Benedict'S Soln(Qualitative) Page 1 of 6 Product name: Benedict's solution Synonyms: Application of the substance/the preparation: Chemicals for synthesis, Laboratory Chemicals Supplier Information: Avonchem Ltd Wellington House 10 Waterloo Street West Macclesfield Cheshire SK11 6PJ Tel: 01625-434300 Fax: 01625-869777 Hazard designation: Harmful Environment Information pertaining to particular dangers for man and environment: Harmful by inhalation, in contact with skin and if swallowed. Harmful to aquatic organisms, may cause longterm adverse effects in the aquatic environment. Classification System The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies 2. Hazards Identification 3. Composition/information on ingredients Chemical classification: Solution in water CAS number: N/A EC number: N/A Dangerous components: Copper (II) sulphate pentahydrate 1.6 CAS No.: 7758-99-8, EC No.: 231-847-6, • R: 22-36/38-50/53 • S: 22-60-61 7. Handling & Storage Eye Contact: Irrigate thoroughly with water for at least 10 minutes. If discomfort persists obtain medical attention. Skin Contact: Wash off thoroughly with soap and water. Remove contaminated clothing and wash before re use. In severe cases, obtain medical attention. Inhalation: Remove from exposure, rest and keep warm. In severe cases obtain medical attention. Ingestion: Wash out mouth thoroughly with water and give plenty of water to drink. Obtain medical attention. 4. First Aid Measures 5. Fire Fighting Measures 6. Accidental Release Measures Fire Risks: Not applicable. Suitable Extinguishing Media: To suit environment. Personal: Wear appropriate protective clothing. Disposal: Absorb on an inert absorbent, transfer to a suitable container and arrange removal by disposal company. Wash site of spillage thoroughly with water and detergent. Spillage: For large spillage's liquids should be contained with sand or earth and both liquids and solids transferred to salvage containers. Any residues should be treated as for small spillage's. Handling: Change contaminated clothing. Wash hands after working with substance. Do not empty into drains. Storage: Store at room temperature (15 to 25°C recommended). Keep well closed and protected from direct sunlight and moisture. 8. Exposure Controls/Personal Protection As appropriate to the situation and the quantity handled. Respirator: Not applicable. Ventilation: Not applicable Gloves: Rubber or plastic Eye Protection: Goggles or face-shield Other Precautions: Plastic apron, sleeves, boots - if handling large quantities. See section 15 for UK exposure limits. 9. Physical and Chemical Properties Physical State: Liquid Appearance: Clear blue Specific Gravity/Density: 1.21 Solubility in water: Soluble. Stable. May crystallise in cold weather. Quantitative data on the toxicity of this product are not available. The product should be handled with the care usual when dealing with chemicals. Possible effects: Inhalation: Skin Contact: Irritation. Eye Contact: Irritation. Ingestion: Further data: Further hazardous properties cannot be excluded. No evidence of carcinogenic properties. No evidence of mutagenic or teratogenic effects. Ecological: Quantitative data on the ecological effect of this product are not available. Adverse ecological effects cannot be excluded in the event of improper handling or disposal. Do not allow to enter drinking water supplies, waste water, or soil! The following applies to copper compounds: biological effects: toxic for aquatic organisms; copper ions toxic for fish, algae, protozoa and bacteria at concentrations below 1 mg/l. Fish: C. auratus toxic from 0.01 mg/l; mussels: 0.55 mg/l lethal in 12 h; oysters: 0.1 mg/l toxic. Chemical Reaction: Bioaccumulation potential: Toxicity: Quantitative data on the ecological effect of this product are not available. Adverse ecological effects cannot be excluded in the event of improper handling or disposal. Do not allow to enter drinking water supplies, waste water, or soil! The following applies to copper compounds: biological effects: toxic for aquatic organisms; copper ions toxic for fish, algae, protozoa and bacteria at concentrations below 1 mg/l. Fish: C. auratus toxic from 0.01 mg/l; mussels: 0.55 mg/l lethal in 12 h; oysters: 0.1 mg/l toxic. 13. Disposal Considerations Chemical residues are generally classified as special waste, and as such are covered by regulations which vary according to location. Contact your local waste disposal authority for advice, or pass to a chemical disposal company. Rinse out empty containers thoroughly before returning for recycling. 14. Transport Information Land Transport ADR: UN: 3082 PK: III Class: 9, , Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. LQ: 7 Maritime Transport IMDG: UN: 3082 PK: III Class: 9, , Marine Pollutant: YES Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Air Transport IATA: UN: 3082 PK: III Class: 9, , Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 15. Regulatory Information Labelling according to EC directives Symbol: Harmful Environment R-phrases: • R: 20/21/22-52/53 Harmful by inhalation, in contact with skin and if swallowed. Harmful to aquatic organisms, may cause longterm adverse effects in the aquatic environment. S-phrases: • S: 36/37-61 Wear suitable protective clothing and gloves. Avoid release to the environment. Refer to special instructions/Safety data sheet. EC-No.: N/A Local Regulations: UK Exposure Limits: None assigned. Long-term: Short-term: Date of issue: 23/09/2009 Important Statement The information above is believed to be accurate and represents the best information currently available from multiple crosschecked sources. However, we make no warranty express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no way shall Avonchem Ltd be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the company has been advised of the possibility of such damages. 16. Other Information