Chapter 19 Notes Honors Chemistry Chapter 19: Acids, Bases, and Salts Section 1 Notes – Acid Base Theories (Read pages 587-593) Acids Taste _________________________ or _________________________ Conduct electricity Strong or weak electrolytes _________________________ React with metals to form _________________________ gas React with bases to form salt and water Changes indicators (turns litmus paper _________________________) Different Classifications of Acids _________________________ o Contains one ionizable hydrogen (Example: _________________________) _________________________ o Contains two ionizable hydrogens (Example: _________________________) _________________________ o Contains three ionizable hydrogens (Example: _________________________) Bases Taste _________________________ Feels _________________________ Strong or weak electrolytes Reacts with acids to form salt and water Changes indicators (turns litmus paper _________________________) Solutions sometimes known as _________________________ Three Definitions of Acids and Bases _________________________ __________________________________________________ _________________________ Arrhenius Acids and Bases Looks at acids and bases in terms of what they ____________________ in __________________ 1 Chapter 19 Notes Honors Chemistry Arrhenius Acid o Produces ____________ or _____________ ions in _________________ solution Arrhenius Base o Produces _____________ ions in _________________________ solution Bronsted-Lowry Acids and Bases Looks at acids and bases in terms of _______________________ ___________________ Bronsted-Lowry Acid o Donates a _________________________ (H+) Bronsted-Lowry Base o Accepts a _________________________ (H+) There’s something about water… Water is _________________________ or _________________________ It can act as an _________________________ or _________________________ Depends on what it is reacting with Conjugate Acids and Bases Conjugate Acid o Formed when a __________________ gains a _________________________ ion Conjugate Base o Remains when an acid has _________________ a ______________________ ion Conjugate Acid-Base Pair o Consists of 2 substances related by the _________________________ or _________________________ of a single _________________________ ion Bases form conjugate _________________________ Acids form conjugate _________________________ Lewis Acids and Bases Looks at acids and bases in terms of _________________________ Lewis Acid o _________________________ a pair of electrons to form a covalent bond Lewis Base o _________________________ a pair of electrons to form a covalent bond 2 Chapter 19 Notes Honors Chemistry Acid-Base Definitions (Summary) Type Arrhenius Acid Definition Base Definition Bronsted-Lowry Lewis Section 2 Notes – Hydrogen Ions and Acidity (Read pages 594-604) Self-Ionization of Water Equation: H2O H+ + OH Ion product constant of water = Kw = [H+][OH-] = _________________________ o This means that the ____________ and _____________ are equal to _________________________ in a _________________________solution o In an _________________________ solution, [H+] will be _________________________ than [OH-] o In a _________________________ solution, [OH-] will be greater than [H+] [ ] represents _________________________ Let’s Use It! Colas are slightly acidic. If the [H+] in a cola solution is 1.0 x 10-5 M, what is [OH-] in the solution? Practice Problems 1. If the hydroxide ion concentration of an aqueous solution is 1.0 x 10-3M, what is the concentration of hydrogen ions in solution? Is the solution acidic, basic, or neutral? 2. Classify each of the following as acidic, basic, or neutral. a. [H+] = 6.0 x 10-10 M b. [OH-] = 3.0 x 10-2 M 3 Chapter 19 Notes Honors Chemistry pH and pOH p represents the mathematical calculation of _________________________ _________________________ (or – log) So pH is _________________________ wheras pOH is _________________________ pH + pOH = _________________________ o In a _________________________ solution, pH and pOH equal ________. o In an _______________________ solution, pH is ___________________ than 7. o In a ______________________ solution, pH is _____________________ than 7. Two Examples 1. A solution has a pH of 12, what is the pOH of the solution? 2. If the [H+] of a solution is 3.4 x 10-10 M, what is the pH and pOH of the solution? Practice Problems – Try it! Find the pH and pOH of each of the following solutions. Classify each as acidic, basic, or neutral. 1. Solution with an [H+] of 0.045 M 2. Solution with an [OH-] of 0.072 M Finding [H+] and [OH-] from pH and pOH Remember that pH = -log [H+] so [H+] = _________________________ This also applies to bases [OH-] = _________________________ Example: If a solution has a pH of 3.2, what is the [H+] in the solution? Practice Problems Find the [H+] and [OH-] for each of the following solutions: 1. A solution with a pH of 11.9 4 Chapter 19 Notes Honors Chemistry 2. A solution with a pOH of 12.4 Section 4 Notes – Neutralization Reactions (Read pages 612-616) Neutralization Reactions The reaction between an _________________________ and a _________________________ Products are _________________________ (ionic compound) and _______________________ Example: HCl + NaOH NaCl + H2O Titration A process used to determine the _________________________ of an _________________________ or _________________________ solution in which a standard solution of _________________________ concentration is added to a measured amount of solution with an _________________________ concentration until an _________________________ signals an _________________________ o Equivalence point – point in the titration where the number of moles of _________________________ ions equals the number of moles of _________________________ ions Indicators Change ____________________ under different conditions of ____________________ Help identify ______________________ and _________________________ solutions Many different indicators (Example: Phenolpthalein) Titration Calculations – Finding the number of moles of acid or base required in a neutralization 1. How many moles of sulfuric acid are required to neutralize 0.50 mol of sodium hydroxide? 5 Chapter 19 Notes Honors Chemistry Practice Problems – You Try It! 1. How many moles of potassium hydroxide are needed to completely neutralize 1.56 mol of phosphoric acid? Titration Calculations – Determining an unknown concentration 1. A 25 mL of H2SO4 is completely neutralized by 18 mL of 1.0 M NaOH. What is the concentration of the H2SO4 solution? Practice Problems – Give It A Shot! 1. How many mL of 0.45 M HCl will neutralize 25.0 mL of 1.00 M KOH? 2. What is the molarity of H3PO4 if 15.0 mL is completely neutralized by 38.5 mL of 0.150 M NaOH? And with that, you’ve officially completed all of the content for intro. chem!! CONGRATS! 6