Scientific method- a logical approach to solving problems by observing and collecting data, formulating hypotheses, testing hypotheses, and formulating theories that are supported by data. Observing and Collecting Data System- a specific portion of matter in a given region or space that has been selected for study during an experiment or observation Formulating Hypotheses Hypothesis- a testable statement in “if- then” format. Testing Hypotheses Experiment- a set of procedures used to test a hypothesis Controls- the experimental conditions that remain constant Dependent Variable- any condition that changes (y-axis) scientist has no control over this variable. Independent Variable- determines the dependent variable (x-axis) scientist has control over this variable. Model- in science is more than a physical object, it is often an explanation of how phenomena occur and how data or events are related Theory- is a brand generalization that explains a body of facts or phenomena Law- how things happen in nature, descriptions of specific relationships under certain conditions in nature. Offer no explanations. Theory- why things happen in nature, well supported descriptions. *laws do not become theories, theories do not become laws. Quantity- something that has magnitude, size, or amount Scientists all over the world have agreed on a single measurement system: SI Weight- a measure of the gravitational pull on matter. Derived Unit- combination of SI base units Mass- a measure of the amount of matter. Matter- anything that has mass and volume. Volume- the amount of space occupied by an object Density- the ratio of mass to volume, or mass divided by volume States of matter- liquid, solid, gas, plasma 1). Liquid- definite volume and indefinite shape. 2). Solid- Definite volume and shape. 3). Gas- No definite volume or shape. 4). Plasma- high temperature physical state of matter in which atoms lose most of their electrons. Conversion factor- a ratio derived from the equality between two different units that can be used to convert from one unit to the other- equal to one. Dimensional analysis- a mathematical technique that allows you to use units to solve problems involving measurements. Accuracy- refers to the closeness of measurements to the correct or accepted value of the quantity measured Precision- refers to the closeness of a set of measurements of the same quantity made in the same way (reproducibility of results) Percent error- Error in measurement- some error or uncertainty always exists in any measurements Significant figures- in a measurement consist of all the digits known within certainty plus one final digit, which is somewhat uncertain or is estimated *All non- zero numbers are significant * A zero between significant figures is significant * A zero to the right of the decimal and at the end is significant * Zero in ones digit, with decimal point shown, nothing after decimal, is significant. Rule for multiplication and Division: -The answer can have no more significant figures than the measurement with the fewest significant figures. Rule for Addition and Subtraction: -The answer can have no more decimal places than the measurement with the fewest decimal places. *if both are whole numbers round to the left-most uncertain digit (LAST SIG FIG) Scientific Notation- numbers are written in the form Mx10n, where the factor M is a number between 1 and 9.99999999999999 and n is a whole number. Problem solving Strategy 1) analyze 2) Plan 3) Solve 4) evaluation Directly proportional- two quantities directly proportional to each other. If dividing one by the other gives a constant value. Inversely proportional- two quantities are inversely proportional if their product is constant. Classification of Matter Mixture- physical blend of two or more kinds of matter, each of which retains its own identity and properties. Homogenous mixture- uniform in composition, aka solutions. Heterogeneous mixture- not uniform in composition. Ways to separate mixtures 1). Filtration 2). Paper chromatography (separate pigments) 3). Centrifuge 4). Crystallization 5). Distillation (separation based on boiling points) Pure substances Pure substance- has a fixed composition * The physical and chemical properties are the same in all samples and it has the same composition in all samples. *Pure substances are either compounds or elements. * The chemical and physical properties of compounds are quite different than their component elements. Basic building blocks of matter Atom- smallest unit of an element that maintains the chemical identity of that element. Element- a pure substance that cannot be broken down into simpler, stable substances and is made of one type of atom. Compound- a substance that can be broken down into simpler stable substances. Each compound is formed from the atoms of 2 or more elements that are chemically bonded in fixed proportions. You can write a formula for a compound, 2 or more capital letters. *compounds have different properties than the elements they are made of. Law of Conservation of Mass- states that mass is neither created nor destroyed during ordinary chemical reactions or physical change. Mass before = mass after Law of Definite Proportions- the fact that a chemical compound contains the same elements in exactly the same proportions by mass regardless of the size of the sample or source of the compound. *Water is H2O, if not H2O, it is not water. Water is the same composition everywhere. Law of Multiple Proportions- if two or more different compounds are composed of the same two elements, then the ratio of the masses of the second element combined with a certain mass of the first element is always a ratio of small whole numbers. Dalton’s Atomic Theory * All matter is composed of extremely small particles called atoms * Atoms of a given element are identical in size, mass, and other properties. Atoms of different elements differ in size, mass, and other properties * Atoms cannot be subdivided, created, or destroyed * Atoms of different elements combine in simple whole number ratios to form chemical compounds *In chemical reactions, atoms are combined, separated, or rearranged. Modern atomic theory called the Quantum Mechanical Model or Electron Cloud Model. *Three major differences from Dalton’s theory -1- Modern theory- atoms are not indivisible, we have protons, neutrons, and electrons. -2-Atoms can be changed from one element to another, not by chemical reactions, but by nuclear reactions. -3-Atoms of the same element are not all exactly alike (isotopes) Cathode- ray tubes supplied evidence of the existence of electrons, which are negatively charged sub-atomic particles that have relatively little mass Thomson- electron, cathode ray tube, plum pudding model of the atom, Rutherford- gold foil experiment, proton and nucleus, used alpha particles. OBSERVATION MOST ALPHAS PARTICLES WENT STRAIGHT THROUGH 1/8000 DEFLECTED CONCLUSION MOST OF ATOM EMPTY SPACE ELECTRONS HERE ATOMS HAVE DENSE POSITIVE CENTER Millikan- oil drop experiment, charge of electron Introduction to Periodic Table Groups- vertical columns of the periodic table (family) *Each element has a unique symbol. * The periodic table shows the elements organized by their chemical properties. 4 Family Names: Group 1A: Alkali Metals Group 2A: Alkaline Earth Metals Group 7A: Halogens Group 8A: Noble Gases Periods- the horizontal rows of elements in the periodic table * Each group contains elements with similar chemical properties (due to the number of valence electrons) * Properties vary throughout periods. Types of Elements * The elements can be classified as metals, nonmetals, metalloids, and noble gases. * These classes occupy different areas of the periodic table Metal- an element that is a good electrical and heat conductor Malleability- can be hammered or rolled into thin sheets Ductile- can be drawn into fine wire Tensile strength- the ability to resist Nonmetal- an element that is a poor conductor of heat and electricity Metalloid- an element that has some characteristics of the metals and some characteristics of nonmetals Noble Gases- don’t chemically react with any other elements. They are unreactive and are found in Group 18. The following should be put on flash cards also: ionic compounds (flash card) *made of metal and nonmetal (or polyatomic ions) *ionic bonding *formula units for representative particles molecular compounds (flash card) * nonmetals only *covalent bonding *molecules for representative particles naming ionic compounds (flash card) 1. name first element 2. name second element, change ending to -ide *never change ending of polyatomic ion *cation (which is the metal, unless it is ammonium) with more than one possible charge must have roman numeral. (Roman numeral equals the charge of the cation) naming molecular compounds (flash card) 1. name first element 2. name second element, change ending to -ide *must use prefixes for subscripts. Exceptions for prefixes--> 1. no mono for first element 1. a 2 syllable prefix, added to a vowel, drop vowel on prefix CO = carbon monoxide (illustrates both rules) writing molecular formulas (flash card) *prefixes give you the subscripts writing formula units (flash card) *overall positive and overall negative charges must cancel out, be neutral, which means numerically it is zero for the final charge. (use George) *if you add a subscript to polyatomic ion you must use ( ). Or stated another way if you have more than one of a polyatomic ion you must add ( ). How do you know when you have a polyatomic ion? (flash card) 1. you see ( ) 2. -ate or -ite (exceptions ammonium, cyanide, and hydroxide) 3. ionic with 3 or more capital letters. When does a cation need a Roman numeral? (flash card) *when it has more than one possible charge, which means it is not in IA, IIA, IIIA or one of the 3 exceptions ---> silver, cadmium, and zinc. Naming acids (flash card) *anion ends in –ide = add hydro- change ending to –ic and acid *anion ends in –ate = change ending to –ic and acid *anion ends in –ite = change ending to –ous and acid Writing formula for acid (flash card) work backwards with rules to get anion cation is always H+ make compound neutral. (use George)