MINISTRY OF SCIENCE AND EDUCATION OF THE REPUBLIC OF KAZAKHSTAN
STATE UNIVERSITY NAMED AFTER SHAKARIM, SEMEY
Document of 3 level by MQS
EMCD
Discipline's program for discipline
«Chemistry of high molecular
compounds» for lecturer
EMCD
« »__09__2014
№ 1 edition
EMCD
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EDUCATIONAL-METHODICAL COMPLEX OF DISCIPLINE
«CHEMISTRY OF OF HIGH MOLECULAR COMPOUNDS»
For the specialty
5B011200– «Chemistry»
DISCIPLINE'S PROGRAM FOR LECTURER
Semey
2014
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Content
1. Sphere of application
2. Normative references
3. General provisions
4. The content of the training courses (modules)
5. The list of topics for individual work of students
6. Educational and methodical map of the discipline
7. Provision map of instructional literature
8. Literature
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1 FIELD OF APPLICATION
Discipline program for teachers as a part of the educational complex by the
discipline "Chemistry of high molecular compounds" is intended for students of
specialty "5B011200" - "Chemistry".
2 NORMATIVE REFERENCES
This program for the teacher establishes the procedure of the organization of
the educational process by the discipline "Chemistry of high molecular
compounds" in accordance with the requirements and recommendations of the
following documents:
- Standard curriculum for specialty "5B011200" - "Chemistry", decree # 158
from 10.04. 2012;
- СТУ 042-ГУ-4-2013 University standard - "General requirements for the
elaboration and design of the Disciplines’ educational - methodological
complexes";
- ДП 042-1.01-2013 Documented procedure - "The structure and content of
Disciplines’ educational - methodological complexes".
3 GENERAL PROVISIONS
3.1 Course "Chemistry of high molecular compounds" introduces students with
the basic provisions of polymer science, with the latest achievements in this field.
It includes issues of receiving, properties and structure of high-molecular
compounds. The course studying promotes to the deeper mastering by students
knowledge on such subjects as "Organic Chemistry", "Biological Chemistry",
"Physical Chemistry".
3.2 The purpose of the discipline: To study the chemical structure and properties of
polymer molecules. Basic concepts of polymer chemistry . Nomenclature of
polymers. Classification of carbo-and hetero- polymers. Characteristic properties
of polymer molecules . Polymer synthesis . General characteristics of the processes
of polymers. Properties of polymerization and polycondensation processes .
Radical polymerization: initiation and its effectiveness, propagation and
termination reactions of macroradicals. Ionic polymerization, ionic polymerization
types, the cationic polymerization, anionic polymerization. Polycondensation.
Features of chemical reactions of polymers. Reaction of the units and
macromolecular reactions of polymeranalogous transformation. Crosslinking of the
macromolecules. Vulcanization. Hardening, degradation, reactions of the end
groups mechano-chemical synthesis. Aggregate and phase state of polymers.
Features glassy, highly elastic and viscous-flow state of polymers. Mechanical
properties of polymers. The electrical properties of the polymers. Classification of
processing methods.
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3.3 The main objective of studying the discipline:
- Deeping of the knowledge by organic and biological chemistry;
- Strengthening of the received and the acquisition of new skills in experimental
work;
- Mastering of synthesis technique and methods of researching organic polymers
3.4 Learning Outcomes:
After the end of the studying discipline a student must be possessed with the
following knowledge and skills (competencies)
to know:
- Chemical structure and properties of polymer molecules.
- Basic concepts of polymer chemistry.
- Nomenclature of polymers.
- Classification of carbo-and hetero- polymers.
- Features of polymerisation and polycondensation.
- A process of radical polymerization: initiation and its efficiency, propagation and
termination reactions. The kinetics of macroradicals.
- A process of ionic polymerization, ionic polymerization types, the cationic
polymerization, anionic polymerization.
- Polycondensation process.
- Features of chemical reactions of polymers.
- Aggregate and phase state of polymers.
- Classification of processing methods.
be able to:
- Use reference and technical literature by the chemistry of polymers;
- Constitute the structural formulas of polymers;
- Compose the polymerization and polycondensation reaction’s schemes;
- Identify and explain the reaction mechanisms of polymer synthesis;
3.5 Prerequisites of course:
- Theoretical foundations of organic chemistry. Polymers. Isomerism. Natural
and synthetic polymers.
- Analytical chemistry. Preparative methods of analysis. Qualitative analysis of
the substance. Modern physico-chemical methods of analysis. Chromatography.
Spectrophotometry.
- Chemistry of functional derivatives of organic molecules. Condensation
reactions, polymerization, copolymerization.
- Colloid chemistry. Colloidal state of matter. Sols. Suspensions. The isoelectric
point of the colloidal solution. Sedimentation methods.
- Biochemistry. Biopolymers. Basic physical and chemical properties. The
biological functions and biochemical reactions.
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3.6 Postrequisites of course:
- Chemical Technology. Reaction mechanisms of organic and inorganic synthesis.
Catalysts. Conditions for synthesis. The yield of product.
- Selected chapters of organic chemistry. Homology. Isomerism. Polymers.
3.7 Extract from the working curriculum:
Cour Semester Credits
se
4
7
2
Lectu
res,
hours
15
Labs,
hours
OH
hours
SSS
hours
Total
hours
15
15
45
90
Table 1
Form of
final
control
exam
4 CONTENT OF DISCIPLINE (MODULE)
Table 2
Name of topics and content
1
Number of
hours
2
Lectures
Lecture № 1-3
Subject: The chemical structure and properties of polymer molecules
1. Basic concepts of polymer chemistry.
2. Nomenclature of polymers.
3. Classification of carbo-and hetero-polymers.
4. Characteristic properties of polymer molecules.
Lecture № 4-5.
Subject: General characteristics of processes of polymers.
1. The main ways of polymer synthesis.
2. General characteristics of the processes of polymers.
3. Features of polymerization and polycondensation processes.
Lecture # 6.
Subject: Radical Polymerization
1. Main stages of radical polymerization
2. Initiation and its effectiveness
3. Propagation and termination reactions of macroradicals
Lecture № 7-8.
Subject: Ioncoordination polymerisation.
1. Mechanism of ionic polymerization,
2. The types of ionic polymerization, cationic polymerization
3. Anionic polymerization.
Lecture # 9.
Subject: The polycondensation.
1. Mechanism of polycondensation
2. Process conditions
3. Hardware design of process.
Lecture № 10-12.
Subject: Structure and Properties of Polymers
1. The structure and properties of polymer organic molecules on the sample of
bioorganic molecules of proteins
3
2
1
2
1
3
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2. The structure and properties of polymer organic molecules on the example
of the polysaccharides
1.
2.
3.
4.
Lecture № 13-14.
Subject: Polymer processing ways into products
1. Classification of methods of polymer processing
2. Pressing
3. Die-casting
4. Blowing-out
Lecture # 15
Topic: Characteristics of polymeric materials and chemical raw materials for
their synthesis
1. Basic properties, characterized the polymeric materials
2. Distinctive capabilities of polymeric materials
Лабораторные занятия
Laboratory work № 1-2. Identification of physical and chemical parameters of
polymers
Laboratory work № 3-4. Determination of the molecular weight of the
polymer by viscometric method
Laboratory work № 5-6. Determination of the resin and filler in the polymer
samples.
Laboratory work № 7-8. Synthesis of the polymer by polycondensation and
study of its properties
Laboratory work № 9-10. Determination of the isoelectric point of the protein
Laboratory work № 11-12. Identification of natural, artificial and synthetic
fibers.
Laboratory work № 13-15. Polymeranalogous conversion of polymers
2
1
2
2
2
2
2
2
3
5. LIST OF TOPICS FOR INDEPENDENT WORK OF STUDENTS
Individual tasks №1.
1. Demonstrate a possible mechanism of chain termination in the polymerization of
ethylene as a result of disproportionation and recombination.
2. Show a scheme of chain polymerization reaction of propylene. Write a radical
mechanism of this reaction (three stages) with acetyl peroxide.
3. Locate hydrocarbons below in order of increasing lightness to chain
polymerization: 1) ethylene, 2) propylene, 3) 2,3-Dimethyl-2-butene, 4) 2-butene.
Individual tasks №2.
1. Show the mezanizm of chain polymerization of butene-1 in the presence of
benzoyl peroxide.
2. Write schemes of chain polymerization for the following compounds: styrene,
acrylonitrile, methyl acrylate. Please give a mechanism of cationic polymerization
for the styrene in the presence of boron fluoride.
3. Teflon - highly stable polymer prepared by polymerization of
tetrafluoroethylene. Make a chart of the reaction.
Individual tasks №3.
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1. For produsing viscose silk the cellulose is treated with sodium hydroxide. After
this to the formed alkyl cellulose is added carbon disulfide and in this conditions
cellulose xanthate (viscose) are obtained. Viscose silk is a hydrolysis product of
the cellulose xanthate in an acidic medium. Write the equation of all these
reactions. What is cellophane?
2. Write the fragment of xylan molecule formula, if it is known that it consists of
residues of β-1,5-D-xylose linked by β-1,4 glycosidic bonds.
3. A.M. Butlerov first realized the dimerization of isobutylene at heating with 60%
sulfuric acid. Obtained dimer is a mixture of two isomers: 2,4,4-trimethylpentene-1
and 2,4,4-trimethylpentene-2. Write the reaction of producing diisobutylenes.
Explain the mechanism of this reaction, taking into account that it proceeds via
carbocation.
4. Make a chart of step polymerization reaction with three molecules of propylene.
Explain the mechanism of this reaction (with the formation of carbocations). Call
trimers obtained by systematic nomenclature.
5. By the polymerization in the presence of sulfuric acid diisobutylene was
obtained from 140g. isobutylene. Unreacted isobutylene was evaporated and
diisobutylene was mixed with bromine, and 120g of bromine was expended.
Determine the percentage yield of diisobutylene.
Individual tasks №4 (Topics of abstract)
1. Thermoplastics - the current state of the industry
2. Thermosets - the current state of the industry
3. Main components of the polymeric compositions
4. Rubber and tire
5. Polymers of natural origin and their derivatives
6. The structure and general properties of polymers
7. Using of polymers in medicine
8. Natural fibers
9. Synthetic fibers
10. Artificial fibers
11. Polymer films
12. Ion exchange resin
13. Plastics based on natural and petroleum asphalts
6. TRAINING-METHODICAL MAP ON DISCIPLINE
Table 3
The topic
Lecture
Chemical
structure and
properties of
polymer
Laboratory
work
Laboratory work №
1-2. Identification of
physical
and
chemical parameters
Visual
aids,
posters,
stands
Laborato
ry
equipme
nt,
Questions for self-study
Form
of
control
To know the chemical current
structure and properties of control
polymer
molecules.
Basic
concepts of polymer chemistry.
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molecules
of polymers
General5.
characteristics
of
the
processes of
polymers.
Laboratory work №
3-4. Determination
of the molecular
weight
of
the
polymer
by
viscometric method
Radical6.
Polymerizatio
n
Laboratory work №
5-6. Determination
of the resin and filler
in
the
polymer
samples.
Ion
7.
Laboratory work №
coordination
7-8. Synthesis of the
polymerisation polymer
by
polycondensation
and study of its
properties
Polycondensat
8.
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reagents, Nomenclature of polymers.
glasswar Classification of carbo-and
e, posters hetero-polymers. Characteristic
properties of polymer molecules.
Laborato To know the basic ways of
ry
polymer synthesis. General
equipme characteristics of the processes
nt,
of polymers. Properties of
reagents, polymerization
and
glasswar polycondensation processes.
e, posters
Laborato To know the concept of radical
ry
polymerization: initiation and its
equipme efficiency, propagation and
nt,
termination
reactions
reagents, Macroradicals kinetics.
glasswar Hand over Quest # 1
e, posters
Laborato
ry
equipme
nt,
reagents,
glasswar
e, posters
Laboratory work № Laborato
9-10. Determination ry
of the isoelectric equipme
point of the protein
nt,
reagents,
glasswar
e, posters
The structure Laboratory work №
and properties 11-12. Identification
of polymers
of natural, artificial
and synthetic fibers.
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current
control
current
control
To know the mechanism of ionic current
polymerization, types of ionic control
polymerization,
cationic
polymerization,
anionic
polymerization.
Know the mechanism of
polycondensation. Steps in the
process. Process conditions.
Solving
the
tasks
on
establishment
of
polycondensation
schemes.
Hand over Quest # 2
Hand over Boundary control
1.
Laborato Know features of chemical
ry
reactions of polymers. Reaction
equipme units
and
macromolecular
nt,
reaction of polymeranalogous
reagents, transformation.
Mechanical
glasswar properties of polymers. The
e, posters electrical properties of the
polymers.
Features
glassy,
highly elastic and viscous-flow
state of polymers.
Answer questions and solve
tasks by individual cards.
Hand over Quest # 3.
current
control
current
control
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Processing
Laboratory work №
polymers into 13-15.
products
Polymeranalogous
conversion of
polymers
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Laborato
ry
equipme
nt,
reagents,
glasswar
e, posters
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Know the ways of stapling
macromolecules. Vulcanization.
Hardening,
degradation
reactions of the end groups,
mechano-chemical
synthesis.
Aggregate and phase state of
polymers. Classification of
processing methods.
Hand over Quest # 4.
Hand over Boundary control
2.
Characteristics1. Laboratory work № Laborato
Know
the
chemical
of
polymer 13-15.
ry
structure and properties of
materials and Polymeranalogous
equipme polymer
molecules.
Basic
chemical raw conversion
of nt,
concepts of polymer chemistry.
materials for polymers
reagents, Nomenclature of polymers.
their synthesis
glasswar Classification of carbo-and
e, posters hetero-polymers. Characteristic
properties of polymer molecules.
current
control
current
control
7. PROVISION MAP OF INSTRUCTIONAL LITERATURE
Table 4
Name of textbooks, study guides
Number of
Number Percenta
copies
of
ge of
students provisio
n
1. Шур
А.М.
Высокомолеклурные
2
5
50
соединения, М., 1981
8 REFERENCES
8.1 Basic
8.1.1 L. Mandelkern, An lntroduction to Macromolecules, Springer-Verlag, New
York, 1992.
8.1.2 R. G. Treloar, lntroduction to Polymer Science, Springer-Verlag, New York,
1990. An excellent and simple introduction to the relationship of polymer physical
properties to structure.
8.1.3 Шур А.М. Высокомолеклурные соединения, М., 1981г.
8.2 Additional
1. 8.2.1 “Nomenclature of regular single-strand organic polymers, 1975”, Pure
Appl. Chem. 48, 373–385 (1976). Reprinted as chapter 5 in Ref. 7.
8.2.2 “Nomenclature of regular double-strand (ladder and spiro) organic polymers
1993”, Pure Appl. Chem. 65, 1561–1580 (1993).
8.2.3“Structure-based nomenclature for irregular single-strand organic polymers
1994”, Pure Appl. Chem. 66, 873–889 (1994).