Name: Date: Block: Activity: Chemical Reactions Purpose: To experiment with chemical reactions To write balanced equations for chemical reactions Material: 8 test tubes, test tube rack, reagent bottles, magnesium ribbon Procedure: i) Please wear safety goggles during this experiment. ii)Your teacher prepared a number of labelled dropping bottles filled with dilute solutions of various compounds. For the following steps, you will mix a few mL of each substance in a test tube. iii) You need to discard the content of each test tube in a special jar and not down the sink!!. iv) Clean each test tube using a test tube brush and water. Clean-up Procedure Thoroughly rinse out all test tubes, in running water. Invert the test tubes in a test tube rack so that they dry out for the next group to use them. Steps: 1. Add a few drops of calcium chloride solution to an equal volume of silver nitrate solution. Describe what happens in the result table. The products are silver chloride and calcium nitrate. 2. Add a few drops of calcium chloride solution to an equal volume of sodium carbonate solution. Describe what happens in the result table. The products are calcium carbonate and sodium chloride. 3. Add a few drops of sodium bicarbonate solution to an equal volume of acetic acid solution. Describe what happens in the result table. The products are sodium acetate, water and carbon dioxide. 4. Add a few drops of copper (II) sulphate solution to an equal volume of sodium hydroxide solution. Describe what happens in the result table. The products are copper (II) hydroxide and sodium sulphate. 5. Add a few drops of copper (II)acetate solution to an equal volume of sodium sulphide solution. Describe what happens in the result table. The products are copper(II) sulfide and sodium acetate. 6. Add a 1 cm piece of magnesium ribbon to a few drops of dilute sulfuric acid. Describe what happens in the result table. The products are hydrogen gas and magnesium sulfate. 1 7. Add a few drops of potassium chromate solution to an equal volume of barium nitrate solution. Describe what happens in the result table. The products are potassium nitrate and barium chromate. 8. Add a few drops of dilute sodium hydroxide solution to a test tube. Add one drop of phenolphthalein indicator to the same test tube. Now add dilute hydrochloric acid one drop at a time to the same test tube, until the colour just disappears. The new products are water and sodium chloride. The acid has « neutralized » the base, and you have made ordinary common salt or sodium chloride, and water. If time permits, boil away the water. The film left behind is sodium chloride. Reagent(Reactant) Bottle collection: Before you begin your experiment, you need to know the chemicals formula for each reactants. Using your data booklet, record the chemical formula for each of the above steps in the following table. Step 1 2 Reactant #1 CaCl2 (aq) CaCl2(aq) 3 NaHCO3(aq) sodium bicarbonate CuSO4(aq) Cu(CH3COO)2(aq) Mg (s) magnesium ribbon K2CrO4(aq) NaOH(aq) 4 5 6 7 8 Reactant #2 AgNO3(aq) Na2CO3(aq) sodium carbonate CH3COOH(aq) acetic acid NaOH(aq) Na2S(aq) H2SO4(aq) Ba(NO3)2(aq) HCl(aq) Results: Step 1 2 3 4 Reactants Calcium chloride, Silver Nitrate Calcium chloride, Sodium carbonate Sodium bicarbonate, Acetic acid Copper(II) sulfate, Products Silver chloride (s) Calcium nitrate (aq) Calcium carbonate(s) Sodium chloride(aq) Sodium acetate(aq), water(l), carbon dioxide(g) Copper(II) hydroxide(s), Observations White solid, ppt (AgCl) White solid, ppt (CaCO3) Bubbles, (gas) (CO2) Blue solid, ppt 2 5 6 7 8 Sodium hydroxide Copper (II) acetate, Sodium sulphide Magnesium, Sulphuric acid Potassium chromate, Barium nitrate Sodium hydroxide, Hydrochloric acid Sodium sulfate(aq) Copper(II) sulphide(s), Sodium acetate (aq) Hydrogen(g), Magnesium sulfate(aq) Potassium nitrate(aq), Barium chromate(s) Water(l), Sodium chloride(aq) (Cu(OH)2) Light blue solid, ppt (CuS) Bubbles, gas (H2) Yellow solid, ppt (BaCrO4) Magenta/pink becomes clear (phenolphthalein) Discussion: 1) For each reaction you carried out, use your data booklet to write the chemical formulas for the products. Step Product #1 Product #2 1 AgCl(s) Ca(NO3) 2(aq) 2 CaCO3(s) NaCl(aq) 3 NaCH3COO(aq) (H2CO3) = CO2(g)+ H2O (l) 4 ** Cu(OH)2(s) Na2SO4(aq) 5 ** CuS(s) NaCH3COO(aq) 6 ** H2(g) MgSO4(aq) 7 ** KNO3(aq) BaCrO4(s) 8 ** H2O(l) NaCl(aq) p.4 2) For each reaction, write the formula equation and then, balance each equation. Some reactions produce a gas or a solid called a precipitate(ppt) (insoluble product). Write (s), (g), (l) or (aq) next to each compound in the equation. (aq) : aqueous,in solution, dissolved in water Hints insoluble (doesn't dissolve well) Step 1 2 3 Balanced Chemical Equation CaCl2(aq) + 2 AgNO3(aq) CaCl2 (aq) + Na2CO3 (aq) 2AgCl(s) 2 NaCl (aq) + Ca(NO3)2(aq) + CaCO3(s) CH3COOH (aq) + NaHCO3(aq) NaCH3COO(aq) + H2O(l) + CO2(g) 3 2NaOH(aq) Cu(OH)2(s) + Na2SO4(aq) 4 CuSO4(aq) 5 Cu(CH3COO)2 (aq) 6 7 8 Mg(s) K2CrO4 (aq) NaOH (aq) + + Na2S(aq) 2NaCH3COO (aq) + CuS(s) + H2SO4(aq) + Ba(NO3)2(aq) + HCl(aq) MgSO4(aq) + H2(g) 2KNO3(aq) + BaCrO4(s) NaCl(aq) + H2O(l) 3) Classify each reaction All are double replacement rxns except for #6 that is a single replacement rxn Conclusion: Name three rules for balancing equations 1) Add coefficient in front of the molecules/compounds 2) Cannot change a chemical formula, cannot change subscripts 3) Same number of atoms on either side of the equation 4