Particles size and composition in Mediterranean countries: geographical variability and short-term health effects MED-PARTICLES Project 2011-2013 Under the Grant Agreement EU LIFE+ ENV/IT/327 Particles size and composition in Mediterranean countries: geographical variability and short-term health effects MED-PARTICLES ACTION 3. Report on: daily concentrations of particles (PM10, PM2.5-10; PM2.5), gases (CO, NO2, O3, SO2) and meteorological parameters (air temperature, humidity, sea-level barometric pressure, wind speed/direction) in the MED-PARTICLES cities Summary: The report describes the study period and type of monitors available for all the measured pollutants, summarizes the environmental and meteorological variables and the correlation between them in the Mediterranean cities involved in the project. Summary statistics used are: mean, standard deviation, percentiles, annual averages and Pearson’s correlation. -------------------------------------------------------------------------- ATHENS (2007-2009) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2007-2009 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 2R, 1B, 3SU, 3T PM2.5 1B, 2SU, 1T PM2.5-10 2SU, 1T NO2 3R, 4B, 4SU, 5T CO 2B, 4T SO2 2R, 2B, 1SU, 3T O3 3R, 3B, 4SU, 4T PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; R: rural; B: background; SU: Sub-urban; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Pollutant / Meteo Days Mean SD Min PM10 (μg/m3) 1,094 38.7 20.8 PM2.5 (μg/m3) 1,069 23.0 PM2.5-10 (μg/m3) 1,041 NO2 (μg/m3) Percentiles Max 5° 25° 50 75° 95° 7.0 17.5 26.5 35.0 45.5 73.3 290.5 10.3 5.0 10.5 16.5 21.5 27.5 41.0 101.0 15.7 15.5 -13.5 3.0 8.0 12.0 18.5 38.0 236.5 1,096 46.4 14.3 16.7 25.0 35.6 45.2 56.1 71.0 104.8 CO (mg/m3) 1,096 1.6 0.9 0.5 0.7 1.0 1.4 1.9 3.5 5.5 SO2 (μg/m3) 1,096 12.8 8.6 2.3 4.0 7.2 10.5 15.6 30.5 64.7 O3 (μg/m3) 1,096 69.9 26.6 9.9 28.7 47.0 71.0 90.7 112.0 137.9 Temperature (°C) 1,094 19.0 7.4 -1.8 7.8 13.2 18.0 25.6 30.7 36.4 Relative humidity (%) 1,096 61.6 14.6 24.0 37.0 50.0 63.0 73.0 83.0 91.0 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 PM2.5-10 NO2 CO SO2 O3 Temp. PM10 (μg/m3) 1.00 PM2.5 (μg/m3) 0.70 1.00 PM2.5-10 (μg/m3) 0.88 0.34 1.00 NO2 (μg/m3) 0.44 0.39 0.30 1.00 CO (mg/m3) 0.32 0.18 0.28 0.62 1.00 SO2 (μg/m3) 0.18 0.19 0.05 0.59 0.65 1.00 O3 (μg/m3) -0.03 0.28 -0.20 -0.07 -0.56 -0.28 1.00 Temperature (°C) 0.16 0.37 -0.01 0.02 -0.36 -0.35 0.76 1.00 Relative humidity (%) 0.03 -0.31 0.21 0.10 0.46 0.17 -0.79 -0.74 RH 1.00 Figure 1. PM10. Annual averages Figure 2. PM2.5. Annual averages 60 R1 50 R2 B1 40 SU1 30 SU2 20 SU3 T1 10 T2 0 2007 R1 PM2.5, annual average (μg/m3) PM10, annual average (μg/m3) 60 50 2009 SU1 SU2 20 SU3 T1 10 T2 0 2007 Mean Year B1 30 T3 2008 R2 40 T3 2008 2009 Year Mean R: rural; B: background; SU: Sub-urban; T: traffic Figure 3. NO2. Annual averages Figure 4. CO. Annual averages 3.5 80 60 40 20 0 2007 2008 2009 R1 R2 R3 B1 B2 B3 B4 SU1 SU2 SU3 SU4 T1 T2 T3 T4 T5 CO, annual average (mg/m3) NO2, annual average (μg/m3) 100 3 B2 2 T1 1.5 T2 1 T3 0.5 T4 Mean 0 2007 Mean Year B1 2.5 2008 2009 Year R: rural; B: background; SU: Sub-urban; T: traffic Figure 5. SO2. Annual averages Figure 6. O3. Annual averages 100 R1 25 R2 20 B1 B2 15 SU1 10 T1 5 0 2007 T2 T3 2008 2009 Mean Year R: rural; B: background; SU: Sub-urban; T: traffic NO2, annual average (μg/m3) SO2, annual average (μg/m3) 30 80 60 40 20 0 2007 2008 Year 2009 R1 R2 R3 B1 B2 B3 SU1 SU2 SU3 SU4 T1 T2 T3 T4 Mean BARCELONA (2003-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2003-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1T PM2.5 1T PM2.5-10 1T NO2 1T CO 1T SO2 1T O3 1T PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; T: traffic The monitor is the same for all pollutants, located on the grounds of CSIC venue, influenced by traffic sources of pollution Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) SO2 (μg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 2,669 2,676 2,669 2,381 2,358 2,509 2,544 2,890 2,890 2,890 36.5 23.7 12.8 40.1 0.7 3.1 61.9 14.4 72.3 1,012 17.2 11.6 10.4 17.3 0.4 2.9 28.2 6.3 12.0 7 3.6 1.9 -6.7 1.3 0.2 0.2 1.3 0.0 28.0 981 14.5 9.4 1.4 14.2 0.3 1.0 15.5 4.5 49.0 1,001 24.8 16.0 6.0 27.6 0.4 1.1 40.0 9.4 66.0 1,009 33.9 21.2 10.5 38.8 0.6 2.0 63.7 14.2 74.0 1,013 45.2 28.9 16.9 50.5 0.8 4.2 82.0 19.6 81.0 1,017 95° 68.1 45.7 31.9 71.2 1.4 8.8 106.8 24.1 89.0 1,024 Max 190.3 104.4 123.4 117.6 3.4 36.3 168.4 29.7 97.0 1,033 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) (mg/m3) CO SO2 (μg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1.00 0.81 0.76 0.39 -0.09 0.31 -0.12 0.07 -0.06 0.32 PM2.5 PM2.5-10 1.00 0.23 0.34 -0.07 0.25 -0.19 -0.08 0.21 0.33 1.00 0.27 -0.07 0.25 0.00 0.20 -0.33 0.17 NO2 CO SO2 1.00 -0.14 0.53 -0.40 -0.27 0.05 0.24 1.00 -0.15 0.01 0.28 0.09 0.01 1.00 -0.20 -0.17 -0.14 0.16 O3 Temp. 1.00 0.58 -0.27 -0.12 1.00 -0.12 -0.05 RH Press 1.00 -0.01 1.00 Figure 1. Annual averages of air pollutants Annual average of pollutants (μg/m3) 90 80 70 PM10 60 PM2.5 50 PM2.5-10 40 NO2 30 CO 20 SO2 10 0 2003 O3 2004 2005 2006 2007 2008 2009 2010 Year PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (100*mg/m3) and SO2 (10*μg/m3) BOLOGNA (2006-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2006-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1T PM2.5 1T PM2.5-10 NO2 1B, 1T CO 1T SO2 O3 1B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; B: background; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° 95° Max PM10 (μg/m3) PM2.5 (μg/m3) NO2 (μg/m3) 1,729 1,767 38.4 25.8 21.6 18.5 4.0 2.4 15.0 8.0 24.0 14.0 32.0 20.0 48.0 32.0 81.0 62.0 189.0 168.4 1,792 50.1 18.2 8.7 21.3 37.2 49.6 62.2 80.1 123.6 CO (mg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1,671 1,565 1,782 1,782 1,781 1.0 63.4 14.7 69.3 1,015 0.4 40.9 8.6 16.7 8 0.3 1.3 -8.9 26.7 978 0.5 6.8 1.4 43.6 1,002 0.7 28.8 7.5 55.9 1,010 1.0 59.9 14.7 68.8 1,015 1.2 92.6 21.9 83.1 1,019 1.7 136.1 27.9 95.6 1,028 3.2 206.0 31.8 100.0 1,042 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 NO2 CO PM10 (μg/m3) 1.00 PM2.5 (μg/m3) 0.96 1.00 NO2 (μg/m3) 0.72 0.69 1.00 CO (mg/m3) 0.59 0.56 0.66 1.00 -0.48 -0.46 0.44 0.34 -0.47 -0.47 0.47 0.27 -0.58 -0.65 0.44 0.25 -0.43 -0.48 0.34 0.20 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) O3 Temp. 1.00 0.83 -0.70 -0.10 1.00 -0.66 -0.12 RH Press 1.00 -0.04 1.00 Figure 1. Annual averages of air pollutants Annual average of pollutants (μg/m3) 80 70 60 PM10 50 PM2.5 40 NO2_b 30 NO2_t 20 CO 10 0 2006 O3 2007 2008 2009 2010 Year PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone NO2_b: NO2, background site; NO2_t: NO2, traffic site All pollutants are expressed as μg/m3 with the exception of CO (50*mg/m3) HUELVA (2003-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2003-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1I PM2.5 PM2.5-10 NO2 1I CO 1I SO2 1I O3 1I PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; I: industrial Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° PM10 (μg/m3) NO2 (μg/m3) CO (mg/m3) SO2 (μg/m3) O3 (μg/m3) Temperature (°C) Barometric pressure (hPa) 1,910 2,151 1,518 2,178 2,500 2,922 2,921 40.8 15.4 1.0 7.0 83.6 18.4 993 21.0 11.6 0.2 4.9 23.7 6.0 148 7.9 2.0 0.4 2.0 13.3 0.0 0 18.0 3.4 0.7 2.3 46.4 9.4 1,005 26.2 7.5 0.8 3.5 66.8 13.6 1,012 36.9 12.5 0.9 5.6 83.0 17.8 1,015 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) SO2 (μg/m3) Temperature (°C) Barometric pressure (hPa) PM10 NO2 CO SO2 1.00 0.15 0.04 0.14 1.00 0.22 0.24 1.00 0.07 1.00 0.16 0.32 -0.01 0.05 0.01 0.07 -0.10 -0.20 0.04 0.13 0.03 0.00 O3 Temp. Press 1.00 0.56 -0.02 1.00 -0.15 1.00 50.3 19.9 1.1 8.8 99.8 23.3 1,018 95° 75.9 34.0 1.4 16.6 122.5 28.0 1,025 Max 322.7 112.0 2.9 40.3 178.1 36.2 1,036 Figure 1. Annual averages of air pollutants Annual average of pollutants (μg/m3) 100 90 80 70 60 PM10 50 NO2 40 CO 30 SO2 20 O3 10 0 2003 2004 2005 2006 2007 2008 2009 2010 Year PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (100*mg/m3) and SO2 (10*μg/m3) MADRID (2004-2009) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2004-2009 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 2T PM2.5 1T PM2.5-10 1T NO2 2T CO 2T SO2 2T O3 2T PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) SO2 (μg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1,716 1,685 1,681 1,713 1,724 1,721 1,720 1,735 1,724 1,729 35.1 17.2 17.6 62.7 0.5 13.3 40.4 15.1 51.1 940 20.1 9.7 11.9 26.6 0.4 7.9 21.5 7.7 15.7 6 5.1 1.1 -3.8 12.4 0.1 3.6 3.7 -0.9 19.3 916 12.1 5.8 4.3 27.6 0.2 6.1 8.1 4.2 30.8 931 20.6 10.5 9.5 42.5 0.3 7.9 22.0 8.6 38.3 937 30.3 15.4 15.0 58.8 0.4 10.2 40.4 14.1 48.2 940 44.3 21.8 22.5 78.8 0.7 16.5 56.8 21.8 62.7 944 95° 73.9 35.4 40.0 116.0 1.2 30.7 75.6 27.6 79.7 949 Max 183.8 125.7 127.1 165.6 2.7 52.1 98.3 31.1 100.0 960 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 PM2.5-10 NO2 CO SO2 PM10 (μg/m3) 1.00 PM2.5 (μg/m3) 0.91 1.00 PM2.5-10 (μg/m3) 0.94 0.72 1.00 NO2 (μg/m3) 0.66 0.63 0.57 1.00 CO (mg/m3) 0.55 0.51 0.46 0.82 1.00 SO2 (μg/m3) 0.45 0.38 0.43 0.70 0.79 1.00 -0.35 0.09 -0.02 0.34 -0.31 0.15 -0.05 0.30 -0.29 0.08 -0.05 0.27 -0.67 -0.28 0.18 0.44 -0.71 -0.47 0.31 0.41 -0.69 -0.61 0.36 0.40 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) O3 1.00 0.65 -0.65 -0.32 Temp. RH 1.00 -0.63 -0.04 1.00 -0.06 Press 1.00 Figure 1. Annual averages of air pollutants Annual average of pollutants (μg/m3) 100 PM10_t1 90 PM10_t2 80 PM2.5 70 PM2.5-10 60 NO2_t1 50 NO2_t2 40 CO_t1 30 20 CO_t2 10 SO2_t1 0 2004 SO2_t2 2005 2006 2007 Year 2008 2009 O3_t1 O3_t2 PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (100*mg/m3) and SO2 (5*μg/m3) MARSEILLE (2001-2008) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2001-2008 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 3B, 1T PM2.5 2B PM2.5-10 2B NO2 3B, 3T CO 1T SO2 3B, 2SU, 1T O3 3B, 3SU PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; R: rural; B: background; SU: Sub-urban; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) SO2 (μg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 2,922 2,390 2,130 2,922 2,844 2,917 2,922 2,921 2,922 2,921 29.1 17.6 8.9 49.7 1.7 6.2 80.2 15.6 65.1 1,016 10.7 8.4 5.4 15.8 0.8 5.0 33.6 7.2 12.4 7 5.3 3.0 -20.0 13.2 0.3 0.0 2.4 -1.9 24.6 989 14.5 7.0 2.0 25.7 0.7 0.7 23.2 4.0 45.0 1,005 21.3 11.9 6.0 38.0 1.1 2.4 56.8 10.1 55.4 1,012 27.8 16.0 8.0 48.7 1.6 5.0 81.0 15.7 65.4 1,016 35.3 22.0 12.0 60.3 2.1 8.7 103.4 21.6 75.0 1,020 95° 48.3 33.0 17.0 78.0 3.2 16.0 134.2 26.5 84.3 1,028 Max 115.0 77.0 83.0 103.5 5.2 30.0 191.8 31.7 96.5 1,039 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) (mg/m3) CO SO2 (μg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) PM2.5 PM2.5-10 1.00 0.82 1.00 0.55 0.62 0.41 0.33 0.07 0.11 0.11 0.32 0.06 0.68 0.51 0.33 -0.10 -0.14 0.30 0.39 1.00 0.06 -0.02 0.10 0.24 0.39 -0.22 0.00 NO2 CO SO2 1.00 0.58 0.42 -0.16 -0.24 0.23 0.44 1.00 0.35 -0.43 -0.46 0.42 0.24 1.00 0.03 -0.03 -0.07 0.15 O3 Temp. 1.00 0.75 -0.56 -0.15 1.00 -0.46 -0.16 RH Press. 1.00 0.12 1.00 Figure 1. PM10. Annual averages Figure 2. PM2.5. Annual averages 30 35 30 25 B1 20 B2 15 B3 10 T Mean 5 0 2001 2002 2003 2004 2005 2006 2007 PM2.5, annual average (μg/m3) PM10, annual average (μg/m3) 40 25 20 B1 15 B2 10 Mean 5 0 2001 2008 2002 2003 Year 2004 2005 2006 2007 2008 Year B: background; SU: Sub-urban; T: traffic Figure 3. NO2. Annual averages Figure 4. CO. Annual averages 2.5 90 80 B1 70 60 B2 50 B3 40 T1 30 T2 20 T3 10 0 2001 CO, annual average (mg/m3) NO2, annual average (μg/m3) 100 Mean 2002 2003 2004 2005 2006 2007 2 1.5 1 0.5 0 2001 2008 T, Mean 2002 2003 Year 2004 2005 2006 2007 2008 Year B: background; SU: Sub-urban; T: traffic Figure 5. SO2. Annual averages Figure 6. O3. Annual averages 100 10 B1 8 B2 B3 6 SU1 4 SU2 2 0 2001 T Mean 2002 2003 2004 2005 2006 2007 2008 Year B: background; SU: Sub-urban; T: traffic O3, annual average (μg/m3) SO2, annual average (μg/m3) 12 90 80 B1 70 60 B2 50 B3 40 SU1 30 SU2 20 SU3 10 0 2001 Mean 2002 2003 2004 2005 Year 2006 2007 2008 MILAN (2006-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2006-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1B, 2T PM2.5 1B PM2.5-10 1B NO2 2B, 3T CO 3T O3 1B, 1T PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; R: rural; B: background; SU: Sub-urban; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1,825 1,638 1,637 1,826 1,822 1,810 1,744 699 1,744 46.3 32.9 14.8 60.0 1.5 60.2 13.9 72.7 1,015 31.0 27.1 11.5 23.8 0.7 43.3 8.3 12.9 8 4.9 0.7 -15.5 12.4 0.3 2.0 -4.7 33.7 980 14.9 6.6 1.0 26.4 0.7 6.7 1.1 50.6 1,003 25.3 14.0 7.4 43.5 1.0 18.7 7.1 63.2 1,010 36.2 22.7 13.1 57.8 1.3 55.0 13.8 73.1 1,015 59.1 45.7 19.3 72.9 1.9 92.3 21.0 83.7 1,020 95° 109.9 88.7 34.5 101.1 2.9 136.7 26.7 91.5 1,029 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) PM2.5 PM2.5-10 NO2 CO 1.00 0.96 1.00 0.71 0.78 0.73 0.54 0.76 0.73 1.00 0.55 0.48 1.00 0.81 1.00 -0.51 -0.52 0.48 0.37 -0.57 -0.58 0.52 0.35 -0.18 -0.18 0.24 0.30 -0.59 -0.60 0.35 0.32 -0.67 -0.68 0.46 0.27 O3 Temp. 1.00 0.85 -0.61 -0.11 1.00 -0.61 -0.13 RH Press. 1.00 0.12 1.00 Max 227.1 177.1 99.3 202.1 5.3 201.4 31.8 96.2 1,043 Figure 1. PM10. Annual averages Figure 2. PM2.5. Annual averages 45 50 40 B 30 T1 20 T2 Mean 10 0 2006 2007 2008 2009 PM2.5, annual average (μg/m3) PM10, annual average (μg/m3) 60 40 35 30 25 20 10 5 0 2006 2010 B, Mean 15 2007 2008 2009 2010 Year Year B: background; SU: Sub-urban; T: traffic Figure 3. NO2. Annual averages Figure 4. CO. Annual averages 2.5 80 70 60 B1 50 B2 40 T1 30 T2 20 T3 10 Mean 0 2006 2007 2008 2009 Figure 5. O3. Annual averages O3, annual average (μg/m3) 80 70 60 50 40 B 30 T 20 Mean 10 2008 1.5 T1 T2 1 T3 Mean 0.5 2007 2008 Year B: background; SU: Sub-urban; T: traffic 2007 2 0 2006 2010 Year 0 2006 CO, annual average (mg/m3) NO2, annual average (μg/m3) 90 2009 2010 Year B: background; SU: Sub-urban; T: traffic 2009 2010 MODENA (2008-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2008-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 2B, 1T PM2.5 1B PM2.5-10 1B NO2 2B, 1T CO 1T O3 1B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone; B: background; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1,096 987 987 1,096 1,068 1,070 1,094 1,094 1,094 38.3 21.0 16.0 51.2 0.7 66.4 14.5 65.6 1,006 22.0 14.3 9.2 18.0 0.3 45.9 8.6 18.5 8 2.0 1.0 -1.0 10.5 0.2 2.3 -7.7 24.5 972 14.0 6.0 5.0 24.6 0.3 5.8 1.0 38.4 992 23.0 12.0 10.0 38.1 0.4 22.9 7.6 50.2 1,001 31.7 16.0 14.0 50.6 0.6 64.2 14.4 63.2 1,006 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 PM2.5-10 NO2 CO O3 Temp. PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1.00 0.95 0.78 0.67 0.73 -0.46 -0.46 0.32 0.37 1.00 0.61 0.62 0.69 -0.48 -0.52 0.37 0.26 1.00 0.59 0.56 -0.30 -0.26 0.10 0.33 1.00 0.75 -0.56 -0.59 0.19 0.21 1.00 -0.68 -0.68 0.45 0.18 1.00 0.89 -0.73 0.05 1.00 -0.64 0.01 48.0 27.0 20.5 62.3 0.9 105.9 21.6 82.5 1,010 95° 84.0 52.0 35.0 82.1 1.4 144.6 27.4 94.8 1,018 RH Press. 1.00 -0.16 1.00 Max 131.7 85.0 55.0 131.8 2.0 197.4 30.6 98.9 1,034 Figure 1. Annual averages of air pollutants Annual average of pollutants (μg/m3) 80 PM10_B1 70 PM10_B2 60 PM10_T 50 PM2.5 40 PM2.5-10 30 NO2_B1 20 NO2_B2 10 0 2008 NO2_T 2009 2010 Year PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (50*mg/m3) CO O3 PALERMO (2006-2009) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2006-2009 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 3T PM2.5 PM2.5-10 NO2 3T CO 1B, 1T SO2 1B, 1T O3 1B, 1T PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; B: background; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° 95° Max PM10 (μg/m3) 1415 35.7 17.1 9.9 17.7 25.4 32.4 41.4 63.4 268.5 NO2 (μg/m3) 1457 43.0 14.3 7.7 21.6 33.0 41.3 52.1 67.8 99.9 (mg/m3) 1401 0.7 0.5 0.1 0.2 0.3 0.5 0.9 1.7 4.9 O3 (μg/m3) 1413 70.7 17.2 21.7 42.4 58.6 70.3 83.1 98.2 134.2 SO2 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1409 1,458 1,329 1,337 5.4 18.8 63.7 1,010 7.1 6.0 12.2 6 0.1 4.1 16.0 982 0.5 10.0 44.5 1,000 1.5 13.7 55.7 1,007 3.1 18.3 63.5 1,010 6.3 23.9 72.2 1,014 17.4 28.0 82.7 1,020 92.1 39.5 99.0 1,034 CO Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 NO2 CO O3 SO2 Temp. PM10 (μg/m3) 1.000 NO2 (μg/m3) 0.382 1.000 CO (mg/m3) 0.357 0.565 1.000 O3 (μg/m3) -0.205 -0.210 -0.516 SO2 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 0.284 0.224 -0.096 0.111 0.385 -0.123 0.134 0.371 0.082 0.068 1.000 -0.320 0.329 0.352 0.277 -0.407 -0.258 0.251 -0.199 0.135 RH Press. 1.000 1.000 -0.557 -0.061 1.000 0.084 1.000 Figure 1. PM10. Annual averages Figure 2. NO2. Annual averages T: traffic Figure 3. O3. Annual averages B: background; T: traffic Figure 5. SO2. Annual averages Figure 4. CO. Annual averages PARMA (2008-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2008-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1B, 1T PM2.5 1B PM2.5-10 1B NO2 1B, 1T CO 1B O3 1B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone; B: background; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° 95° Max PM10 (μg/m3) 1091 33.7 18.7 1.0 13.0 21.0 29.0 42.5 70.0 133.0 PM2.5 (μg/m3) 1066 21.0 15.8 0.0 6.0 11.0 15.0 26.0 53.0 106.0 PM2.5-10 (μg/m3) 1062 11.3 8.2 -11.0 0.0 6.0 11.0 15.5 24.0 71.0 NO2 (μg/m3) 1095 38.1 15.6 6.0 16.7 24.8 36.1 49.9 64.8 98.3 CO (mg/m3) 1035 0.88 0.36 0.3 0.45 0.6 0.79 1.13 1.55 2.14 O3 (μg/m3) 1033 1052 1050 1050 68.6 15.3 63.7 1,005 42.9 8.5 19.1 7 3.7 -6.8 21.1 971 7.6 1.5 36.2 992 28.9 8.5 48.0 1,001 70.0 15.2 60.9 1,005 103.5 22.4 80.5 1,009 137.3 27.9 95.9 1,017 183.5 30.7 100.8 1,033 RH Press. Temperature (°C) Relative humidity (%) Barometric pressure (hPa) Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 PM2.5-10 NO2 PM10 (μg/m3) 1.000 PM2.5 (μg/m3) 0.901 1.000 PM2.5-10 (μg/m3) 0.439 0.057 1.000 NO2 (μg/m3) 0.619 0.617 0.027 1.000 CO (mg/m3) 0.598 0.580 0.048 0.851 -0.391 -0.358 0.261 0.359 -0.446 -0.494 0.332 0.328 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) CO O3 Temp. 1.000 0.117 -0.731 -0.696 1.000 0.289 -0.751 -0.681 0.859 -0.059 0.440 0.479 -0.740 0.127 0.118 0.172 0.028 1.000 -0.634 1 0.020 -0.134 1.000 Figure 1. Annual averages of air pollutants Annual average of pollutants (μg/m3) 80 70 PM10_B 60 PM10_T 50 PM25 40 PM25-10 30 NO2_B 20 NO2_T 10 0 2008 CO_B O3_B 2009 2010 Year PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (50*mg/m3) REGGIO EMILIA (2008-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2008-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 2B,1T PM2.5 1B PM2.5-10 1B NO2 2B,1T CO 1T O3 1B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone; B: background; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° 95° Max PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) 1096 1059 1059 1096 1051 35.2 21.5 10.7 40.6 0.94 20.2 14.5 6.4 15.7 0.44 3.3 1.0 0.0 8.2 0.13 13.0 7.0 3.0 19.3 0.31 21.7 12.0 6.0 28.6 0.6 29.3 17.0 9.0 38.4 0.89 42.7 27.0 13.0 50.3 1.23 77.3 52.0 23.0 68.7 1.77 137.3 93.0 50.0 105.7 2.48 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1000 1095 1095 1095 70.5 14.7 66.1 1,006 45.1 8.6 18.3 8 2.0 -7.5 24.1 972 7.3 1.3 38.8 992 29.4 7.8 50.7 1,001 69.9 14.4 64.8 1,006 106.5 21.9 83.1 1,010 147.6 27.7 94.5 1,018 198.3 30.8 99.1 1,034 RH Press. Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM10 (μg/m3) PM2.5 PM2.5-10 NO2 PM2.5 (μg/m3) 1.000 0.955 1.000 PM2.5-10 (μg/m3) 0.764 0.592 1.000 NO2 (μg/m3) 0.651 0.661 0.394 1.000 CO (mg/m3) 0.559 0.538 0.308 0.680 -0.414 -0.404 0.314 0.341 -0.470 -0.487 0.407 0.257 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) CO O3 Temp. 1.000 -0.116 -0.643 -0.566 1.000 -0.055 -0.700 -0.554 0.854 -0.010 0.357 0.349 -0.721 0.305 0.160 0.246 0.022 1.000 -0.616 1 -0.007 -0.148 1.000 Figure 1. Annual averages of air pollutants PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (50*mg/m3) ROME (2006-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2006-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1R,1B,2T PM2.5 1R,1B,1T PM2.5-10 1R,1B,1T CO8H 1R,3B,2T NO2 2B,3T O38H 1R,2B SO2 1R,2B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; R: rural; B: background; SU: Sub-urban; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Pollutant / Meteo Days Mean SD PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) 1,824 1,818 1,816 1,826 1,826 1,825 34.5 19.6 13.2 59.2 1.3 69.2 14.1 10.0 6.9 16.9 0.7 35.2 SO2 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1,457 1,804 1,804 1,804 1.3 15.9 72.3 1,014 0.8 7.0 10.7 7 Min 7.3 0.0 -11.0 11.9 0.2 0.8 5° Percentiles 25° 50 75° 16.6 7.5 4.0 32.5 0.5 12.1 25.0 12.9 8.5 46.1 0.8 40.4 32.0 17.5 12.5 59.5 1.1 72.3 95° Max 40.9 62.7 133.3 24.0 39.5 72.6 16.7 24.5 83.0 70.8 88.1 117.3 1.5 2.8 4.3 95.5 123.9 169.2 0.0 0.4 0.8 1.1 1.7 2.8 5.8 -0.1 5.4 10.4 15.4 21.9 27.3 31.0 33.1 52.3 65.4 73.7 80.6 87.4 97.4 982 1,002 1,010 1,014 1,018 1,026 1,039 Table 3. Pearson correlations between air pollutants and meteorological parameters PM2.5PM10 PM2.5 NO2 CO O3 SO2 Temp. RH Press. 10 PM10 (μg/m3) PM2.5 (μg/m3) PM2.5-10 (μg/m3) NO2 (μg/m3) CO (mg/m3) O3 (μg/m3) SO2 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1.00 0.87 0.68 0.57 0.61 -0.24 0.43 -0.07 0.17 1.00 0.27 0.64 0.68 -0.34 0.39 -0.25 0.20 0.44 0.54 1.00 0.15 1.00 0.18 0.71 1.00 0.08 -0.48 -0.70 1.00 0.29 0.30 0.23 0.11 1.00 0.28 -0.47 -0.55 0.78 0.15 -0.02 0.30 0.44 -0.57 -0.18 0.10 0.34 0.31 -0.04 0.27 1.00 -0.52 1.00 -0.02 -0.12 1.00 Figure 1. PM10. Annual averages Figure 2. PM2.5. Annual averages R: rural; B: background; T: traffic Figure 3. NO2. Annual averages Figure 4. CO. Annual averages R: rural; B: background; T: traffic Figure 5. O3. Annual averages R: rural; B: background; T: traffic Figure 6. SO2. Annual averages THESSALONIKI (2007-2009) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2007-2009 see detail in table 1 daily and hourly values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 1R,2B, 2T PM2.5 1B,1T PM2.5-10 1B,1T NO2 2R,1B,1T,1U O3 2R,1T,1B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: sulphur dioxide; O3: ozone; R: rural; B: background; SU: Sub-urban; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles 25° 50 75° 95° 24.0 14.9 35.3 22.0 44.4 27.7 56.5 34.7 88.2 50.1 164.9 99.3 1.2 6.6 11.3 15.8 22.2 39.0 65.7 15.3 10.4 21.5 32.2 43.6 56.5 69.9 99.9 27.5 7.4 14.6 7 3.1 -1.8 24.0 993 19.7 38.9 56.0 79.2 108.4 141.1 7.8 13.2 18.0 25.6 30.7 36.4 37.0 50.0 63.0 73.0 83.0 91.0 1,006 1,012 1,016 1,020 1,028 1,036 Pollutant / Meteo Days Mean SD Min PM10 (μg/m3) PM2.5 (μg/m3) 1,096 1,096 48.2 29.5 19.6 11.2 10.4 1.9 PM2.5-10 (μg/m3) 1,096 18.1 10.0 NO2 (μg/m3) 1,037 44.5 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1,077 1,096 1,096 1,082 59.5 19.0 61.6 1,016 5° Max Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 PM2.5-10 NO2 PM10 (μg/m3) 1 PM2.5 (μg/m3) 0.95 1.00 PM2.5-10 (μg/m3) 0.93 0.77 1.00 0.62 0.58 0.58 1.00 -0.36 -0.13 0.25 0.21 -0.26 -0.03 0.16 0.20 -0.42 -0.22 0.30 0.19 -0.31 -0.37 0.31 0.23 NO2 (μg/m3) O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) O3 Temp. RH Press. 1.00 0.61 -0.65 -0.27 1.00 -0.75 -0.41 1.00 0.17 1.00 Figure 1. PM10. Annual averages Figure 2. PM2.5. Annual averages R:rural; B: background; T: traffic Figure 3. NO2. Annual averages R: rural; B: background; T: traffic Figure 4. O3. Annual averages TORINO (2008-2010) Study period: Type of monitors used for air pollutants: Type of data (hourly/daily): 2006-2010 see detail in table 1 daily values Table 1. Number and type of monitors used to collect data on air pollutants Pollutant Monitors PM10 2R,1T,1B PM2.5 2R,1B NO2 1T,2B CO 2T,1B SO2 2T O3 1B PM: particulate matter; NO2: nitrogen dioxide; CO: carbon monoxide; SO2: solphur dioxide; O3: ozone; B: background; T: traffic Table 2. Overall description of the air pollutants and meteorological parameters Percentiles Pollutant / Meteo Days Mean SD Min 5° 25° 50 75° 95° Max PM10 (μg/m3) PM2.5 (μg/m3) NO2 (μg/m3) 1795 1692 1826 49.74 34.4 59.8 35.14 28.32 25.24 1.01 4 12.74 13.24 6 26.04 24.59 14 41.27 37.5 24 56.1 66 48 74 CO (mg/m3) 1826 1.04 0.8 0.04 0.06 0.4 0.87 1.5 2.55 4.14 SO2 (mg/m3) 1808 6.62 3.93 1.22 2.39 4.06 5.56 7.98 15.13 25.73 O3 (μg/m3) Temperature (°C) Relative humidity (%) Barometric pressure (hPa) 1686 1714 671 1712 68.56 12.69 63.82 1015.38 46.68 8.03 11.48 7.84 121 242 90 190 105.22 197.93 2.13 6.13 23.88 66.63 104.75 148.63 190.88 -10.36 0.39 5.69 12.85 19.67 24.74 28.4 32.55 44.99 55.83 63.4 72.48 82.23 88.97 981 1002.8 1010.6 1015.3 1020 1029.2 1043.6 Table 3. Pearson correlations between air pollutants and meteorological parameters PM10 PM2.5 NO2 CO SO2 PM10 (μg/m3) 1.00 PM2.5 (μg/m3) 0.96 1.00 NO2 (μg/m3) 0.75 0.73 1.00 (mg/m3) 0.78 0.77 0.80 1.00 SO2 (mg/m3) 0.75 0.75 0.82 0.86 1.00 O3 (μg/m3) -0.62 -0.64 0.14 0.36 -0.63 -0.65 0.13 0.36 -0.55 -0.61 -0.11 0.35 -0.77 -0.80 0.05 0.43 -0.67 -0.73 -0.16 0.34 CO Temperature (°C) Relative humidity (%) Barometric pressure (hPa) Figure 1. Annual averages of air pollutants O3 Temp. RH Press. 1.00 0.87 -0.27 -0.30 1.00 -0.12 -0.30 1.00 -0.08 1.00 PM: particulate matter; NO2: nitrogen dioxide; SO2: solphur dioxide; CO: carbon monoxide; O3: ozone All pollutants are expressed as μg/m3 with the exception of CO (50*mg/m3) Conclusions: The PM10 and NO2 were measured in all the 14 cities, PM2.5 in 12 cities, Pm2.5-10 in 10 cities. SO2 was measured only in 7 cities, while CO2 in 12 cities. The highest concentration of PM10 was measured in Turin (49.7 µg/m3), followed by Thessaloniki (48.2 µg/m3), and the lowest in Marseille (29.1 µg/m3). Also the Pm2.5 was higher in Turin then the other cities. The highest concentration of NO2 was measured in Milano (60 µg/m3), followed by Rome (59.2 µg/m3) and Turin (59.8 µg/m3).