1 Name ___________________________________ Date ___________________Period _________ Atomic Structure What is an atom? _________________________________________________________________ Democritus ____________________________________________________ Dalton’s Atomic Theory 1. __________________________________________________________ 2.___________________________________________________________ 3. ___________________________________________________________ 4. ___________________________________________________________ Discovery of the Electron by _________________________ by using a cathode ray tube. ____________ discovered the __________ and __________ of an electron Discovery of the Nucleus by _________________________. Concluded __________________ ________________________________________________________ Bohr _____________________________________________________________ The atom contains three subatomic particles. Label the atom diagram below and write out the definitions of each subatomic particle. 2 Which two particles are found in the nucleus? _______________ and _______________ Atoms are always NEUTRAL particles: # ____________________ = # ____________________ ATOMIC NUMBER - How many protons does Sodium have? _____ How many electrons does Sodium have? ____ How many protons does Oxygen have? _____ How many electrons does Neon have? ____ How many protons does Sulfur have? _____ How many electrons does Magnesium have? ____ MASS NUMBER – How many neutrons does Magnesium have? _____ How many neutrons does Chromium have? _____ How many neutrons does Carbon have? _____ For each element find the number of protons, neutron, electrons, mass number and atomic number. 3 ISOTOPE – Write in hyphen notation (element name – mass #) Carbon Isotope Example: Carbon – 12 has _______ protons and _______ neutrons Carbon – 14 has _______ protons and _______ neutrons Isotopic Notation is a way of displaying information for an atom or ion. Mass number SYMBOL Atomic number Example Write the isotopic notation for an atom containing 5 protons, 6 neutrons and 5 electrons. Practice Write the isotopic notation for an atom which contains 8 neutrons, has a mass number of 17. 4 Average ATOMIC MASS – Average Atomic Mass = (% isotope #1)(mass of #1) + (%isotope #2)(mass of #2) + . . . . . NOTE: You must change the percentages to decimals before putting them into the equation. Example Naturally occurring chlorine is 75.53% chlorine-35 and 24.47% chlorine-37. What is the average atomic mass? Practice The element neon consists of three isotopes with masses 19.99, 20.99 and 21.99 amus. These three isotopes are present in nature to the extent of 90.92%, 0.25% and 8.83% respectively. Calculate the atomic mass of neon. Practice The element silver exists in nature as two isotopes, Ag-107 and Ag-109. The accepted atomic mass of silver is 107.87amu. Which isotope is more abundant? How do we know the isotopes of the elements and their masses…. A mass spectrometer Practice: Calculate the average atomic mass of the element whose mass spectrometer data is below. Practice: First calculate the percent abundance of each isotope and then calculate the average atomic mass of this element, finally what element does this represent? 5 Calculating % abundances Example Calculate the percent abundance for each isotope of boron if the average atomic mass is 10.811 amu and: Isotope B-10 B-11 Mass (amu) 10.0129 11.0093 Practice Calculate the percent abundance for each isotope of neon if the average atomic mass is 20.1797 amu and: Isotope Mass (amu) Ne-20 19.992 Ne-22 21.991 Ions Atoms = contain the same number of _________ as __________. Atoms are ___________. Atoms ___________ have an electrical charge. Protons Electrons Carbon Chlorine Sodium Calcium Valence electrons What are they: ________________________________ What are they involved in: ___________ Neutrons 6 Octet Rule = Atoms tend to _____, _____, or _______ until they have ________ electrons in their outer energy level. Charge = the ________ of the atom and the number of _______________ Name this element: __________ How many valence electrons? ______ Will it gain or lose electrons? ______ How many? ____ Charge_______ Name this element: ____________ How many valence electrons? ______ Will it gain or lose electrons? _______ How many? _____ Charge ______ Ions = Do NOT contain the same number of _________ as _________ due to the gain or lost of ___________. Ions DO have electrical charges. Protons Electrons Neutrons C-4 Cl-1 Na+1 Ca+2 There are two types of ions: 1) Cations = have more ________ than _________; the ion will have a _____________ charge. __________ and __________ make cations. 2) Anions = have more _________ than __________; the ion will have a _____________ charge. _______________ make anions. 7 Decide what type of ion each of the following are. (Cation or anion) Type of Ion Type of Ion Calcium Ion Oxide Ion Nitride Ion Lead Ion Potassium Ion Hydrogen Ion Bromide Ion Silver Ion To name ions: To name Cations = Ions with a ________ charge. 1) If the metal is Group 1A, 2A, Ag, Zn, Cd, or Al (or hydrogen) just name the metal Ex. Ca+2 = ______________ 2) If the metal is not listed above use roman numerals to indicate the charge. Ex. Fe+3 = _____________ To name Anions = Ions with a _________ charge. 1) Write the name of the non-metal 2) Change the ending to –ide Ex. Cl-1 = ____________ Ion # of protons # of electrons Name of ion Ion S-2 Ni+2 Al+3 O-2 Fe+2 Pb+2 N-3 F-1 K+1 Mg+2 Zn+2 P-3 # of protons # of electrons Name of ion 8 Chemical Configuration Atomic # Mass # # of protons # of electrons # of neutrons 30 31 37 Net Charge Cl 1 42 17 5 13 +3 26 30 +2 Periodic Table ________________________ arranged the elements by atomic weights and properties. He left gaps where he predicted the discovery of new elements in his creation of the periodic table. He is coined the “father of periodic table” _________________ arranged the periodic table as it is today according to the _______________ __________. The arrows represent ________ or ___________ They have similar __________ and ____________ The arrows represent ______________ They do not have ____________ _____________ Indicates the number of ___________ ____________. 9 Metals Nonmetals Metalloids Metalloid = All METALS have several characteristics in common: 1. ____________________________________ 2. ____________________________________ 3. ____________________________________ 4. ____________________________________ 5. ____________________________________ All NON-METALS have (almost) opposite characteristics: 1. ________________________________________ 2. ________________________________________ 3. ________________________________________ 4. ________________________________________ 5. ________________________________________ 6. ____________________________________ Remember that the number of protons must equal the number of __________ in a neutral atom. # of protons = the _________________ Electrons at each energy level Level 1: ______eLevel 2: ______eLevel 3: ______e- Draw the Bohr diagram for the following elements. Lithium Magnesium Boron Silicon 10 Nitrogen Sulfur Fluorine Argon Valence Electrons What are they? ______________________________________________________________ What are they involved in? _____________________________ Family Names How many valence electrons does each family/group have? Alkali metals Alkaline earth metals Halogens Noble Gases Transition metals How many valence electrons do the following elements have? ________ Sodium ________Xenon ________Aluminum ________Bromine ________Strontium ________Potassium 11 What charge will the following groups have? What is the charge after each element below loses or gains electrons? Charge Charge Calcium Oxygen Nitrogen Magnesium Potassium Aluminum Bromine Cadmium 12 Trends in the periodic table SHIELDING - a barrier made of ______________ which serves to decrease the pull of the nucleus on the outer electrons. Shielding _____________ as you go _________a column because there are more innershell electrons due to more and more shells of electrons. Ex: There are only 2 shells of electrons in lithium and therefore only ONE INNER SHELL of shielding, but as you move down the column, cesium has 6 shells of electrons and therefore 5 INNER SHELLS which serve as shielding. Shielding is considered to be ____________as you move ___________a period because the number of inner shells are staying the same. Ex: Sodium has 3 shells of electrons and therefore 2 INNER SHELLS of electrons of shielding and chlorine which is in the same period STILL HAS ONLY 3 SHELLS of electrons and 2 INNER SHELLS of shielding. Practice: Which has more shielding calcium or barium? _________ Which is has more shielding iodine or chlorine? _________ Nuclear Charge - As the number of _________ increases so does the positive charge of the nucleus. As the nuclear charge ____________ the attraction between ___________ and ___________ is stronger. Whose outer electrons have a greater pull from the nucleus? Sodium or Chlorine Gold or Cesium Lithium or Oxygen 13 ATOMIC RADIUS - 1/2 the ___________ between the radius of two ________ of an element Draw the general trend of atomic radius. The size of an atom _______________as you move ______________ a column because: (1) the atoms have _______ orbits of electrons (2) shielding is ____________ down the column which means the outermost electrons are not held as tightly and "roam" out to a bigger diameter. As you move _____________ a period from left to right, the size of the atom ___________ because: (1) there are more _____________ in the nucleus (which means it can act as a stronger magnet) but the nucleus is still pulling on the same number of orbits and there is no additional _____________ to cut down on the pull of the nucleus. Practice: Which atom is larger? Zr or Sn ___________ Why: Which atom is larger? Li or Cs _____________ Why: Put these elements in order of increasing atomic radius? P, F, As, Rb, Sr 14 Ion Size # of protons Cations _________ electrons. The atomic radius ______________. Why: ___________________________ # of electrons Li Li+1 Na Na+1 K K+1 ___________________________ Anions _________ electrons. The atomic radius ______________. Why: ___________________________ ___________________________ # of protons F F-1 Cl Cl-1 Br Br-1 Practice: Which would be larger, aluminum atom or aluminum ion? Why: Which would be larger, fluorine ion or fluorine atom? Why: Which would be larger, oxide ion or sulfide ion? Why: # of electrons 15 Isoelectronic = A group of _______ all containing the same number of _____________. O2-, F-, Na+, Mg2+, Al3+ All of these contain _____ electrons. The more positive the ion = the ________ the ion The more negative the ion = the ________ the ion Practice: Arrange the following in order of increasing size Cl-1, Al+3, P-3, Mg+2, Na+1 Arrange the following in order of decreasing size Mg2+, Ca2+, Be2+, Sr2+