Name:______________________________________ Date:______________________ Per. #:_______ Chemistry Semester 1 Final Exam Study Guide – Units 1-3 Vocabulary Conversion factor Dimensional analysis Atom Nucleus Electron cloud Proton Neutron Electron Charge Ion Molecule Formula Unit Element Substance Mixture Solution Mole Double displacement Actual yield Periodic table Element Period Group Atomic number Atomic mass Symbol Subatomic particle Atomic mass units Valence electron Isotope Homogeneous Heterogeneous Chemical Bond Covalent Bond Ionic Bond Cation Avogadro’s Number Stoichiometry Theoretical yield Percent yield Metals Semimetals (metalloids) Nonmetals Alkali metals Alkaline earth metals Transition metals Halogens Noble gases Atomic radius Ionization energy Electronegativity Anion Nomenclature Polyatomic Ion Physical property Chemical property Physical change Chemical change Molar Mass Density TOPICS Unit 1 – States of Matter, SI Units, Atoms, and the Periodic Table Notes 1.1 – States of Matter (pgs. 6 – 9) o Know the major differences between the 3 states of matter: solid, liquid, and gas. o Know whether each state has definite or indefinite volume or shape. Notes 1.2 – SI Units (pgs. 33 – 38) o Know the SI base units for length, volume, and mass (meter, liter, and gram, respectively) o Understand that prefixes are used to multiply base units by powers of 10. Notes 1.3 – SI Prefixes and Scientific Notation (pgs. 33 – 38, pgs. 50 – 54) o Know the definitions and be able to make conversion factors for 5 SI prefixes: Kilo, centi, milli, micro, and nano. Example: Definition: centi means 1/100th Conversion Factor: 1 m = 100 cm o Know how to convert numbers from standard notation to scientific notation, and vice versa. Example: Standard notation: 6,200,000 Scientific notation: 6.2 x 106 o Know how to solve multiplication and division problems using scientific notation. Notes 1.4 – Intro to Dimensional Analysis (pgs. 40 – 42) o Know how to solve dimensional analysis problems using SI base units and prefixes as conversion factors. o The 5 Steps 1. Identify the given 2. What unit are you trying to convert to (the “arrow”) 3. Determine appropriate conversion factor(s) 4. Set up the equation. Start with the given and multiply by conversion factor(s) in fraction form. Cancel units. 5. Solve by multiplying tops and dividing by bottoms. Notes 1.5 – Atoms and the Periodic Table (pgs. 67 – 69) o Know Dalton’s 4 rules of Atomic Theory o Know the basic model of the atom (nucleus made of protons and neutrons with electrons surrounding) o Know how to read the periodic table and how to find the # of protons, neutrons, and electrons in an atom. o Know what isotopes are. Notes 1.6 – Reading the Periodic Table (pgs. 135 – 136) o Know the difference between the atomic number and atomic mass. Know how to determine the number of protons, neutrons, and electrons using the periodic table. Name:______________________________________ Date:______________________ Per. #:_______ o Understand why the atomic mass number has a string of numbers after the decimal based on the weighted average of isotopes. Notes 1.7 – Atomic Experiments (pgs. 72 – 76) o Know how J. J. Thomson used cathode ray tubes to discover the electron and deduce the existence of the proton. o Know how Rutherford’s gold foil experiment worked and what feature of the atom he discovered with it. o Know the difference between Thomson’s “plum-pudding” model and Rutherford’s model of the atom. o Know how Mendeleev organized the periodic table and what he discovered about elements in the same group. Notes 1.8 – History of the Periodic Table (pgs. 133 – 135) o Know how Mendeleev originally grouped elements in his periodic table. o Know why elements in the same family have similar reactivity. o Know the special family/section names and where they are on the PT: alkali metals, alkaline earth metals, transition metals, boron-nitrogen groups, halogens, noble gases, lanthanides, actinides. Notes 1.9 – Periodic Trends (pgs. 150 – 162) o Know how the size of an atom changes when it becomes a positive (+) or negative (-) ion. o Know the trends of increasing/decreasing as you move down a group or to the right across a period for the following characteristics. Atomic radius Ionization energy Electronegativity Metallic properties o Know what conductivity, luster, malleability, and ductility mean in relation to metals. Unit 2 – Types of Matter, Covalent and Ionic Bonding, Lewis Structures, Molecular Shape, Polarity, IMFs Notes 2.1 – Types of Matter – pgs. 11 - 14 o Know the major differences between the 4 types of particle: Atom, ion, molecule, and formula unit o Know the differences between the 3 types of matter (or substance): Elements, compounds, and mixtures o Know the difference between homogenous and heterogeneous mixtures and be able to identify them. Notes 2.4 – Electron Configuration – pgs. 111 - 122 o Know how to use the Periodic Table to determine the electron configuration, Noble gas notation, or orbital diagram of any element. o Know what is meant by the Aufbau Principle, the Pauli Exclusion Principle, and Hund’s Rule. Notes 2.5 – Lewis Dot Structures and Covalent Bonds – pgs. 178 - 185 o Know what valence electrons are and how to find the number of valence electron for any main group element using the periodic table. o Know what the Octet Rule means. o Understand how a covalent bond is made of at least two shared electrons between two nonmetals. Notes 2.6 – Ionic Bonding and Nomenclature – pgs. 222 - 226 o Understand that an Ionic bond forms from the attraction of at least two oppositely charged ions. o Know how to name covalent compounds using prefixes. o Know how to name ionic compounds not using prefixes. o Know how to get the formula of an ionic compound from the name. Unit 3 – The Mole, Stoichiometry, Balancing Chemical Reaction Equations Notes 3.1 – The Mole (pgs. 82 – 87) o Know the definition of the mole as the number of atoms in exactly 12 grams of carbon-12. o Know that a mole of ANY substance is equal in amount to Avogadro’s number, or 6.022 1023 particles. o Know that the molar mass is the sum of atomic masses of every atom in a molecule and know how to find the molar mass of any chemical using the periodic table. o Know that the units of molar mass are in grams/mole. o Know how to use Avogadro’s number, and the molar mass to convert between units of particles, moles, and grams. Notes 3.3 – Chemical Reaction Notation (pgs. 261 – 269) o Know how to get the formula of a covalent or ionic compound from the name. o Know how to identify the reactants and products in a chemical reaction equation. o Understand the different uses of coefficients and subscripts in a chemical reaction equation. o Know how to identify a symbolic equation from the word form of an equation. Notes 3.4 – Balancing Chemical Reaction Equations (pgs. 270 – 274) o Know how to balance chemical reaction equations. o Know how to deal with subscripts that are outside of parentheses, as in the 2 in Pb(NO 3)2. Notes 3.5 – The Five Types of Chemical Reaction (pgs. 276 – 283) o Know how to identify double displacement reactions o Know how to find the products of double displacement reactions if given the reactants. Name:______________________________________ Date:______________________ Per. #:_______ Notes 3.6 – Stoichiometry (pgs. 299 – 301, 304 - 311) o Know how to use the mole ration from a balanced chemical reaction equation as a conversion factor. o Know how to convert from moles or grams of a reactant to moles or grams of a product. Notes 3.7 – Theoretical Yield (pgs. 312 – 317) o Know how to find the theoretical yield of a product when given the mass of both reactants. Know the difference between substances and mixtures and chemical vs. physical properties o Know the difference between homogeneous and heterogeneous mixtures. Practice Problems Unit 1 1. Convert each base unit to the following prefixed units. Base Unit KiloCenti- Milli- 5 meters 5000 mm 0.005 km 500 cm 6 meters 6 grams 5.5 liters 100 grams 2. A rock is weighed on a balance and is found to have a mass of 125 grams. When put in a graduated cylinder, the water level rises from 25 mL to 50 mL. What is the density of the rock? Mass Volume (change) Calculation Density 3. Which would you expect to have a larger atomic radius: Magnesium (Mg) or Sulfur (S)? Explain. 4. Which would you expect to have a larger electronegativity: Lithium (Li) or Fluorine (F)? Explain. 5. How many liters are in 15.5 milliliters? Arrow: Equation: _________________ _________________ Conversion Factors: Solution: Name:______________________________________ Date:______________________ Per. #:_______ 6. How many meters are in 12,334 centimeters? Arrow: Equation: _________________ _________________ Conversion Factors: Solution: Unit 2 1. What type of particle is each of the four examples below? a) Bi_____________ b) Fe2+______________ c) H2O_______________ d) NaCl_________ 2. Label each of the following as an element, compound, or mixture. For any example that is a mixture, tell whether it is homogenous or heterogeneous. Sample Type of Substance Type of Mixture a) air b) chlorine gas (Cl2) c) rust (Fe2O3) 3. Name the following covalent compounds Example: NF3 nitrogen trifluoride a) SF6 ______________________________________________________________ b) N2O5 ______________________________________________________________ c) C4H8 ______________________________________________________________ 4. Name the following Ionic compounds Example: CaBr2 calcium bromide a) CuCl2 ______________________________________________________________ b) NaF ______________________________________________________________ c) Al2O3 ______________________________________________________________ 5. Determine the correct formula for the following ionic compounds. Example: Sodium chloride Na+ and Cl- NaCl Iron (III) oxide Fe3+ and O2- Fe2O3 a) calcium oxide ____________________________________________________ b) copper (II) bromide ___________________________________________________ c) sodium nitrate ____________________________________________________ Name:______________________________________ Date:______________________ Per. #:_______ 6. Write the electron configuration, Noble gas configuration and orbital diagram for Cl and Fe. Name Electron Configuration Noble Gas Configuration Chlorine, Cl Orbital Diagram Iron, Fe Orbital Diagram Unit 3 1. Identify the number of moles of each substance. # grams # moles # atoms/molecules a) 32 grams O2 d) 1.204 1024 molecules NH3 b) 128 grams SO2 e) 3.011 1023 atoms Si c) 22 grams He f) 9.033 1023 molecules Cl2 2. Find the molar mass of the following substances. a) Ga ______________________ b) MgSO4 ______________________ c) CH3OH ______________________ d) Ca(OH)2 ______________________ 3. How many atoms are in 25 grams of MgSO4? 4. What is the mass in grams of 3.011 1024 atoms of sodium (Na)? # moles Name:______________________________________ Date:______________________ Per. #:_______ 5. Write and balance the following chemical reaction equation in symbolic form. “Potassium iodide reacts with lead (II) nitrate and yields lead (II) iodide and potassium nitrate.” 6. Balance the following reaction equations. a) ____ Cr + ____O2 ____Cr2O3 b) ____ Fe + ____Cl2 ____FeCl3 c) ____ C6H8 + ____O2 ____CO2 + ____H2O d) _____CaCl2 + _____AgNO3 _____AgCl + _____Ca(NO3)2 e) ____Al + ____CuO ____Al2O3 + ____Cu Use the above reaction equations to solve the following stoichiometry problems. Use the GUESS method. 7. How many moles of carbon dioxide can be produced from 4 moles of C6H8? 8. How many grams of aluminum is needed to produce 150 grams of aluminum oxide (Al2O3)? Name:______________________________________ Date:______________________ Per. #:_______ 9. If 45 grams of potassium oxide (K2O) is reacted with 45 grams of water, what will be the theoretical yield, in grams, of potassium hydroxide (KOH)? _____ K2O + _____H2O _____KOH Molar mass of K2O:__________________ Molar mass of H2O:__________________ Molar mass of KOH:__________________ #1: 45 g K2O # g KOH #2: 45 g H2O # g KOH