IGOR LEHNHERR Dept. of Earth and Environmental Sciences University of Waterloo 200 University Ave. W Waterloo, ON, N2L 3G1 Ph.: (905) 865-5226 (c) Email: ilehnher@uwaterloo.ca Website: www.ualberta.ca/~lehnherr Citizenship: Canadian and Swiss CAREER AND EDUCATION POSTDOCTORAL FELLOW W. Garfield Weston fellow in Northern Research, Department of Earth and Environmental Sciences, University of Waterloo, Ontario; Advisor: Dr. S.L. Schiff 2012- PROJECT COORDINATOR Department of Biological Sciences, University of Alberta, Edmonton, and Department of Earth and Environmental Sciences, University of Waterloo, Ontario; Advisors: Drs. D.W. Schindler and S.L. Schiff 2011 DOCTORATE OF PHILOSOPHY IN ENVIRONMENTAL BIOLOGY Department of Biological Sciences, University of Alberta, Edmonton Dissertation: Production and Cycling of Methylated Mercury Species in High Arctic Freshwater and Marine Ecosystems; Advisor: Dr. V.L. St. Louis 2004-2011 BACHELOR OF SCIENCE (Double Major in Chemistry and Biology) Departments of Chemistry and Biology, University of Victoria, British Columbia Senior project: Synthesis and Characterization of Silanol Complexes of Zirconium; Advisor: Dr. D.J. Berg 1999-2003 CERTIFICATE OF SCIENCE Faculty of Arts and Science, Yukon College, Whitehorse, Yukon Territory 1998-1999 AWARDS, GRANTS AND HONOURS RESEARCH GRANTS Northern Contaminants Program Grant (in review) Co-authored the proposal entitled, “Quantifying contaminant loadings, water quality and climate change impacts in the world´s largest lake north of 74° latitude (Lake Hazen, Quttinirpaaq National Park, Northern Ellesmere Island, Nunavut)” (Aboriginal Affairs and Northern Development Canada – AANDC Climate Change and Atmospheric Research Grant (NSERC) (in review) Co-wrote the proposal entitled, “Impacts of a Changing Climate on Active Layer Thaw and Freshwater Chemistry in Canada's Sovereign and Resource-Rich Arctic” Igor LEHNHERR January 2013 1/17 Northwest Territories Cumulative Impact Monitoring Program 2012-2014 Co-wrote the proposal entitled, “Snowpack accumulation: influence on caribou distribution, surface water chemistry and lake productivity” ($162,225, Aboriginal Affairs and Northern Development Canada - AANDC) Northern Contaminants Program Grant 2010-2011 Co-authored the proposal entitled, “Resolving the Arctic Ocean Methylmercury Conundrum” ($70,323, largest amount granted by AANDC out of 22 applications in its category) Northern Scientific Training Program Research Grant Awarded in support of my Ph.D. research ($8,500, AANDC) 2005-2008 Circumpolar/Boreal Alberta Research Grant Awarded in support of my Ph.D. research ($2,500, Canadian Circumpolar Institute) 2006-2007 MAJOR AWARDS W. Garfield Weston Postdoctoral Fellowship in Northern Research 2012-2014 National, awarded by the Association of Canadian Universities for Northern Studies ($50,000/yr) NSERC Postgraduate Scholarship – Doctoral National, held at the University of Alberta ($21,000/yr) 2005-2008 Alberta Ingenuity Studentship 2006-2010 Awarded based on academic and research merit, held at the University of Alberta ($26,000/yr) NSERC Canada Graduate Scholarship – Master’s National, held at the University of Alberta (17,500/yr) 2004-2005 Canadian Society of Chemical Industry Merit Award 2003 Awarded to the top graduating student (highest GPA) in Chemistry, held at the University of Victoria Exemplary Distinction For outstanding performance in the Doctoral comprehensive (Candidacy) exam, University of Alberta 2008 NSERC Undergraduate Research Award National, held at McGill University ($5,000) 2003 Walter H. John’s Graduate Fellowship Institutional, held at the University of Alberta ($4,750/yr) 2004-2008 University of British Columbia Gladys Estella Laird Graduate Fellowship Institutional, declined ($8,000) 2004 Igor LEHNHERR January 2013 2/17 Yukon Excellence Awards 1999-2003 Territorial, awarded based on academic standing, held at the University of Victoria ($6000) MINOR AWARDS Alberta Department of Advanced Education Graduate Student Scholarship For outstanding academic achievement in the first year of a Master’s program, held at the University of Alberta ($2,000) 2006 Science Graduate Scholarship Institutional, entrance scholarship, held at the University of Alberta ($2,000) 2004 J. Gordin Kaplan Graduate Student Award Institutional, held at the University of Alberta ($1,300) 2006 American Chemical Society, Division of Analytical Chemistry Award 2002 Awarded to the top undergraduate student in Analytical Chemistry, University of Victoria Dean’s Honour List Institutional, awarded to the top 10% in the Faculty of Science, University of Victoria 2000-2003 The President’s Scholarship Institutional, held at the University of Victoria ($2,500/yr) 2001-2003 The Yukon Conservation Society’s Ted Parnell Memorial Scholarship 2001 Territorial, awarded for excellence in the environmental sciences, held at the University of Victoria ($500) C. B. Husky’s Scholarship 1999-2003 Territorial, awarded based on academic standing, held at the University of Victoria ($250) PUBLICATIONS Refereed Publications in Scientific Journals 2012 Kirk, J. L., I. Lehnherr, M. Andersson, B. Braune, L. Chan, P. A. Dastoor, D. Durnford, A. L. Gleason, L. L. Loseto, A. Steffen, and V. L. St. Louis. 2012. Mercury in Arctic marine environments: sources, pathways and exposure. Environmental Research, 119: 64-87. (journal impact factor = 3.2) 2012 Lehnherr, I., V. L. St. Louis, C. A. Emmerton, J. D. Barker and J. L. Kirk. 2012. Methylmercury cycling in high Arctic wetlands: sources and sinks. Environmental Science & Technology, 46: 10514-10522. (featured on the cover of ES&T, journal impact factor = 4.8) 2012 Lehnherr, I., J. L. Kirk and V. L. St. Louis. 2012. Methylmercury cycling in high Arctic wetlands: controls on sedimentary production. Environmental Science & Technology, 46: 10523-10531. (featured on the cover of ES&T) Igor LEHNHERR January 2013 3/17 2011 Lehnherr, I., V. L. St. Louis, H. Hintelmann and J. L. Kirk. 2011. Methylation of inorganic mercury in polar marine waters. Nature Geoscience, 4: 298-302. (journal impact factor = 10.4) 2011 St. Louis, V. L., A. Derocher, I. Stirling, J. A. Graydon, C. Lee, E. Jocksch, E. Richardson, S. Ghorpade, A. K. Kwan, J. L. Kirk, I. Lehnherr and H. K. Swanson. 2011. Climate-induced changes in foodweb structure affecting mercury levels in Polar Bears (Ursus maritimus). Environmental Science & Technology, 45: 5922-5928. 2011 Mowat, L. D., V. L. St. Louis, J. A. Graydon, and I. Lehnherr. 2011. Influence of forest canopies on the deposition of methylmercury to boreal ecosystem watersheds. Environmental Science & Technology 45: 5178-5185. 2009 Lehnherr, I. and V. L. St. Louis. Importance of ultraviolet radiation in the photodemethylation of methylmercury in freshwater ecosystems. 2009. Environmental Science & Technology 43: 5692-5698. 2009 Graydon, J. A., V. L. St. Louis, H. Hintelmann, S. E. Lindberg, K. A. Sandilands, J. W. M. Rudd, C. A. Kelly, M. T. Tate, D. P. Krabbenhoft, and I. Lehnherr. 2009. Investigation of uptake and retention of atmospheric Hg(II) by boreal forest plants using stable Hg isotopes. Environmental Science & Technology 43: 4960-4966. 2008 Kirk, J. L., V. L. St. Louis, H. Hintelmann, I. Lehnherr, B. Else and L. Poissant. 2008. Methylated mercury species in marine waters of the Canadian high and sub Arctic. Environmental Science & Technology 42: 8367-8373. 2007 St. Louis, V. L., H. Hintelmann, J. A. Graydon, J. L. Kirk, J. Barker, B. Dimock, M. J. Sharp, and I. Lehnherr. 2007. Methylated mercury species in polar marine surface water and snowpacks. Environmental Science & Technology 41: 6433-6441. Journal Publications Accepted or in Preparation 1. Lehnherr, I. Mercury and methylmercury biogeochemistry with special reference to Canadian Arctic ecosystems: a review. To be submitted to Environmental Reviews January 2013. 2. Lehnherr, I., J. Venkiteswaran, V. L. St. Louis, C. A. Emmerton, and S. L. Schiff. Ecosystem metabolism in High Arctic ponds and lakes. To be submitted to Limnology and Oceanography Spring 2013. 3. St. Louis, V. L., I. Lehnherr, J. D. Barker, J. A. Graydon, J. L. Kirk and C. Emmerton. Net ecosystem exchange of CO2 and CH4 from ponds and lakes in the Canadian High Arctic. To be submitted to Environmental Science & Technology Summer 2013. Igor LEHNHERR January 2013 4/17 Other Refereed Publications 1. Lehnherr, I., official contributor to: Chen, C. Y., C. T. Driscoll, K. F. Lambert, R. P. Mason, L. Rardin, C. V. Schmitt, N. S. Serrell, E. M. Sunderland. 2012. Sources to Seafood: Mercury Pollution in the Marine Environment. Hanover, NH: Toxic Metals Superfund Research Program, Dartmouth College. 2. Lehnherr, I., co-author of two chapters on mercury in marine and freshwater ecosystems in: Canadian Arctic Report on Contaminants III, J. Chételat and B. Braune, eds. Northern Contaminants Program, Aboriginal Affairs and Northern Development Canada, in press. 3. Lehnherr, I., lead author of the chapter entitled “Processes Contributing to the Net Production of Methylmercury in Canadian Freshwater Ecosystems” for the Canadian Mercury Assessment Report completed under the umbrella of the Clean Air Regulatory Agenda Mercury Science Program, in review. Non-Refereed Publications 1. Lehnherr, I. 2003. L’Adjonction de Calcium dans la Fabrication de Mozzarella. (26 pp.) Technical report on the effect of low-level additions of calcium during Mozzarella production on milk protein recovery and overall yield; includes new protocol for the measurement of ionic calcium in dairy matrices using ion-selective electrodes. (Internship work with Estavayer Lait Société Anonyme (ELSA), Estavayer-Le-Lac, Switzerland) 2. Lehnherr, I and Berg, D.J. 2003. Synthesis and Characterization of Silanol Complexes of Zirconium. Undergraduate Research Paper, Department of Chemistry, University of Victoria. TEACHING/TRAINING and SUPERVISORY EXPERIENCE These various activities have helped me to develop teaching, leadership, communication and interpersonal skills as well as taking responsibility for people under my supervision: Teaching Assistant 2005 University of Alberta, Biology 381: People, Pollution and the Environment taught concepts of environmental science, answered questions and provided students with feedback on assignments graded exams in a fair and consistent manner Experiential Teaching Created and delivered a special presentation on the study of contaminants in the Arctic, including both a lecture and laboratory demonstration, worked with students to collect and process samples for a study on the distribution of mercury in Arctic marine waters and mentored high school students throughout the 2-week field course of the “Schools on Board” program. This unique educational program brings high school students from across Canada to the Arctic to work and learn alongside world-class scientists during an oceanographic cruise on board of the CCGS Amundsen icebreaker Igor LEHNHERR January 2013 5/17 Additional Teaching and Outreach Activities 2006-present Received training on teaching undergraduate students through the University of Alberta Professional Development Program’s Teaching Week 2011 by participating in workshops such as Preparing and delivering lectures, Teaching effectively in the Lab, and Leading group discussions Prepared and delivered teaching lecture on atomic structure for a 1st-year chemistry course, and prepared problem set and quiz to accompany/complement lecture material (Yukon College, Dec. 2010) Authored articles for the Experimental Lakes Area (ELA) Newsletter designed to educate the public on current environmental issues and on-going research at the ELA Delivered carefully prepared lectures, slideshows and interactive presentations to visiting high school students at the University of Alberta on a variety on topics ranging from general environmental science to “What it’s like to be a graduate student” Presented to Inuit elementary and high school students touring the CCGS Amundsen research icebreaker during a community visit in Resolute Bay, Nunavut Worked with and trained youth and adults from northern communities to collect and process samples during field campaigns in the Arctic Tutor 1999-present Tutored a large number of undergraduate and high school students in a broad range of scientific disciplines such as Chemistry, Biology, Physics, and Mathematics Instructed students in both one-on-one and group settings Training of Highly Qualified Personnel 2005-present Trained, supervised and mentored undergraduate students (7) and laboratory technicians (6) in the collection of environmental samples in diverse field settings and in the analysis of water/sediment/tissue samples using state of the art techniques, including inductively-coupled mass spectroscopy and cold vapor atomic fluorescence spectroscopy Mentoring of Graduate Students 2006-present Provided training for graduate students in safe laboratory and analytical chemistry techniques Assisted graduate students to develop models based on thermodynamics and chemical kinetics to quantify biogeochemical processes such as chemical degradation and air-water gas exchange Assisted graduate students with experimental and sampling design and provided feedback on results RESEARCH EXPERIENCE Carbon Cycling, Ecosystem Productivity and Climate Change Impacts in Arctic Freshwater Ecosystems 05/2012-present (Postdoctoral fellow, supervised by Dr. S. Schiff, University of Waterloo, in collaboration with Drs. M. English,Wilfrid Laurier University and V. St. Louis, University of Alberta) Arctic wetlands, ponds and lakes are common features on the Arctic landscape, providing valuable resources to wildlife and humans. These systems also act as biogeochemical hotspots, and can be very Igor LEHNHERR January 2013 6/17 productive. Rates of ecosystem productivity dictate how much energy flows through foodwebs, impacting the abundance of higher-level organisms (e.g., fish), as well as the net carbon balance, controlling whether a particular system is carbon source or sink. This research strives to obtain a process-level understanding of ecosystem productivity and respiration, in order to better understand how climate-induced changes in hydrology (change in precipitation patterns, timing of ice-out and snowmelt, deepening of the active layer overlaying permafrost, etc.) and catchment vegetation (increased vegetation cover, shifts in plant community structure) are impacting carbon cycling dynamics and Arctic freshwaters ecosystems on both the short and long-term. Applied novel measurements of stable isotopes ratios in dissolved oxygen and dissolved inorganic carbon to quantify whole-pond primary production and ecosystem respiration, two processes which ultimately control the net ecosystem exchange of CO2 from aquatic ecosystems Measured N2O air-water fluxes and modeled rates of denitrification Collected sediment cores from lakes to reconstruct ecosystem productivity over longer time periods, allowing for the examination of climate change impacts on lake ecosystems. Conducted limnological survey of ponds and lakes Speciation and Deposition of Atmospheric Mercury in the Pristine Boreal Ecoregion (Scientist, CARA Mercury Science Program) 05/2011-present The Clean Air Regulatory Agenda (CARA) Mercury Science Program was developed to provide scientific information to support regulatory activities pertaining to atmospheric emissions of mercury in Canada. As part of the CARA program, I have been quantifying the concentrations of various chemical species of mercury in the atmosphere at the Experimental Lakes Area using state-of-the-art instrumentation capable of continuously acquiring speciation and concentration data. This data is crucial for parameterizing and developing models describing the chemistry of atmospheric mercury and its deposition to landscapes, as well as for developing policy pertaining to emissions. setup, calibrated, maintained and trouble-shot Tekran Speciation Units to quantify atmospheric mercury concentrations and deposition Nutrient Cycling in Experimentally Eutrophied Lake 227 (Postdoctoral fellow/Project Coordinator, supervised by Drs. S. Schiff, University of Waterloo and D. Schindler, University of Alberta) 05/2011-06/2012 Eutrophication is the world’s most widespread water quality problem, resulting in cyanobacteria blooms and fish kills that have important implications from a fisheries and lake management perspective. High phosphorus (P) concentrations have been identified as one of the key factors resulting in eutrophication of lakes, and as a result regulations and controls have been implemented in an effort to reduce P loading to freshwaters. However, there is still considerable debate as to whether nitrogen (N) should be similarly regulated as this nutrient may also play an important role in controlling algal biomass and lake eutrophication. This research aims to determine whether N is a limiting nutrient (on a seasonal time scale) for algal growth in eutrophied lakes and, from a management perspective, whether costly treatment of waste water to remove N would be a cost effective means of managing lake eutrophication. Igor LEHNHERR January 2013 7/17 Coordinated and conducted sampling for the whole-ecosystem experimental addition of P to eutrophic Lake 227 at the world-renowned Experimental Lakes Area, trained and supervised students and technicians Measured sediment-water fluxes of species of N, P, and carbon (C) using a novel benthic flux chamber Quantified in-lake biogeochemical processes (e.g., respiration, sedimentation, mercury transformations) using a variety of techniques, including the use of stable-isotopes Assembled whole-watershed mass balances for N Resolving the Arctic Ocean Methylmercury Conundrum 06/2010-12/2011 (Postdoctoral fellow, supervised by Dr. V. L. St. Louis, University of Alberta and in collaboration with Dr. H. Hintelmann, Trent University) Monomethylmercury (MeHg), the toxic form of mercury that biomagnifies through foodwebs, is present in some Arctic marine mammals and fish at concentrations above the Canadian commercial marketing limit even though concentrations of MeHg in bulk seawater are relatively low compared to other aquatic systems. This begs the question as to what is the cause and mechanism of the efficient transfer of MeHg from marine waters into local foodwebs. We are currently investigating the hypothesis that particulate matter provide favorable micro environments for the production of MeHg and that organisms at the base of the foodweb feeding on detritus and particulate matter are in fact experiencing greater exposure to MeHg than would be predicted from concentrations measured in bulk seawater. Co-wrote the successfully funded proposal Collected suspended particles to perform the first ever measurements of particulate-bound MeHg in polar marine waters Quantified full suite of dissolved Hg species (total-, monomethyl-, dimethyl- and elementalmercury) throughout the water column Examined the role chemical and biological oceanographic parameters in controlling Hg distribution, speciation and bioaccumulation Compared various sampling protocols to allow correction of old data sets for sampling artifacts Production and Cycling of Methylmercury in Arctic Aquatic Ecosystems 09/2004-04/2011 (Ph.D. thesis project, supervised by Dr. V. L. St. Louis at the University of Alberta) The neurotoxin methylmercury (MeHg) is found in some Arctic marine animals and freshwater fish at levels that may be harmful to Northern Peoples consuming them as food. Because MeHg is the form of mercury (Hg) that is bioaccumulated and biomagnified, the key process which causes Hg to enter into foodwebs is the methylation of inorganic Hg(II) to MeHg in aquatic environments. Thus, the objective of my Ph. D. research was to determine the sources of MeHg to Arctic foodwebs by obtaining a mechanistic understanding of the processes controlling the production and cycling of this toxin in Arctic freshwater and marine systems. I have been able to quantify water-column Hg(II) methylation in oceans and conclusively demonstrate that it is a major source of MeHg to marine ecosystems, that high Arctic wetlands, despite cool temperatures and relatively limited availability of organic matter, are sites of MeHg production and that the photo-degradation of MeHg in aquatic systems is mediated by UV radiation and not visible light, as had been previously reported. The results from my research will Igor LEHNHERR January 2013 8/17 provide valuable input for global and regional Hg models as well as an understanding of the sources of MeHg to Arctic aquatic foodwebs, which will be useful in designing strategies to minimize MeHg exposure risks to fish, animals and people of the Arctic. Independently conceived original research, formulated hypotheses, designed and performed experiments, collected and analyzed data, constructed models and published manuscripts Secured funding for this project by successfully applying for research grants Utilized cutting-edge stable-isotope tracer techniques to quantify rates of MeHg production and degradation in water and sediments Employed both whole-ecosystem approaches and controlled experiments in field and laboratory settings to answer research questions Organized, coordinated and led eight different field campaigns in the remote Canadian Arctic, including three oceanographic cruises Performed sample analysis using clean room and trace metal protocols in combination with state-of-the-art instrumentation including gas chromatography inductively coupled mass spectrometry (GC-ICP/MS) and cold vapor atomic spectroscopy (CVAFS) Developed, implemented and adapted techniques, such as species-specific isotope dilution mass spectrometry, for the analysis of MeHg in a variety of environmental matrices (water, atmosphere, sediments, biological tissues) Collaborated with researchers across Canada (Drs. Holger Hintelmann, Scott Lamoureux, Derek Muir) on a number of projects and contributed in a large multidisciplinary team setting (e.g., ArcticNet, a Network of Centres of Excellence of Canada) Transfer of Terrestrial Mercury to Aquatic Systems in High Arctic Catchments (Research Assistant, University of Alberta) 04/2007-08/2011 Quantified the export of terrestrial mercury (total Hg and MeHg) from streams draining two separate lake watersheds at the Cape Bounty Arctic Watershed Observatory (CBAWO) Examined the impacts of climate change (e.g., permafrost degradation, changes in precipitation and hydrology) on the export of Hg from these catchments Collaborated with university (Dr. Scott Lamoureux, Queen’s University) and government scientists (Dr. Derek Muir, Environment Canada) to successfully complete this research These results will be integrated with those of my collaborators investigating Hg and carbon cycling in lakes receiving water from my study streams to obtain an ecosystem-scale understanding of Hg biogeochemistry in these changing high latitude systems Net Ecosystem Exchange of Greenhouse Gases in Arctic Wetland and Tundra Ecosystems (Research Assistant, University of Alberta) 05/2005-08/2010 Carbon dioxide (CO2) and methane (CH4) are important greenhouse gases (GHGs) that influence the atmosphere’s heat budget, and hence global climate. Currently it is not known whether many Arctic ecosystems are net sources or sinks of CO2 and CH4, despite the importance of this information for constructing global climate models. We are now quantifying the fluxes of these gases from aquatic (wetland) and terrestrial (tundra) ecosystems at the highest latitudes ever studied, as well as examining Igor LEHNHERR January 2013 9/17 the impacts of climate change on these processes and whether feedback effects on carbon cycling might result from these changes. Planned and participated in five field seasons on Ellesmere Island Used continuous measurements of dissolved CO2 and CH4 in wetland ponds and gas-exchange velocities based on wind speed to calculate air-water fluxes of these gases Demonstrated that wetland sites are a sink of atmospheric carbon dioxide but a source of methane to the atmosphere during the growing season Collected and processed water chemistry/limnological samples used to characterize each site Assisted in the set-up of a state-of-the-art eddy covariance flux tower in 2008 and 2009 at the most northerly location to date, with which we were able to demonstrate that during the growing season, the tundra landscape is a sink of atmospheric carbon dioxide Clean Air Regulatory Agenda: Mercury Science Program (Consultant/contractor, Environment Canada) 02/2009 and 03/2010 Collected sediment cores from lakes in Alberta (2009) and Ontario (ELA, 2010) to reconstruct the historical deposition of Hg to these lakes Collected sediments using a gravity corer, sectioned sediment cores, collected and processed water samples for various chemical parameters using clean techniques Sources of Methylmercury to Northern Caribou Herds (Research Assistant, University of Alberta) 06/2007 – 08/2007 Caribou meat can be a significant source of MeHg to Northern peoples since it makes up a large portion of their diet. To determine the ultimate source of MeHg to caribou and Northern peoples, we compared terrestrial and marine sources of MeHg in lichens – one of the principal food sources of caribou – by collecting lichens in transects moving away from coastal areas where MeHg of marine origin is deposited in wet and dry atmospheric deposition. Assisted in the design and planning of the research project Led the research team for the field component of this research, which was conducted on Devon and Bathurst Islands, Nunavut Calcium Additions as a Means of Increasing Milk Protein Recovery and Overall Yield in the Manufacture of Mozzarella Cheese 09/2003 – 12/2003 (Industrial Internship, Estavayer Lait Société Anonyme, Switzerland) Optimized levels of added calcium chloride during industrial production of mozzarella cheese to increase the recovery of milk protein and the overall yield, while retaining product quality Developed a new protocol for the measurement of ionic calcium in dairy matrices using ionselective electrodes Implemented the use of ion-selective electrodes to optimize the amount of calcium added and the equilibration parameters, such as time, temperature and pH, during milk maturation. Developed the project, conducted all chemical analyses for calcium, milk proteins and other parameters, and co-directed industrial-scale trials Igor LEHNHERR January 2013 10/17 Presented my findings to representatives from R&D and upper management, with the result that the company decided to implement my recommendations on optimal calcium concentrations, changing their mozzarella fabrication process accordingly Photoreduction of Aqueous Mercury in the Presence of Oxalate 05/2003 – 08/2003 (Undergraduate Research Assistant, supervised by Dr. P. A. Ariya, McGill University) Designed and completed the synthesis of Hg complexes containing organic ligands and characterized these complexes using nuclear magnetic resonance spectroscopy Conducted kinetic studies using these Hg complexes, as well as ionic Hg, to examine the role of organic anions in the (photo-)reduction of Hg(II) to Hg(0) over a range of pH and chloride concentrations Employed a variety of analytical techniques and tools such as Raman, UV-Visible and atomic fluorescence spectroscopy to complete this research Demonstrated that: (1) Hg both directly and indirectly bound to oxalate can be photoreduced, (2) the presence of chloride ions inhibits the reaction and (3) pH plays an important roles by dictating the speciation of the various chemical species involved Synthesis and Characterization of Silanol Complexes of Zirconium 01/2003 – 04/2003 (Undergraduate thesis project, supervised by Dr. D. J. Berg, University of Victoria) Synthesized a number of novel organometallic complexes using inert-atmosphere glove-box techniques Characterized synthesis products using Infrared and nuclear magnetic resonance spectroscopy, mass spectrometry and X-ray crystallography PRESENTATIONS AT SCIENTIFIC MEETINGS (* denotes presenting author) 1. Lehnherr, I.* S. L. Schiff, D. M. Orihel, D. W. Schindler, S. N. Higgins, M. J. Paterson, D. T. Callaghan, M. Holoka and J. J. Venkiteswaran. The importance of sediment return in subsidizing nitrogen requirements for algal production in an experimentally eutrophied lake (Lake 227). 66th Meeting of the Society of Canadian Limnologists, January 3-5, 2013, Windsor, ON (poster). 2. Kirk, J. L., I. Lehnherr, A. Gleason, D. Muir, V. St. Louis. The impact of eutrophication on mercury cycling in Lake 227 at the Experimental Lakes Area in northwestern Ontario. 66th Meeting of the Society of Canadian Limnologists, January 3-5, 2013, Windsor, ON (oral). 3. Venkistwaran, J. J., S. L. Schiff, S. N. Higgins, I. Lehnherr. Effects of internal carbon support on the 13C of organic carbon in an experimentally eutrophied lake. 66th Meeting of the Society of Canadian Limnologists, January 3-5, 2013, Windsor, ON (poster). Igor LEHNHERR January 2013 11/17 4. Lehnherr, I.*, J. J. Venkiteswaran, V. L. St. Louis, S. L. Schiff, C. A. Emmerton. Ecosystem metabolism and air-water exchange of greenhouse gases in High Arctic ponds. American Geophysical Union Fall Meeting, December 2-7, 2012, San Francisco, CA, USA (poster). 5. Kirk, J. L., I. Lehnherr, A. Gleason, D. Muir, V. St. Louis. The impact of eutrophication on mercury cycling in Lake 227 at the Experimental Lakes Area in northwestern Ontario. American Geophysical Union Fall Meeting, December 2-7, 2012, San Francisco, CA, USA (oral). 6. J. L. Kirk, D. Muir, I. Lehnherr, A. Gleason, V. L. St. Louis. The impact of eutrophication on mercury cycling in Lake 227 at the Experimental Lakes Area in Northwestern Ontario. Gordon Research Seminar - Environmental Sciences: Water, June 23-24, 2012, Holderness, NH, USA (poster). 7. Lehnherr, I.*, V.L. St. Louis, J. L. Kirk, C. A. Emmerton, J.D. Barker. Methylmercury cycling in High Arctic wetlands: what are the controls on production? International Polar Year 2012 Conference, April 22-27, 2012, Montreal, QC (oral). 8. Lehnherr, I.*, V. L. St. Louis and H. Hintelmann. Particulate and dissolved methylated mercury species in marine waters of the Canadian Arctic Archipelago: implications for bioaccumulation. International Polar Year 2012 Conference, April 22-27, 2012, Montreal, QC (poster). 9. St. Louis, V.L., I. Lehnherr, S.F. Lamoureux, J.A. Graydon, J.D. Barker, C.A. Emmerton, J.L. Kirk. Net ecosystem exchange of carbon dioxide and methane from lakes and wetlands in the Canadian High Arctic. International Polar Year 2012 Conference, April 22-27, 2012, Montreal, QC (oral). 10. Kirk, J. L., D. Muir, A. Gleason, I. Lehnherr, V. St. Louis, S. Lamoureux, T. Lewis, K. Stewart, D. Iqaluk and B. Iqaluk. The transfer of terrestrial mercury to freshwater ecosystems at Cape Bounty, Melville Island, Nunavut. International Polar Year 2012 Conference, April 22-27, 2012, Montreal, QC (poster). 11. Lehnherr, I.* Sediment-water fluxes of nitrogen and phosphorus nutrients in an experimentally eutrophied boreal lake (L227, Experimental Lakes Area). 2nd Annual Lake 227 Project Meeting, Canada Centre for Inland Waters, January 18, 2012, Burlington, ON (oral). 12. Lehnherr, I.*, V.L. St. Louis, J. L. Kirk, C. A. Emmerton. Methylmercury cycling in High Arctic wetlands: what are the controls on production? The Society of Environmental Toxicology and Chemistry North America 32nd Annual Meeting, November 13-17, 2011, Boston, MA, USA (oral). 13. Lehnherr, I.*, V. L. St. Louis, H. Hintelmann. Mercury speciation in Arctic marine waters. 19th Annual Northern Contaminants Program Results Workshop, September 20-21, 2011, Victoria, BC (oral; invited). 14. Lehnherr, I.*, V. L. St. Louis, J. L. Kirk and C. A. Emmerton. Methylmercury cycling in High Arctic wetlands: what are the controls on methylmercury production? 10th International Conference on Mercury as a Global Pollutant, July 24-29, 2011, Halifax NS (oral). Igor LEHNHERR January 2013 12/17 15. St. Louis, V. L., A. Derocher, I. Stirling, J. Graydon, C. Lee, E. Jocksch, E. Richardson, S. Ghorpade, A. Kwan, J. L. Kirk and I. Lehnherr. Differences in mercury bioaccumulation amongst polar bears (Ursus Maritimus) from the Canadian high and sub Arctic. 10th International Conference on Mercury as a Global Pollutant, Halifax, Canada, July 28th, 2011 (oral). 16. Kirk, J., V. St. Louis, D. Muir, I. Lehnherr, S. Lamoureux, T. Lewis, K. Stewart, D. Iqaluk, C. Tunks, G. Lawson. The transfer of terrestrial mercury to freshwater aquatic ecosystems of the Canadian High Arctic. 10th International Conference on Mercury as a Global Pollutant, July 2429, 2011, Halifax NS (poster). 17. Kirk, J. L., D. Muir, A. Gleason, J. Coty, V. L. St. Louis, I. Lehnherr, B. Iqaluk, D. Iqaluk, S. Lamoureux, K. Stewart, T. Lewis. The transfer of terrestrial mercury to freshwater Arctic ecosystems of Cape Bounty, Melville Island, Nunavut. 10th Experimental Lakes Area Seminar Series, Experimental Lakes Area, Ontario, Canada, July 13th, 2011 (oral; invited). 18. Lehnherr, I.* Production and cycling in methylmercury in Arctic freshwater ecosystems. Experimental Lakes Area Seminar Series, June 29, 2011, Experimental Lakes Area, ON (oral; invited) 19. Lehnherr, I.*, V. L. St. Louis, J. L. Kirk and J. D. Barker. Production and cycling of methylmercury in high Arctic wetlands. American Geophysical Union Fall Meeting, December 13-17, 2010, San Francisco, CA, USA (poster). 20. Kirk, J. L., D. Muir, C. Tunks, L. Alpi, G. Lawson, D. Iqaluk, B. Iqaluk, V. St. Louis, I. Lehnherr, S. Lamoureux, K. Stewart and T. Lewis. The transfer of terrestrial mercury to Arctic freshwater ecosystems, Melville Island, Nunavut. The Society of Environmental Toxicology and Chemistry North America 31st Annual Meeting, November 7-11, 2010, Portland, OR, USA (oral). 21. Lehnherr, I.*, V. L. St. Louis and H. Hintelmann. Mercury speciation in Arctic marine waters. 18th Annual Northern Contaminants Program Results Workshop, September 28-30, 2010, Whitehorse, YT (poster). 22. Lehnherr, I.*, V. L. St. Louis and H. Hintelmann. Production and cycling of methylated mercury species in Arctic marine waters. American Geophysical Union Fall Meeting, December 14-18, 2009, San Francisco, CA, USA (oral). 23. Barker, J. D., V. L. St. Louis, I. Lehnherr, and J. A. Graydon. Net ecosystem exchange of CO2 and CH4 in the high Arctic (81° N) during the growing season. American Geophysical Union Fall Meeting, December 14-18, 2009, San Francisco, CA, USA (poster). 24. Lehnherr, I.*, V. L. St. Louis and H. Hintelmann. Production and cycling of methylated mercury species in Arctic marine waters. 6th ArcticNet Annual Scientific Meeting, December 8-11, 2009, Victoria, BC (oral). 25. Kirk, J., D. Muir, V. St. Louis, S. Lamoureux, I. Lehnherr and T. Lewis. The transfer of terrestrial mercury to aquatic ecosystems at the Cape Bounty Arctic Watershed Observatory (CBAWO) Melville Island, Nunavut. 6th ArcticNet Annual Scientific Meeting, December 8-11, 2009, Victoria, BC (oral). Igor LEHNHERR January 2013 13/17 26. Lehnherr, I.* and V. L. St. Louis, H. Hintelmann and J. L. Kirk. Production and cycling of methylated mercury species in Arctic marine waters. 9th International Conference on Mercury as a Global Pollutant, June 7-12, 2009, Guiyang, China (oral). 27. Lehnherr, I.* and V. L. St. Louis. The importance of UV radiation in the photodemethylation of methylmercury. 9th International Conference on Mercury as a Global Pollutant, June 7-12, 2009, Guiyang, China (poster). 28. Lehnherr, I.*, J. L. Kirk, V. L. St. Louis and H. Hintelmann. Methylation and ocean-atmosphere fluxes of mercury in Arctic marine waters. Arctic Change International Conference, December 912, 2008, Québec, QC (poster). 29. Lehnherr, I. *, J. L. Kirk, V. L. St. Louis, and H. Hintelmann. The Biogeochemistry of Methylated Mercury in Arctic Marine Waters. Department of Biological Sciences Graduate Student Research Days, University of Alberta, February 14, 2008, Edmonton, AB (poster). 30. St. Louis, V. L., J. A. Graydon, J. L. Kirk, L. Mowat and I. Lehnherr. The dynamic exchange of atmospheric mercury with Arctic and Boreal ecosystems. Special Seminar, Harvard University, January 31, 2008, Boston, MA, USA (oral; invited). 31. Lehnherr, I.*, J. L. Kirk, V. L. St. Louis, and H. Hintelmann. The Biogeochemistry of Methylated Mercury in Arctic Marine Waters. 4th ArcticNet Annual Scientific Meeting, December 11-14, 2007, Collingwood, ON (poster). 32. St. Louis, V. L., H. Hintelmann, J. A. Graydon, J. L. Kirk, J. Barker, B. Dimock, M. J. Sharp and I. Lehnherr. Methylated mercury species in Canadian high Arctic marine waters and snowpacks. Experimental Lakes Area Seminar Series, July 12, 2007, Experimental Lakes Area, ON (oral; invited). 33. Kirk, J. L., I. Lehnherr, V. L. St. Louis, and H. Hintelmann. Toxic mercury species in Arctic seawaters. Department of Biological Sciences Graduate Student Research Days, University of Alberta, February 9, 2007, Edmonton, AB (poster). 34. Lehnherr, I.*, J. L. Kirk, V. L. St. Louis, and H. Hintelmann. Toxic mercury species in Arctic seawaters. 3rd ArcticNet Annual Scientific Meeting, December 12-15, 2006, Victoria, BC (poster). 35. St. Louis, V. L., J. L. Kirk, and I. Lehnherr*. Production of toxic mercury species in Canadian Arctic ecosystems. Circumpolar Students Association Northern Speaker Series, October 24, 2006, Edmonton, AB (oral). 36. Lehnherr, I.*, V. L. St Louis and J. D. Barker. The production and cycling of methylmercury in high arctic ponds. 8th International Conference on Mercury as a Global Pollutant, August 6-11, 2006, Madison, WI, USA (oral). 37. Kirk, J. L., V. L. St. Louis, H. Hintelmann, and I. Lehnherr. Potential sources of monomethyl mercury to Arctic marine ecosystems. 8th International Conference on Mercury as a Global Pollutant, August 6-11, 2006, Madison, WI, USA (oral). Igor LEHNHERR January 2013 14/17 38. St. Louis, V. L., J. A. Graydon, J. L. Kirk and I. Lehnherr. Recent advances in understanding the biogeochemical cycling of mercury. Experimental Lakes Area Seminar Series, May 24, 2006, Experimental Lakes Area, ON (oral; invited). 39. St. Louis, V. L., J. A. Graydon, J. L. Kirk and I. Lehnherr. Recent advances in understanding the biogeochemical cycling of mercury. Department of Biological Sciences Seminar Series, University of Alberta, January 27, 2006, Edmonton, AB (oral). 40. Lehnherr, I*. 2003. L’Adjonction de Calcium dans la fabrication de Mozzarella. Presentation of internship work conducted at Estavayer Lait Société Anonyme, December 2003, Estavayer-LeLac, Switzerland (oral). 41. Raofie, F., I. Lehnherr and P. A. Ariya. 2003. Kinetics and Mechanism of Reduction of Mercuric Ion with Organic Matter. 3rd Annual Collaborative Mercury Research Network (COMERN) General Congress, November 5-7, 2003, St. Andrews, NB (poster). 42. Lehnherr, I.* and P. A. Ariya. 2003. Photoreduction of Aqueous Mercury in the Presence of Oxalate. Presentation of NSERC USRA work to members of the Chemistry, and Atmospheric and Oceanic Sciences Departments, July 30, 2003, McGill University, Montreal, QC (oral). 43. Lehnherr, I.* and D. J. Berg. 2003. Synthesis and Characterization of Silanol Complexes of Zirconium. Undergraduate Research Seminar, Department of Chemistry University of Victoria. April 3, 2003, Victoria, BC (oral). PROFESSIONAL ACTIVITIES Executive Member, ArcticNet Student Association (ASA) ArcticNet is a Network of Centres of Excellence of Canada that brings together scientists in the natural, health and social sciences with their partners from Inuit organizations, government agencies and the private sector to study the impacts of climate change in the coastal Canadian Arctic; its student association counts over a thousand members. Held the position of Secretary and Communications Officer in 2007-2008 Contributed to and published the ASA newsletter to keep students updated on funding opportunities, field schools, on-going research and upcoming workshops/conferences Organized, with the other ASA Executives, the Student Day symposium and workshop at the Arctic Change 2008 international conference hosted in Quebec City. Responsible for updating the ASA website Translated documents between French and English Participated in the additional ASA initiatives such as organizing regional workshops and outreach activities Scientific Expert, Coastal and Marine Mercury Ecosystem Research Collaborative (C-MERC) C-Merc is an international team of scientists and stakeholders assembled to elucidate key processes related to the inputs, cycling and uptake of mercury in marine ecosystems. The findings from this initiative will be translated and distributed to public health and policy stakeholders. Igor LEHNHERR January 2013 15/17 co-lead of the Ocean System synthesis paper for the Arctic Ocean region and co-author on the summary report on policy implications of mercury in marine environments Contributing Author, Canadian Arctic Contaminant Assessment Report (CACAR-III) and the current Canadian Mercury Assessment Co-author of two chapters on mercury concentrations and transformations in marine and fresh waters for CACAR-III (in press) Lead author of chapter on mercury transport and transformations in aquatic ecosystems for the Canadian Mercury Assessment conducted under the umbrella of the Clean Air Regulatory Agenda Mercury Science Program Professional Affiliations and Memberships: Association of Polar Early Career Scientists: Member, 2011-present Society of Environmental Toxicolgy and Chemistry: Member, 2011-present American Geophysical Union: Student member, 2009-2011; Member, 2011-present ArcticNet – a Network of Centres of Excellence of Canada: Member, 2005-present ArcticNet Student Association: Student member, 2005-2011; Member 2011-present Canadian Society of Chemical Industry: Student member, 2003-2004 Golden Key International Honor Society: Member, 2000-present Journal Referee Since 2007, I have been asked to referee numerous scientific articles for peer-reviewed journals such as Proceedings of the National Academy of Science, Environmental Science & Technology, Marine Chemistry, Chemosphere, Environmental Chemistry, Environmental Toxicology and Chemistry, and Science of the Total Environment. Media Coverage 1. Featured in December 2012 edition of Canadian Geographic for research conducted in the Canadian Arctic. 2. Following the publication of “Methylation of inorganic mercury in polar marine waters” in Nature Geoscience in April 2011, over a hundred news organization around the world covered the story, including CBC television, CBC radio, Science Daily, The European Commission’s Science for Environment Policy (the European Commission's environmental news service for policy makers, distributed to over 13,000 subscribers), The Edmonton Journal, The Vancouver Sun, The Montreal Gazette, Nunatsiaq News, and the Canadian Chemical News. As part of this coverage, I was interviewed television, radio and other newsmedia. 3. Nunatsiaq News Feature. Arctic contaminants threaten polar bears. Jane George, August 6, 2010. 4. Environment & Energy News PM. Scientists offer some clues to how mercury enters ocean, June 28, 2010. 5. Nunatsiaq News Feature. Scientists seek key to mercury mystery. John Thompson, August 24, 2007. Conference Service 1. Co-organizer and convener, Mercury in Arctic Environments, special session, 10th International Conference on Mercury as a Global Pollutant, Halifax, Canada, July 2011. 2. Co-chair, Polar Terrestrial and Freshwater Ecosystems (Biogeochemistry, Hydrology), International Polar Year 2012 Conference, Montreal, Canada, April 2012. Igor LEHNHERR January 2013 16/17 Language Skills I am able to fluently speak, read, write and communicate effectively in both English and French. Igor LEHNHERR January 2013 17/17