PS 9.10 Review: Chapter 9 Stoichiometry 1. One of the key steps in producing pure copper from copper ores is the reaction below: Cu2S (s) + Cu2O (s) → Cu (s) + SO2 (g) (unbalanced) After balancing the reaction, determine how many dozen copper atoms could be produced from a dozen molecules of the sulfide and two dozen of the oxide of copper(I). Also how many moles of copper could be produced from one mole of the sulfide and two moles of the oxide? a. 1 dozen and 1 mole b. 2 dozen and 2 moles c. 3 dozen and 3 moles d. 6 dozen and 6 moles 2. Carbon tetrachloride, CCl4 (commonly called “carbon tet”), is used extensively as a solvent in laboratories and in industry. How many moles of Cl atoms are needed to react with 2.20 moles of carbon to produce CCl4? a. 2.20 mole b. 4.00 moles c. 4.40 moles d. 8.80 moles 3. Propane, C3H6, is a common fuel used in heating homes in rural areas. Predict how many moles of CO2 are formed when 3.74 moles of propane are burned according to C3H6 + 6O2 3CO2 + 6H2O a. 11.2 moles b. 7.48 moles c. 3.74 moles d. 1.25 moles 4. Zirconium is a metal that is used in the design of catalytic Converters, and that can be isolated from the carbide in a 2-step process: ZrC + 4Cl2 ZrCl4 + CCl4 ZrCl4 + 2Mg Zr + 2MgCl2 How many moles of Zr can be produced from 3.00 moles of Cl2? a. 0.25 moles b. 0.75 moles c. 1.25 moles d. 4.00 moles 5. How many grams of oxygen are needed to react with 42.8 g of chromium in the production of Cr2O3, a common paint pigment? a. 42.8 g b. 33.4 g c. 19.8 g d. 10.5 g (p 1 of 2) 6. Ammonium nitrate decomposes when heated to form “laughing gas,” N2O, and water. If this reaction forms 36.0 g H2O, how many grams of N2O are also formed? a. 36.0 g b. 40.0 g c. 44.0 g d. 48.0 g 7. Acetylene burners are used in metal welding because acetylene (C2H2) flames are very hot. How many grams of calcium carbide are needed to produce 10.0 g C2H2? CaC2 + 2H2O Ca(OH)2 + C2H2 a. 24.7 g b. 64.1 g c. 10.0 g d. 15.5 g 8. The Haber process is very important in industry because it converts atmospheric nitrogen into a more reactive form: N2(g) + 3H2(g) 2NH3(g) How many moles of ammonia can theoretically be produced from a mixture containing 3.0 moles each of nitrogen and hydrogen? a. 1.0 mole b. 2.0 moles c. 3.0 moles d. 0.5 moles 9. How many grams of NH3 can be produced from the mixture of 3.0 g each of nitrogen and hydrogen by the Haber process? N2 + 3H2 2NH3 a. 2.0 g b. 3.0 g c. 3.6 g d. 6.0 g 10. Find the percent yield of product if 1.5 g of SO3 is produced from 1.0 g of O2 via the reaction: 2S + 3O2 2SO3 a. 75% b. 80% c. 88% d. 92% PS 9.10 Review: Chapter 9 Stoichiometry (p 2 of 2) ANSWERS 1. Choice D becomes obvious once we have balanced the equation: Cu2S(s) + 2Cu2O(s) 6Cu(s) + SO2(g) 2. D provides the correct response. We need 4 times as many moles of Cl atoms as of C atoms. 3. A provides the correct response: 3.74 moles C3 H 6 x 4. Choice B . Dimensional analysis yields: 3.0 moles Cl2 x 3 moles CO 2 11.2 moles C3 H 6 1 mole C3 H 6 1 mole Zr 0.75 moles Zr 4 moles Cl2 5. Choice C can be easily arrived at if we first write the balanced equation and then use dimensional analysis. 4Cr + 3O2 2Cr2O3 1 mole Cr 3 moles O 2 32.0 g O 2 42.8 g Cr x x x 19.8 g Cr 52.0 g Cr 4 moles Cr 1 mole O 2 6. Choice D. First we write a balanced equation and then we use dimensional analysis NH4NO3 N2O + 2H2O 36.0 g H 2 O x 1 mole H 2 O 1 mole N 2 O 44.0 g N 2 O x x 44.0 g N 2 O 18.0 g H 2 O 2 moles H 2 O 1 mole N 2 O 7. Choice A. Using dimensional analysis: 10.0 g C 2 H 2 x 1 mole C 2 H 2 1 mole CaC2 64.1 g CaC2 x x 24.7 g CaC2 26.0 g C 2 H 2 1 mole C 2 H 2 1 mole CaC2 8. Choice B.. First we must realize that this is a limiting reactant problem because specific amounts of both reactants are provided. Then we must determine which reagent is limiting. In order for all the nitrogen to react, how much hydrogen is needed? 3 moles H 3.0 moles N 2 x 2 1 mole N 2 9.0 moles H 2 needed But we have only 3.0 moles of H2, so H2 is limiting and determines how much product will form: 3.0 moles H 2 x 2 moles NH3 2.0 mole NH3 3 moles H 2 9. Choice C correctly predicts the amount of product. First we must find the limiting reagent via the number of moles. We might ask “How much hydrogen is needed to use up all of the nitrogen?” 3.0 g N 2 x We have : 1 mole N 2 3 moles H 2 x 0.32 mole H 2 needed 28.0 g N 2 1 mole N 2 3.0 g H 2 x 1 mole H 2 1.5 moles H 2 2.0 g H 2 This is more than is needed, so there is excess H2 and N2 is limiting. 3.0 g N 2 x 2 moles NH3 17.0 g NH3 1 mole N 2 x x 3.6 g NH3 28.0 g N 2 1 mole N 2 1 mole NH3 10. Choice C is correct. First we find the maximum yield of product: 1.0 g O 2 x 2 moles SO 3 80.1 g SO 3 1 mole O 2 x x 1.7 g SO 3 32.0 O 2 3 moles O 2 1 mole SO 3 We then divide the yield by the theoretical yield: 1.5 g x 100% 88% 1.7 g