Chemistry I Chapter 3 Outline ATOMS: THE BUILDING BLOCKS OF MATTER For graded assessments, you will need to be familiar with the following terms: Law of conservation of mass, law of definite proportions, law of multiple proportions, atom, nuclear forces, atomic number, isotope, mass number, nuclide, atomic mass unit (amu), average atomic mass, mole, Avogadro’s number, molar mass. I. THE ATOM: FROM PHILOSOPHICAL IDEA TO SCIENTIFIC THEORY A. Foundations of Atomic Theory: Be familiar with names that are attributed to theorizing about the smallest, indivisible part of matter (the atom); names from ancient Greece as early as 400b.c. such as Democritus and Aristotle. (pg. 67) i. Which of the two above philosophers first described the atom as “indivisible”? ____________________________________________ ii. Which of the two above mentioned philosophers did not believe in the atom but instead believed that all matter was continuous? ____________________________________________ (STANDARD: CLE 3221.1.1) B. Dalton’s Atomic Theory: Be familiar with Dalton’s 5 statements that theorized the characteristics of all atoms. (pg. 68) i. All matter is composed of ___________________________________ called atoms. ii. Atoms of a given element are identical in ___________, _________, and other ________________; atoms of different elements differ in _____________, _______________, and ______________________. iii. Atoms cannot be _____________, _____________, or ____________________. Iv. Atoms of different elements combine in simple ______________________________________ to form compounds. v. In chemical reactions, atoms are ________________, ____________, or _____________. **NOTE: the purpose of this exercise is to practice associating these ideas with the historical scientist John Dalton. There is, in fact, a unit of measurement named after him in the sub discipline, biochemistry. Dalton’s atomic theory will come up many times throughout your academic career in the sciences and as such, it is also a standard that his theory work is familiar. vi. According to Dalton’s theory, the law of conservation of mass is explained in that chemical reactions involve merely the combination, separation, or rearrangement of atoms and that during these processes atoms are not subdivided, created, or destroyed. Refer to pg. 69, figure 2. Which example illustrates this law? _________________________________ Which of the two illustrates the law of definite proportions? __________________________________ Define the law of definite proportions. _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________. C. Modern Atomic Theory: Understand that although these historical scientific pioneers contributed greatly to what we understand about science today, their ideas, particularly Dalton’s, have been modified according to more contemporary scientific data. i. One important concept that remains unchanged is that ii. Another concept that remains unchanged is that _____________________________________________________ _____________________________________________________ _____________________________________________________ (STANDARD CLE 3221.1.1 & CLE 3221.3.4) II. THE STRUCTORE OF THE ATOM (pg. 72 – 76) A. Electron Discovery: What are the two regions that all atoms have? _______________________________________________________. i. The nucleus consists of the subatomic particles ___________ and ______________. ii. ____________ are located outside the nucleus, are in constant orbital motion about the nucleus, and are involved in forming chemical bonds. iii. Proton, neutrons and electrons are called ______________________. iv. What is a cathode ray composed of? ____________________________________________ ____________________________________________ v. Ernest Rutherford used what to help substantiate the composition of an atom?__________________________________________ vi. According to Rutherford et. al., the nucleus of an atom is incredibly __________________; this conclusion was based on the fact that the alpha particles that bombarded the gold foil ______________________. vii. Please review Rutherford et. al., experiment illustrated on pg. 74, figure 6. Be able to explain how this group of researchers were able to theorize on the structure of an atom and how their theories contribute to contemporary science and our understanding of the atomic structure – the fact that an atom is composed of an incredibly dense nucleus composed of protons and neutrons with a ‘cloud’ of electrons in constant orbital motion about this positively charged nucleus. B. Composition of the Atomic Nucleus: The proton’s positive charge is equal in magnitude to the negative charge of an electron. Atoms are electrically neutral because they contain equal numbers of protons and electrons. A neutron is ________________________. i. In terms of mass, list the greatest to the smallest of the subatomic particles. _________________________________ ii. The number of protons determines that atom’s _____________. iii. Define nuclear forces. _______________________________ _____________________________________________________ _____________________________________________________ _____________________________________________________. C. The Sizes of Atoms: Because atomic radii are so small, they are expressed using what unit? _______________________________. Express the conversion factor for 1pm to the meter. ________________ __________________________________________________________. (STANDARDS CLE 3221.1.1 & CLE 3221.Inq.2 – 6) III. COUNTING ATOMS (pg. 77 – 87) A. Atomic Number: Define the atomic number as it appears on a periodic table of elements. __________________________________________________________ __________________________________________________________. B. Isotopes: are atoms of the same _______________ that have different _____________. They have a different number of ___________ than ______________; this is why they have a different mass from a ground state elemental atom. C. Mass Number: the mass number of an element is the total number of protons and neutrons that make up the nucleus of an isotope or atom. i. Review table 2 on page 78 for an example of the difference between the varying isotopes of the hydrogen atom. D. Designating Isotopes: Review this section and understand how isotopes are expressed. If you have questions, please let me know. For example, Uranium – 235 has a mass number of 235 which is the protons + neutrons but Uranium only has 92 protons, therefore it will have 143 neutrons. You will need to refer to your periodic table to confirm this. E. Relative Atomic Masses: Know that one atomic mass unit, or 1 amu, is 1/12 of the mass of a carbon-12 atom. i. Although isotopes have different masses, they do not differ significantly in their ______________________. (pg. 81) F. Average Atomic Masses of Elements: Define average atomic mass. ________________________________________________________ ________________________________________________________ i. Understand relative abundance of elemental species as indicated on pages 80 – 82. G. Relating Mass to Numbers of Atoms: Define the mole. ___________ __________________________________________________________ __________________________________________________________. H. What is Avogadro’s Number? ________________________________ ___________________________________________________________ ___________________________________________________________ I. Molar mass is defined as the mass of one mole of pure substance. J. Practice the sample problems on pages 84 – 87. You will need to know how to convert grams to moles, moles to grams, moles to atoms, atoms to moles and etc…. (STANDARD CLE.3221.MATH.2)