CHEMICAL EQUATIONS AND REACTIONS A chemical reaction is __________________________________________________ ____________________________________________________________________. A chemical equation is __________________________________________________ _____________________________________________________________________. RULES FOR WRITING CHEMICAL EQUATIONS: 1) You must know how the substances react and what new substances they form. 2) You must know the correct formulas of the reactants and products. 3) Every chemical equation must balance. (The Law of Mass Conservation must be satisfied). Word Equations: _______________________________________________________. Formula Equation: _____________________________________________________. TERMS TO KNOW: Reactants: ____________________________________________________________. Products: _____________________________________________________________. :______________________________________________________________. + sign: _____________________________________________________________. Physical States of the Substances are often indicated: Gas: _________________________________________________________________. Liquid: _______________________________________________________________. Solid: ________________________________________________________________. Aqueous: _____________________________________________________________. Other Symbols: : Heat added -1- Pt : : ________________________________________________________________ 300 C : _____________________________________________________________ Practice Writing Word and Formula Equations: 1. Calcium reacts with sulfur to produce calcium sulfide. 2. Sodium reacts with fluorine to produce sodium fluoride. 3. Carbon disulfide solid reacts with oxygen gas to produce carbon dioxide gas and sulfur dioxide gas. 4. Aqueous solutions of potassium chloride and silver nitrate react to produce aqueous potassium nitrate and solid silver chloride. 5. Ca(OH)2(aq) + H3PO4(aq) 6. Fe(s) + HCl(aq) 7. KNO3(s) Ca3(PO4)2(s) + H2O(l) FeCl2 (aq) + H2(g) KNO2(s) + O2 (g) -2- GUIDELINES FOR BALANCING CHEMICAL EQUATIONS Balancing by Inspection: According to the Law of Conservation of Matter, mass must be conserved in a chemical reaction. Therefore, there must be the same number of atoms or moles of atoms of each element before and after the reaction. (On each side of the equation). Balancing by inspection is just a process used to look at the equation & make sure all elements are balanced on each side of the equation. Guideline 1: Write the correct formulas for the reactants and the products, using the correct symbols. Once you have written a correct formula, DO NOT change it during the balancing operation. Instead, place numbers called coefficients in front of the formula to obtain a balanced equation. Example: Guideline 2: Select an element to begin balancing the equation. Usually select the element from the compound containing the most atoms that is present in the largest number. DO NOT select an element in a polyatomic ion, DO NOT select H or O. Example: Guideline 3: Next, balance the polyatomic ions that remain the same on both sides of the equation. Balance these as a single unit. (Sometimes you may have to adjust the coefficient you used in the previous step). In this example ____________ remains unchanged. Example: -3- Guideline 4: Balance the H atoms, then the O atoms. If they appear in the polyatomic ion you already balanced, DO NOT consider them again. Example: Guideline 5: Check all coefficients to make sure they are WHOLE NUMBERS, in the lowest possible ratio. If any coefficients are fractions, multiply the equation by the denominator to make coefficients whole numbers. If not smallest ratio, reduce. BALANCE BY INSPECTION EXAMPLES: For each of the following, write the formulas and balance the equation. 1. Solid iron metal & aqueous hydrochloric acid react to produce aqueous iron(II) chloride and hydrogen gas. 2. Aluminum hydroxide and phosphoric acid react to produce aluminum phosphate and water. 3. Butane gas (C4H10) and oxygen react when heated to produce carbon dioxide gas and liquid water. 4. Solid potassium nitrate is heated to produce solid potassium nitrite and oxygen gas. 5. Hydrochloric acid is added to limestone (calcium carbonate) producing carbon dioxide gas, water, and calcium chloride. -4- More Practice: Change the following word equations into chemical equations and balance them. 1. Sodium chloride + Lead (II) nitrate Lead (II) chloride + Sodium nitrate 2. Ferric oxide + Hydrochloric acid Ferric chloride + Water 3. Sodium hydrogen carbonate + phosphoric acid Sodium phosphate + Carbon dioxide + Water 4. Calcium iodide + sulfuric acid Hydrogen Iodide + Calcium sulfate 5. Barium nitrate + Sulfuric acid Barium sulfate + Nitric acid 6. Iron (II) sulfide + Hydrobromic acid Hydrosulfuric acid and Iron (II) bromide 7. Sodium hydrogen sulfite + Sulfuric acid Sodium sulfate + Sulfur dioxide + Water 8. Aluminum sulfate + Sodium hydroxide Aluminum hydroxide + Sodium sulfate -5-