DEPARTMENT OF GEOLOGY Msc. Thesis - Geology 1. HARUNA, AHMED ISAH GEOLOGY, GEOCHEMISTRY AND ORIGIN OF GYPSUM MINERALIZATIO N IN CHAD BASIN (NORTH EASTERN NIGERIA) APRIL, 1998 A field trip was conducted in order to evaluate the geology, geochemistry and origin of gypsum mineralization in Chad Basin part of which is the research area. The gypsum mineralization covered an area of about 2247.75 km2 within the Chad Basin and comprises of five different forms; Detrital, Balatino Laminated, Selenite, SatinSpar, and Alabaster. The thickness of the gypsum forms increases with depth, and they are emplaced at various depths. All the gypsum forms retained traces of former lamination except detrital gypsum therefore lamination is a primary structure. The chemical composition of the gypsum forms showed that they are all high grade (over 70% CaS04.2H2O). The moisture content could be used to show fractured areas where circulation of water is easier. Alabaster gypsum is the heaviest as such more suitable for cement works. The chemical composition of all the gypsum forms revealed high trace elements content which could be the product of the brine mixing phenomenon. The petrographic studies of the Balatino, Selenite, SatinSpar and Alabaster gypsum forms revealed that they all recrystallized from the primary laminations during the early diagenesis. The recrystallization appeared to be perpendicular to the primary laminations. There is dissemination of anhydrite in the matrix of the gypsum forms which shows the effect of incomplete rehydration after upliftment. The origin of gypsum mineralization in Chad Basin is both sedimentary and diagenetic. So, based on high trace element content and primary lamination, a brine mixing hypothesis was proposed for the origin of the gypsum mineralization in the Chad Basin. 2. ISA, MUHAMME D TAHIR PETROLEUM SOURCE ROCK EVALUATION AND PALEOENVIRON MENT OF ASHAKA CEMENT QUARRY GONGILA FORMATION, PART OF GONGOLA BASIN OF THE UPPER BENUE TROUGH, NORTHEASTNIGERIA. APRIL, 1998 A geochemical and micropaleontological study of the argillaceous sequence of Cenomanian-Turonian Gongila Formation from a quarry site located at the Ashaka Cement Company part of Gongola Basin of the Upper Benue Trough was carried out. The main objective of the study was to clarify the type, quantity and thermal maturity of the sedimentary organic matter of the Gongila Formation. The study involved the analysis of shale samples from the quarry site at three different locations. Petroleum source rock characterisation was carried out by a combination of standard geochemical techniques including: Rock-Eval pyrolysis, soxhlet extraction as well as computerised gas chromatography/mass spectrometry of the saturate fractions of the extract for the composition and distribution of suitable hydrocarbon geochemical fossils. The analytical data revealed the abundance of low to intermediate organic rich matter of generally less than optimal maturitystatus for petroleum generation. The presence of monospecific pyritised planktonic foraminiferal fauna served as an indication of waning marine influence accompanied by periodic depletion of oxygen in the seafloor arising from high influx of terrestrial organic matter. The dominance of Heterohelix with a reduced test size and the absence of keel planktonic foraminifera is a clear indication of shallow marine environment in the study area. 3. MAIGARI, ABUBAKAR SADIQ CLAY MINERALOGY AND GEOCHEMISTRY OF THE KERRIKERRI FORMATION, UPPER BENUE TROUGH, N.E NIGERIA APRIL, 1998 The mineralogy and geochemistry of Alkaleri. Dukku, Gombe, Gombe Abba, Kirfi, and Mainamaji clay deposits, from the Palaeocene Kerri-Kerri Formation were studied. In all the samples analysed, the diffractograms obtained showed that kaolinite was the dominant clay mineral while chlorite, vermiculite, illite, and montmorillonite were present only in trace amounts. Quartz and feldspar were the dominant non- clay minerals with subordinate amount of mica and goethite. The avearge chemical composition of all the clay deposits showed significant amount of SiO2 and A12O3 while Fe2 O3, TiO2, MnO, MgO, CaO, K2O, Na2O and P2O6 values were relatively low. Comparison with the mineralogical composition of internationally recognised kaolinite deposits showed that the Dukku clay has Further investigations be carried out on the KerriKerri formation clay deposits to determine the accurate reserves of the deposits as well as other detailed characteristics for the purpose of their development and exploitation to meet industrial requirements. chemical composition similar to that of China and agricultural clays characterised by moderate silica and high alumina content with moderate fluxing elements. On the other hand, the Gombe and Gombe Abba clays showed chemical characteristics similar to the St. Louis fire clay characterised by very high silica and moderate alumina contents, while Alkaleri clays were chemically similar to agricultural clays with moderate silica and alumina contents. 4. MAMMAN, YUSUF DABARI FORAMINIFERAL APRIL, BIOSTRATIGRAP 1998 HY AND PALEOECOLOGY OF THE DUKUL FORMATION, UPPER BENUE TROUGH, NORTHEASTERN NIGERIA Lithological and microfaunal (foraminifera and ostracods) studies of the Dukul formation were carried out from three 3 outcrop sections around Lakun village, within the Dadiya syncline, Yola arm of the Upper Benue Trough, Nigeria. A total of 29 shale samples from 3 outcrop sections were analysed for their microfossils. Lithological studies showed that the formation comprises of black shales interbedded within grey marls, mud stones and biomicritic limestones. The foraminifera microfaunas from the 3 sections comprised of 17 species and 10 genera, while the ostracod microfauna comprises of 7 species and 6 genera. The most predominant foraminiferal microfaunas from the 3 sections are agglutinated benthics (Haplophragmoides spp, Trochammina spp. and Ammobaculites spp). In section 1sample1 (black shale), over 6000 individuals of monospecific planktonic foraminifera (99% Heterohelix) were recovered which represent 99% of the total foraminifera from that section. Plantonic foraminifera recovered from the 3 sections are Heterohelix globulosa and Hedbergella spp. The Ostracod assembleges are Brachycyrhere sapucariensis, Ovocytheridea apiformis, Ovocytheridea symmetrica, Cytherella comanchensis, Krithe spp and Cytheropteron spp. The most predominant ostracod genera are Cytherella and Ovocytheridea. Foraminifera and ostracod microfaunas recovered from black shale in sample I, section 1 showed a pyritizsd test. Preliminary organic geochemical Studies of the black shales indicated high Total Organic Carbon (TOC 1.71% wt) with optimum maturity of Tmax 4360C and HI 35.1. From foraminifera and ostracods assemblages, the formation is Lower Turonian in age. The presence of high population of monospecific planktonics, black laminated pyritized shale, paucity of benthics and high TOC indicate that the shale unit at the bottom of section 1 may have been deposited under anoxic conditions in an open marine (inner to middle shelf) environment. 5. ABUBAKAR, MUHAMMA D BELLO PGS/97CENOMANIAN98/403003 TURONIAN ANOXIC EVENT AND POTENTIAL PETROLEUM SOURCE ROCKS OF THE UPPER BENUE TROUGH, NIGERIA FEBRU ARY, 2001 Predominantly planktonic foraminiferal-rich horizons within the Cenomanian - Turonian boundary, inferred from ammonite, have been identified in the Cenomanian - Turonian sequences of the Upper Benue Trough. The planktonic/benthonic ratios in these horizons range from 0 - 95% with values between 80 - 90% more frequent. These ratios point to very rapid changes in water depth between inner shelf to lower bathyal which is very unlikely. The recovered planktonic foraminifera are non-keeled morphogroups represented by heterohelicids, globigerina-like hedbergellids and few guembelitricids. These are believed to be shallow water dwellers that tolerated anoxic conditions. The abundance of non-keeled planktonic foraminifera in the Cenomanian Turonian sequences of the Upper Benue Trough and the lack of incipiently keeled forms, therefore indicate shallow water and/or raise oxygen minimun zone. The paucity of the benthonic foraminifera in general and calcareous forms in particular, and the preponderance of the planktonic taxa are therefore 6. EKWO, EDWIN OCHENI PGS/97PETROGRAPHY FEBRU 98/403004 AND RESERVOIR ARY, POTENTIAL OF 2001 GONGILA FORMATION LIMESTONE AT THE ASHAKA CEMENT QUARRY, GONGOLA BASIN, UPPER BENUE TROUGH NORTHEAST, NIGERIA attributed to oceanic anoxia which correlates well with the global Cenomanian -Turonian Oceanic Anoxic Event (CTOAE). In such environments, bottom water masses are depleted in oxygen and consequently cannot support the residence of bottom feeders and benthic scavengers. Organic matter in sediments deposited in anoxic water is commonly more abundant, better preserved and more lipid rich, hence usually better hydrocarbon source rock than those deposited under oxygenated condition. The reservoir potentials of the Upper Cenomanian to Middle Turonian Gongila Formation at the Ashaka Cement quarry was investigated based on petrographic study. The formation represents a transgressive sequence with smaller lithostratigraphic units made up of basal limestone and marly limestone, which are overlain by black shales with thin limestone layers. Petrographic analyses of the limestone samples indicate depositional textural variations from fossiliferous micrite (mudstone) through skeletal wackestone and packstone with peloids and dolomites in places. Thin section results indicate that the limestones have undergone both syndepositional, early and late diagentic alterations such as micritization, cementation and compaction, dissolution, recrystallization and dolomitization. This sequence of the diagenetic alteration influenced the porosity as well as the quality and development of the reservoir facies. Packstone and skeletal wackestone lithofacies have better reservoir characteristics than the mudstone lithofacies. The fair to good porosity estimates in these lithofacies account for the 7. YANGO, NELSON SEBRE PGS/97DEPOSITIONAL 98/403001 ENVIRONMENTS AND RESERVOIR PROPERTIES OF THE GOMBE SANDSTONE, UPPER BENUE TROUGH, NORTH EASTERN NIGERIA FEBRU ARY, 2001 8. EZE, BONIFACE CHINERO PGS/2000 SEDIMENTOLOG DECEM Y AND BER, 2002/4030 PALAEOENVIRON 2002 intermediate to enhanced reservoir characterization. The Gombe Sandstone is the most top most unit of the cretaceous sediments in the Gongola arm of the upper Benue Trough. It is underlain by the marine Pindiga formation and overlain by the Tertiary Kerrikerri formation. The Gombe sandstone consists of mudstones, ironstones, siltstones, shales sandstones and clays. Field studies and laboratory analyses were conducted to determine their provenance, depositional environments and reservoir properties. Based on the paleoenvironmental diagnostic characteristics; the lithofacies, sedimentary structures, ichnofossils and petrology; an estuarine and deltaic depositional environments have been recognized. Fluvial (distributary channel) and paralic (interdistributary channel) environments have also been identified. The sandstones are fine (2.40 – 2.80Փ), medium (1.03 – 1.87Փ) and coarse (0.30 – 0.85Փ) grained, with the fine – grained dominating. They are poorly (2.60Փ) to moderately well sorted (0.60Փ); mostly leptokurtic, fine skewed and bimodal in distribution, thus indicating more than a single source. The subangularity of some of the grains, presence of large feldspar grains, and the preponderance of stable heavy minerals (ZTR) suggest both igneous/metamorphic and recycled sediment sources for the Gombe sandstone. The distributary channel sandstone facies could constitute the major reservoir of the Gombe sandstones. The Early Turonian Dukul Formation in the Yola Basin consists part of the Late Cenomanian-Turonian marine sequence in the Dadiya Syncline and comprises shales interbedded with thin limestones. Petrographic studies of 9. UZOEGBU, MMADUAB UCHI UCHE 15 MENT OF THE CRETACEOUS DUKUL FORMATION IN THE YOLA ARM OF THE UPPER BENUE TROUGH, NORTH-EAST, NIGERIA PGS/2000 2001/4030 24 ORGANIC GEOCHEMISTRY AND PALEOENVIRON MENT OF CRETACEOUS DUKUL FORMATION, UPPER BENUE TROUGH, NIGERIA the limestones indicate various lithofacies which grade from bioclastic- packstone ill the basal units through bioclastic wackestone-packstone, bioclastic-wackestone and mudstones upwards. Diagenetic alteration affected the different lithofacies by differential dissolution of bioclastic fossil fragments, precipitation of calcite and dolomite cements, and development of porosity types such as intercrystalline, moldic and vuggy. These porosities are economically significant as they have produced moderate to high quality reserviors. The lithofacies, physical sedimentary structures and macrofossil such as bivalves, mulluscs and ostracods gastropods suggest shallow marine setting on a carbonate platform. Foraminiferal assemblages recovered were predominantly of arenaceous benthonic agglutinated forms: Ammobaculites sp., Haplophragmoides sp, and Ammotium sp. all of which indicate a shallow marine anoxic environment. A few non-keeled planktonic foraminifers such as Heterohelix sp, were recovered vhich indicate a similar environment. Generally, sedimentologic and biostratigraphic features of the Dukul Formation indicate deposition on a low energy, shallow water carbonates platform in an open marine to lagoonal environment. JANUA RY, 2003 Rock-eval pyrolysis, organic petrographic techniques and microfaunal studies (foraminifers and ostracods) of the Dukul Formation were carried out from 7 outcrop sections around Lakun Village, within the Dadiya Syncline, Yola arm of the Upper Benue Trough, Nigeria. The TOC values for the source rock intervals of the Dukul Formation range from 0.34 to 0.91%. The average TOC value of 0.56% for the Dukul shales indicates low concentration of organic matter. The genetic potentials of all the samples yield less than 10. TUKUR, AMADU PGS/2000 2001/4030 18 HYDROCARBONGENERATIVE POTENTIAL OF CRETACEOUS COALS FROM THE BENUE TROUGH (NIGERIA) SEPTE MBER, 2003 2,OOOppm of hydrocarbons indicating poor potential for generating commercial amount of hydrocarbons. Rock-eval data indicate the prevalence of terrestrially derived type III kerogen implying their potential to generate gas. Tmax values from the pyrolysis of the shales of the Dukul Formation range from 429 to 436°C with an average of 432°C. This value corresponds to maturity level within the oil window. The foraminiferal microfaunas from the 7 sections comprise both planktonic and benthonic taxa which are Heterohelix sp., Haplophragmoides sp., Ammotium sp., and Ammobaculites sp. The ostracod assemblages comprise Brachycytheridea sp., Ovocytheridea sp., Cytherella sp., Cythereis sp. and Rostrocytherida sp ., The predominant genera are Cytherella and Ovocytheridea. From foraminiferal and ostracod assemblages, the formation is Early Turonian in age. The presence of large numbers of planktonics,the paucity of benthics and moderate TOC values indicate that the share unit at the outcrop sections may have been deposited under anoxic conditions in an open marine (inner to middle shelf) environment. Rock-Eval pyrolysis has been widely accepted as a standard method of analyzing sedimentary rocks especially coals for hydrocarbon prospectiveness. This method was used to analyse twenty –one coal samples from the Benue Trough of Nigeria: four samples from the Mamu Formation; fourteen samples from the Agwu Formation; two samples from the Lamja Sandstone and one sample from the Gombe Sandstone (lower, middle and upper Benue Trough respectively). The four samples from the Mamu Formation have an average TOC of 44.03 wt%, an average SI of 2.14 mg/g, an average S2 of 133 mg/g and an average Tmax of 431°C. The hydrogen indices (HI) are very high, ranging from 266 mgHC/gTOC to 327 mgHC/gTOC. The mean HI from S2 VS. TOC plot is about 363 (r2=O.9877) mgHC/gTOC. This figure places these coals into type II organic matter that can generate oil and gas. The T max values suggest an on set of oil generation. The fourteen samples from the Awgu Formation have an average TOC of 46.23 wt%, SI of 172 mg/g and Tmax of 4520C. Awgu 1, Awgu 6 and Awgu 7 show exceptionally low HI, low SI and low S2 but the Tmax values for these samples fall within the optimal temperature for hydrocarbon generation. HI for the rest of the samples ranges from 1.20 to 267 mgHC/gTOC. All the samples from the Awgu Formation have an average HI of 280 mgHC/gTOC from S2 vs. TOC diagram. But on HI vs. 10plot, the samples plotted on all the organic matter types' tracks. The HI value of 182 mgHC/gTOC from S2 vs. TOC plot implies that coals from the Upper Benue Trough have type III organic matter with gas and oil source potential. The Tmax of 438°C indicates that the samples from the Lamja Sandstone are within early to middle oil window. While the Tmax of 4230C from the sample of the Gombe Sandstone implies immaturity. 11 KWAYA, PGS/2000 TUMBA JIBA 2001/4030 22 PETROLEUM SOURCE ROCK EVALUATION OF THE DUKUL JULY, 2003 Rock Eval pyrolysis data combined with biomarker studies have been carried out to determine the petroleum source potential of the Cenomanian - Turonian Dukul Formation, Upper Benue Trough, Northeastern Nigeria. Foraminiferal analysis was also carried out in order to investigate the various paleoenvironments of the formation. TOC values range from 0.33 - 0.93wt%, with average of 0.56wt% indicating moderate content of organic matter. Thermal maturity (Tmax) ranges from 429 - 436°C, thus indicating transitionally early mature early to peak oil window. Based on Hydrogen indices (HI), the organic matter of the formation is mainly type III (HI<250). From the graphs of HI vs 0I and of T max vs HI it is evident that organic matter of the Dukul Formation is generally gas-prone. The presence of agglutinated foraminifers with only a few planktonic taxa (Heterohelix), indicates a brackish-shallow marine environment where anoxic conditions prevailed. The organic matter is of mixed origin (continental and marine). This is possible, where continental deposits were deposited in the marine environment through fluvial systems. The petroleum source potential of the organic matter of the Cenomanian-Turonian Dukul Formation can therefore be interpreted to be moderate. FORMATION UPPER BENUE TROUGH, NORTHEASTERN NIGERIA. 12. HARUNA, ISMAILA VELA PGS/2000 2001/4030 28 TRACE METAL CONTENT IN NEAR BANK SEDIMENTS OF THE DASS AREA, N.E NIGERIA APRIL, 2004 A detailed and systematic geochemical investigation utilising near bank sediments as sample medium was conducted around Dass. The aim was three fold: one, to relate the geochemical composition of recent near bank sediments on a number of catchments to a broadly defined bedrock lithology and two, to provide information on trace metal content in near bank sediments that may reflect their concentration in the associated waters and thirdly, to provide baseline data bank for future environmental studies including possible anomalous heavy metal contents in near bank sediments which may reflect in associated surface and underground waters. To achieve this, a total of 114 coarse and fine near bank sediments samples were collected over an area of 247km2. The coarse samples were subjected to 13. YAMBIU, IDRIS BUBA PGS/2000 2001/4030 21 DEPOSITIONAL ENVIRONMENTS, PETROGRAPHY AND RESERVOIR EVALUATION OF THE CAMPANOMAASTRICHTIAN GOMBE SANDSTONE IN THE GOMBE AREA, UPPER BENUE TROUGH, NORTH EASTERN NIGERIA. AUGUS T, 2004 visual mineral identification while the fine samples were treated with cold and hot HN03 and analysed for Pb, Cu, Co, Cd, Cr, Zn, Au, Mn, Mg, Ca, Fe and K. Descriptive statistical methods together with mono- and multi- element geochemical maps were employed in the interpretation of the resultant geochemical data. The various interpretative techniques together point to a granitic Iterrain with high mineral potentials in the localities along the western flank of the area. These mineral include: amethyst, tourmaline, aquamarine and beryl. The flank also represents a geochemical hot spot for anomalously high heavy metal content that are due to metal-rich rocks. Low proportions of the metals in non-residual phase of the sediments, indicated by the ratio of hxMe to cxMe, however, suggest low or normal concentrations in the associated water columns. Sandstones (25 samples) from the Gombe Sandstone were subjected to granulometric analysis. Textural parameters computed from sieving include: graphic mean grain size, standard deviation (sorting), skewness, kurtosis and median. Total averages (Փ) of these textural parameters are 2.55Փ, 1.17Փ, 0.25Փ, 1.00Փ and 2.25Փ respectively. Bivariate Scatter plots of mean vs. first percentile, standard deviation vs. first percentile, standard deviation vs. mean, standard deviation vs. Skewness and C-M pattern, suggest a dominance of fluvial processes for the Gombe Sandstone in the area studied. Petrographic analysis has defined the Gombe Sandstones to be quartzwackes- subarkoses, which are both texturally and compositionally immature. The Gombe Sandstone is composed of sandstones, siltstones, mudstones, shales, minor ironstones (ferruginised siltstones) and minor limestones. Palaeocurrent analysis shows south southeasterly and north northeasterly sources, unidirectional (280°) current system with a unimodal distribution. Some histograms show bimodality indicating more than one source area. From environmental synthesis, the Gombe Sandstones is interpreted to be deposited in shallow marine, lacustrine delta and fluvial (braided river) systems. The lacustrine delta system, however, is influenced mainly by fluvial processes, as shown by univariate grain size parameters and bivariate scatter plots. Reservoir evaluation has indicated that sandstones of the delta front, delta plain and braided river deposits constitute the most probable reservoir of the formation. Petrophysical attributes (porosity and permeability) of the formation are in the range of 19-25% and 0.1-0.2 D (l00-200 mD) respectively. 14. VALDON, YUNIS BOGA PGS/2000 2001/4030 17 SEDIMENTOLOG Y AND DEPOSITIONAL ENVRONMENTS OF THE KERRI KERRI FORMATION IN THE DUGURI AREA, GONGOLA BASIN, N.E NIGERIA AUGUS T, 2004 The present work deals with the sedimentological and paleoenvironmental studies of the Kerri Kerri Formation around Duguri and environs. The formation is composed of flat-lying to gently dipping coarse sandstones, ferruginised sandstones, siltstones and mudstones based on the six lithostratigraphic sections studied. The sandstones which constitute the major part of the formation are fine to very coarse-grained, moderately to poorly sorted, mostly of bimodal patterns, negatively skewed to positively skewed, and vary from platykurtic to very leptokurtic. The grain size parameters and their bivariate relations indicate the environment of deposition of the formation to be fluviatile in origin. The subangular to angular grain shape shows that the Kerri Kerri Formation was deposited due to fluvial processes. The More studies is hereby recommended in order to define the various depositional environments in he area. Studies on the kaolinitic deposits encountered in the area is necessary to evaluate its genesis, quality and commercial viability. few sub-rounded grains observed may have come from a reworked source. The paleocurrent analysis indicates that these sandstones were deposited by unimodal, southeasterly-flowing currents. 15. CHAANDA, MOHAMME D SULEIMAN PGS/2000 2001/4030 20 ENVIRONMENTA APRIL, L 2004 GEOCHEMISTRY OF THE TIN MINING DISTRICT OF TILDEN FULANI, NORTHEASTERN NIGERIA. Stream sediment and water samples from wells, streams and mining ponds were analysed. The samples were analysed for the elements Cu, Pb, Zn, and Cd, within the Tilden Fulani Mining District, with the aim of determining their concentration in both water and stream sediments to highlight their impact on the environment, and serve as reconnaissance work. In all seventy six stream sediment samples were obtained from the area of study, air dried, sieved to - 75 μm digested with cold HN03 acid while 54 water samples were also obtained, ionized with 1% HN03 and analysed using the Atomic Absorption Spectrophotometer (AAS). The results obtained indicate that of all the elements analyzed, only Cd was observed to have high concentration in stream sediments in all parts of the study area. The high concentration of Cd could be due to both natural and anthropogenic activities. The water samples reveal that the metalliferous ions were within the World Health Organisation standard except for Fe, Pb and Cd with high concentration values above the WHO standard. This could be regarded as a potential source of contamination to the surrounding water systems, though at the moment the waters used by residents of this area may be regarded to be safe. It is therefore recommended that further work be carried out to cover the entire area in order to monitor the concentration level of these elements in the environment, enforce mining laws to check the 16. TIMOTHY, PETER BATA PGS/2000 2001/4030 29 PETROGRAPHIC AND SEDIMENTOLOGI C STUDIES OF THE PALEOGENE KERRI-KERRI FORMATION AROUND MAINAMAJI, BAUCHI STATE UPPER BENUE TROUGH. FEBRU ARY, 2004 17. ELIJAH, HAMANDA EZEKIEL PGS/2001 2002/4030 35 A STUDY OF SEPTE TRACE METALS MBER, DISPERSION IN 2005 JOS-BUKURU MINING DISTRICT AND IT’S IMPLICATION ON THE ENVIRONMENT abuse of land use and treat water used for consumption. The Palaeogene Kerri-Kerri Formation is composed of flat-lying to gently dipping basal conglomerates, grits, sandstones, siltstones and mudstones. The formation represents the record of Early Cenozoic sedimentation in the Upper Benue Trough. The Kerri-Kerri Formation around Mainamaji consists of three main lithofacies: a mudstone-claystone facies; a siltstone facies; and a sandstone facies. Facies/sedimentologic examination revealed that sands of the Kerri- Kerri Formation around Mainamaji were deposited in a fluvial setting, at low river stage when the materials held in suspension were deposited along with the coarser materials. This is responsible for the high matrix content of the formation. Petrographic examination of thin sections revealed that the Kerri- Kerri Formation is at both redoxomorphic and locomorphic stages of diagenesis, as revealed by quartz with silica overgrowths and authigenic kaolinites as void fillers. The alteration of feldspars to kaolinite has created a grain matrix ratio different from that of the original sediments with a decrease in its textural maturity. The concentration of trace metals (Cd, Cr, Co, Cu, Fe, Pb, and Ni) in soil, stream sediments, mine dump, water and tailing samples from the Jos Bukuru mining area have been determined with the specific objectives of evaluating contamination level in soil and water. In all forty-five (45) samples were obtained from soil, stream sediments, mine dumps, water and ore tailing. All samples were collected, stored in labeled polythene bags and plastic It is recommended that a detailed sedimentogic work be carried out on the outcrops of the KerriKerri Formation in other areas, so as to construct a regional sedimentologic model and a petrographic statement. Further diagenetic history of the formation should be further investigated on a regional base, in order to fully understand the genesis of the kaolinite encountered in the area. 1. Further studies should be undertaken to thoroughly evaluate the level of trace metal contamination in water, soil, stream sediments and air of the Jos-Bukuru mining district. 2. There may be some containers. Water samples were acidified with HN03 acid to prevent loss of metals. All samples were analyzed using the atomic absorption spectrometer (AAS). Ranges of concentrations obtained for the trace metals examined in the Jos- Bukuru mining area indicated the following order of dominance; soil: Fe> Pb> Cu = Ni > Co > Cr> Cd; stream sediments: Fe> Pb > Ni > Co> Cr > Cu > Cd; mine dump: Fe> Pb > Ni > Cu > Co > Cr > Cd; tailings: Pb > Fe > Cu > Co > Ni > Cr > Cd; and water: Fe> Ni = Co > Pb > Cr > Cu > Cd. Concentrations of trace metals analyzed for this study show that the range for soil falls below average concentration in soils and clay. The concentration of Co, Pb, and Ni in water fall above W.H.O recommended water levels. The high concentrations of these metals in water bodies of the Jos - Bukuru mining area is believed to be due to mining and mineral- processing activities in the study area and these may cause health problems. Other sources of these metals in the media analyzed include the bedrock (Granites) but contribution from this source is considered to be minimal considering the mineralogy of the rocks. 18. TANKO, PGS/2001 GEOCHEMICAL SEPTE Geochemical analysis using X-Ray fluorescence diseases that could be linked to the concentration of trace metals investigated in the study area. Therefore, further collaborative studies with medical doctors; agriculturists and other specialists are to be conducted to find a correlation between trace elements and epidemiological abnormalities: 3. Geochemical informations be supplied to farmers and communities since deficiency can be as damaging as excess. For example, soil deficient in copper (less than 1 ppm) or vegetation ash (less than 25 ppm) caused unhealthy births in animals (Warren 1961). 4.Such studies to be conducted on vegetables like Cabbage, Lettuce, Carrot, farmed on the Plateau. YA’U ISHAK EXPLORATION 2002/4030 FOR MINERALS 37 IN SOME MINING DISTRICTS AROUND KEFFI, NORTH CENTRAL NIGERIA (NASARAWA STATE) MBER, 2005 spectrometry (XRF) was carried out on 97 samples collected from mining districts around Keffi area. 58 samples are soils, while 39 are stream sediments (20 samples from River Andu and 19 samples from Angwan Mayo River). The samples were analyzed for Sn, Nb, Ta, W, Li, Be, Rb and Zr to determine the levels of metal abundance in the two sample media, with the aim of establishing potentials for mineralization in the area. The results revealed mostly normal background concentrations (populations) in most of the samples but the average concentrations of the trace-elements in the study area are higher than the average normal concentrations in soil, provided in (Rose et aI, 1979 and Siegel,1974) which is pointing to possible potential of mineralization in the study area. The anomalous concentrations of trace-elements and indicator-elements around pegmatites in the area revealed the relationship between the host rocks (migmatites and schists) and the mineralization bodies (pegmatites and granitic rocks). The average concentrations in (ppm) of the main elements association (Sn, Nb,Ta, W) and indicator elements (Li, Be, Rb and Zr) around unexploited pegmatites in Angwan Mayo, Andu and Sabon gida villages are as follows; Soil samples 58.01 ppmSn, 79.21 ppmNb, 38.67ppmTa, 92.61ppmW, 73.8IppmLi, 2.21ppmBe, 165.89ppmRb and 422.84ppmZr. Stream sediment samples (River Andu) 60.78 ppm Sn, 62.28 ppmNb, 49.00 ppm Ta, 89.5 ppm W, 2.92 ppm, 86.78 ppm Li, 3.95 ppm, 3.95 ppm Be, 212.00ppm Rb and 500.55 ppm Zr. Stream sediment samples (Angwan Mayo River) 93.97 ppm Sn, 60.29 19. MOHAMME D, AUDU DAYA PGS/2001 2002/4030 38 AN INVESTIGATION OF ECONOMIC POTENTIALS OF MAGNESITE IN THE TSAKASIMTA AREA, ADAMAWA STATE. 20. SHETTIMA, BUKAR PGS/2001 SEDIMENTOLOG Y AND 2002/4030 RECONSTRUCTIO SEPTE MBER, 2005 SEPTE MBER, 2005 ppm Nb, 48.18 ppm Ta, 92.40 ppm W, 92.37 ppm Li, 4.35 ppm Be, 198.18 ppm Rb and 487.66 ppm Zr. These results give an indication that a more detailed study will lead to the discovery of ore deposits in the area. The study area is located in topographic Shani NE sheet 154NE in Gombi Local Government Area of Adamawa State. Reconnaissance Survey of the area was carried out. Detailed geologic map of the deposit was produced. Forty-five (45) pits were excavated on a grid pattern of 100m x 100m. Samples were collected from each pit where magnesite occurred. The magnesite was probably formed as a result of continuous alteration of the ultra basic rocks, (olivine rich basalt and gabbros) by the action of carbonated hydrothermal fluids. Chemical analysis of the magnesite samples were carried out using X-ray fluorescence (XRF) method. The samples were analysed for the percentage oxides of these elements, Si02, MgO, MnO, Fe203, A1203, CaO, Ti02 and K20. The result of this analysis shows that there is marked correlation between Si02 and MgO (where the value of Si02 is high, that of MgO is low, and vice-versa). The weighted average chemical value of MgO is 35.80%. This value of MgO shows that the magnesite is of good quality. The total mineable reserve of the magnesite has been estimated to be 523, 179.60 metric tones. The deposit is very shallow with flat terrain, so that the whole reserve could be mined by open cast method. The Yolde Formation is composed of sandstone, siltstones, mudstones claystones, shales and minor limestone and under petrographic analysis is defined 21. DAUDA, IDRIS FIKA 39 N OF DEPOSITIONAL ENVIRONMENTS OF THE YOLDE FORMATION IN THE GONGOLA ARM OF THE UPPER BENUE TROUGH, NIGERIA. PGS/1999 2000/4030 13 POSSIBILITIES FOR HYDROCARBONTRAPPING STRUCTURES IN THE CRETACEOUS GONGOLA BASIN SEPTE MBER, 2006 to be subarkose to quartzarenite, which texturally and compositionally range from submature to mature. From the fining upwards, and coarsening upwards cycles diagnosed in the lithostratigraphic sections, fluvial and deltaic distributary and mouth bars are respectively suggested. The sedimentological studies from granulometric analysis of the textural parameters which include: graphic mean size, standard deviation (sorting), skewness and kurtosis, and the total average of these textural parameters are: 2.21Ø 1.02 Ø, 0.37 and 1.29 respectively. Most of the bivariate plots indicated dominance of fluvial environments, however, one indicated dominance of coastal environment. The probability curve plots is dominated by two sand populations curves indicating prevalence of unidirectional currents. Paleocurrent analysis shows a dominant northeasterly source and minor northwesterly source, and the Yolde Formation was interpreted to be deposited in a fluvial (braided river) to transitional (deltaic, barrier island and coastal plain of alluviation) environments. Evaluation of structures resulting from deformation and stratigraphic relationship, mainly faults, folds and unconformities exposed in outcrop sections, was carried out in the Gombe area of the Gongola Basin, Upper Benue Trough, with a view to predict possible hydrocarbon trapping structures at depth. In addition to the main Gombe fault, field observations show the existence of two other normal faults, one in the western part of Gombe environs that seems syndepositional with Gombe Sandstone and the other in a tributary of the Arowa stream (Bima Sandstone). Several strike-slip/shear faults mostly exposed along river channels with a general NWSE trend are very conspicuous in the field. Two separate sets were identified, with the younger sets generally trending 3000 to 3600 cutting the older sets generally trending 1800 to 2400. Other structures observed include part of an anticline with crestal faults in Kware stream, an anticline in the Arowa stream, an angular/intraformational unconformity, channel fills with bar sedimentation and a minor shale diapir. The general stratigraphy of the basin, comprising sandstones and shales horizons that may likely form the reservoirs and source rocks and seal facies respectively and the existence of faults, folds, unconformities and other stratigraphic features with favourable closures) are factors making the Gongola Basin worthy of hydrocarbon exploration. 22. MELA, VICTOR PGS/2001 2002/4030 31 PETROGRAPHY FEBRU AND ARY, PALAEOENVIRON 2007 MENT OF THE PINDIGA FORMATION (KANAWA MEMBER) IN THE GONGOLA BASIN, NIGERIA The Upper Cenomanian to Lower Turonian Pindiga Formation (Kanawa Member) consists of a shale succession with interbedded limestones. Petrographics studies of the limestones indicate various lithofacies which include packstone (packed biomicrite) wackestone (sparse biomicrite) and mudstones (micrite). Diagenetic changes such as neomophism, calcitization, dissolution and micritization have affected the different lithofacies, most of these changes have modified primary sediment textures, original fabrics and other limestones components. Petrographic and palaeoenvironment evidence suggest that these microfacies were deposited in relatively low energy open marine to quite water lagoonal environments. Foraminiferal assemblages recovered were predominantly composed of arenaceous benthonic agglutinated forms: for example Ammobaculites sp. Haplaphragmoides sp, and Ammotium sp, all of which indicate a shallow marine environment. A few non-keeled planktonic foraminifers such as Heterohelix, and Guembelitria, were recovered which indicate a similar environment. Generally, sedimentologic and biostratigraphic features of the Kanawa Member indicate deposition on a low energy, shallow water muddy ramp, which occasionally and briefly become tolerable for carbonate- secreting organism. 23. ALUWONG, KUSHAI CALEB PGS/2004 2005/4030 40 APPLICATION OF REMOTE SENSING AND GIS IN GEOLOGICAL MAPPING AND MINERAL PROSPECTING OF TORO AND ENVIRONS (BAUCHI STATE) AUGUS T, 2008 Remote sensing and Geographic Information System (GIS) application was carried out in the Geological Mapping and Mineral prospecting of Toro and Environs, Bauchi State. The objectives of this work were to attempt the utilization of spectral reflectance properties of surface processes due to mineralization to map out the Geological boundaries using Landsat ETM data. To use the information generated to produce maps that will be useful as exploration guide and to also delineate mineralized boundaries and potential for ore body occurrences in the area. The study focused on image processing and 24. NNAJI, CHIGBOGU EZECHIMEL U SUNDAY PGS/2004 2005/4030 46 DEPOSITIONAL ENVIRONMENTS OF THE BASAL MEMBER OF KERRI-KERRI FORMATION, MAY, 2008 digitization of existing images to correlation information as well as ground truthing to confirm results. The geological map produced indicating the following rock types; Undifferentiated Basement Complex, Porphyritic Biotite Granite, Biotite Granite, Newer Basalts and Dyke Swamps. Tectonic mapping showed that structures generally trend NE-SW and NWSE in line with the principal fracture direction on the Basement Complex. The rivers and vegetation of Toro and Environs are generally structurally controlled. The results revealed the importance of image processing which was carried out In the following order; Image Enhancement, Clustering/Classification, Supervised classification, Image ratio, Tectonic mapping approach, Vegetation (Geobotanical) and Digital Terrain Modeling. Economic mineral potential zone of the Toro and Environs include Dogo Daji, Dutse Moro, Panshanu others are Juga, Buri, Leru and Jarawan Kogi. Economic minerals found within Toro and Environs are Cassiterite, Topaz, Aqua marine, Zircon, and Columbite. The Basal Member of Kerri-Kerri Formation around Misau and Darazo areas is composed of flat-lying to gently dipping basal conglomerates, sandstones, siltstones and mudstones. The underlying rocks of the basement complex (gneisses and granites) are severely and deeply weathered. The lithofacies in The diagenetic history of the formation could be further investigated on a regional scale, especially with a view to AROUND MISAU AND DARAZO AREAS, UPPER BENUE TROUGH, NORTH EAST NIGERIA 25. OKEGYE, JOSEPH IDOHMA PGS/2004 2005/4030 47 HEAVY METALS CONCENTRATIO N IN UDEGE MBEKI MINING DISTRICT AND THEIR IMPLICATIONS ON UDEGE MBEKI ENVIRONS, NASARAWA STATE. the study area include conglomerate facies; sandstone facies; siltstone facies; and mudstone facies. Facies/sedimentologic examination revealed that the sandstones or the Basal Member of KerriKerri Formation were deposited in a fluvial to fluvio-lucustrine settings. Most of the analysed samples belong to the medium to coarse- gained sandstones, ranging from poorly sorted (1.071.92Ø) to moderately well sorted and moderately sorted (0.53-0.97Ø); to moderately well sorted and moderately sorted (0.53-0.97Ø); medium grained (1.05-1.6 Ø) to coarse- grained (0.20-0.95 Ø) sandstones; mesokurtic (0.94-1.07) to leptokurtic (1.12-1.30); and positively skewed (0.15-026 Ø) to very positively skewed (0.36-1.22 Ø). 2008 Geochemical survey was carried out in Udege Mbeki Mining District, Nasarawa State. The objectives of the study were to asses the levels of surface and ground water and soil contamination by heavy metals in the three media sampled water, soil and mine dumps, to produce geochemical information of the area and the likely effects of the study heavy metals with remedies; to also identify possible sources of contamination. Forty (40) samples were collected. The samples were digested with nitric acid (HN03) and analysed by atomic spectrometer (AAS). The study focused on seven heavy metals; Cd, Cr, Co, Cu, Fe, Pb and Ni. The result of the samples revealed that the metal average concentration of the different media are in the following order; water; Fe>Co>Pb>Cu>Cr Cd>Ni, Soil; understanding fully, the genesis of the greyish colouration, arguably characteristics of the study area. Fe>Pb>Co>Cu>Cd>Ni>Cr and Mine dumps Fe>Pb>Cu>Co>Ni>Cd>Cr. In water, Cd, Co, Fe and Pb are above World Health Organization (WHO), World River Mean (WRM) and limits for Salmonid fish in fresh water (LSFW). The concentration of Ni in water is slightly higher while Cr and Cu in water are lower than WHO tolerable limits. The concentration of Cr, Cu and Ni in water are also higher than WRM. The concentration of Cu and NI are higher than permissible limits for (LSFW) while Cr in water met the exact concentration for LSFW, this is due to both geogenic and anthropogenic factors. 26. UCHEBO, ANTHONY UGOCHUKW U PGS/2004 2005/4030 38 DEPOSITIONAL ENVIRONMENTS AND PETROGRAPHY OF LAMJA SANDSTONE, YOLA BASIN UPPER BENUE TROUGH, NORTHEASTERN NIGERIA. DECEM BER, 2010 The Lamja Sandstone is the topmost unit of the Cretaceous sediments in the Yola Basin of the Upper Benue Trough of northeastern Nigeria. The formation conformably overlies the Numanha Shale. The exposures of the formation occur on the eastern and southern fringes of the Tertiary Lunguda Basalt Plateau which unconformably overlies it. Field studies and laboratory analyses were conducted to determine its depositional environments. The Lamja Sandstone consists of shale, coal, siltstone, sandstone, sandy limsestone and carbonaceous sandstone while the dominant sedimentary structures are parallel lamination. Petrographic studies show that the sandstone samples are poorly-moderately sorted, very fine-fine grained and sub-angular-subrounded; it is not only immature but also contains more than 15% of detrital clay matrix (lithicwacke). Granolumetric data show a graphic mean size of 2.82 ø (Fine grained sandstone), mean standard The palynological studies should be carried out in order to determine biofacies sequence and palaeoenvironment of deposition for the unit. The sedimentological model of the formation should also be formulated. 27. ABDULLAHI , ADAMU MOHAMME D PGS/2004 2005/4030 43 GEOLOGY AND PETROCHEMISTR Y OF GWONGWON PEGMATITE FIELD WAMBA, NASARAWA STATE MARC H, 2011. deviation of 1.62 ø (poorly sorted) while the skewness values are positively fine skewed and kurtosis showing an average value of 0.860 (mesokurtic). Bivariate plots standard deviation verse skewness, standarded deviation verse mean and standard deviation verse first percentile for sample studied fell within the river environment. The sample of the cumulative probability curves plotted for the most of the samples are characteristics of fluvial log - probability plots and seems to be diagnostic for fluvial environment. Based on the results of the analyses, it is suggested that the depositional environments of the Lamja Sandstone ranges from perhaps deltaic environment (fan delta) to shallow marine. Twenty four rock samples were collected from the Gwon-Gwon pegmatite field at Wamba, Nasarawa State. They include six samples of granites, eleven samples of pegmatites and seven samples of undifferentiated migmatities. Representative samples from each group were selected and divided into two parts. One part was used to make thinsections for petrographic studies, while the second group was used for geochemical analysis. Petrographic studies show that there is consistent enrichment in colour (within the rock mass) of muscovite from blue to greenish colour which is also persistent with increase in quantity of rare metals. This could be an indication of fractionation. The petrographic studies also show the presence of two mica (muscovite and Biotite) in the granitoids which suggest that it is a two mica granitoid. Geochemical analysis on the second group of the selected samples Thorough isotopegeochemistry should be carried out on individual granites and pegmatite samples which will be used in dating; confirming the link between the patent granite and the pegmatites, and also it will give a possible genesis of mineralization. was carried out using the X-Ray Fluorescence (XRF) Spectrometry method. The samples were analyzed for their major elements, minor elements and trace elements. The results placed the granites as fertile types of granites which are silicic (Quartzrich) and peraluminous (AL/CNK> 1.1) suggesting an S- type origin.It results in the crystallization of Al-rich minerals like Muscovite. The development of the rare-metal pegmatite of Gwon-Gwon is probably related to granite magmatism. The ternary plots deduced a probable genetic link between the granitoids and the pegmatites with incomplete fractionation which could be due to incomplete partial melting or poor sourcing of materials during the partial melting. The clustering of the samples of rocks and pegmatite on the plot also suggests that fractionation was precisely partial. The paucily of rare elements in the migmatite preclude it from being the origin of the pegmatites because there is no evidence of fractionation of the migmatite. The rate of weathering in the study area was not intensive because the pegmatite and granites are underexposed. Tin-ore (Cassiterite) was won only from partial weathering of the granitic rocks and by blasting the pegmatite for the in-situ cavity fillings within the buried pegmatites. 28. 29. 30.