Name: _________________________________ Date: _____________ Period: ____ Lab – Molecular Models Introduction: Lewis structures can be used to predict molecular and ionic geometries (shapes), as well as polarity. Generally, atoms have eight electrons in their outer shell (octet rule). In addition, valence electrons exist in electron domains around atoms in either bonded pairs or non-bonded (lone) pairs. These electron domains can be used to predict the overall geometry of a molecule because electrons repel each other. This method is termed valence-shell electron-pair repulsion (VSEPR) theory. Materials: molecular models kits Methods and Analysis: Construct each of 12 molecular species, and then complete a data table including the following: 1. 2. 3. 4. 5. 6. 7. 8. 9. Total valence electrons Lewis structure Total electron domains Total lone pairs (nonbonded) ABnEm category Predicted molecular geometry (shape) Predicted bond angle(s) Symmetry (symmetrical or asymmetrical) Polarity (yes or no) Tips for Modeling Kit: -Yellow wood spheres are H and any atom forming only one bond (like F, Cl, etc.). -Red wood spheres are usually O (forms two bonds). -Black wood spheres can be any atom with 4 domains (4 bonds) (3 bonds & 1 E pair) (2 bonds & 2 E pairs). -Clay sphere is the central atom if exactly 3 domains are needed. -Wood sticks are for single bonds (shared E pairs) and/or lone E pairs on the central atom only. -Double or Triple Bonds are made with springs NOT wooden pegs. 1 Total Lewis Structure: Valence Electrons: H2 O 8 OR Total Molecular Electron Geometry Domains: 4 (Shape): # of Lone Pairs: 2 ABmEn: AB2E2 Total Lewis Structure: Valence Electrons: bent Polar Molecule: Bond Angle(s): Total Lewis Structure: Valence Electrons: Molecular Geometry (Shape): Total Lewis Structure: Valence Electrons: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): Yes or No Symmetrical or Asymmetrical Polar Molecule: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): # of Lone Pairs: ABmEn: Symmetrical or Asymmetrical Polar Molecule: # of Lone Pairs: NH3 Yes or No 109.5o # of Lone Pairs: HCN CCl4 Total Electron Domains: Symmetrical or Asymmetrical Yes or No Symmetrical or Asymmetrical Polar Molecule: Bond Angle(s): Yes or No 2 CF2Cl2 Total Lewis Structure: Valence Electrons: Molecular Geometry (Shape): # of Lone Pairs: (CFC or chlorofluorocarbon) Total Lewis Structure: Valence Electrons: Total Lewis Structure: Valence Electrons: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): Total Lewis Structure: Valence Electrons: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): Symmetrical or Asymmetrical Yes or No Symmetrical or Asymmetrical Polar Molecule: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): # of Lone Pairs: ABmEn: Yes or No Polar Molecule: # of Lone Pairs: H2S Symmetrical or Asymmetrical Polar Molecule: # of Lone Pairs: BF3 HF Total Electron Domains: Yes or No Symmetrical or Asymmetrical Polar Molecule: Bond Angle(s): Yes or No 3 Total Lewis Structure: Valence Electrons: Total Lewis Structure: Valence Electrons: H H C O H CH3OH H Total Lewis Structure: Valence Electrons: C2H6 Total Lewis Structure: Valence Electrons: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): # of Lone Pairs: Yes or No Symmetrical or Asymmetrical Polar Molecule: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): Yes or No Symmetrical or Asymmetrical Polar Molecule: ABmEn: Bond Angle(s): Total Electron Domains: Molecular Geometry (Shape): # of Lone Pairs: ABmEn: Symmetrical or Asymmetrical Polar Molecule: # of Lone Pairs: (two central atoms) (two central atoms) Molecular Geometry (Shape): # of Lone Pairs: O2 C2H4 Total Electron Domains: Yes or No Symmetrical or Asymmetrical Polar Molecule: Bond Angle(s): Yes or No 4