Name: ________________________________________________ Date of Midterm: _____________________________ CP Chemistry Midterm Exam: Topic List and Review Chapter One: Matter and Change Definition of chemistry and matter Characteristics of mixtures Definition of physical and chemical change Metals, non-metals and metalloids Branches of chemistry States of matter Classification of matter Elements & compounds Chapter Two: Measurements and Calculations Scientific method Mass, volume and density Accuracy and precision Significant figures Scientific notation Metric prefixes SI Units of measure Conversion factors Percent error Calculations using significant figures Qualitative vs. quantitative Conversions between Kelvin and Celsius Chapter 3: Atoms the Building Blocks of Matter Dalton’s law of atomic theory Law of definite proportions Atomic structure Properties of protons, neutrons and electrons Atomic mass Isotopes Molar mass Law of conservation of mass Law of multiple proportions Scientists/tools/experiments-atomic structure Atomic number Calculate average atomic mass* Mole and Avogadro’s number Gram↔ Mole↔ Atom Conversions Chapter 4: Arrangement of Electrons in Atoms Properties of Waves Visible light spectra Energy (E= hν) Ground state and excited state electrons Electromagnetic radiation Speed of light (c = λν) Line spectra Electron configuration Chapter 5: The periodic Law Historical perspective of the periodic table Groups / Periods Organization of the periodic table Electron configuration Main group elements (s & p block) Blocks of periodic table (s,p,d & f) Family properties Valence electrons Periodic trends: atomic radius, ionization energy, electronegativity Chapter 6: Chemical Bonding Electronegativity & type of chemical bond Polar covalent bonds Lewis dot structures Single, double, triple bonds and resonance Common ions and ionic bonds Ionic bonds Non-polar covalent bonds Chemical formulas Lone pair electrons Molecular geometry-VSEPR and polarity Chapter 7: Chemical Formulas and Chemical compounds Recognizes ions and charges Write molecular formulas (covalent) Gram/mole/mass conversions* Calculate empirical formulas* Write balanced formula units (ionic) Molar mass (gram formula mass)* Calculate percent composition* * Be able to solve problems by performing calculations (similar to previous tests and worksheets) CP Chemistry Midterm Review Page #1 Define the following. 1. Physical change 2. Chemical change (chemical reaction) 3. Quantitative observations 4. Qualitative observations – 5. Precision – 6. Accuracy Lab Safety. 7. Write down all lab safety procedures that apply to the following scenario: Flame Test Lab Procedure: 1. At each station there is a wooden splint soaking in a known compound. 2. Write down the name of the compound into your data table. 3. Pick up the wooden splint and hold it over the hottest part of the Bunsen burner flame. (This is the center towards the base of the flame. Do NOT touch the wooden splint to the Bunsen burner.) 4. Record the color of the flame in your data table. 5. Replace the wooden splint into the solution. 6. Go to the next station and repeat steps 2-5. 7. Determine which element ion was responsible for the color. 8. Repeat steps 2-5 for the 4 unknown compounds. Record this information under the “Unknown Compounds” in the Data section. Applicable Safety Rules to Follow (be sure to number your procedures): _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ _______________________________________________________________________________________________ CP Chemistry Midterm Review Page #2 Significant Digits. How many significant figures are in each measurement? 8. 1.20 __________ 12. 0.20300 __________ 9. 0.007 __________ 13. 140000 __________ 10. 123.400 __________ 14. 5.698 x 1.23 __________ 11. 7.8 X 1023 __________ 15. 7.8/1.29 __________ Scientific Notation. Convert the following between scientific notation and standard notation. 16. 4,200 ____________________ 19. 3.50 x 105 ____________________ 17. 0.000652 ____________________ 20. 9.99 x 10-3 ____________________ 18. 1.23 ____________________ 21. 2.00 x 10-1 ____________________ Density. Answer the following. Remember to round your answer to the appropriate number of significant figures. 22. An object has a mass of 5.25 g and a volume of 1.2 ml. What is the density? 23. An object has a density of 2.2 g/ml and a mass of 4.9 g. What is the volume? 24. An object has a volume of 3.25 ml and a density of 1.2 g/ml. What is the mass? Percent Error 25. If a student determines the density of a copper object is 8.46 g/ml and the accepted value is 8.96 g/ml, what is the percent error? Unit Conversions 26. Convert 9,014 kg to g 27. Convert 7.2 L to mL CP Chemistry Midterm Review Page #3 Define. 1. Atom - 2. Ion - 3. Isotope - History. 4. Describe the experiment that JJ Thomson used to discover the electron. 5. Ernest Rutherford conducted the gold foil experiment to disprove Thomson’s plum pudding model. Describe the outcome of the experiment. Atomic Structure. 6. The smallest unit of an element that still maintains the properties of that element is a(n) ___________________. 7. The subatomic particles, ___________________ and ___________________ have about the same mass. 8. Fill in the table (parts of an atom). Charge Proton Neutron Electron Location CP Chemistry Midterm Review Page #4 9. Fill in the Chart Element Ion 2 Atomic Number Mass Number Protons H+1 24 Mg+2 39 K 15 N-3 16 O-2 7 Li+1 Electron Configuration and Dot Diagrams 10. Write the electron configuration for Fluorine. 11. Write the electron configuration for Cadmium. 12. Identify the following elements by symbol and name: a. 4d10 __________________________________________ b. 6p2 __________________________________________ c. 5s1 __________________________________________ 13. Draw the Lewis dot structure for Chlorine. 14. Draw the Lewis dot structure for Boron. Neutrons Electrons CP Chemistry Midterm Review Page #5 Periodic Table Trends. 1. Label the table with the following: Alkali Metals Halogens Alkaline Earth Metals Metalloids Chalcogens Lanthanide Series Transition Metals Actinide Series Noble Gases Metals Nonmetals +1, +2, +3, +/-4, -1, -2, -3 s, p, d, f blocks Group Period 2. In terms of electron arrangement, which group is chemically un-reactive due to a full outside shell? ___________________________ 3. Which element touching the staircase is not a metalloid? ____________________________ 4. Follow the numbers in the boxes of the elements in one group as you trace down the group. What do you notice about the changes in the atomic mass as you go down the group? _____________________________ a. What about the number of electron shells? ______________________________________________ 5. Atomic radius ________________ across a period and _________________ down a column. 6. Electronegativity ________________ across a period and _________________ down a column. 7. Ionization energy ________________ across a period and _________________ down a column. 8. The major reason for each of these trends across a period is an increase in _______________ ______________. The major reason for each of these trends down a group is an increase in ________________ ______________. CP Chemistry Midterm Review Page #6 Formula Writing and Percent Composition. Calculate the formula weight for the following and determine the percent composition for the underlined element: 9. Na2SO4 10. (NH4)3PO4 Formula writing Write the formulas for the following 1. aluminum oxide _______________ 6. aluminum phosphate _______________ 2. copper (I) nitrate _______________ 7. manganese (II) bromate _______________ 3. calcium sulfate _______________ 8. diboron tetrabromide _______________ 4. chromium (IV) silicide _______________ 9. carbon tetrachloride _______________ 5. aluminum sulfate 10. iodine pentafluoride _______________ _______________ Write the names for the following 11. Na2O __________________________________ 12. KOH __________________________________ 13. (NH4)2SO3 __________________________________ 14. Fe2O3 __________________________________ 15. Cu2SO4 __________________________________ 16. S5Cl9 __________________________________ 17. CH4 __________________________________ 18. N2S3 __________________________________ 19. CO __________________________________ 20. HNO3 __________________________________ Bonding. 19. Ionic bonds usually occur between ____________________________ and ____________________________ and involves the sharing/transfer of electrons. (circle one) 20. Covalent bonds usually occur between ___________________________ and ____________________________ and involves the sharing/transfer of electrons. (circle one) CP Chemistry Midterm Review Page #7 Match the characteristic/properties with the appropriate type of bonding (either a or b goes on each line): a. Covalent Bonds b. Ionic Bonds 21. ______ Low solubility 25. ______ Does not conduct electricity 22. ______ Soluble in water 26. ______ Conducts electricity 23. ______ High electronegativity difference 27. ______ Low melting point 24. ______ Low electronegativity difference 28. ______ High melting point Based on electronegativity, predict if they will form ionic, covalent, or polar covalent bonds. ie. Bromine monoxide 3.5- 2.8 = 0.7 (type of bond) 29. Phosphorus trichloride __________________ _________________ 30. Magnesium fluoride __________________ _________________ 31. Iodine (I2) __________________ _________________ 32. Rubidium chloride __________________ _________________ 33. Potassium oxide __________________ _________________ 34. Carbon monoxide __________________ _________________ Wavelength, Frequency and Energy. 1. Calculate the wavelength of light if the frequency of the radiation is 9.8 x 1014 Hz. 2. Calculate the energy of a radiant energy with a frequency of 2.70 x 1015 Hz. 3. What frequency is radiation with a wavelength of 2.90 x 10-6 cm? What is the energy?