Ca4C2 Ca2C C Ca Ca Ca C Ca 18 52. What volume of water do you need to make a 25.5% salt water solution if you are given 30 g of salt? Step1 : Given Step2 : C: 25.5 g/ 100 mL : 0.255 g/mL V = m/C = 30 g / 0.255 g/mL m: 30 g V? 53. ___m___ _C x V = 117.65 mL Which are ionic compound(s)? Circle the correct answer. 1 pt. a. NaCl b. CCll4 Answer: a and d c. NI3 d. CaO 54. Draw the Newton-Lewis structure when you combine barium with chlorine. 2 Ba +2 Cl -1 pts. BaCl2 Ba Cl Cl Cl Ba Cl 19 2 pts. 55. Draw the he Newton-Lewis structure when you combine phosphorous with carbon. 2 pts. Covalent bond formed by two non-metals that SHARE electrons. C+4 P-3 C 3P 4 P P C P P C C P C P C P C P 56. the mass in grams in 300 mL of NaOH solution knowing that the concentration of this solution is 7.6 mol/ L. 2 pts. Find Step1 : Given Step2 : Step3 : m? n=CxV m = n x mMm V: 0.3 L = 7.6 mol/L x 0.3 L = 2.28 mol x 40 g/mol C: 7.6 mol/L = 2.28 mol = 91.2 g ___n___ _C x V n? mMm: 40 g/mol ___m____ n x mMm 20 57. the mass in grams in 150 mL of HF solution knowing that the concentration of this solution is 6 mol/ L. 2 pts. Find Step1 : Given Step2 : Step3 : m? n=CxV m = n x mMm V: 150 mL: 0.15 L = 0.15 x 6 = 0.9 x 20 C: 6 mol/L = 0.9 mol = 18 g n? ___m____ n x mMm mMm: 20 g/mol 58. ___n___ _C x V the mass in grams in 75 mL of Al2O3 solution knowing that the concentration of this solution is 2.67 mol/ L. 2 pts. Find Step1 : Given Step2 : Step3 : m? n=CxV m = n x mMm V: 75 mL: 0.075 L = 2.67 x 0.075 = 0.200 x 102 C: 2.67 mol/L = 0.200 mol = 20.4 g ___n___ _C x V n? mMm: 102 g/mol ___m____ n x mMm 21 59. the mass in grams in 120 mL of AlCl3 solution knowing that the concentration of this solution is 1.35 mol/ L. 2 pts. Find Step1 : Given Step2 : Step3 : m? n=CxV m = n x mMm V: 120 mL: 0.12 L = 1.35 x 0.12 = 0.162 x 133.35 C: 1.35 mol/L = 0.162 mol = 21.6 g n? ___m____ n x mMm mMm: 133.35 g/mol 60. ___n___ _C x V the number of moles in 120 mL of H2Fe2O3 solution knowing that the concentration of this solution is 250 g/ L. 2 pts. Find Step1 : Given Step2 : Step3 : n? m=CxV n = m / mMm V: 120 mL: 0.12 L = 250 x 0.12 = 30 / 162 C: 250 g/L = 30 g = 0.185 mol ___m___ _C x V m? mMm: 162 g/mol ___m____ n x mMm 22 61. the number of moles in 300 mL of AlNaO2 solution knowing that the concentration of this solution is 75 g/ L. 2 pts. Find Step1 : Given Step2 : Step3 : n? m=CxV n = m / mMm V: 300 mL: 0.3 L = 75 x 0.3 = 22.5 / 82 C: 75 g/L = 22.5 g = 0.274 mol ___m___ _C x V m? ___m____ n x mMm mMm: 82 g/mol 62. the number of moles in 225 mL of CaCO3 solution knowing that the concentration of this solution is 135 g/ L. 2 pts. Find Step1 : Given Step2 : Step3 : n? m=CxV n = m / mMm V: 225mL: 0.225 L = 135 x 0.225 = 30.4 / 100 C: 135 g/L = 30.4 g = 0.304 mol ___m___ _C x V m? mMm: 100 g/mol ___m____ n x mMm 23 63. the number of moles in 400 mL of CaCO3 solution knowing that the concentration of this solution is 200 g/ L. 2 pts. Find Step1 : Given Step2 : Step3 : n? m=CxV n = m / mMm V: 400 mL: 0.4 L = 200 x 0.4 = 80 / 100 C: 200 g/L = 80 g = 0.80 mol ___m___ _C x V m? ___m____ n x mMm mMm: 100 g/mol 64. If you were given 16 g of NaBHO3 in 200 mL, what is the molarity (molar concentration mol/ L) of this solution? 2 pts. Step1 : Given Step2 : Step3 : m: 16 g n = m/mMm C = n/V V: 200 mL: 0.2 L = 16 / 83 = 0.193 / 0.2 n? = 0.193 mol = 0.964 mol/L C ? mol/L ___n___ _C x V mMm: 83 g/mol 65. ___m____ n x mMm If you were given 24 g of CHCl3 in 175 mL, what is the molarity (molar concentration mol/ L) of this solution? 2 pts. Step1 : Given Step2 : Step3 : m: 24 g n = m/mMm C = n/V V: 175 mL: 0.175 L = 24 / 119.35 = 0.201 / 0.175 n? = 0.201 mol = 1.15 mol/L C ? mol/L mMm: 119.35 g/mol ___m____ n x mMm ___n___ _C x V 24 66. If you were given 50 g of N2O in 154 mL, what is the molarity (molar concentration mol/ L) of this solution? 2 pts. Step1 : Given Step2 : Step3 : m: 50 g n = m/mMm C = n/V V: 154 mL: 0.154 L = 50 / 40 = 1.14 / 0.154 n? = 1.14 mol = 7.38 mol/L ___m____ n x mMm C ? mol/L ___n___ _C x V mMm: 44 g/mol 67. If you were given 100 g of NaClO in 250 mL, what is the molarity (molar concentration mol/ L) of this solution? 2 pts. Step1 : Given Step2 : Step3 : m: 100 g n = m/mMm C = n/V V: 250 mL: 0.250 L = 100 / 74.45 = 1.34 / 0.250 n? = 1.34 mol = 5.37 mol/L C ? mol/L ___n___ _C x V mMm: 74.45 g/mol 68. ___m____ n x mMm If you were given 55 g of NaHCO3in 300 mL, what is the molarity (molar concentration mol/ L) of this solution? 2 pts. Step1 : Given Step2 : Step3 : m: 55 g n = m/mMm C = n/V V: 300 mL: 0.300 L = 55 / 84 = 0.655 / 0.3 n? = 0.655 mol = 2.18 mol/L C ? mol/L mMm: 84 g/mol ___m____ n x mMm ___n___ _C x V 25 69. Convert 10 % AlCl3 (aq) into molarity (mol/ L). 2 pts. Step1 : Given Step2 : Step3 : 10 % : 10 g /100 mL : 0.10 g/mL n = m/mMm C = n/V = 0.10 / 133.35 = 0.00075 / 0.001 = 0.00075 mol = 0.75 mol/L ___m____ n x mMm n? V?L ___n___ _C x V mMm: 133.35 g/mol 70. Convert 9 % H4Al2O4 (aq) into molarity (mol/ L). 2 pts. Step1 : Given Step2 : Step3 : 9 % : 9 g /100 mL : 0.09 g/mL n = m/mMm C = n/V = 0.09 / 122 = 0.00074 / 0.001 = 0.00074 mol = 0.74 mol/L ___m____ n x mMm n? V?L ___n___ _C x V mMm: 122 g/mol 71. Convert 25 % Mg(OH)2 (aq) into molarity (mol/ L). 2 pts. Step1 : Given Step2 : Step3 : 25 % : 25 g /100 mL : 0.25 g/mL n = m/mMm C = n/V = 0.25 / 58 = 0.43 / 0.001 = 0.43 mol = 4.3 mol/L ___m____ n x mMm n? V?L mMm: 40 g/mol ___n___ _C x V 26 72. Convert 18 % (CH3)2CHOH (aq) into molarity (mol/ L). 2 pts. Step1 : Given Step2 : Step3 : 18 % : 18 g /100 mL : 0.18 g/mL n = m/mMm C = n/V = 0.18 / 60 = 0.003 / 0.001 = 0.003 mol = 3.0 mol/L ___m____ n x mMm n? V?L ___n___ _C x V mMm: 60 g/mol The following numbers are considered to be advanced problems. They are a good practice for you to complete when you are comfortable with molarity. 73. What amount of solvent must be added to a solution that contains 200 g of FeS2 in 200 mL of water to obtain a final concentration of 2 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 200 mL: 0.2 L n = m/mMm C1V1= C2V2 Water = V2-V1 C1 ? = 200 / 120 8.3 x 0.2 = 2 x V2 = 0.83 – 0.2 n? = 1.7 mol V2 = 0.83 L = 0.63 L C2: 2 mol/L C1= n/V1 m: 200 g = 1.7 / 0.2 V2 ? = 8.3 mol/L Water ? mMm: 120 g/mol 27 74. What amount of solvent must be added to a solution that contains 75 g of Na 2B4O7 • H2O in 100 mL of water to obtain a final concentration of 0.25 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 100 mL: 0.1 L n = m/mMm C1V1= C2V2 Water = V2-V1 C1 ? = 75 / 220 3.41 x 0.1 = 0.25 x V2 = 1.364 – 0.1 n? = 0.341 mol V2 = 1.364 L = 1.264 L C2: 0.25 mol/L C1= n/V1 m: 75 g = 0.341 / 0.1 V2 ? = 3.41 mol/L Water ? mMm: 220 g/mol 28 75. What amount of solvent must be added to a solution that contains115 g of HCl in 240 mL of water to obtain a final concentration of 0.56 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 240 mL : 0.24 L n = m/mMm C1V1= C2V2 Water = V2-V1 = 115 / 36.45 13.15 x 0.24 = 0.56 x V2 = 5.64 – 0.24 = 3.16 mol V2 = 5.64 L = 5.40 L C1 ? n? C2: 0.56 mol/L C1= n/V1 m: 115 g = 3.16 / 0.24 V2 ? = 13.15 mol/L Water ? mMm: 36.45 g/mol 29 76. What amount of solvent must be added to a solution that contains265 g of PbO 2 in 120 mL of water to obtain a final concentration of 3 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 120 mL : 0.12 L n = m/mMm C1V1= C2V2 Water = V2-V1 = 265 / 239 9.24 x 0.12 = 3 x V2 = 0.37 – 0.12 = 1.11 mol V2 = 0.370 L = 0.25 L C1 ? n? C2: 3 mol/L C1= n/V1 m: 265 g = 1.11 / 0.12 V2 ? = 9.24 mol/L Water ? mMm: 239 g/mol 30 77. What amount of solvent must be added to a solution that contains140 g of CrBr2 in 80 mL of water to obtain a final concentration of 4.1 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 80 mL : 0.08 L n = m/mMm C1V1= C2V2 Water = V2-V1 = 140 / 212 8.25 x 0.08 = 4.1 x V2 = 0.66 mol V2 = 0.161 L = 0.161 – 0.08 C1 ? = 0.081 L n? C2: 4.1 mol/L C1= n/V1 m: 140 g = 0.66 / 0.08 V2 ? = 8.25 mol/L Water ? mMm: 212 g/mol 31 78. What amount of solvent must be added to a solution that contains 230 g of SnF 4 in 60 mL of water to obtain a final concentration of 1.25 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 60 mL : 0.06 L n = m/mMm C1V1= C2V2 Water = V2-V1 = 230 / 195 19.66 x 0.06 = 1.25 x V2 = 1.18 mol V2 = 0.944 L = 0.944 – 0.06 C1 ? = 0.884 L n? C2: 1.25 mol/L C1= n/V1 m: 230 g = 1.18 / 0.06 V2 ? = 19.66 mol/L Water ? mMm: 195 g/mol 32 79. What amount of solvent must be added to a solution that contains140 g of C 16H36N in 20 mL of water to obtain a final concentration of 0.15 mol/ L? 2 pts. Step1 : Given Step2 : Step3 : Step4 : V1: 20 mL : 0.02 L n = m/mMm C1V1= C2V2 Water = V2-V1 = 140 / 242 28.93 x 0.02 = 0.15 x V2 = 0.579 mol V2 = 3.86 L = 3.86 – 0.02 C1 ? = 3.84 L n? C2: 0.15 mol/L C1= n/V1 m: 140 g = 0.579 / 0.02 V2 ? = 28.93 mol/L Water ? mMm: 242 g/mol 33