MODULE 4 – ENVIRONMENTAL ASPECTS OF BROWNFIELD REGENERATION MODULE 2 Author: Contact: Slides: Planning in Brownfield Regeneration Barbara Vojvodíková, Marcela Maturová barbara.vojvodikova@vsb.cz, marcela.maturova@vsb.cz 27 (1 + 25 + 1) List of References: European Commission. (2010). Communication from the Commission – Europe 2020. A Strategy for Smart, Sustainable and Inclusive growth, Brussels, COM March 3rd European Soil Portal – Soil Data and Information Systems (2012) [online] [cit 12.3.2012] http://eusoils.jrc.ec.europa.eu/library/themes/contamination/ European Environmental Agency (2007) Overview of progress in the management of contaminated sites in Europe, [online] [cit 12.3.2012] http://www.eea.europa.eu/data-and-maps/figures/overviewof-progress-in-the-management-of-contaminated-sites-in-europe European Environmental Agency (2007b) Overview of Activities Causing soil Contamination in Europe [online] [cit 12.3.2012] http://www.eea.europa.eu/data-and-maps/figures/overview-of-activitiescausing-soil-contamination-in-europe/ European Environmental Agency (2007c) Overview of Contaminants Affecting Soil and Groundwater in Europe Europe, [online] [cit 12.3.2012] http://www.eea.europa.eu/data-and-maps/figures/overviewof-contaminants-affecting-soil-and-groundwater-in-europe Ministry of Enviroment (2008), Metodický pokyn 14/2008, Hodnocení priorit -kategorizace kontaminovaných a potenciálně kontaminovaných mist Ministry of Enviroment (2011), Věstník ministerstva životního prostředí 3/2011 Metodický pokyn odboru ekologických škod MŽP - Analýza rizik kontaminovaného území, [online] [cit 12.3.2012] http://www.mzp.cz/osv/edice.nsf/46861B2409735127C125784E0043418B/$file/OVVVestnik_3_2011-09032011.pdf U.S. EPA, (1997), Ecological Risk Assessment Guidance for Superfund: Process for Designing and Conducting Ecological Risk Assessments, Interim Final; Appendix A - Example Ecological Risk Assessment for Hypothetical Sites United States Environmental Protection Emergency (2001a) A Citizen’s Guide to Activated Carbon Treatment [EPA 542-F-01-020], United States Environmental Protection Emergency (2001b) A Citizen’s Guide to Air Stripping [EPA 542-F-01-016], United States Environmental Protection Emergency (2001c) A Citizen’s Guide to Bioremediation [EPA 542-F-01-001], United States Environmental Protection Emergency (2001d) A Citizen’s Guide to ChemicalOxidation [EPA 542-F-01-013] United States Environmental Protection Emergency (2001e)A Citizen’s Guide to Excavation [EPA 542F-01-023]). United States Environmental Protection Emergency (2001f) A Citizen’s Guide to Soil Washing [EPA 542-F-01-008 ], United States Environmental Protection Emergency (2001g) A Citizen’s Guide to Thermal Desorption [EPA 542-F-01-003] , Tylčer J. in Jackson. J (2005).: Brownfields snadno a lehce- attachment 4, Praha 2005 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 1 Manual – Slide 1 Title slide - please retain the authors´ names but you can add your name for making presentation, especially when adding your own examples. Slide 2 Manual – Slide 2 Awareness level in the field of environmental aspects of brownfield regeneration: What does contaminated site means? What are basic steps in site exploration in relation to environmental burdens? What is elementary classification of decontamination methods? How do selected decontamination methods work? Slide 3 Manual – Slide 3 The goals of this teaching unit are mainly: Environmental aspects of brownfield regeneration encompass broad range of problems; fauna and flora, landscape impacts, health risks. Each of the problem group itself is so complex that it would need standalone presentation. That is why this unit is focused only on contamination. Approaches to contamination assessment are outlined and selected decontamination methods introduced. Slide 4 Manual – Slide 4 The content of this teaching unit consists of the following topics to be explained in details: Contaminated site term definition Environmental assessment procedure Sampling steps Decontamination methods classification Decontamination methods examples 80 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 5 Manual – Slide 5 Environmental aspects can be explained from various points of view. If we can understand term environment as an area – space for living. We have to calculate social, architectonical, economical as well as human health aspect. Because the other parts including the next parts in this curse is for this presentation important contamination as the significant effects on human health. As we can see on this slide, contamination can be present in construction – it can be danger if we want to use this areal for example for housing. And when we demolished this construction we have to do something with danger waste. Contamination which is present in soil can be migrating to air and effect human health in form of volatile Dust. Also is necessary monitoring position of contamination in saturated zone. If this underground d water use as drinking water it can be very danger for human health. That why is necessary to speak about contamination and decontamination methods as a possibility to reduce hazards. Slide 6 Manual – Slide 6 This is general definition of contaminated site. It is definition of the state which is confirmed by e.g. performed examinations. 81 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 7 Manual – Slide 7 More interesting are localities are those where we assume that contamination could be present but we are not certain. Special attention should be paid to such sites and environmental assessment should be carried out. Slide 8 Manual – Slide 8 Environmental assessment comprises of three phases however it is not required to design detail of remediation actions in first assessment of the site. Slide 9 Manual – Slide 9 This preliminary site evaluation is based especially on economical demands for site examination. It is not economically affordable to perform detailed analysis of the whole area so places need to be identified where the worst situation is expected according to the site’s past use. Slide 10 Manual – Slide 10 After site assessment has been carried out the most risky areas are examined. The goal is to determine borders of the worst contaminated zone. 82 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 11 Manual – Slide 11 Sampling itself consists of seven steps: 1. a sample is planned; 2. a sampling point is identified; 3. the sample is collected; 4. the sample is transferred to the laboratory; 5. the sample is analyzed; 6. the sample expires and is discarded; and 7. the sample reincarnates as a chemical data point. Slide 12 Manual – Slide 12 Appropriate remediation methods can be designed according to assessment findings. Following two goals should be set for soil remediation: eliminate exposure of living organism to contamination eliminate sources of groundwater contamination Slide 13 Manual – Slide 13 Decontamination methods can be classified by these criteria by place according remediated media type according used strategies Slide 14 Manual – Slide 14 "In situ" decontamination is a treatment method that involves removing the pollutants in place and cleaning the soil and the groundwater "ex-situ" means that the contaminated materials are extracted or removed from the environment, either definitively (in the case of destruction), or temporarily (in the case that the contaminated products are "cleaned"). 83 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 15 Manual – Slide 15 Different media types require different decontamination technologies. Slide 16 Manual – Slide 16 Pollutants immobilization: Barriers, Solidification and stabilisation Exchange from liquid phase to soil phase by chemical reaction. Dispersing by chemical reaction. Extraction and separation from environment This group includes thermal desorption, washing, dissolvent extraction, venting, treatment of groundwater by separation of phases, activated carbon adsorption, air stripping and combination of these approaches. When choosing from these methods and their combinations it is necessary to select those which offer the most efficient transportation mechanism so that maximal overall efficiency is reached. Disintegration and transformation of pollutant Thermal, biological and chemical methods. Examples of selected methods follow. Slide 17 Manual – Slide 17 This is an example of contaminated soil isolating without its further cleaning. Contaminated soil was extracted, concentrated on a single place and isolated. The place had been adapted to a park. The photo was taken in Ruhr District, Germany. 84 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 18 Manual – Slide 18 Thermal desorption removes harmful chemicals from soil and other materials (like sludge and sediment) by using heat to change the chemicals into gases. These gases are collected with special equipment. The dust and harmful chemicals are separated from the gases and disposed of safely. The clean soil is returned to the site. Thermal desorption is not the same as incineration, which uses heat to destroy the chemicals. Slide 19 Manual – Slide 19 This scheme describes procedure of thermal desorption process; the scheme was taken from below-mentioned source. A lot of useful descriptions of various methods can be found on the US EPA website. Thermal desorption uses equipment called a desorber to clean polluted soil. Soil is excavated and placed in the desorber. The desorber works like a large oven. When the soil gets hot enough, the harmful chemicals evaporate. To get the soil ready for the desorber, workers may need to crush it, dry it, blend it with sand, or remove debris. This allows the desorber to clean the soil more evenly and easily. Slide 20 Manual – Slide 20 It’s the process of forcing air through polluted water to remove harmful chemicals. The air causes the chemicals to change from a liquid to a gas (evaporate). The gas is then collected and cleaned. It’s commonly used to treat groundwater as part of a pump and treat remedy. 85 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 21 Manual – Slide 21 Air stripping is safe to use. Air strippers can be brought to the site so polluted water does not have to be transported to a cleanup facility. The polluted water is contained throughout cleanup so there is no chance for coming into contact with the water. The polluted gases that are produced by the air stripping are cleaned up and tested. Slide 22 Manual – Slide 22 Chemicals tend to stick or absorb to some types of soil more than others. For instance, chemicals absorb more to fine-grained soils like silt and clay than to larger-grained soils like sand and gravel. Soil washing helps separate the silt and clay from the larger-grained, cleaner soils Soil washing can clean up a variety of chemicals, such as fuels, metals, and pesticides that can absorb to soil. 86 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 23 Manual – Slide 23 Before using soil washing, soil dug from the polluted area is sifted to remove large objects, like rocks and debris. The sifted soil is placed in a machine called a scrubbing unit. Water is added to the polluted soil in the scrubbing unit. The mixture of soil and water is passed through sieves, mixing blades, and water sprays. This washes the silt and clay from the larger-grained soil and separates them. Some of the pollution may dissolve in the water or float to the top. The polluted wash water is removed and cleaned up at a treatment plant. The clean water then can be reused in the scrubbing unit or discharged. The silt and clay may be washed again in the scrubbing unit or cleaned using another method like bioremediation or thermal desorption The sand and gravel that settle to the bottom of the scrubbing unit also are tested for chemicals. If the sand and gravel are clean, they can be placed back on the site. If pollution is still present, they are washed again in the scrubbing unit. If necessary, another method is used to finish the cleanup. Slide 24 Manual – Slide 24 http://www.frtr.gov/matrix2/section4/4_1.html In addition to degradation of adsorbed fuel residuals, volatile compounds are biodegraded as vapors move slowly through biologically active soil. The U.S. Air Force has produced a technical memorandum which summarizes the results of bioventing treatability studies of fuels conducted at 145 US Air Force sites. The memorandum discusses overall study results and presents cost and performance data and lessons learned. Regulatory acceptance of this technology has been obtained in 30 states and in all 10 EPA regions, and the use of this technology in the private sector is growing rapidly following USAF leadership. Bioventing is a medium to long-term technology. Cleanup ranges from a few months to several years. 87 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 25 Manual – Slide 25 Bioventing techniques have been successfully used to remediate soils contaminated by petroleum hydrocarbons, nonchlorinated solvents, some pesticides, wood preservatives, and other organic chemicals. While bioremediation cannot degrade inorganic contaminants, bioremediation can be used to change the valence state of inorganics and cause adsorption, uptake, accumulation, and concentration of inorganics in micro or macroorganisms. These techniques, while still largely experimental, show considerable promise of stabilizing or removing inorganics from soil. Factors that may limit the applicability and effectiveness of the process include: The water table within several feet of the surface, saturated soil lenses, or low permeability soils reduce bioventing performance. Vapors can build up in basements within the radius of influence of air injection wells. This problem can be alleviated by extracting air near the structure of concern. Extremely low soil moisture content may limit biodegradation and the effectiveness of bioventing. Monitoring of off-gases at the soil surface may be required. Aerobic biodegradation of many chlorinated compounds may not be effective unless there is a cometabolite present, or an anaerobic cycle. Low temperatures may slow remediation, although successful remediation has been demonstrated in extremely cold weather climates. 88 Module 4 – Environmental Aspects of Brownfield Regeneration Slide 26 Manual – Slide 26 What did we learn For determination of site’s environmental burdens it is necessary to perform site investigation. Based on the findings a proper decontamination method or combination of methods must be chosen. There are many decontamination methods and their suitability depends on media type and contaminants detected. Slide 27 Manual – Slide 27 Please, open discussion on this topic. 89