Chemical Equations and Equation Stoichiometry Review 1. A sample of magnesium carbonate is heated. a) Write a balanced molecular equation for this reaction (include phases) and indicate the type of reaction: If exactly 4.75 g of the magnesium carbonate is heated, b) Calculate the mass of gas produced: c) Calculate the volume of gas produced at STP: d) Calculate the number of gas molecules produced: e) Calculate the mass of the other product: f) Calculate the mass of magnesium carbonate that must be heated to produce 75.0L of the gas at STP: 1 2. When nitrogen gas reacts with oxygen gas to produce nitrogen dioxide gas, 33.2 kJ of heat is absorbed per mole of nitrogen dioxide . a) Write a BME for this reaction and include phases and the energy term: b) What class of reaction is this: c) Identify substance oxidized and substance reduced: If one was to produce 200.0 g of nitrogen dioxide gas, d) Calculate the masses of nitrogen and oxygen gases needed to react produce this amount of gas: e) Calculate the energy involved in the reaction in (d): f) Calculate the volumes of nitrogen and oxygen gases, measured at STP, needed to produce 200.0 g of nitrogen dioxide: g) Calculate the volume the nitrogen dioxide would occupy at STP: 2 3. A sample of potassium metal is placed in water. a) What class of reaction is this? b) Include phases for: BME: CIE: NIE: c) Identify substance oxidized and substance reduced: If exactly 0.220 g of potassium reacts with excess water, d) Calculate the mass of gas produced: e) Will the resulting solution conduct electricity? Explain. f) If the solution is allowed to evaporate, calculate the mass of solid left: g) Calculate the mass of water needed to react with the 0.200 g of potassium: h) If the reaction releases 3750 kJ per mole of potassium reacted, calculate the amount of heat released when the 0.200 g of potassium reacts with the water: 3 4. Aqueous solutions of iron(II)chloride and sodium hydroxide are mixed: a) Include phases for: BME: CIE: NIE b) What class of reaction is this? If 3.20 g of the iron(II) chloride reacts with 1.75 g of the sodium hydroxide: c) Determine the limiting reactant: d) Calculate the mass of precipitate formed: e) Calculate the mass of excess reactant left over: f) If 2.50 g of precipitate is actually collected, calculate the percent yield: 4 5. A sample of gaseous butane, C4H10, is burned in air. The reaction releases 2430 kJ per mole of butane. a) What class or reaction is this? b) Write a BME and include the phases and energy term: If exactly 500.g of butane reacts with 1.200 X 103 liters of oxygen gas at STP, c) Determine the limiting reactant: d) Calculate the mass of carbon dioxide produced: e) Calculate the mass of water produced: f) Calculate the mass of excess reactant that remains: g) Calculate the number of molecules of excess reactant: h) Calculate the amount of heat released: 5 6. Equal volumes of equal concentrations of sulfuric acid and sodium hydroxide are mixed. The reaction has ∆H = -53.3 kJ/mol acid. Write the following and include phases: a) BME: b) CIE: c) NIE: d) Classify reaction: If exactly 49.0 g of sulfuric acid reacts with sufficient sodium hydroxide, e) Calculate the mass of water formed: f) Name the salt formed: g) Calculate the mass of the salt formed: h) Calculate the mass of sodium hydroxide reacted: i) Calculate the amount of heat involved in the reaction: 6 7. A sample of lithium chlorate is heated. a) Write a BME and include phases: b) Classify reaction: If 1.20 g of the lithium chlorate is heated, c) Calculate the mass of salt formed: d) Calculate the mass of gas produced: e) Calculate the volume of gas produced: f) Calculate the number of gas molecules produced: g) The salt formed does not conduct electricity in the solid phase but will conduct electricity when dissolved in water. Explain: 7 8. A sample of molten (liquid) potassium chloride undergoes electrolysis. a) Write a BME and include phases: b) Classify reaction: c) Calculate the mass of salt that must be electrolyzed to produce 95.0 L of the product gas at STP: d) If 55.0 g of the potassium chloride is electrolyzed, calculate the mass of solid product formed: e) If 24.6 g of the solid is actually obtained in part (b), calculate the percent yield: f) In a separate electrolysis, 90.0 L of the gas was collected at STP. If this represents a 77.5% yield, calculate the mass of potassium chloride that had to be electrolyzed to produce 100% yield. 8