The Color of Quantum Aron Fristoe, Educator, MathScience Innovation Center Developed with funding from the MathScience Innovation Center Adapted from the “LED Color Strip Kit” available through the Institute of Chemical Education http://ice.chem.wisc.edu/ Major Understanding Classical Newtonian Physics describes the behavior and motion of matter at the macroscale. As the size of matter becomes smaller and transitions into the nanoscale, predictions of properties based on classical physics begin to fail and quantum mechanics must be used to predict and explain the behavior of matter. At the heart of quantum mechanics is the concept of the particle-wave duality of matter which states that all matter exhibits either wave-like or particle like properties depending on the methods used to observe them. For matter at the nanoscale, wave character becomes more important. In addition, quantum systems at the atomic and subatomic scale can only allow energy of certain discrete amounts to enter or exit. When this occurs, the energy levels are considered to be quantized. In this lesson, students will use LED light strips to explore the science and math behind quantum effects and discover Planck’s Constant. Grade/Subject Physical Science, Chemistry and Physics Objectives Explain light is caused by the release of photons when electrons move from ground to excited state and back to ground state. Measure wavelengths of light and the voltage needed to light an LED. Calculate and explain the relationships between wavelength, frequency and energy. Calculate and use Planck’s constant. Time Anticipatory Set: What causes light? Activity: Get to Know Your LED Kit Demonstration: Viewing Gas Discharge Tubes Demonstration: What are Waves? Activity: Measuring the wavelengths of light Activity: Activity: Finding Voltage and Crunching the Numbers Closure: Periodic Properties and LED lights Practice Assessment 10 min 10 min 10 min 5 min 20 min 20 min 10 min Variable Materials For the class: Computer Projector PowerPoint Gas discharge tubes and power supply Hydrogen is needed and additional tubes can be used. Graphing calculators For each group of students working in pairs (up to 30) LED light strip (available from the Institute of Chemical Education) 9 volt battery Clipboard Three ¼” Binder Clips Christmas Tree light bulb with wire leads exposed 500 lines/mm linear diffraction grating (available from Rainbow Symphony) Vernier LabQuest and voltage probe or other voltage meter State and National Correlations Instructional Strategies Virginia Standards of Learning: Physical Science (PS.3, PS.9); Chemistry (CH.2, CH.6); Physics (PH. 9, PH.12) National Science Education Standards: Physical Science: Structure of Atoms 1. Anticipatory Set: What Causes Light? (Slides 1-5) Introduce the nature of light with the video “What the Heck is Light” which is linked on Slide 3. Use slides 4 & 5 to discuss the Quantum model of the atom. Introduction to the properties of light and relationship to the quantum model of the atom 2. Activity: Inquiry Based Investigation on LED Lights using the LED Color Strip (Slide 6) Have students use the LED Color Strip, 9 Volt Battery, incandescent Christmas tree light bulb, and a digital camera (cell phone cameras are adequate) to complete the questions to the “Getting to Know Your LED Kit” Activity Sheet. Student Data Sheet; Student Data Sheet Key The digital camera/cell phone camera is for viewing the InfraRed LED. Not all cameras will be able to see the light emitted. Using a web-cam is a nice way to demonstrate this to the whole class. Main Idea: Differentiate between LED and incandescent light; differentiate between IR and visible light. Examine a diode. 3. Demonstration Using Gas Discharge Tubes (Slides 7-10) Turn on the hydrogen discharge tube and have students look through the diffraction slides to view the emission spectra pattern. A dark room will allow the best viewing opportunity. Students may have to move closer to the discharge tubes to see the emissions spectra. Leave slide 7 up on the screen so the students can see the pattern they are looking for. Repeat with the remaining gas discharge tubes. Use slides 8-10 to summarize how Bohr used the emissions spectra to determine electrons are found in energy levels and how different types of light fixtures use excited light to emit light. 4. Demonstration: What are waves? (Slides 11-12) Use Slide 11 to discuss the Electromagnetic Spectrum and introduce wavelength and frequency Use the Wave Applet linked at Slide 12 to demonstrate the properties of waves. 5. Activity: Measuring Wavelengths of Light (Slides 13-14) Slide 14 shows the recommended set up. Have students follow the directions and complete the questions on the Student Activity Sheet. Main Idea: Explore the relationship between color and wavelength of that particular color. 6. Activity: Finding Voltage and Crunching the Numbers (Slide 15) Have students follow the directions and complete the questions on the Student Activity Sheet. Main Idea: Understand Planck’s constant and the linear relationships between wavelength, frequency, and energy. 7. Closure: Periodic Properties (Slides 16-24) Prior to discussing the results of the last activity, discuss how LED lights work using Slides 16-22. Stress that knowing Periodic Properties such as atomic radius and number of valence electrons determine the wavelength of light that is produced. Point out that “Band Gap” energy is a special type of ionization energy and is similar to the atomic emissions spectra observed earlier in the lesson. The energy of the bond determines the wavelength of light. Use Slide 23 to review possible answers to the last activity. Use Slide 24 to discuss Planck’s constant its relevance. Extensions 1. Have the students research LED lights and what combinations of elements will give different colored lights. 2. Have the students design a lab on the efficiency of LED lights. Assessment Sample items are provided for use in the checking students’ understanding. Paper/Pencil Assessment: The Color Of Quantum Paper/Pencil Assessment Key Project and Rubric The following table shows how the assessment items are related to specific objectives. Objective Paper-Pencil Test Students will understand that 2 light is caused by the release of photons when electrons move from ground to excited state and back to ground state. Measure wavelengths of light 5, 7 and the voltage needed to light an LED Calculate and explain the 3, 4, 6 relationships between wavelength, frequency and energy. Use Planck’s Constant 1 Major understanding Product/Performance Activity 1: LED strip Activity 2: Measurement of wavelengths. Activity 2: Measurement of wavelengths. Activity 2: Analyze calculated relationship between energy and frequency. Project and Student Rubric Teaching Tips This lesson was adapted from the “LED Color Strip Kit” available at the Institute of Chemical Education http://ice.chem.wisc.edu/ LED light strips may be purchased from ICE and the LED Color Strip Kit manual provides many additional activities and information on where to purchase additional supplies. Supplies Institute for Chemical Education (ICE) ICE provides many resources for teaching nanoscience across the science curriculum. http://ice.chem.wisc.edu/ Rainbow Symphony Rainbow Symphony carries a variety of diffraction gradients and other light related products. http://www.rainbowsymphony.com/ References Institute for Chemical Education (ICE) ICE provides many resources for teaching nanoscience across the science curriculum. http://ice.chem.wisc.edu/ MathScience Innovation Center Information on educational programs available to students, teachers, and school divisions as well as procedures for registering for programs. http://msinnovation.info MathinScience: Find resources which teach core math and science standards, integrate calculator and computer-based technologies, and introduce 21st Century concepts in the areas of fractal geometry, nanotechnology, and engineering. http://mathinscience.info Recommended reading Orzel, Chad. How To Teach Physics To Your Dog. New York: Scribner, 2010. Kakalios, James. The Amazing Story Of Quantum Mechanics, A Math-free Exploration Of The Science That Made Our World. New York: Gotham, 2011