1 Auxiliary Material for: 2 Spatial extent and degree of oxygen depletion in the deep proto-North Atlantic basin 3 during Oceanic Anoxic Event 2 4 5 Niels A.G.M. van Helmonda, Itzel Ruvalcaba Baronib, Appy Sluijsa, Jaap S. 6 Sinninghe Damstéb,c and Caroline P. Slompb 7 a Marine Palynology and Paleoceanography, Department of Earth Sciences, Faculty 8 of Geosciences, Utrecht University. Laboratory of Palaeobotany and Palynology, 9 Budapestlaan 4, 3584 CD Utrecht, Netherlands b 10 Geochemistry, Department of Earth Sciences, Faculty of Geosciences, Utrecht 11 12 University. Budapestlaan 4, 3584 CD Utrecht, Netherlands c NIOZ, Royal Netherlands Institute for Sea Research, P.O. Box 59, 1790 AB Den 13 Burg, Texel, Netherlands. 14 Geochemistry, Geophysics, Geosystems, 2014 15 Introduction 16 This data set contains all geochemical data used in this study, listed per sample 17 (ts01.docx). Bold data are generated in this study, other data is compiled from 18 previous publications (Table 2). In fs01.pdf all measured redox sensitive elements are 19 plotted for the studied sites. 20 1. ts01.docx all geochemical data used in study. 21 1.1 Column “Leg”, the number of the leg of the Deep Sea Drilling Project (DSDP) or 22 Ocean Drilling Program (ODP) of which the drilled site is part of. 23 1.2 Column “Site”, the DSDP or ODP site the studied samples originate from. 24 1.3 Column “Hole”, sometimes multiple holes are drilled per DSDP or ODP site, this 25 indicates from which hole the studied samples originate from. 26 1.4 Column “Core”, the core from which the studied sample originates. 27 1.5 Column “Section”, the section of the core from which the studied sample 28 originates. 29 1.6 Column “top depth (cm)”, the upper limit of the sampled interval. 30 1.7 Column “base depth (cm)”, the lower limit of the sampled interval. 31 1.8 Column “Sample depth (mbsf)”, the average sample depth, i.e. the average of the 32 top depth and base depth, in meters below seafloor (mbsf). 33 1.9 Column “TOC (%)”, the total organic carbon content (TOC). 34 1.10 Column “δ13Corg/TOC (‰ VPDB)”, the stable isotopic composition of carbon in 35 organic matter or total organic carbon content, measured versus the international 36 standard, the Vienna Peedee Belemnite (VPDB). 37 1.11 Column “Corg/Ptot (mol/mol)”, the molar ratio of organic carbon and phosphorus. 38 1.12 Column “P (ppm)”, the concentration of phosphorus in parts per million. 39 1.13 Column “Al (%)”, the concentration of aluminum. 40 41 1.14 Column “Fe (%)”, the concentration of iron 42 1.15 Column “Mo (ppm)”, the concentration of molybdenum in parts per million. 43 1.16 Column “V (ppm)”, the concentration of vanadium in parts per million. 44 1.17 Column “Mn (ppm)”, the concentration of manganese in parts per million. 45 1.18 Column “Zn (ppm)”, the concentration of zinc in parts per million. 46 1.19 Column “Ni (ppm)”, the concentration of nickel in parts per million. 47 1.20 Column “Cu (ppm)”, the concentration of copper in parts per million. 48 1.21 Column “Cr (ppm)”, the concentration of chromium in parts per million. 49 1.22 Column “S (%)”, the concentration of sulphur. 50 2. fs01.pdf Lithology, chemostratigraphy (δ13Corg, δ13CTOC and TOC), Corg/P, Mo, V, 51 Mn, Zn, Ni, Cr, Cu, Fe/Al and S for sites 367 (a), 386 (b), 603 (c), 641 (d) and 1276 52 (e). Grey shades highlight the OAE2-interval, based on the positive excursion in 53 δ13Corg/ δ13CTOC and elevated TOC content, with the subdivision into different phases 54 of the CIE marked by an “A”, “B” or “C” after Kuypers et al. (2002). mbsf: meters 55 below seafloor. 56 57 References 58 Kuypers, M.M.M., R.D. Pancost, I.A. Nijenhuis, and J.S. Sinninghe Damsté (2002), 59 Enhanced productivity led to increased organic carbon burial in the euxinic North 60 Atlantic basin during the late Cenomanian oceanic anoxic event. Paleoceanography, 61 17, PA1052, doi:10.1029/ 2000PA000569.