ENVIRONMENTAL PERFORMANCE OF THE ADELAIDE DESALINATION PLANT Tim Kildea 1, Vanesa Ayala 2, Milind Kumar 1, Guillermo Hijos 2, Javier Artal 2 1. South Australian Water Corporation, Adelaide, SA 2. AdelaideAqua, Adelaide, SA ABSTRACT Desalination has come to the fore in Australia as a means of “water proofing” Australian coastal cities against drought. The construction of large desalination plants along the coast has generated considerable public debate. Assurance was provided to the community that the care for the local terrestrial and marine environment remained a core value in the development of the project. Marine monitoring studies undertaken for the Adelaide Desalination Project have shown that the saline waste stream discharged to the marine environment rapidly disperses and dissolved oxygen concentrations adjacent to the outfall are conducive for maintaining a healthy aquatic ecosystem. The project has been an outstanding success in terms of meeting its operational and environmental commitments. INTRODUCTION years. At handover, the ADP had already delivered in excess of 17 GL of high quality drinking water into SA Water’s distribution system. The ADP incorporates a high level of operational flexibility, with nominal daily production rates from 30 to 300 ML/d, in 15 ML/d increments. This flexibility was necessary due to the multiple sources of drinking water for Adelaide (catchment, River Murray, desalination) and the need to ensure optimum usage of lower cost, climate dependent water sources. At maximum plant production rate of 100 GL per year, ADP can produce approximately 50 % of Adelaide’s current drinking water needs, providing the only climate independent source of water for the city. Although this provides some water security for Adelaide, the ADP is only one of a number of strategies that the State is incorporating to meet city’s growing water needs. The South Australian Water Corporation (SA Water) is a government-owned utility which provides water and wastewater services to more than 1.5 million people in South Australia. In December 2007, following years of severe drought conditions, the State Government announced the Adelaide Desalination Project as part of a major investment in securing water supplies for the State. The building of the 100 gigalitres Adelaide Desalination Plant (ADP) early 2009. The plant was was constructed by AdelaideAqua, consisting of McConnell Dowell, ACCIONA Agua. (GL) per year commenced in designed and a consortium Abigroup and The ADP is the largest and most complex water infrastructure project ever delivered by SA Water. The $1.824 billion project was delivered on time and within budget; an outstanding achievement for SA Water and the AdelaideAqua consortium. The ADP (Fig. 1) was officially handed over to the Operator, AdelaideAqua Pty. Ltd. (AAPL), on 12 December 2012. AAPL are a partnership between ACCIONA Agua and TRILITY, who have a contract to operate and maintain the plant over the next 20 Figure 1 Adelaide Desalination Plant Environmentally, the ADP has one of the lowest carbon footprints of any desalination plant in the world. A contract with AGL has ensured that the ADP is powered by GreenPower accredited energy over the next 20 years. The energy consumption of the total plant has been optimised through sustainable design and by recovering residual energy by using outfall turbines. Ultra Filtration pre-treatment (with washwater recovery) coupled with patented high recovery Reverse Osmosis membranes (48.5%) minimises seawater abstraction requirements to achieve optimum energy consumption. The above processes have contributed to a specific energy consumption of approximately 3.7 kWh/kL. There were number of key environmental drivers for the project other than reducing the carbon footprint. During the environmental assessment process a number of committments were made to the community in regards to the care of the local terrestrial and marine environment, in the region of the ADP. Over 250,000 native plants of local providence were planted around the ADP, which also included the development of an extensive wetland ecosystem for the management of stormwater on site. During the construction phase, initiatives such as marine tunnelling for the intake and outfall pipework, using large tunnel boring machines, protected sensitive nearby habitats including coastal cliffs and offshore reefs. The intake of large volumes of seawater by desalination plants is often a focus of community concern, in particular protecting local marine wildlife. The ADP intake structure was designed to minimise entrapement and entrainment of marine organisms by setting a maximum seawater intake velocity of 0.15 m/s, which is equivalent to the average current veloicty in the region. The structure was also located in deep water away from local reefs and far from nursery fish grounds. Finally, duckbill valves were incorporated into the diffuser design to assist in the rapid dispersion of the saline concentrate waste generated from the desalination process, into the marine environment. A novel engineering solution which has increased the effectiveness of the diffuser when operating at low flow rates. In Australia, detailed monitoring studies have been developed by the plant operators and owners to assess the environmental performance of seawater reverse osmosis (SWRO) desalination plants. These studies have provided a substantial volume of information which shows the positive outcomes of good planning and engineering in minimising potential impacts to the environment. This paper aims to present some of the water quality data collected for the Adelaide Desalination Project, in particular salinity and dissolved oxygen concentrations. The results focus on the performance of the ADP in dispersing saline concentrate waste into the marine environment. Salinty concentrations adjacent to the diffuser are compared to results obtained from ecotoxicological studies conducted as part of the environmental impact assessment process. The comparisons aim to provide an appraisal of how well the plant performs in meeting its enviromental commitments. METHOD The data presented in this paper are based on three separate studies. These studies are: Water Quality Characterisation Study In order to estimate the temporal and spatial dispersion of the saline concentrate from the ADP diffusers, monthly oceanographic surveys are undertaken in the region of the outfall. Water column profiling is undertaken at sites 100 m, 500 m and 5 km north and south of the Adelaide Desalination Plant outfall, at a water depth of 5 m, 10 m, 15 m, 20 m and 25 m. Three reference sites, located approximately 10 km offshore, are included in the study, which encompasses a total survey area of 100 km2. At each site, vertical distribution of specific conductivity (uS/cm), dissolved oxygen (mg/L), pH, turbidity (NTU), water temperature (degrees Celsius) and depth was obtained using a YSI 6600 series V4 sonde. Depth profiles were undertaken by lowering the instrument through the water column at a rate of approximately 0.2 metres per second. Data, which included the instruments position (longitude and latitude) and depth (metres) in the water column, were logged and stored every two seconds. Diffuser performance A study was undertaken to assess the intensity and dispersion of the saline concentrate from the ADP diffuser under a “worst case” scenario of low tidal currents and a maximum production rate of 300 ML/d. The survey was undertaken on 4th June 2013, coinciding with a local period of minimal tidal movement (termed a “dodge tide”), low wind (< 10 knots) and calm seas (<0.5m). Specific conductivity, dissolved oxygen, water temperature and depth were recorded at the seafloor at over 70 sites, covering an area over 100 km2 around the ADP outfall. Spatial plots were derived using the grid-based graphic program Surfer 8 (Golden Software Inc.), which interpolates irregularly spaced XYZ data into a regularly spaced grid. The grid was then used to produce an image map to show how concentrations (salinity and DO) changed across a defined area. The data are interpolated using the “Natural Neighbour” algorithm, which is a geostatistical gridding method used to express the spatial trends that occur for each of the different parameters. Ecotoxicology Work carried out for the Environmental Impact assessment of the Adelaide Desalination Project (SA Water 2009) utilised ecotoxicology testing in order to assess the potential biological impacts that saline concentrate may have upon marine organisms. The study utilised, where possible, South Australian species. Five species from four taxonomic levels (polychaete, crustacean, plant, fish and phytoplankton) were utilised in the ecotoxicological experiments to derive an ecological trigger value that represented the dilution required for the safe disposal of saline concentrate into the marine environment. The results from this study recommended a safe dilution factor of 23:1 to protect 99% of typical marine species. RESULTS AND DISCUSSION Average salinity concentrations The main focus of desalination research, worldwide, has been assessing how rapidly saline concentrate waste streams disperse in the receiving waters (Roberts et al. 2010). The results from these studies have been highly variable and have shown that dispersion occurs over a wide distance range, extending from tens of metres to several kilometres. The variation in dispersion has been attributed to differences in plant capacities, diffuser designs, local oceanographic features and sampling methods (Roberts et al. 2010). In the majority of cases the studies have shown that the salinity concentration is usually no greater than two parts per thousand (ppt) above the background salinity within 20 m of the outfall. Thereafter the saline concentrate plume rapidly disperses with salinity concentrations only slightly greater than background levels (< 0.5 ppt) within a couple of hundred metres of the point of discharge (Roberts et al. 2010). It should be noted that the majority of these studies have been conducted in the Mediterranean Sea, which is characterised as a shallow, low-energy environment; conditions considered to be sub-optimal for the rapid dispersion of saline concentrate waste streams. Results from the water quality monitoring of the Adelaide Desalination Plant have shown that there is a high degree of variation associated with the dispersion of saline concentrate into the marine environment (Figure 2). Average salinity concentration measured on the seafloor, 100 metres from the diffuser, at a depth between 15 m and 20 m is represented by the red line. The blue hashed line represents background salinity concentration on the seafloor, approximately 10 km from the ADP diffuser. Error bars represent standard deviation. Figure 2: Salinity concentrations on the seafloor Monthly background salinity concentrations vary from 35.6 ppt to 37 ppt, dependent on the time of the year. This is natural for Gulf St Vincent (GSV) and is a result of oceanic seawater mixing with the seawater in the Gulf. Generally the GSV gets saltier in summer from natural freshwater evaporation and decreases in salinity during winter as freshwater enters via seasonal rains. Density driven currents develop in GSV over summer, and saltier water from the upper parts of the Gulf moves past Port Stanvac in late autumn/early winter. Hence average background salinity concentrations in the Port Stanvac region are highest around May/June. Another feature is the movement of oceanic seawater in response to the prevailing southerly winds. The seawater moves into the Gulf and mixes in the vacinity of Port Stanvac. Bye and Kämpf (2008) noted that Port Stanvac lies at the junction of two opposing gyres and this is reflected in the large standard deviations observed for the average salinity concentrations. Salinity concentrations are highly variable not only monthly but weekly and sometimes daily. The majority of time the difference in salinity concentration between background and 100 m from the diffuser is less than 0.5 ppt. The largest averge difference observed was 1 ppt during the month of July (Figure 2). Based on the summary of results outline in the Roberts et al. (2010) review on desalination plant discharges, the ADP diffusers are performing better than any other large plant worldwide. It should be noted that the results presented in Figure 2 are based on a range of daily plant production rates and oceanograpic mixing conditions; variables which would influence the rate of dispersion of the saline concentrate waste from the diffusers. Salinity contours To effectively assess diffuser performance, a study was required which incorporated “a worse case scenario” of poor mixing conditions (dodge tide, wind <10 knots and swell/seas < 0.5 m) at the maximum plant production of 300 ML/d. GSV is characterised by a phenomana called a “dodge tide”. The “dodge tide” is an interplay between semidiurnal lunar and solar tidal constituents, which result in “significantly” weakened tidal currents on a fortnightly basis (Kämpf and Clarke 2012). It has been speculated that during dodge tide events, “brine underflows” would form consisting of a thin layer of hypersaline water spreading along the seafloor, becoming rapidly depleted in dissolved oxygen (Kampf and Clarke 2012). The diffuser performance study was undertaken on the 4th June, 2013, under optimal “worse case scenario” conditions. A salinity contour map (Figure 8) was generated from over 70 sample points covering an area of approximately 100 km 2. The contours represent salinity concentrations (ppt) on the seafloor, in the vicinity of the ADP diffuser (yellow circle). The x and y axes represent eastings and northings and provide a measurement in metres of the size of the plume footprint. The footprint is detectable over a distance of approximately 6 km by 4 km. The maximum salinity concentration oberserved was 38.1 ppt approximately 100 m south of the ADP outfall (Figure 3). At this point the plume is approximately 4 metres thick on the sea floor. Brine discharges are often denser than seawater of natural salinities, and therefore plumes tend to extend further along the seafloor than at the surface (Roberts et al. 2010). As predicted, the data clearly shows that elevated salinity concentrations are restricted to the seafloor (Figure 3). Salinity varies naturally with tidal cycles, particularly due to the mixing of oceanic water and gulf water, as observed in the variability of the ambient salinity concentrations (Figure 2). Thus exposure to elevated salinity concentrations is likely to vary both spatially and temporally, particularly with changing tides and weather patterns. The footprint observed (Figure 8) is considered to be the worst case scenario and therefore the salinity concentrations at other times are likely to be substantially lower. This is reflected in the average salinity data obtained at other times of the year while the plant has been operational (Figure 2). Dissolved Oxygen The question posed by Kämpf and Clarke (2012) on whether dissolved oxygen becomes depleted as a result of the denser saline water moving across the seafloor is a simple one to answer. No. In Figure 4, average ambient seafloor dissolved oxygen concentrations throughout the year are compared with dissoved oxygen concentrations measured 100 metres from the diffuser, at a depth between 15 m and 20 m. Error bars represent standard deviation to the mean. When the two are compared, there is no significant difference between the background dissolved oxygen (DO) concentrations on the seafloor and those around the ADP diffuser. Figure 4: Seafloor oxygen concentrations Figure 3: Salinity profile through the water column Thereafter the plume quickly disperses to concentrations approximately 0.6 ppt above background salinity within 1 km of the outfall. It then follows the depth gradient moving into deeper water, reaching background concentrations of 37.3 ppt, approximately 4.5 km south of the outfall. This is reiterated by the dissolved oxygen profile through the water column, 100m north and south of the ADP diffuser (Figure 5). These measurements were taken during the diffuser performance study and suggest that DO concentrations decrease slightly from the surface to the bottom; an observation that is expected due to normal surface water oxygen supersaturation (>100%). Dupavillion and Gillanders (2009) exposed cuttlefish embryos (Sepia apama) to a range of salinities until their hatch date. Their results showed that there was no significant reduction in size and weight of hatchlings until salinity concentrations were greater than 42 ppt. Beattie (2009) found that ascidians (Ascidiaceae) and sea stars (Ophiuroidea) reacted in a similar way when exposed to different concentrations of saline concentrate. The results from this study suggested that until salinity reached a threshold of 44 ppt, there was no impact on survival rates. Figure 5: Dissolved oxygen profile through the water column On a regional scale there is no discernable difference in DO concentrations on the seafloor (Figure 9). The results presented are from a diffusion performance study undertaken during a dodge tide. Black crosses represent sampling points and white crosses represent the exclusion zone surrounding the ADP intake and outfall. The x and y axes represent eastings and northings and provide a measurement of distance in metres. DO concentrations remain a consistent 7.5 mg/L across the 100 km2 sampling region. This is somewhat contradictory to Kämpf and Clarke (2012) speculation on “brine underflows” depleting oxygen on the seafloor. The World Health Organisation (WHO) provided a synthesis of all ectoxicological studies published in peer review journals and suggested a more conservative threshold of 10% above maximum background salinity concentration (equating to 40.7 ppt for Port Stanvac). Results to date from ADP suggest that salinity concentrations recorded on seafloor, around the diffuser are well below all these thresholds. A comparison of threshold values are presented in Figure 6. Environment Protection Authority criteria for healthy marine ecosystems stipulate a DO concentration threshold of 6 mg/L. DO concentrations adjacent to the diffuser have been measured at 7 mg/L or greater throughout the year (Figure 4). Ecotoxicology The final question that could be asked is, “Is the elevated salinty concentration observed around the ADP outfall halmful to marine life?”. The ecotoxicological studies undertaken as part of the Environmental Impact assessment (SA Water 2009) recommended a safe dilution factor of 23:1 to protect 99% of typical marine species. This equates to 39 ppt based on maximum background salinity concentration of 37.4 ppt. This is a conservative estimate as most of the organisms tested did not show signs of stress until salinity concentrations reach 40 ppt or above. The maximum salinity concentration recorded next to the ADP diffuser was 38.1 ppt (Figure 2). All things considered, these results suggest that there should be minimal impact to the organisms living around the ADP outfall. Other studies on the toxicological effects of brine on local South Australian marine species support this conclusion (Dupavillion and Gillanders 2009, Beattie 2009). Figure 6: Comparing salinity concentrations to ecotoxicology results CONCLUSION Whilst studies have identified several potential mechanisms by which desalination plants may impact upon marine ecosystems many published review articles and case studies cite little or no peer reviewed literature and present little of no empirical data to support statements regarding environmental effects of desalination (Roberts et al. 2010). Hence it is unclear whether the potential impacts of desalination plants are assumed or have been determined through rigorous ecological research. Marine monitoring studies undertaken for the Adelaide Desalination Project have shown that the saline waste stream discharged to the marine environment rapidly disperses and dissolved oxygen concentrations adjacent to the outfall are conducive for maintaining a healthy aquatic ecosystem. The project has been an outstanding success in terms of meeting its operational and environmental commitments. Figure 7: Marine life around the ADP outfall, April 2013 ACKNOWLEDGMENTS Many thanks to: Lorenzo Andreacchio and Dusty Rietveld for their assistance in data analysis, figures and introduction;and Matt Blaikie, Carol Sims and Lorenzo for their editorial red pen. REFERENCES Beattie K., 2009. Desalination Impacts on Marine Invertebrates: Effluent Toxicity. Honours thesis. Flinders University. Bye, J and Kämpf, J. 2008. Physical Oceanography. In Natural History of Gulf St Vincent p56-70. Royal Society of South Australia. Dupavillon, J., and Gillanders, B. 2009. Impacts of seawater desalination on the giant Australian cuttlefish Sepia apama. Marine Environmental Research 67, 207-218. Kämpf, J. and Clarke, B. 2012. How robust is the environmental impact assessment process in South Australia? Behind the scenes of the Adelaide seawater desalination project. Marine Policy. Roberts, D, Johnston, E. and Knott, N. 2010. Impacts of desalination plant discharges on the marine environment: A critical review of published studies. Water Research 44, 51175128. SA Water (2009) Proposed Adelaide Desalination Plant Environmental Impact Statement, Government of South Australia. World Health Organisation (WHO) 2007. Desalination for Safe Water Supply:Guidelines for the Health and Environmental Aspects Applicable to Desalination, Public Health and the Environment World Health Organisation, Geneva. Figure 8: Salinity contours around the ADP diffuser 9 6118000 8.8 8.6 8.4 6116000 8.2 8 7.8 7.6 6114000 7.4 7.2 7 6112000 6.8 6.6 6.4 6.2 6110000 6 6108000 260000 262000 264000 266000 268000 270000 Figure 9: Regional dissolved oxygen concentrations 272000