Chemistry Unit Plans Science Curriculum Unit Chemistry Clarifying Objective: 1.1.1 Weeks: 1 Days: 5 days Essential Standard Chm.1.1 Analyze the structure of atoms and ions. Chemistry Unit Plans Clarifying Objectives Chm.1.1.1 Analyze the structure of atoms, isotopes, and ions. (3 Days) Chm.1.1.2. Analyze an atom in terms of the location of electrons.(2 Days) Essential Questions Knowledge/Skills What is the structure of an atom? Can you draw it? Students know how to: How does the structure of an atom look like? • characterize protons, neutrons, electrons by location, relative charge, relative mass (p=1, n=1, e=1/2000). • use symbols: A= mass number, Z=atomic number. Where can an electron, proton and neutron be found in an atom? Given # protons + # neutrons = A, what is Z for a given atom? What is the charge of…(a proton, a neutron, an electron)? What does… (235, 92) mean in this isotope notation, :23592U ? How can you use the information about average atomic mass on the periodic table to decide whether 13 6C is or isnot the most abundant isotope of carbon? Given a family of isotopes with the actual isotopic mass and relative abundance for each, calculate the average atomic mass for the isotope’s family. • use notation for writing an isotope symbol, for example 235 92 U or U-235 or Uranium-235. • identify isotopes using mass number and atomic number and relate it to the number of protons, neutrons and electrons. • differentiate average atomic mass of an element from the actual isotopic mass and mass number of specific isotopes. (Use example calculations to determine average atomic mass of atoms from relative abundance and actual isotopic mass to develop understanding). • analyze diagrams related to the Bohr model of the hydrogen atom in terms of allowed, discrete energy levels in the emission spectrum. • describe the electron cloud of the atom in terms of a probability model. • relate the electron configurations of atoms to the Bohr and electron cloud models. Vertical Alignment 6.P.2.1 Recognize that all matter is made up of atoms and atoms of the same element are all alike, but are different from the atoms of other elements. PSc.2.1.4 Interpret data presented in Bohr model diagrams and dot diagrams for atoms and ions of elements 1 through 18. Chemistry Unit Plans PSc.2.2.1 Infer valence electrons, oxidation number, and reactivity of an element based on its location in the Periodic Table. Learning Progressions How can a student successfully analyze the structure of atoms, isotopes, and ions? Draw the atomic diagram of an atom starting with a circle representing the nucleus containing # protons (p+) and neutrons (n, zero charge). All of an atom’s mass is in there. Next draw rings (call them shells) around the nucleus to represent energy levels where electrons can be found. Fill up the shells following the Octet rule: Up to 2 electrons in first shell, up to 8 in second,8,18,18,32,32. Calculate the atomic mass of the atom drawn above and emphasize the origin of it: Protons + neutrons alone. Show them why the mass number of an isotope is a whole number rather than a decimal number as shown for most elements on the periodic table. Write the name of the atom using both the isotope’s name (example: Oxygen-16) and the isotope’s notation, 168O. Have students draw the atomic diagram for an atom represented by its isotope’s notation. Have students draw atomic diagrams for each atom from hydrogen to…argon. They need to name each isotope using the isotope’s name and the isotope’s notation or symbol. Have students draw atomic diagrams for each member of a family of isotopes: What stays the same? What changes? Charges:Draw the atomic diagram of a neutral atom. Add the # charge of protons (+) and the number charge of electrons (-) = 0. Next eliminate the electrons from outer shell and repeat calculation. Result = origin of positive charge. Call an atom with a positive charge as “cation”. Repeat process by completing outer shell to its corresponding maximum # electrons allowed in that particular layer. Result = Origin of negative charge. Call each atom with a negative charge as “anion”. Call the above charged atoms, ions. Tell students this only happens when atoms combine to make new substances. Make sure students understand charges as originated by the movements of electrons, protons and neutrons are not involved at all and stay where they are, in the nucleus. Have students draw atomic diagrams for each ion of a given set. Have students write down the isotope notation and name for each ionic atomic diagram of a given set. Show students how to calculate average atomic mass of a given set of isotopes. Make extra clear that the isotope with the most relative percent abundance has an atomic mass that is the closer to the one shown on the periodic table for such element. Assessments/Probes Chemistry Unit Plans Formative Assessment Summative Assessment Monitor and coach students as they draw and name atomic diagrams, work on charges, and calculate average atomic masses of a given family of isotopes. http://www.nysedregents.org/chemistry/ Click For Formative Assessment 1 Iron Bar Formative Assessment Probe.pdf Salt Water Formative Assessment Probe.pdf Using the textbook’s assessments, test generators, the internet…research each topic from the knowledge/skills section above under the headline “atomic structure multiple choice test” – as one example- and you can put together a test with valuable items that are inquiry and critical thinking oriented. Make sure to include items under different formats (multiple choices, fill in the blank, scenarios, short answers…) that test students’ understanding of concepts and applications like Turning the Dial Formative Assessments Packaged6.pdf What is a Hypothesis? Formative Assessments Packaged-7.pdf Where an electron…(proton, neutron) can be found in an atom? Given # protons + # neutrons = A, what is Z for a given atom? Given an atom notation, atomic diagram, what is the charge of the atom? What does (235, 92) mean in this isotope notation, 23592U? How can you use the information about average atomic mass on the periodic table to decide whether 136C is or isnot the most abundant isotope of carbon? Given a family of isotopes with the actual isotopic mass and relative abundance for each, calculate the average atomic mass for the isotope’s family. Vocabulary atomic structure, nucleus, layers or shells, atomic mass, ion, cation, anion, atomic number and isotope Resources Resource Folder\Presentational Files (Powerpoints)\Week 1 - Atomic Structure Excellent interactive website to build your own atomic diagram: http://www.classzone.com/books/earth_science/terc/content/investigations/es0501/es0501page04 .cfm DPI resources addressing this objective: http://www.ncpublicschools.org/docs/curriculum/science/units/high/chemistry/unit2.doc Support information, diagrams about motion of electrons: Chemistry Unit Plans http://web.jjay.cuny.edu/~acarpi/NSC/3-atoms.htm http://www.nclark.net/Atom CCS Science Curriculum Unit Chemistry Clarifying Objective: 1.1.3 Week: 2 Days: 5 Days Essential Standard Chm.1.1 Analyze the structure of atoms and ions. Explain the emission of electromagnetic radiation in spectral form in terms of the Bohr model. Chemistry Unit Plans Clarifying Objectives Chm.1.1.3Explain the emission of electromagnetic radiation in spectral form in terms of the Bohr model. Essential Questions 1. How does an electron jump to the next energy level? -----When an electron gains an amount of energy equivalent to the energy difference, it moves from its ground state to a higher energy level. 2. What happens when an electron resumes its ground state energy level? When the electron moves to a lower energy level, it releases an amount of energy equal to the energy difference in these levels as electromagnetic radiation (emissions spectrum). 3. Why are there different colors of light emitted from different elements? Knowledge/Skills Describe the concepts of excited and ground state of electrons in the atom: Articulate that this electromagnetic radiation is given off as photons. Understand the inverse relationship between wavelength and frequency, and the direct relationship between energy and frequency. Use the “Bohr Model for Hydrogen Atom” and “Electromagnetic Spectrum” diagrams from the Reference Tables to relate color, frequency, and wavelength of the light emitted to the energy of the photon. Explain that Niels Bohr produced a model of the hydrogen atom based on experimental observations. Vertical Alignment 6.P.1.2 Explain the relationship among visible light, the electromagnetic spectrum, and sight. PSc.2.1.4 Interpret data presented in Bohr model diagrams and dot diagrams for atoms and ions of elements 1 through 18. Learning Progressions Students should have a good understanding of the ground state of electrons for each element (Aufbau, Pauli, and Hund) and how to identify the energy level at ground state (electron configuration). Explaining that the excitation of electrons requires energy and the relaxing of electrons results in the release of energy via the emission of electromagnetic radiation (photons of light). Understanding the inverse relationship of wavelength and frequency and the direct relationship between energy and frequency can be demonstrated with calculations of problems using C = Wavelength, X = Frequency. Using Bohr's model of hydrogen, demonstrate the concept of orbits and explain that energy increases in each successive orbit, and lowers as it orbits close to the nucleus. Assessments/Probes Chemistry Unit Plans Formative Assessment Summative Assessment Boiling time and Temperature Formative Assessments Packaged-7.pdf http://www.nysedregents.org/chemistry/ Resource Folder\Chemistry Essential Standard Probes\Chemistry-Week 2 or 3 F.A.P..doc Vocabulary quanta, photon, wavelength, frequency, electromagnetic radiation Bohr, spectrum, energy levels and orbital Resources Resource Folder\Presentational Files (Powerpoints)\Week 2 - Electron Configuration Resource Folder\EOC Sets\EOCSet3 - Quantum Model of the Atom.doc CCS Science Curriculum Unit Chemistry Clarifying Objective: 1.2.1 Week: 3 Days: 5 days Essential Standard Chm. 1.2.1: Understand the bonding that occurs in simple compounds interms of bond type, strength, and properties. Clarifying Objectives Chm. 1.2.1: Compare (qualitatively) the relative strengths of ionic, covalent, and metallic bonds. Essential Questions Draw the electronic configurations for a neutral metal atom and for a neutral nonmetal atom, then draw the electronic configurations for their ionic versions respectively. Which electronic configuration is more Knowledge/Skills Students should be able to: • Describe how ions are formed and which arrangements are stable (filled d-level, or half-filled d-level). • Appropriately use the term cation as a positively Chemistry Unit Plans stable in each case? Why? What is a cation? What is an anion? What is the valence shell of a particular atom based on its location on the periodic table? What is the charge of a particular atom based on its location on the periodic table? How are ionic bonds formed? In an ionic compound, why is the nonmetal atom negative? In an ionic compound, why is the metal atom positive? How are covalent bonds formed? Why are atoms sharing electrons in a covalent bond? charged ion and anion as negatively charged ion. • Predict ionic charges for representative elements based on valence electrons. • Apply the concept that sharing electrons form a covalent compound that is a stable (inert gas) arrangement. • Draw Lewis (dot diagram) structures for simple compounds and diatomic elements indicating single, double or triple bonds. Vertical Alignment PSc.2.1.4 Interpret data presented in Bohr model diagrams and dot diagrams for atoms and ions of elements 1 through 18. PSc.2.2.1 Infer valence electrons, oxidation number, and reactivity of an element based on its location in the Periodic Table. PSc.2.2.2 Infer the type of chemical bond that occurs, whether covalent, ionic or metallic, in a given substance. Learning Progressions Review how a charge forms in an atom: Based on the outer shell of an atomic diagram losing all the valence electrons to become positive (if a metal) or the atom gaining or adding enough electrons to complete the valence shell with eight electrons and to become negative (if a nonmetal). For example, draw the atomic diagram for aluminum atom with 13 electrons total (neutral). Draw an arrow to the right of your aluminum atomic diagram and draw another aluminum atomic diagram to the right of the arrow as a product, just this time eliminate the valence shell of aluminum. On top of the arrow write “-3 electrons” indicating that aluminum lost three electrons to a non-shown nonmetal atom. Do the protons and electrons math count on both aluminum atomic diagrams and show that the aluminum on the left side is neutral and the one on the product side is +3 as expected of aluminum metal. Aluminum +3 is more stable (full shell) than aluminum neutral. Tell students to call Al+3 a “cation” or positive ion; that +3 is called an ionic charge. Repeat the process using oxygen atomic diagram. On top of the arrow write “+2 electrons” indicating you are adding 2e to the oxygen on the left. On the right side of the Chemistry Unit Plans arrow oxygen now has the valence shell completed with eight valence electrons and is now more stable than when missing two electrons (neutral). Tell students that O-2 is called an “anion” or negative ion; that -2 is called an ionic charge. Using the same atomic diagrams for aluminum and oxygen it is easily demonstrated that the charge an atom acquires is the same as the number of electrons involved in the process of losing or gaining electrons! ADDRESS MISCONCEPTION!: Negative charge (-) stem from adding electrons that are negatives to the valence shell (and not a subtraction of something!), while a positive charge (+) stem from losing electrons -and the valence shell- of the metal atom (as opposed to adding something!). Next, write the extended electronic configuration underneath each of the atomic diagrams you used above (aluminum and oxygen). Write the electronic configuration below aluminum neutral and aluminum positive, also below oxygen neutral and oxygen negative. MAKE SURE students note the valence shell in each electronic configuration and being able to follow you as you compare the valence shell electronic configuration of aluminum neutral and aluminum cation (what is missing?). Do the same when comparing oxygen neutral’s electronic configuration and oxygen anion’s (what is added?). Ask students which electronic configuration from aluminum is more stable? Neutral aluminum or the charged aluminum? Why? (Full or half full shells/electronic configurations resemble noble gases electronic configurations. Metals acquire noble gas configurations by losing electrons and nonmetals gain noble gas electronic configurations by adding electrons). Students should now feel comfortable with looking at the valence shell or electronic configuration of a particular known element and decide whether it is a positively charged atom or a negatively charged atom depending on whether the valence shell or electronic configuration for the valence shell is missing or completed. The Nature of an ionic bond (ionic compound). Start by drawing the atomic diagram of sodium and the atomic diagram for chlorine. Draw an arrow and redraw both atomic diagrams together but not touching each other, forming a product and showing the charges as depicted below : Chemistry Unit Plans The product is A positively charged sodium ion (left) and a negatively charged chlorine ion (right). Na+Cl- Another example using calcium atom and chloride ion: Draw the atomic diagram for neutral calcium plus the atomic diagram for a neutral chlorine atom followed by an arrow Tell students that calcium metal loses the valence shell (two electrons) and chlorine gains one electron to complete its valence shell. Calcium needs to lose two electrons, not just one; therefore you have to use chlorine on the left side. Draw the product on the right side as follows: Notice that in the product, calcium is missing its fourth shell (valence shell) and each chloride atom now has the outer shell with eight electrons each. Call the attention on the atoms being together but not touching; they stay in very close proximity due to charge attraction between the atoms. Notice that calcium is in the center and the arrangement is linear. Repeat the reactions above this time only using Lewis Dot notations (letters). Move the dots from around the metal to over the nonmetals in the product. Make sure to show the charges in the upper right corner of each letter. At this point, provide a set of combination of metal plus nonmetal atoms for the students to practice forming products (salts) through ionic bonds. Notice that the metal atom must be in front –first- in the product or formula. Chemistry Unit Plans Repeat the reactions above using the charged symbols. Example: Al +3 plus Cl -1 The 3 becomes the subscript for the chloride ion and the 1 becomes understood for aluminum, to form aluminum chloride: AlCl3 Same happens between O-2 and B+3 to form B2O3. When using polyatomic ions, you have to use parenthesis. Example: Mg+2 and OH-1 The 2 becomes the subscript for the hydroxide ion, but a set of parenthesis is needed to indicate 2 of each the O and the H. The 1 becomes the understood subscript for Mg. Once together, they form magnesium Hydroxide: Mg(OH)2. Same happens between SO4-2 and Ti+4: The product is Ti2(SO4)4 but you have to simplify the subscripts to become Ti(SO4)2. At this point, provide a set of polyatomic ions for the students to form ionic products. The Nature of a covalent bond (molecular compound): Start by drawing an atomic diagram for neutral carbon and another for neutral hydrogen in the form of an equation (C + H → ). Show the students the fact that when two nonmetal atoms combined they do so by coming together to share electrons from the outer shell (valence shell). Tell students that carbon has four electrons in outer shell and hydrogen has only one. Carbon needs to gain four electrons to complete the valence shell with 8 electrons according to the Octet Rule. Hydrogen needs only one electron to complete the valence shell with two electrons. Carbon will have to get the extra four electrons from hydrogen but hydrogen can only make available one electron. Hydrogen has no problem with completing its valence shell by getting one electron from carbon. Carbon will have to combine with four hydrogen atoms. Carbon and hydrogen will complete each other valence shells by sharing electrons as shown in the following product: → Repeat the same explanation this time using oxygen and water. The product will look like Chemistry Unit Plans → Draw the unpaired electrons from valence shell of oxygen as paired up. The atomic diagrams for the water molecule above shows those electrons as paired up oriented in the space (tetrahedral) but is better to show these electrons together as in At this point is good to give students several exercises to practice drawing covalent bonds in the formation of molecular compounds. Repeat the same two examples above ( C + H and O + H) this time using the Lewis dot structures or letter symbols for each atom. The products as well as other example products are shown below: **Address misconceptions and prevent misunderstanding: Notice that lone pair electrons already part of a Lewis dot symbol are not normally used for bonding but left unused in the same place around the atom. That’s the case for N group, O group or column, and fluorine family which all have lone pair electrons. **Tell students that the final shared electronic arrangement in the product of covalent bonds (molecular compounds) resembles the electronic arrangement of noble gases in the sense that every atom now has the valence shell completed with eight electrons as dictated by the Octet Rule (Hydrogen is an exception). Give students several exercises to practice formation of molecular compounds through sharing electrons (covalent bonding). In the case of compounds containing multiple bonds repeat the same explanation as above using carbon and oxygen. The product is Chemistry Unit Plans 2 Again, the oxygen atoms should show the lone pair electrons unused (absent in the diagram above). Another good example is taking two nitrogen atoms and combining them together to form a triple bond. Each nitrogen atom will carry a lone pair electron. Give students several exercises to practice multiple bonds using Lewis dot structures like formation of O2, P2, C2H2 and the ones below: The use of the Periodic Table to predict valence shells and charges This is better achieved through an activity: Ask students to draw Lewis dot symbols for each of the first 18 elements of the periodic table using a blank periodic table as template. Once finished, students should be able to visualize the trends and patterns per family or groups (showing the same valence shell per column). Show the positive charge for every metal by looking at how many electrons a particular metal atom loses (all electrons from valence shell). Show the negative charge for a nonmetal atom by looking at how many electrons the nonmetal atom needs to complete eight electrons in the valence shell. As with the valence shell patterns, the groups or families also display the same charge. Assessments/Probes Formative Assessment There are several formative assessments embedded in the “Learning progression” above as classwork and assignments. Make sure students are getting the right understanding and visuals (diagrams and Lewis symbols) from those applications or class exercises. Chapter assessments from the textbook are a good source of Summative Assessment http://www.nysedregents.org/chemistry/ Use textbook assessments and other sources of multiple choices and context problem items to assess students through a test. Chemistry Unit Plans homework for the purpose of practice and assessment of skills associated with writing ionic and covalent compounds. Is it a Solid? Formative Assessments Packaged-2.pdf Pennies Formative Assessments Packaged.pdf Vocabulary ionic compounds, metallic compounds, covalent compounds, single bonds, double bonds, triple bonds monoatomic, polyatomic, molecule, covalent, valence electron, patterns, trends Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 3 - Bonding Extraordinary power point delivering the same lessons depicted in this standard: http://www.cottonchemistry.bizland.com/chapter9/Chapter%209%20Chemical%20Names%20an d%20Formulas.ppt#387,14,Predicting Ionic Charges Chemistry Unit Plans Week 4 -- Spiral Back/Review/Exam CCS Science Curriculum Unit Chemistry Clarifying Objective: 1.1.3 Week: 5 Days: 5 days Essential Standard Chm.1.3 Classify the components of the Periodic Table. Explain the characteristics of the elements based on their position on the Periodic Table. Clarifying Objectives Chm.1.3.1 - Classify the components of a periodic table (period, group, metal, metalloid, nonmetal, transition) using the Periodic Table, Groups (families) Chm.1.3.2 Infer the physical properties (atomic radius, metallic and nonmetallic characteristics) of an element based on its position on the Periodic Table. Chm.1.3.3 Infer the atomic size, reactivity, electronegativity, and ionization energy of an element from its position on the Periodic Table Essential Questions 1 W1. What can be determined about elements that are located in the same vertical column? Knowledge/Skills 2. What trends are able to be predicted by utilizing the periodic table? 3. Why are there different colors of light emitted from different elements? 4. Where are metals, non-metals, Identify groups as vertical columns on the periodic table. o Know that main group elements in the same group have similar properties, the same number of valence electrons, and the same oxidation number. o Summarize that reactivity increases as you go down within a group for metals and decreases for nonmetals. Periods Chemistry Unit Plans metalloids, halogens, noble gases, inner transition metals, and outer transition metals located? 5. Can you explain the trends as it relates to the electrons and the nucleus? (Shielding, atomic radius, etc.) 6. When given two different elements, can you differentiate the differences in physical properties? 7. Can you write the correct electron configuration of any element based on the position of the element on the periodic table? o Identify periods as horizontal rows on the periodic table. Metals/Nonmetals/Metalloids o Identify regions of the periodic table where metals, nonmetals, and metalloids are located. o Classify elements as metals/nonmetals/metalloids based on location. Representative elements (main group) and transition elements o Identify representative (main group) elements as A groups or as groups 1, 2, 13-18. o Identify alkali metals, alkaline earth metals, halogens, and noble gases based on location on periodic table. o Identify transition elements as B groups or as groups 3-12. Infer the physical properties (atomic radius, metallic and nonmetallic characteristics) of an element based on its position on the Periodic Table. Using the Periodic Table, Atomic and ionic radii o Define atomic radius and ionic radius. o Know group and period general trends for atomic radius. o Apply trends to arrange elements in order of increasing or decreasing atomic radius. Explain the reasoning behind the trends. o Compare cation and anion radius to neutral atom. Metallic Character o Compare the metallic character of elements. o Use electron configuration and behavior to justify metallic character. (Metals tend to lose 8. Can you predict the oxidation number of an element according to its position on the periodic table? Chemistry Unit Plans electrons in order to achieve the stability of a filled octet.) o Relate metallic character to ionization energy, electron affinity, and electronegativity. Electron configurations/valence electrons/ionization energy/electronegativity o Write electron configurations, including noble gas abbreviations (no exceptions to the general rules). Included here are extended arrangements showing electrons in orbitals. o Identify s, p, d, and f blocks on Periodic Table. Identify an element based on its electron configuration. (Students should be able to identify elements which follow the general rules, not necessarily those which are exceptions.) Determine the number of valence electrons from electron configurations. Predict the number of electrons lost or gained and the oxidation number based on the electron configuration of an atom. Infer the atomic size, reactivity, electronegativity, and ionization energy of an element from its position on the Periodic Table Define ionization energy and know group and period general trends for ionization energy. Explain the reasoning behind the all trends. Apply trends to arrange elements in order of increasing or decreasing ionization energy. Define electronegativity and know group and period general trends for electronegativity. Explain the reasoning behind the trend. Chemistry Unit Plans Vertical Alignment 6.P.2.1 Recognize that all matter is made up of atoms and atoms of the same element are all alike, but are different from the atoms of other elements. PSc.2.1.4 Interpret data presented in Bohr model diagrams and dot diagrams for atoms and ions of elements 1 through 18. PSc.2.2.1 Infer valence electrons, oxidation number, and reactivity of an element based on its location in the Periodic Table. PSc.2.2.2 Infer the type of chemical bond that occurs, whether covalent, ionic or metallic, in a given substance. Learning Progressions By properly introducing the Periodic table, students will be able to utilize the table as a tool to predict bonding types, proper formulations of different compounds, nomenclature, and various physical properties of the elements based solely on its position on the periodic table. Students should label the periodic table with the following information: Groups, families, charges, energy levels, orbital blocks, trends in electronegativity, ionic size, ionic radius, reactivity, ionization energy, the alkali, alkaline earth metals, transition metals, metalloids, halogens and noble gases. After discussing the layout of the periodic table, emphasis should be placed on understanding the trends by comprehending the interaction of the nucleus with the outer shell electrons. Factors like shielding, ionization energy and atomic radius correlation, and octet rule should be reinforced to provide conceptual understanding of the trends instead of merely memorizing the trends. Assessments/Probes Formative Assessment Summative Assessment Chemical Bonds Formative Assessments Packaged-4.pdf http://www.nysedregents.org/chemistry/ Is It Made of Molecules Formative Assessments Packaged-10.pdf Vocabulary first ionization energy, second ionization energy, electronegativity, octet rule, alkali groups, families, Mendeleev, periodicity, ionic radius, and orbitals Chemistry Unit Plans metals, alkaline metals, anion, atomic radius, cation, electronegativity, halogens, ion, ionization energy, metalloids, metals, noble gases, periodic law, transition metals, Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 4 - Periodic Trends Resource Folder\EOC Sets\EOCSet4-Periodic Trends.doc CCS Science Curriculum Unit Chemistry Clarifying Objective: 1.2.5 Week: 6 Days: 5 Days Essential Standard Chm.1.2 Compare the properties of ionic, covalent, metallic, and network compounds. Explain the characteristics of the elements based on their position on the Periodic Table. Clarifying Objectives Chm.1.2.5 Compare the properties of ionic, covalent, metallic, and network compounds. Chm.1.2.3 Compare inter- and intra- particle forces. Chm.1.2.4Interpret the name and formula of compounds using IUPAC convention. Essential Questions Knowledge/Skills 1. What are characteristics of ionic bonding? • What are characteristics of covalent bonds? What are the characteristics of metallic bonding? • What is bond polarity? W What is VSEPR Theory? Why do bond angles change when lone pairs of electrons are present? • Explain how ionic bonding in compounds determines their characteristics: high MP, high BP, brittle, and high electrical conductivity either in molten state or in aqueous solution. Explain how covalent bonding in compounds determines their characteristics: low MP, low BP, poor electrical conductivity, polar nature, etc. Explain how metallic bonding determines the characteristics of metals: high MP, high BP, high conductivity, malleability, ductility, and luster. Chemistry Unit Plans • What are the different molecular geometrical shapes? • Can you rank the relative strength of the different types of bonds including Hydrogen bonds, dipole-dipole forces and dispersion forces? What are double and triple bonds? What are the different intermolecular forces in molecular compounds? • When are prefixes used to name compounds? • Does the name of the metal always come first when naming binary ionic compounds? • What is meant by the term polyatomic ion? When must Roman Numerals be used when writing ionic compounds? • • What does the Roman Numeral signify? How are charges assigned to Group I, II, and Al? How are charges assigned to the nonmetals? Are charges important when naming covalent compounds? • • • • • • • Describe bond polarity. Polar/nonpolar molecules (relate to symmetry) ; relate polarity to solubility—“like dissolves like” Apply Valence Shell Electron Pair Repulsion Theory (VSEPR) for these electron pair geometries and molecular geometries, and bond angles - Electron pair - Molecular (bond angle); Linear framework – linear; Trigonal planar framework– trigonal planar, bent; Tetrahedral framework– tetrahedral, trigonal pyramidal, bent; Bond angles (include distorting effect of lone pair electrons – no specific angles, conceptually only) Explain why intermolecular forces are weaker than ionic, covalent or metallic bonds Explain why hydrogen bonds are stronger than dipole-dipole forces which are stronger than dispersion forces Apply the relationship between bond energy and length of single, double, and triple bonds (conceptual, no numbers). Describe intermolecular forces for molecular compounds. H-bond as attraction between molecules when H is bonded to O, N, or F. Dipoledipole attractions between polar molecules. London dispersion forces (electrons of one molecule attracted to nucleus of another molecule) – i.e. liquefied inert gases. Relative strengths (H>dipole>London/van der Waals). Write binary compounds of two nonmetals: use Greek prefixes (di-, tri-, tetra-, …) Write binary compounds of metal/nonmetal* Write ternary compounds (polyatomic ions)* Write, with charges, these polyatomic ions: nitrate, sulfate, carbonate, acetate, and ammonium. Know names and formulas for these Chemistry Unit Plans • common laboratory acids: HCl, HNO3, H2SO4, HC2H3O2, (CH3COOH) *The Stock system is the correct IUPAC convention for inorganic nomenclature. Vertical Alignment PSc.2.2.2 Infer the type of chemical bond that occurs, whether covalent, ionic or metallic, in a given substance. PSc.2.2.3 Predict chemical formulas and names for simple compounds based on knowledge of bond formation and naming conventions. Learning Progressions This is a one day unit. The students will be introduced to bonding elements together and discovering what type of bond is occurring. Based on the type of bonding that occurs, different characteristics can be observed. Use different properties to have students deduce what type of bond is present. Provide examples of element that combine and predict what type of bonds will form. Students should understand the repulsion that electrons have when forming bonds. This repulsion causes different molecular shapes and is compounded when lone pairs of electrons are involved. By discussing intermolecular forces, students can identify the reasons why different compounds have different geometries. Students will reinforce their knowledge of the Periodic Table by identifying the different elements that will be involved in bonding. They should be able to identify charges of the metals (Except Transition Metals) and the charges of the nonmetals based on their group number. All ionic bonds must have an equal number of positive charges from the cation to compliment the charges of the non-metals. Transition Metals must have a Roman Numeral to assign the positive charge of the ion due to their variable valence numbers. Covalent bonding uses prefixes with the exception of Mono- on the first nonmetal if singular. Assessments/Probes Formative Assessment Summative Assessment Resource Folder\Chemistry Essential Standard Probes\Week 5 F.A. Probes http://www.nysedregents.org/chemistry/ Chemistry Unit Plans Vocabulary covalent, ionic bond, metallic bond, conductor, chemical formula, electron dot structure, ionic bonds, ionic compounds, metallic bonds, octet rule, valence electron, bond dissociation energy, diatomic molecule, covalent compound, polar bond, unshared pair, VSEPR theory, molecule, hydrogen bond, intermolecular forces polarity, malleability, ductility, melting point Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 5 - Nomenclature Resource Folder\EOC Sets Resource Folder\EOC Sets\EOCSet7.doc CCS Science Curriculum Unit Chemistry Clarifying Objective: 2. 2.3 Week: 7 Days: 6 (One Week and One Day) Essential Standard Chm.2.2 Analyze chemical reactions in terms of quantities, product formation, and energy. Clarifying Objectives Chm.2.2.2 Analyze the evidence of chemical change. Chm.2.2.3 Analyze the Law of Conservation of Matter and how it applies to various types of chemical equations (synthesis, decomposition, single replacement, double replacement, and combustion). Chemistry Unit Plans Essential Questions Knowledge/Skills What are the products of an acid-base neutralization reaction? What is water’s unique property due to hydrogen bonding? List and explain all of the common symbols used in chemical equations. What 2 quantities are always conserved in every chemical reaction? What is the law of conservation of mass in terms of definite and multiple proportions? Write complete equations and balance them from word equations. Students know how to: • Identify acid-base neutralization as double replacement. • Write and balance ionic equations. • Write and balance net ionic equations for double replacement reactions. • Recognize that hydrocarbons (C, H molecule) and other molecules containing C, H, and O burn completely in oxygen to produce CO2 and water vapor. • Use reference table rules to predict products for all types of reactions to show the conservation of mass. • Use activity series to predict whether a single replacement reaction will take place. • Use the solubility rules to determine the precipitate in a double replacement reaction if a reaction occurs. What is used to identify whether a substance is soluble or insoluble? What are ions called that are not directly involved in the reaction? Take a word equation, write a skeleton equation, balance it, identify solids and aqueous solutions, write complete ionic equation, cross out spectators and write out the net ionic equation. What are the indicators of a chemical change? Vertical Alignment PSc.2.2.3 Predict chemical formulas and names for simple compoundsbased on knowledge of bond formation and namingconventions. PSc.2.2.4 Exemplify the Law of Conservation of mass by balancingchemical equations. PSc.2.2.5 Classify types of reactions such as synthesis, decomposition,single replacement or double replacement. Chemistry Unit Plans Learning Progressions Monitor and coach students as they write and balance equations, as they work on classifying types of reactions and write balanced net ionic equations. Be sure to pay close attention to students (to assure proper usage) as they use they use their reference table to access the activity series to predict products for single replacement reactions(ONLY) and as they review the solubility rules to determine whether or not a precipitate will form based upon if a cmpd is soluble or insoluble. Assessments/Probes Formative Assessment Burning Paper\Burning Paper Formative Assessment.pdf Nails in a Jar Cookie Crumbles Formative Assessments Packaged-3.pdf Ice Cubes in a bag Formative Assessments Packaged.pdf Lemonade Formative Assessments Packaged-2.pdf Mixing Water Formative Assessments Packaged-5.pdf The Rusty Nails Formative Assessments Packaged-6.pdf Resource Folder\Chemistry Essential Standard Probes\Week 6 F.A. Probes Summative Assessment http://www.nysedregents.org/chemistry/ Using the textbook’s assessments, test generators, the internet, research each topic from the knowledge/skills section above under the headline “Chemical Reactions multiple choice test” –as one example- and you can put together a test with valuable items that are inquiry and critical thinking oriented. Make sure to include items under different formats (multiple choices, fill in the blank, scenarios, short answers…) that test students’ understanding of concepts and applications like: Balancing equations. Identifying types of Rxns. Writing skeleton equations based off of nomenclature. Writing balanced net ionic equations (identifying spectator ions). Indicators of a chemical change. Will a precipitate form or not. Chemistry Unit Plans Vocabulary Avogadro’s number, empirical formula, molar mass, molar volume, mole, percent composition, representative particle, STP, activity series, balanced equation, catalyst, chemical equation, coefficients, combination reaction, combustion reaction, decomposition reaction, completes ionic equation, spectator ion, single replacement reaction, skeleton equation Resources Formative and Summative Assessment Tutorial: www.studyisland.com DPI resources addressing this objective: www.ncpublicschools.org/accountability/.../sampleitems/6 Resource Folder\Presentational Files (PowerPoint’s)\Week 6 - Reactions Resource Folder\EOC Sets\EOCSet6.doc Week 8 – Spiral Back/Review/ Exam Chemistry Unit Plans CCS Science Curriculum Unit Chemistry Clarifying Objective: 2.2.4 Week: 9 Days: 4 (week 6 carried over by 1 day) Essential Standard Chm.2.2Analyze chemical reactions in terms of quantities, product formation, and energy. Clarifying Objectives Chm.2.2.4 Analyze the stoichiometric relationships inherent in a chemical reaction. Chemistry Unit Plans Chm.2.2.5Analyze quantitatively the composition of a substance (empirical formula, molecular formula, percent composition, and hydrates). Essential Questions Knowledge/Skills What are molar ratios? Can you change the subscripts within a chemical compound or must you only change coefficients? Why do we assume we have 100 grams of the compound in question? Differentiate between empirical formula and molecular formula. What does part/whole times 100 mean in terms of % composition? How do you identify compounds with hydrates? Compare hydrate versus anhydrous ionic compound. Interpret coefficients of a balanced equation as mole ratios. • Use mole ratios from the balanced equation to calculate the quantity of one substance in a reaction given the quantity of another substance in the reaction. (given moles, particles, mass, or volume and ending with moles, particles, mass, or volume of the desired substance) • Calculate empirical formula from mass or percent using experimental data. • Calculate molecular formula from empirical formula using molecular weight. • Determine percentage composition by mass of a given compound. 1. • Perform calculations based on percent composition. • Determine the composition of hydrates using experimental data. Vertical Alignment Chem 2.2.3 Analyze the Law of Conservation of Matter and how it applies to various types of chemical equations (synthesis, decomposition, single replacement, double replacement, and combustion). Learning Progressions Students should understand that molar ratios are the equivalent to a recipe. There are a Chemistry Unit Plans known number of reactants that yield a known amount of product. The students should be able to replace the number of moles with their equivalent volume (gas at STP), equivalent weight via molar mass, and the number of particles (Avagadro’s Number) and vice versa. Once students master the mole concept, they should be able to take that knowledge and apply it to finding out theoretical yields. Differentiate the meaning of actual yield and theoretical yield, and have them find out the “efficiency” of the reaction. The learner can then grasp the concept of empirical formula by understanding percent composition. Hydrates can be introduced after empirical formula when we talk about anhydrous versus hydrate compounds. Assessments/Probes Formative Assessment Summative Assessment Resource Folder\Chemistry Essential Standard Probes\Week 7 F.A. Probes http://www.nysedregents.org/chemistry/ Vocabulary actual yield, excess reagent, limiting reagent, mole ratio, percent yield, stoichiometry, theoretical yield Strategy for vocabulary: Writing a recipe, brochure. Resources www.studyisland.com www.ncpublicschools.org/accountability/.../sampleitems/6 Lessons in action videos: Resource Folder\Presentational Files (PowerPoint’s)\Chemistry-Week 7.doc Resource Folder\Presentational Files (PowerPoint’s)\Week 6-7 - The Mole Concept Resource Folder\Labs From Scott Grumelot\Lab7Stoichiometry.doc Resource Folder\EOC Sets\EOC Set 8 - Stoichiometry Problems.doc Chemistry Unit Plans CCS Science Curriculum Unit Chemistry Clarifying Objective: 2.2.1 Weeks: 10 Days: 5 Essential Standard Chm.2.2 Analyze chemical reactions in terms of quantities, product formation, and energy. Clarifying Objectives Chm.2.2.1 Explain the energy content of a chemical reaction. Chm.2.1.3 Interpret the data presented in phase diagrams. Chm.2.1.4 Infer simple calorimetric calculations based on the concepts of heat lost equals heat gained and specific heat. Essential Questions Using a reaction coordinate diagram for an exothermic reaction explain each of the following concepts and locate the concept in the diagram: a) energy of reactant(s) and product(s), b) activation energy, c) activated complex, d) transition state, e) energy consumption (energy barrier or activation energy), f) energy production (excess heat), g) and ground state energy (lower energy level where the substance is more stable). Answer the above questions for an endothermic reaction coordinate diagram. Calculate the heat necessary to change 10 g of ice(s) at 0°C to 10 g of water(l) at 0°C Knowledge/Skills Students know how to: • Explain collision theory – molecules must collide in order to react, and they must collide in the correct or appropriate orientation and with sufficient energy to equal or exceed the activation energy. • Interpret potential energy diagrams for endothermic and exothermic reactions including reactants, products, and activated complex. • Draw phase diagrams of water and carbon dioxide (shows how sublimation occurs). Identify regions, phases and phase changes using a phase diagram. • Use phase diagrams to determine information such as (1) phase at a given temperature and pressure, (2) boiling point or melting point at a given pressure, (3) triple point of a material. • Recognize that, for a closed system, energy is neither lost nor gained only transferred between Chemistry Unit Plans Write thermochemical equations for each of the following: a) the vaporization of one mole of chloromethane, CH3Cl(l) b) ΔHo c) vap = 21.5 kJ/mol d) components of the system. • Complete calculations of: q=mCpΔT, q = mHf , q = mHv, and q lost=(-q gain) in water, including phase changes, using laboratory data. b) the solidification of one mole of water. The combustion of methane is an exothermic process that releases 890.4 kJ of f) energy. e) a) Write a balanced chemical equation for this reaction and include the g) enthalpy change as a term in the equation. Nitrogen gas reacts with oxygen gas to produce dinitrogen monoxide gas. i) 2 N2(g) + O2(g) + 163.2 kJ → 2 N2O(g) h) j) Is the reaction endothermic? a) or exothermic? Explain. Consider this equation for a reaction that occurs in a catalytic converter of an automobile. 2 CO(g) + 2 NO(g) → N2(g) + 2 CO2(g) + 746 kJ a) How much energy is released per mole of carbon dioxide gas produced? Vertical Alignment PSc.2.1.2 Explain the phases of matter and the physical changes that matter undergoes. Chemistry Unit Plans PSc.2.2.4 Exemplify the Law of Conservation of mass by balancing chemical equations. Chem 1.2.3 Compare inter- and intra- particle forces. Chem. 2.2.3 Analyze the Law of Conservation of Matter and how it applies to various types of chemical equations (synthesis, decomposition, single replacement, double replacement, and combustion). Chem. 2.2.4Analyze the stoichiometric relationships inherent in a chemical reaction. Learning Progressions Introduce this unit by explaining that a chemical reaction is incomplete without showing the energy component associated with either reactants or products, chemical reactions consume or produce energy. Use the applet below or any other equivalent resource to explain the kinetic theory of gas particles. Make sure you use appropriate concepts like particles travel in straight lines at a constant speed only changed by changes in temperature, the collisions between particles are elastic collisions (meaning the energy is not lost or gained but stays constant if temperature is constant). In a liquid, the kinetic theory applies much in the same way but particles move past each other. The kinetic theory of particles in a solid material is minimum due to the particles being held together through chemical bonds; only able to vibrate and rotate but not translational movement (These are called degrees of freedom). Click on the applet below to redirect your browser to the interactive or animated view. Chemistry Unit Plans The temperature of an ideal monatomicgas is a measure of the average kinetic energy of its atoms. The size of helium atoms relative to their spacing is shown to scale under 1950 atmospheres of pressure. The atoms have a certain, average speed, slowed down here two trillionfold from room temperature. Introduce this unit by explaining that a chemical reaction is incomplete without showing the energy component associated with either reactants or products, chemical reactions consume or produce energy. The diagram below represents this concept during a chemical reaction. Explain that molecules must collide in order to react, and they must collide in the correct or appropriate orientation and with sufficient energy to equal or exceed the activation energy. Factors affecting the rate of collision are concentration, higher temperature, stirring, and surface area of colliding molecules/particles. Use the following reaction coordinate diagram for an exothermic reaction to introduce and to explain the concepts of energy of reactant(s) and product(s), activation energy, activated complex, transition state, energy consumption (energy barrier or activation energy), energy production (excess heat), and ground state energy (lower energy level where the substance is more stable). Chemistry Unit Plans Diagram of a catalytic reaction, showing the energy niveau depending on the reaction coordinate. For a catalyzed reaction, the activation energy is lower. Use the following reaction coordinate diagram for an endothermic reaction to introduce and to explain the concepts of energy of reactant(s) and product(s), activation energy, activated complex, transition state, energy consumption (energy barrier or activation energy), energy production (excess heat), and ground state energy (lower energy level where the substance is more stable). Together, the products O2 and atomic O, have a higher energy than the reactant O3 and energy must be added to the system for this reaction. This is primarily due to the very high energy (low stability) of the oxygen atom that is produced. The oxygen atom produced has a higher energy than ground state oxygen. Energy, either light or heat energy, added to the ozone will cause one O-O bond to break. Use the following diagram or its equivalent to explain the different physical changes (phase changes) that occur in a material when submitted under different changes of temperature and pressure. This a phase diagram for water, showing all three phases. The lines represent conditions of equilibrium between phases. Chemistry Unit Plans The blue lines represent conditions of equilibrium. For example, there is an equilibrium between ice and liquid (melting and freezing) represented by the vertical blue line separating both areas. This equilibrium is written as The Triple point is the condition of temperature and pressure in at which all three phases exist together at equilibrium. For water, this is 0.0099 °C and 0.006 atmospheres. Law of conservation of matter Chemistry Unit Plans Heat transfers from higher energy matter to lower energy matter: q= m Cp ∆T Heat transfer during a phase change: ∆Hm ∆Hfreezing ∆Hvap ∆Hc etc. Assessments/Probes Formative Assessment Summative Assessment Freezing Ice Formative Assessments Packaged.pdf http://www.nysedregents.org/chemistry/ Ice Cold Lemonade Formative Assessments Packaged-3.pdf Is it Melting? Formative Assessments Packaged-9.pdf Objects and Temp Formative Assessments Packaged-7.pdf The Mitten Problem Formative Assessments Packaged-8.pdf What’s in the Bubbles? Formative Assessments Packaged-2.pdf Ice Water Formative Assessments Packaged-6.pdf Vocabulary endothermic process, enthalpy, exothermic process, heat, heat capacity, heat of combustion, heat of reaction, Hess’s Law, Law of Conservation of Mass, specific heat, standard heat of formation, surroundings, system, thermochemical equation, and thermochemistry Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 8 -- Heat Resource Folder\EOC Sets\EOCSet9.doc www.ncpublicschools.org/accountability/.../sampleitems/6 Chemistry Unit Plans CCS Science Curriculum Unit Chemistry Clarifying Objective: 2.1.5 & 3.2.4 Week: 11 Days: 5 Essential Standard Chm.2.2Analyze chemical reactions in terms of quantities, product formation, and energy. Clarifying Objectives Chm.2.1.5 Explain the relationships among pressure, temperature, volume, and quantity of gas, both qualitative and quantitative. Chm.3.2.4 Summarize the properties of solutions. Essential Questions Knowledge/Skills What is STP? Name the units and equivalence statements at STP. W What are the relationships with gas solubility and pressure and temperature? Name the four gas laws that are used when one variable is held constant. What determines the R value we use in the ideal gas law? Identify characteristics of ideal gases. • Apply general gas solubility characteristics. • Apply the following formulas and concepts of kinetic molecular theory. Combined gas law (P1V1/T1 = P2V2/T2) and applications holding one variable constant: for PV=k, P1V1 = P2V2; for V/T=k, V1/T1= V2/T2; for P/T=k, P1/T1 = P2/T2. Note: Students should be able to derive and use these gas laws, but are not necessarily expected to memorize their names. Ideal gas equation (PV=nRT) Avogadro’s law (n/V=k), n1/V1 = n1/V2 Dalton’s law (Pt=P1+P2+P3 …) Vapor pressure of water as a function of temperature (conceptually). Whose law says all the partial pressures must add up to the total pressure? Compare and contrast homogenous and heterogeneous. What is an electrolyte? What are the different types of solutions? Chemistry Unit Plans Chem.3.2.4 Summarize the properties of solutions. Explain the colligative properties. • Identify types of solutions (solid, liquid, gaseous, aqueous). • Define solutions as homogeneous mixtures in a single phase. • Distinguish between electrolytic and non-electrolytic solutions. • Summarize colligative properties (vapor pressure reduction, boiling point elevation, freezing point depression, and osmotic pressure). Vertical Alignment 6.P.2.3 Compare the physical properties of pure substances that are independent of the amount of matter present including density, melting point, boiling point, and solubility to properties that are dependent on the amount of matter present to include volume, mass and weight PSc.2.1.3 Compare physical and chemical properties of various types of matter. Chem 2.2.4Analyze the stoichiometric relationships inherent in a chemical reaction. Chem 2.1.3 Interpret the data presented in phase diagrams. Learning Progressions The gas laws are basic algebra word problems. Students should be able to identify which variable is constant, and to identify conditions that are not at STP. Pressure units will determine the R value we use in the Ideal Gas Law. The introduction to solutions will allow the students to identify hetero/homogeneous solutions and identify the colligative properties. Assessments/Probes Formative Assessment Warming Water Formative Assessments Packaged-7.pdf Summative Assessment http://www.nysedregents.org/chemistry/ Chemistry Unit Plans Floating Balloon Formative Assessments Packaged-4.pdf Hot and Cold Balloons Formative Assessments Packaged-5.pdf Thermometer Formative Assessments Packaged-3.pdf Vocabulary surfactant, suspension, surface tension, Tyndall effect, weak electrolyte, Boyles Law, Charles, Law, Combined Gas Law, compressibility, Daltons Law of partial pressure, diffusion, effusion, Gay-Lussacs Law, Grahams law of effusion aqueous solution, Brownian motion, colloid, electrolyte, emulsion, hydrate, non-electrolyte, solute, solvation, solvent, strong electrolyte, ideal gas constant, ideal gas law, partial pressure Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 9 --The gas laws *www.scilinks.org www.ncpublicschools.org/accountability/.../sampleitems/6 www.delicious.com/kwcombs2010 search tags with chemistry Chemistry Unit Plans Week 12 – Spiral back/Review/Exam CCS Science Curriculum Unit Clarifying Objective: 3.1.1, 3.2.6, 3.2.5. Week: 13 Days: 5 Chemistry Unit Plans Chemistry Essential Standard Chm.3.1Understand the factors affecting rate of reaction and chemical equilibrium. Clarifying Objectives Chm. 3.1.1 Explain the factors that affect the rate of a reaction (temperature, concentration, particle size and presence of a catalyst). Chm. 3.2.6 Explain the solution process. Chm. 3.2.5 Interpret solubility diagrams. Essential Questions Knowledge/Skills • How does (increasing or decreasing) the following factors affect the rate of a chemical reaction? -The nature of reactants -Temperature -Concentration -Surface area -Catalyst -Pressure • What causes a material to become insoluble? • Why are certain materials soluble? • What occurs during the solution process? Is the overall process endothermic or exothermic? Explain. • How can you identify substances using their physical properties? Or their solubility? • Use the solubility to graph to analyze the trend in solubility in gases and solids as Temperature increases or/and decreases • • • • • • • • Understand qualitatively that reaction rate is proportional to number of effective collisions. Explain that nature of reactants can refer to their complexity and the number of bonds that must be broken and reformed in the course of reaction. Explain how temperature (kinetic energy), concentration, and/or pressure affect the number of collisions. Explain how increased surface area increases number of collisions. Explain how a catalyst lowers the activation energy, so that at a given temperature, more molecules will have energy equal to or greater than the activation energy. Develop a conceptual model for the solution process with a cause and effect relationship involving forces of attraction between solute and solvent particles. A material is insoluble due to a lack of attraction between particles. Describe the energetics of the solution process as it occurs and the overall process as exothermic or endothermic. Explain solubility in terms of the nature of solute-solvent attraction, temperature and pressure (for gases). Use graph of solubility vs. temperature to identify a substance based on solubility at a Chemistry Unit Plans • particular temperature. Use graph to relate the degree of saturation of solutions to temperature. Vertical Alignment Chem 2.2.1 Explain the energy content of a chemical reaction Chem. 3.2.4 Summarize the properties of solutions Learning Progressions Assessments/Probes Formative Assessment Summative Assessment Sugar Water Formative Assessment.pdf http://www.nysedregents.org/chemistry/ Resource Folder\Chemistry Essential Standard Probes\Week 10 Vocabulary solubility, aqueous solution, Brownian motion, colloid, electrolyte, emulsion, hydrate, non-electrolyte, solute, solvation, solvent, strong electrolyte, surfactant, suspension, surface tension, Tyndall effect, weak electrolyte, activation energy, catalyst, saturated solutions, unsaturated solutions, super-saturated solutions Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 10 and 11 and 13-- Solutions and Equilibrium www.studyisland.com www.scilinks.org www.ncpublicschools.org/accountability/.../sampleitems/6 www.delicious.com/kwcombs2010 search tags with chemistry Chemistry Unit Plans CCS Science Curriculum Unit Chemistry Clarifying Objective: 3.1.2 & 3.1.3 Week: 14 Days: 5 Essential Standard 3.1 Understand the factors affecting rate of reaction and chemical equilibrium. Clarifying Objectives 3.1.2Explain the conditions of a system at equilibrium. 3.1.3 Infer the shift in equilibrium when a stress is applied to a chemical system. Essential Questions Explain what is meant by forward reaction and reverse reactions. What are the factors that affect equilibrium? What is meant by stresses on a reaction? What happens if concentration of a reactant is increased? Where would the shift favor? Knowledge/Skills Define chemical equilibrium for reversible reactions. • Distinguish between equal rates and equal concentrations. • Explain equilibrium expressions for a given reaction. • Evaluate equilibrium constants as a measure of the extent that the reaction proceeds to completion. • Determine the effects of stresses on systems at equilibrium. (Adding/ removing a reactant or product; adding/removing heat; increasing/decreasing pressure) Chemistry Unit Plans • Relate the shift that occurs in terms of the order/disorder of the system. Vertical Alignment Chem 2.2.3 Analyze the Law of Conservation of Matter and how it applies to various types of chemical equations (synthesis, decomposition, single replacement, double replacement, and combustion). Chem 2.2.2 Analyze the evidence of chemical change. Chem 2.1.3 Interpret the data presented in phase diagrams. Chem 3.2.4 Summarize the properties of solutions. Learning Progressions Equilibrium is easily understood by visualizing a Newton’s Cradle. Explaining to the learners that when a reaction takes place, the products can become reactants and reverse the reaction. This happens until the system reaches equilibrium. Different stresses will favor either products or reactants. Assessments/Probes Formative Assessment Summative Assessment Resource Folder\Chemistry Essential Standard Probes\WEEK 11 http://www.nysedregents.org/chemistry/ Vocabulary equilibrium, shift, forward reaction, reverse reaction, and stressor Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 10 and 11 and 13-- Solutions and Equilibrium Chemistry Unit Plans *www.scilinks.org www.ncpublicschools.org/accountability/.../sampleitems/6 www.delicious.com/kwcombs2010 CCS Science Curriculum Unit Chemistry search tags with chemistry Clarifying Objective: 3.1.2 & 3.1.3 Week: 15 Days: 5 Essential Standard 3.2 Understand solutions and the solution process. Clarifying Objectives 3.2.1 Classify substances using the hydronium and hydroxide concentrations. 3.2.2 Summarize the properties of acids and bases. Essential Questions Knowledge/Skills Chemistry Unit Plans Contrast the properties of acids and bases. What does the pH scale tell us? Does a higher pH mean higher concentration? Does strength (high degree of dissociation) and pH have a direct correlation? What is a Hydronium ion? Distinguish between acids and bases based on formula and chemical properties. • Differentiate between concentration (molarity) and strength (degree of dissociation). No calculation involved. • Use pH scale to identify acids and bases. • Interpret pH scale in terms of the exponential nature of pH values in terms of concentrations. What is a Hydroxide ion? What must the Hydronium Ion concentration times the Hydroxide Ion concentration be equal to? Can you calculate pH of a given concentration Acidic solution? The pH plus the pOH must equal what? • Relate the color of indicator to pH using pH ranges provided in a table. • Compute pH, pOH, [H+], and [OH-]. - Distinguish properties of acids and bases related to taste, touch, reaction with metals, electrical conductivity, and identification with indicators such as litmus paper and phenolphthalein. Vertical Alignment PSc.2.2.3 Predict chemical formulas and names for simple compounds based on knowledge of bond formation and naming conventions. PSc.2.2.6 Summarize the characteristics and interactions of acids and bases. Chem 3.2.4 Summarize the properties of solutions. Chem 3.2.6 Explain the solution process. Learning Progressions Acids and bases are a continuation of equilibrium. Acids plus bases must equal an ionic salt plus water. A solution’s pH plus pOH must equal 14. The new standard does not differentiate between Arrhenius, Lewis, and Bronsted-Lowery Acids. We will use the H+ as the abbreviation for the Hydronium ion and OH- for the hydroxide ion. Assessments/Probes Chemistry Unit Plans Formative Assessment Summative Assessment Resource Folder\Chemistry Essential Standard Probes\Week 12 acids bases pH http://www.nysedregents.org/chemistry/ Vocabulary acid dissociation constant, acidic solution, alkaline solution, amphoteric, base dissociation constant, basic solution, buffers, buffer capacity, conjugate acid, conjugate acid-base pair, conjugate base, diprotic acid, end point, equivalence point, hydronium ion, ion-product constant for water, Lewis acid, Lewis base, monoprotic acids, neutral solution, neutralization, reaction, pH, salt hydrolysis, self-ionization, standard solution, strong acid, strong base, titration, triprotic Acid, weak acid & base Resources Resource Folder\Presentational Files (PowerPoint’s)\Week 12 -- pH *www.scilinks.org www.ncpublicschools.org/accountability/.../sampleitems/6 www.delicious.com/kwcombs2010 CCS Science Curriculum Unit Chemistry search tags with chemistry Clarifying Objective: 3.2.3 Week: 16 Days: 5 Essential Standard Chm.3.2 Understand solutions and the solution process. Chm.1.1 Analyze the structure of atoms and ions. Clarifying Objectives Chemistry Unit Plans Chm.3.2.3Infer the quantitative nature of a solution (molarity, dilution, and titration with a 1:1 molar ratio). Chm.1.1.4 Explain the process of radioactive decay by the use of nuclear equations and half-life. Essential Questions What is the molarity in moles per liter of solution of 5 grams NaCl dissolved in 200 ml of solution? How much Na2SO4 in grams is dissolved in 28.56 ml of a 1.5 M Na2SO4? Knowledge/Skills Students know how to: • Compute concentration (molarity) of solutions in moles per liter. • Calculate molarity given mass of solute and volume of solution. • Calculate mass of solute needed to create a solution of a given molarity and volume. • Solve dilution problems: M1V1 = M2V2. Which volume will 300 grams of a 0.5M • Ca(OH)2 occupy? • How many milliliters of a 4M NaCl solution should be dissolved to prepare 75 ml of a 1M NaCl solution? What is the concentration of a 25 ml sample of H2SO4 if it was titrated with 54 ml of 1.5M NaOH? Complete nuclear equations for each type of nuclear decay (or find out Perform 1:1 titration calculations: MAVA = MBVB Determine the concentration of an acid or base using titration. Interpret titration curve for strong acid/strong base. Chemistry Unit Plans the mystery element or particle) In β+ decay, the total number of protons is increased, decreased, or unchanged? In αalpha decay, the total number of protons is increased by 2, decreased by 4, decreased by 2, unchanged? In β- decay, the total number of nucleons is increased by 1, decreased by 1, decreased by 2, unchanged? An atom that undergoes electron capture (beta particle) emits a: gamma ray, positron, helium nucleus, and electron? What type of radioactive decay does not change the atomic number or mass number of an Chemistry Unit Plans element? A. B. C. D. electron capture gamma ray alpha decay beta decay If you have 200.0 g of radioisotope with a half-life of 5 days, how much isotopewould remain after 15 days? 25 g. Which fact is not important when drawing conclusions from C–14 dating? Living organisms exchange carbon with the atmosphere. C–14 has a halflife of 5,730 years. Dead organisms do not exchange carbon with the atmosphere. C–14 emits beta particles. Vertical Alignment PSc.2.3.1 Compare nuclear reactions including; alpha decay, beta decay and gamma decay; nuclear fusion and nuclear fission. Chemistry Unit Plans PSc.2.3.2 Exemplify the radioactive decay of unstable nuclei using the concept of half-life. Chem 2.2.4 Analyze the stoichiometric relationships inherent in a chemical reaction. Chem 3.2.1 Classify substances using the hydronium and hydroxide concentrations. Chem 3.2.2 Summarize the properties of acids and bases. Learning Progressions Molarity Dilution, M1V1 = M2V2 Titration Lab activity: Titration Show how to complete nuclear equations for the radioactive decay of a) Alpha decay, 24He b) Beta decay, -10e c) Gamma decay, ooγ Emphasize to the students that it is important for them to memorize each of the nuclear particles’ symbols, charges, mass, and atomic numbers. Assign several examples of nuclear equations for the students to complete. Example: alpha decay → 24He+2 + 90134Th 138 U 92 Tell students that the nuclear equations are very simple IF completed by applying the law of conservation of mass numbers and atomic numbers on both sides of the equation. Compare the penetrating ability of alpha, beta, and gamma radiation. Half-life and the use of carbon dating. Compare radioactive decay with fission and fusion Assessments/Probes Formative Assessment Summative Assessment Resource Folder\Chemistry Essential Standard Probes\WEEK 13 Molarity http://www.nysedregents.org/chemistry/ Review Links with all subject matter included: Chemistry Unit Plans Resource Folder\Chemistry Essential Standard Probes\WEEK 13 Nuclear decay http://www.iq.poquoson.org/2008vasol/eocchem/eocchem08.htm http://www.iq.poquoson.org/2007vasol/eocchem/eocchem07.htm http://www.iq.poquoson.org/2005vasol/eocchem/eocchem05.htm Additional F.A. Questions: What is the molarity in moles per liter of solution of 5 grams NaCl dissolved in 200 ml of solution? How much Na2SO4 in grams is dissolved in 28.56 ml of a 1.5 M Na2SO4? Which volume will 300 grams of a 0.5M Ca(OH)2 occupy? How many milliliters of a 4M NaCl solution should be dissolved to prepare 75 ml of a 1M NaCl solution? What is the concentration of a 25 ml sample of H2SO4 if it was titrated with 54 ml of 1.5M NaOH? http://www.iq.poquoson.org/2004vasol/eocchem/eocchem04.htm http://www.iq.poquoson.org/2003vasol/eocchem/EOCchem03.ht m http://www.iq.poquoson.org/2002vasol/eocchem/EOCchem02.ht m Vocabulary concentration, molarity, dilution, titration, radiation, radioactivity, radioisotopes, transmutation &trans uranium elements Resources alpha particle, beta particle, fission, fusion, gamma ray, Geiger counter, half-life, ionizing radiation, positron, radiation Chemistry Unit Plans Resource Folder\Presentational Files (PowerPoint’s)\Week 14 --Nuclear Chemistry Resource Folder\Presentational Files (PowerPoint’s)\Week 10 and 11 and 13-- Solutions and Equilibrium Resource Folder\Presentational Files (PowerPoint’s)\Week 15 and 16 -- Final Review An excellent compilation of websites where you can find animated or interactive applets about titration: http://nrhs.nred.org/www/nred_nrhs/site/hosting/Resources4Science/ResourceSites/Titrationweb/ titrationmain.htm http://apcentral.collegeboard.com/apc/members/courses/teachers_corner/30907.html?type=print Discipline Essential Standard Objective Applicable Chem Unit Week 17/18 Review Spiral back Prep for students entering AP Chemistry the following Year Final Exam Chemistry Unit Plans Information & Technology (CTE/ITE) HS.SI.1 Evaluate resources needed to solve a given problem. 1-3 HS.TT.1 Use technology and other resources for assigned tasks. HS.RP.1 Design project-based products that address global problems. HS.SE.1 Analyze issues and practices of responsible behavior when using resources. S.ID. 7 Interpret linear models. 1-3 A.CED.2 Create equations that describes numbers or relationships. 2-3 N.Q.1 Reason quantitatively and use units to solve problems. 2-3 1-3 3 3 Algebra 2 N.RN.2 Applying the laws of exponents using numerical bases and integer exponents is in 8th grade CCSS. This is an extension of applying the laws of exponents. At this level, address these laws using rational exponents focusing on using fractional exponents with a 1-3 S.ID.6 Summarize, represent, and interpret data on two categorical and quantitative variables. 1-3 S.ID. 7 Interpret linear models. 1-3 A.CED. 2 Create equations that describe numbers or relationships. 1-3 Chemistry Unit Plans Reading Standards for Literacy in Science 6–12, page 62 A.REl.3 Solve equations and inequalities in one variable. 1-3 A.REI.10 Represent and solve equations and inequalities graphically. 1-3 A.REI.1 Understand solving equations as a process of reasoning and explain the reasoning. 1-3 F.IF.6 Interpret functions that arise in applications in terms of the context. 2-3 F.LE.1 Construct and compare linear and exponential models and solve problems. 2-3 F.LE.2 Construct and compare linear and exponential models to solve problems. 2-3 F.LE.3 Construct and compare linear, quadratic, and exponential models and solve problems. 3 RLS. 9-10.1 Cite specific textual evidence to support analysis of science and technical texts, attending to the precise details of explanations or descriptions. 1-3 RLS.9-10.2 Determine the central ideas or conclusions of a text; trace the text’s explanation or depiction of a complex process, phenomenon, or concept; provide an accurate summary of the text. 1-3 RLS.9-10.3 Follow precisely a complex multistep procedure when carrying out experiments, taking measurements, or performing technical 1-3 Chemistry Unit Plans tasks, attending to special cases or exceptions defined in the text. RLS.9-10.4 Determine the meaning of symbols, key terms, and other domain-specific words and phrases as they are used in a specific scientific or technical context relevant to grades 9–10 texts and topics. 1-3 RLS.9-10.5 Analyze the structure of the relationships among concepts in a text, including relationships among key terms (e.g., force, friction, reaction force, energy). 1-3 RLS.9-10.6 Analyze the author’s purpose in providing an explanation, describing a procedure, or discussing an experiment in a text, defining the question the author seeks to address. 1-3 RLS.9-10.7 Translate quantitative or technical information expressed in words in a text into visual form (e.g., a table or chart) and translate information expressed visually or mathematically (e.g., in an equation) into words. 1-3 RLS.9-10.8 Assess the extent to which the reasoning and evidence in a text support the author’s claim or a recommendation for solving a scientific or technical problem. 1-3 RLS.9-10.9 Compare and contrast findings presented in a text to those from other sources (including their own experiments), noting when the findings support or contradict previous explanations or accounts. 1-3 RLS.910.10 By the end of grade 10, read and comprehend science/technical texts in the grades 9–10 text complexity band independently and 1-3 Chemistry Unit Plans proficiently. Writing Standards for Literacy in Science 6–12,page 64 NOTE: Students’ narrative skills continue to grow in these grades. The Standards require that students be able to incorporate narrative elements effectively into arguments and informative/explana tory texts. In science, students must be able to write precise enough descriptions of the step-by-step procedures they use in their investigations or technical work that others can replicate them and (possibly) reach the same results. WLS.9-10.1 Write arguments focused on discipline-specific content. a. Introduce precise claim(s), distinguish the claim(s) from alternate or opposing claims, and create an organization that establishes clear relationships among the claim(s), counterclaims, reasons, and evidence. b. Develop claim(s) and counterclaims fairly, supplying data and evidence for each while pointing out the strengths and limitations of both claim(s) and counterclaims in a discipline-appropriate form and in a manner that anticipates the audience’s knowledge level and concerns. c. Use words, phrases, and clauses to link the major sections of the text, create cohesion, and clarify the relationships between claim(s) and reasons, between reasons and evidence, and between claim(s) and counterclaims. d. Establish and maintain a formal style and objective tone while attending to the norms and conventions of the discipline in which they are writing. e. Provide a concluding statement or section that follows from or supports the argument presented. 1-3 WLS.9-10.2 Write informative/explanatory texts, including the narration of historical events, scientific procedures/ experiments, or technical processes. a. Introduce a topic and organize ideas, concepts, and information to make important connections and distinctions; include formatting (e.g., headings), graphics (e.g., figures, tables), and multimedia when useful to aiding comprehension. 1-3 b. Develop the topic with well-chosen, relevant, and sufficient facts, extended definitions, concrete details, quotations, or other information and examples appropriate to Chemistry Unit Plans the audience’s knowledge of the topic. c. Use varied transitions and sentence structures to link the major sections of the text, create cohesion, and clarify the relationships among ideas and concepts. d. Use precise language and domain-specific vocabulary to manage the complexity of the topic and convey a style appropriate to the discipline and context as well as to the expertise of likely readers. e. Establish and maintain a formal style and objective tone while attending to the norms and conventions of the discipline in which they are writing. f. Provide a concluding statement or section that follows from and supports the information or explanation presented (e.g., articulating implications or the significance of the topic). North Carolina Essential Standards Guidance North Carolina Essential Standards Guidance I.SE.1 Understand the meaning and importance of personal responsibilit y and selfawareness. I.SE.1.1 Explain the role of personal responsibility in leadership. I.SE.2 Understand the relationship between self and others in the broader world. I.SE.2.1 Exemplify how peer pressure can be both a negative and positive influence. I.SE.3 Use communicat ion strategies I.SE.3.1 Use communication strategies to take a position and to defend a stand on controversial issues. 1 I.SE.1.2 Integrate personal responsibility into the way you live your life on a daily basis. 1 I.SE.2.2 Evaluate one’s own behaviors in a variety of situations, making adjustments as needed to produce more positive results. I.SE.2.3 Explain the impact of self-direction, initiative, and self-control on interpersonal relationships. 1 Chemistry Unit Plans effectively for a variety of purposes and audiences.