Chemical Equations and Reactions Name: Date: Period: 1. A chemical equation is balanced if there is an __________________ number of each kind of _____________________ on both sides of the equation. 2. Determine the number of atoms of each kind in each of the following: a. CaCO3 _____ Ca, _____ C, _____ O b. (NH4)2SO4 _____ N, _____ H, _____ S, _____ O c. 3 H2O _____ H, _____ O d. 4 Mg(OH)2 _____ Mg, _____ O, _____ H e. 5 Ba(NO3)2 _____ Ba, _____ N, _____ O 3. Now look at the following chemical equations. Count the number of atoms of each element on the reactant and product side. Determine if the statement is a balanced equation. a. 2 Na + 2 H2O 2 NaOH + H2 Reactants Products _______ Na _______ _______ H _______ _______ O _______ b. 4 NH3 + 6 NO 5 N2 + 6 H2O Reactants Products _______ N _______ _______ H _______ _______ O _______ c. NaCl + F2 Balanced? Yes _____ No _____ Balanced? Yes _____ No _____ NaF + Cl2 Reactants Products _______ Na _______ _______ Cl _______ _______ F _______ Balanced? Yes _____ No _____ d. 3 NaBr + H3PO4 2 HBr + Na3PO4 _______ Na _______ _______ Br _______ _______ H _______ _______ P _______ _______ O _______ Balanced? Yes _____ No _____ e. N2H4 + N2O4 3 N2 + 4 H2O Balanced? Yes _____ No _____ f. 2 Bi + 3 F2 2 BiF3 Balanced? Yes _____ No _____ g. Al + Ni(NO3)2 Al(NO3)3 + Ni Balanced? Yes _____ No _____ h. 3 NaBH4 + 4 BF3 2 B2H6 + 3 NaBF4 Balanced? Yes _____ No _____ i. 4 C3H5(NO3)3 6 N2 + O2 + 12 CO2 + 10 H2O Balanced? Yes _____ No _____ j. Ca10F2(PO4)6 + 7 H2SO4 2 HF + 3 Ca(H2PO4)2 + 7 CaSO4 Balanced? Yes _____ No _____ Directions: Balance the following reactions. Place a “B” at the end of any that are balanced as written. 4. _____ Zn + _____O2 → 5. _____HI → _____H2 + _____ZnO _____I2 6. _____B + _____F2 → _____BF3 7. _____N2 + _____H2 → _____NH3 8. _____Fe + _____H2O → _____Fe3O4 + _____H2 9. H2SO4 → BaCl2 + O2 → BaSO4 + P4O10 10. P + 11. KClO3 → 12. C3H8 13. Cu + AgNO3 → 14. Te + H2O → 15. La(NO3)3 + 16. RhO3 → 17. Hf + N2 → 18. Ga + H2SO4 → 19. PdCl2 + HNO3 → 20. RbBr + AgCl → 21. PaI5 → 22. Fe2O3 → 23. Cu + Cl2 → 24. Na + O2 → Na2O 25. H2 + O2 → H2O 26. Na2SO4 + CaCl2 → 27. Al2O3 → Al + 28. C2H6 + O2 → CO2 + 29. SO3 + H2O → H2SO4 30. SiCl4 → 31. C + KCl + O2 O2 → + CO2 + TeO + RhO + Ag H2 La(OH)3 + NaNO3 O2 Hf3N4 Pa + Ga2(SO4)3 + H2 Pd(NO3)2 + AgBr + HCl RbCl I2 Fe Si + H2O Cu(NO3)2 + NaOH → H2 → HCl + O2 CuCl2 CaSO4 + O2 Cl2 CH4 H2O NaCl 32. Br2 + NaI → NaBr + I2 33. Zn + HCl → ZnCl2 + H2 34. H2S + O2 → 35. Ba(NO3)2 + 36. C5H12 + O2 → CO2 + 37. HgO → Hg + O2 38. H2SO4 + Pb + 39. C6H12O6 + 40. Ca + 41. C6H12O6 → C2H5OH + 42. HC2H3O2 + NaHCO3 → H2O + SO2 Na2SO4 → BaSO4 + H2O PbO2 → O2 → H2 O → NaNO3 PbSO4 + CO2 + H2O H2O Ca(OH)2 + H2 CO2 CO2 + NaC2H3O2 + H2O Challenging: O2 → H2 O Na2SO4 + 43. NaCl + SO2 + 44. Fe2O3 + CO → 45. Ca3(PO4)2 + C + 46. C + O2 47. Mg + 48. CuO + C → Cu 49. NH3 + O2 → NO2 50. O3 51. Cu 52. C8H18 53. Sn CO2 + HCl Fe SiO2 → CaSiO3 + CO + P4 More: → CO O2 → MgO → + CO2 + H2O O2 + + + → AgNO3 O2 HF → Cu(NO3)2 + Ag CO2 + H2O + H2 → SnF2 + HCl 54. Al(OH)3 55. Ca3(PO4)2 56. Fe 57. NH4NO3 → 58. C Al2O3 59. N2 60. BaCl2 61. C6H12O6 62. Al 63. CO2 64. NO 65. Al + 66. HgO → 67. KClO3 68. CaBr2 69. H2O + + + Li3PO4 73. Ca(OH)2 74. Al2(SO4)3 O2 + + H2O Fe2O3 + → CO2 + P → HNO3 Ca(OH)2 → H2O + Ca3P2 C Li + Al2O3 Li2CO3 → → + H2O H2 O2 → O2 NaCl O2 + Fe → + + Al2(SO4)3 + Na3P + + Fe → + CO2 NH3 KCl + CaSO4 CO2 BaSO4 → → Hg 72. + → H2SO4 C2H6 Al → LiOH H2 71. H2O → O2 + + NH3 Fe2O3 C6H12O6 P → → → H2O H3PO4 + Na2SO4 + + Fe3O4 + + → N2O + 70. 75. → H2 + AlCl3 H2SO4 O2 + → P2O5 + + NaBr H2 H2 O + + H2O O2 Ca(NO3)2 → Al(OH)3 + H2O + CaSO4 76. N2 + 77. CH4 + 78. Fe2O3 + 79. AsCl3 80. C3H8 81. K2S 82. Al 83. H2S 84. Fe 85. Ca(NO3)2 → H2 → O2 + → + KOH S8 + H2O + H2O As2S3 + CO2 → CuBr2 O2 + → → O2 + Fe H2S + CO2 → H2 + + NH3 + CuS HCl H 2O + KBr Al2O3 → → Na3PO4 → H2 O + K2S Ca3(PO4)2 + NaNO3 FeS DIRECTIONS: Refer to the unbalanced chemical equation below to answer the following questions. Write your answers in the space provided. Al(NO3)3 + FeCl2 → Fe(NO3)2 + AlCl3 86. Write the names of the reactants in this equation: _______________________________________ _____________________________________ 87. Write the names of the products in this equation: _______________________________________ _____________________________________ 88. Balance the equation above. What is the coefficient for Al(NO3)3? ___________ What is the coefficient for FeCl2? ___________ What is the coefficient for Fe(NO3)2? ___________ What is the coefficient for AlCl3? ___________ 89. How many oxygen atoms are there on each side of the balanced equation? __________ 90. What should you do if an equation you have written cannot be balanced? ________________________ __________________________________________________________________________________ 91. How is balancing an equation related to the Law of Conservation of Matter? _____________________ ___________________________________________________________________________________ 92. Describe the correct way to balance an equation: ___________________________________________ ___________________________________________________________________________________ 93. How are the physical states of the reactants and products indicated in a chemical equation? __________ ___________________________________________________________________________________ Write complete equations for the following using the state symbols! Remember the seven diatomic elements !!! 93a.Two molecules of solid sodium chloride decompose when exposed to an electric current into two atoms of sodium metal and 1 molecule of chlorine gas. 93b.One molecule in a barium chloride solution reacts with one molecule in a sodium sulfate solution to produce 1 molecule of solid barium sulfate and 2 molecules of sodium chloride in solution. 93c.Two molecule of solid potassium chlorate, when heated, decompose into two molecules of solid potassium chloride and 3 molecules of oxygen gas. 93d. One molecule of solid calcium carbonate decomposes when heated into one molecule of solid calcium oxide and 1 molecule of carbon dioxide gas. 93e. Two molecules of solid aluminum hydroxide decomposes when heated into one molecule of solid aluminum oxide and three molecules of water vapor . 93f. One atom of zinc metal when mixed with two molecules of a hydrochloric acid solution react and produce one molecule of zinc chloride in solution and one molecule of hydrogen gas. DIRECTIONS: Write balanced chemical equations for each of the following reactions. Indicate the physical state of the reactants and products (ex – s,g,l,aq). 94. Hydrogen gas reacts with nitrogen gas to produce ammonia gas (NH3). 95. Hydrogen bromide gas reacts with oxygen gas to produce liquid water and bromine gas. 96. When a solid piece of magnesium is placed in hydrochloric acid, hydrogen gas bubbles off and magnesium chloride is left in solution. 97. Hydrochloric acid can be added to calcium carbonate to produce calcium chloride in solution, carbon dioxide gas and water. 98. Solid carbon disulfide can be used to form carbon dioxide gas and sulfur dioxide gas when it reacts with oxygen gas. 99. Solid manganese dioxide reacts with hydrochloric acid to produce manganese (II) chloride, liquid water and chlorine gas. 100. Write the equation for the following reaction: ammonia, NH3, reacts with hydrochloric acid to form ammonium chloride. 101. When heated, calcium carbonate decomposes to form calcium oxide and carbon dioxide. Write the equation for this reaction: 102. Write the equation for the following reaction: barium oxide reacts with water to form barium hydroxide. 103. Acetaldehyde, CH3CHO, decomposes to form methane, CH4, and carbon monoxide. Write the equation for this reaction. 104. Write the equation for the following reaction: zinc reacts with copper (II) nitrate to form zinc nitrate and copper. 105. When heated, calcium sulfite decomposes to form calcium oxide and sulfur dioxide. Write an equation for this reaction. 106. Write the equation for the following reaction: iron metal reacts with sulfuric acid to form iron (II) sulfate and hydrogen gas. 107. Azomethane, C2H6N2, decomposes to form ethane, C2H6, and nitrogen gas at 297 °C. Write an equation for this reaction. 108. Write out the equation for the following reaction: carbon monoxide reacts with chlorine gas to form phosgene, COCl2. 109. Manganese (II) iodide decomposes when exposed to light to form manganese and iodine. Write an equation for this reaction. 110. Write a balanced chemical equation for the reaction in which dinitrogen pentoxide reacts with water to form nitric acid. 111. Magnesium reacts with titanium (IV) chloride to produce magnesium chloride and titanium. Write the balanced equation for this reaction. 112. Write a balanced chemical equation for the reaction in which carbon reacts with zinc oxide to produce zinc and carbon dioxide. 113. Bromine reacts with sodium iodide to form sodium bromide and iodine. Write the balanced equation for this reaction. 114. Write a balanced chemical equation for the reaction in which phosphorus trichloride reacts with chlorine gas to produce phosphorus pentachloride. 115. Phosphorus reacts with bromine to produce phosphorus tribromide. Write the balanced equation for this reaction. 116. Calcium hydride reacts with water to produce calcium hydroxide and hydrogen gas. Write the balanced equation for this reaction. 117. Write the balanced chemical equation for the reaction in which sulfuric acid reacts with potassium hydroxide to produce potassium sulfate and water. 118. Write a balanced chemical equation for the reaction in which propane, C3H8, reacts with oxygen gas to produce carbon dioxide and water. 119. Benzene, C6H6, reacts with oxygen gas to produce carbon dioxide and water. Write the balanced equation for this reaction. Synthesis Reactions Equations Chemical reactions are happening around you all the time. A match burns. A car rusts. Food spoils. Leaves decay. These are just a few chemical reactions. Probably the most important chemical reactions take place in your body. They are happening this very moment. Digestion is a chemical process. So is respiration. In every one of your trillions of cells, chemical reactions are taking place all the time. Life depends upon chemical reactions. There are several kinds of chemical reactions. One kind is a synthesis reaction. “Synthesis” means putting together. A synthesis reaction combines substances, usually elements (but sometimes smaller compounds), to form a new, larger compound. When the compound forms, we say it has been synthesized. Below is a “model” of a synthesis reaction. A + B → AB Element + Element → Compound 1. RUSTING When iron rusts, it combines with oxygen. → 4Fe + 3O2 iron + oxygen → 2Fe2O3 iron oxide (rust) link up to form Compound Element + Element 2. THE BURNING OF CARBON Charcoal is made of the element carbon, C. When carbon burns, it combines with oxygen. This produces the gas carbon dioxide, CO2. C + O2 carbon → + oxygen Element + Element CO2 → carbon dioxide link up to form Compound A synthesis reaction is like any other kind of chemical reaction. No matter is created or destroyed. The atoms just change their arrangement. Equation I: CO2 + C → 2CO2 Equation II: CO2 + H2O → H2CO3 120. How is Equation I different from the other synthesis equations seen in this packet? ________________ ___________________________________________________________________________________ 121. 1. How is Equation II different from the other synthesis equations seen in this packet? _____________ ___________________________________________________________________________________ 122. Look at the equations below. Identify the synthesis reactions by placing a check (√) next to it. Equation a. 2K + Br2 → 2KBr b. 2H2O → 2H2 + O2 c. NaCl → Na + Cl d. 4Au + 3O2 → 2Au2O3 e. 2Na + 2HCl → 2NaCl + H2 f. Cu + Br2 → CuBr2 g. ZnSO4 + FeCl2 → ZnCl2 + FeSO4 h. 2Na + Br2 → 2NaBr i. 2HgO → 2Hg + O2 j. CH4 + 2O2 → CO2 + 2H2O A Synthesis Reaction Not a Synthesis Reaction Decomposition Reaction Synthesis reactions build compounds. Anything that can be built can also ne taken apart. The breakdown of a compound into simpler substances is called decomposition. Decomposition is a chemical process. Let’s look at two examples: 1. Common table salt (sodium chloride) is a compound composed of the elements sodium and chlorine. It can be melted, and if electricity is passed through melted sodium chloride, it decomposes. It changes back into atoms of sodium and chlorine. Here is the reaction: electricity 2Na breaks it into 2NaCl sodium chloride (compound) sodium (element) + Cl chlorine (element) The decomposition of a compound by means of electricity is called electrolysis. Only certain compounds can be decomposed by electrolysis. Usually these compounds are liquids. 2. Potassium chlorate (KClO3) is a compound composed of potassium, chlorine and oxygen. Heat decomposes potassium chlorate into oxygen and potassium chloride (a simpler compound.) Here is the reaction: 2KClO3 potassium chlorate (compound) heat breaks down into 2KCl + potassium chloride (a simpler compound) 3O2 oxygen (element) Notice that the decomposition is not complete, the oxygen has been separated, but the potassium and chlorine are still joined in the compound, potassium chloride. Another kind of decomposition reaction can separate potassium chloride into its elements. Only certain compounds can be decomposed with heat Look at the diagram above and previous page. Electrolysis decomposes water. This is the equation for the reaction: 2H2O → 2H2 + O2 water → hydrogen + oxygen Equation a. CuCl2 → Cu + Cl2 b. 3Hf + 2N2 → Hf3N4 c. Zn + 2HCl → ZnCl2 + H2 d. C3H8 + 5O2 → 4H2O + 3CO2 e. 2NaOH → 2Na + O2 + H2 f. Fe + S → FeS g. CaCl2 + FeSO4 → Ca SO4 + FeCl2 h. 4P + 5O2 → 2P2O5 i. 3CuCl2 + 2Al → 2AlCl3 + 3Cu A Synthesis Reaction A Decomposition Reaction Neither Ca(OH)2 → CaO + H2O j. 170. Identifying Synthesis and Decomposition Reactions: Matching: ______ 123. synthesis reaction A) breaks down compounds ______ 124. decomposition reaction B) uses electricity ______ 125. electrolysis and heat C) methods of decomposition ______ 126. electrolysis D) simpler than a compound ______ 127. an element E) builds compounds Short Answer: 128. Does boiling decompose water? ________________ 129. What does boiling do to water? _________________________________________________________ ___________________________________________________________________________________ Series of Metals Element Lithium Potassium Barium Calcium Sodium Magnesium Aluminum Manganese Zinc Chromium Iron Cobalt Nickel Tin Lead Hydrogen* Copper Mercury Silver Platinum Gold Ease of oxidation increases Activity * Hydrogen is included in the activity series of metals because it has a positive oxidation number. Single & Double Replacement & Combustion Packet In a Single Replacement Reaction a free element takes the place of or replaces another element that is part of a compound. The element that was replaced is now “free.” A + free element BC → compound AC new compound + B new free element Let’s study an actual replacement reaction – one between zinc (Zn) and hydrochloric acid (HCl). The zinc is the “free” element and the hydrochloric acid is the compound. Zn + HCl → ZnCl2 The zinc replaces the hydrogen. + H2 The hydrogen gas is set free. The reaction produces a new compound, zinc chloride (ZnCl2), and free hydrogen (H2). Notice that the elements we started with are the elements we ended with, they are just arranged in a different way. This kind of reaction is called a single replacement reaction where a free element replaces an element that is part of a compound. For example, if you do a simple experiment of placing an iron nail (Fe) in a solution of copper (II) sulfate (CuSO4), you will see that after a few minutes the nail is coated with copper metal. Here is the equation for the reaction: Fe + CuSO4 → FeSO4 + Cu Single Replacement Reactions Decide whether each reaction is possible. Place a check next to the reactions that are possible. 130. _____ Zn + CuSO4 ZnSO4 + Cu 131. _____ Pb + Mg(NO3)2 Pb(NO3)2 + Mg 132. _____ AgCl2 + Zn ZnCl2 + Ag 133. _____ 2HCl + Ca CaCl2 + H2 134. _____ Pt + 2HCl PtCl2 + H2 Write balanced equations for the following single replacement reactions. Make sure to check that each reaction is possible on your Activity Series List. 135) Magnesium metal reacts with hydrochloric acid to produce magnesium chloride and hydrogen gas. 136) Sodium Chloride reacts with potassium to produce potassium chloride and sodium. 137) Zinc Sulfate reacts with copper to produce zinc metal and copper (II) sulfate. 138) Cobalt (II) oxide reacts with aluminum to produce aluminum oxide and cobalt. 139) Nickel (III) sulfate reacts with zinc to produce zinc sulfate and nickel 140. Identify (√) the following reactions as Synthesis (Syn), Decomposition (Decomp),Single Replacement (SR) or None of These Equation a. C + 2S → CS2 b. 2H2O2 → 2H2 + O2 c. 2Al + 6HCl → 2AlCl3 + 3H2 d. Li3PO4 + 3NaF → 3LiF + Na3PO4 e. Zn + PbO → ZnO + Pb f. CuCl2 + 2KBr → CuBr2 + 2KCl g. CuSO4 + Fe → Cu + FeSO4 h. 2Na + Br2 → 2NaBr i. 2HgO → 2Hg + O2 j. C3H8 + 5O2 → 3CO2 + 4H2O Synthesis Reaction Decomposition Reaction Single Replacement Reaction None of These Double Replacement Reactions: A double replacement reaction takes place between two compounds. A part of one compound changes place with a part of the other compound. This produces two new compounds. AB + compound → CD AD compound + new compound CB new compound The positive ion of one compound switches place with the positive part of the other compound. Let’s look at an example of a double replacement reaction between sodium hydroxide and hydrochloric acid: NaOH + HCl → NaCl + HOH The sodium and hydrogen change places and two new compounds form, NaCl and HOH (water). Example #1) BaCl2 barium chloride + Na2SO4 → sodium sulfate BaSO4 + barium sulfate 2NaCl sodium chloride 141. Identifying Double Replacement Reactions: Equation a. Mg(OH)2 + 2HCl → MgCl2 + 2H2O b. C6H10O5 +H2O → C6H12O6 c. Na2SO4 + BaCl2 → 2NaCl + BaSO4 d. 3Mg + N2 → Mg3N2 e. H2SO4 + BaCl2 → 2HCl + BaSO4 f. CH4 + 2O2 → CO2 + 2H2O g. ZnCO3 → ZnO + CO2 h. CuSO4 + H2S → H2SO4 + CuS i. NH4NO3 → 2H2O + N2O j. C6H12 + 9O2 → 6CO2 + 6H2O A Double Replacement Reaction Not a Double Replacement Reaction 142. Identify (√) the following reactions as Synthesis (Syn), Decomposition (Decomp), Single Replacement (SR) , Double Replacement (DR) , Other Equation Reaction Type Syn. a. N2 + 3H2 → 2NH3 b. 2Br2 + 2H2O → 4HBr + O2 c. Mg + 2HCl → MgCl2 + H2 d. 2KBr + H2SO4 → K2SO4 + 2HBr e. H2SO3 → H2O + SO2 f. C6H12O6 + 6O2 → 6CO2 + 6H2O g. NaCl + AgNO3 → NaNO3 + AgCl h. H2 + Cl2 → 2HCl i. H2CO3 → H2O + CO2 j. C3H8 + 5O2 → 3CO2 + 4H2O Decomp. S.R. D.R. Other Combustion Reactions: A combustion reaction takes place between a hydrocarbon (a compound made of hydrogen and carbon) and the element oxygen. Oxygen is a diatomic element which means it is so reactive it will bond with itself. Therefore the oxygen in the air required for combustion is O2. Carbon dioxide and water are always the products for these types of reactions. CH → + O2 CO2 hydrocarbon oxygen + H2 O carbon dioxide water For example, when natural gas (methane, CH4) is burned with oxygen (O2) carbon dioxide (CO2) and water (H2O) are produced. CH4 + 2O2 methane → oxygen CO2 + 2H2O carbon dioxide water In another example, cellular respiration, our body metabolizes glucose (C6H12O6) with oxygen (O2) and we produce carbon dioxide (CO2) and water (H2O). In this case the “hydrocarbon” also contains oxygen. C6H12O6 + 6O2 glucose oxygen → 6CO2 carbon dioxide + 6H2O water 143. A Combustion Reaction Equation a. Mg(OH)2 + 2HCl → MgCl2 + 2H2O b. 2Br2 + 2H2O → 4HBr + O2 c. C3H8 + 5O2 → 3CO2 + 4H2O d. 3Mg + N2 → Mg3N2 e. H2SO4 + BaCl2 → 2HCl + BaSO4 f. CH4 + 2O2 → CO2 + 2H2O g. ZnCO3 → ZnO + CO2 h. C6H10O5 +H2O → C6H12O6 i. NH4NO3 → 2H2O + N2O j. C6H12 + 9O2 → 6CO2 + 6H2O Not a Combustion Reaction 144. Identify (√) the following reactions as Synthesis (Syn), Decomposition (Decomp), Single Replacement (SR) , Double Replacement (DR) , Combustion (C) Reaction Type Equation Syn. a. CO2 → C + O2 b. NaCl + AgNO3 → NaNO3 + AgCl c. S + Cl2 → SCl2 d. BaCl2 + 2NaOH → 2NaCl + Ba(OH)2 e. C3H8 + 5O2 → 3CO2 + 4H2O f. CH4 → C + 2H2 g. Pb(NO3)2 + Mg → Pb + Mg(NO3)2 h. Mg + 2HCl → MgCl2 + H2 i. H2SO4 → H2 + S + 2O2 j. 2O2 + N2 → N2O4 k. 3CaBr2 + 2Na3P → Ca3P2 + 6NaBr l. 2KI + Br2 → 2KBr + I2 m. C6H12O6 → 6C + 6H2O Decomp. S.R. D.R. C n. C6H12 + 9O2 → 6CO2 + 6H2O o. Si + O2 → SiO2 p. 2NaI + Pb(NO3)2 → 2NaNO3 + PbI2 q. 2C8H18 + 25O2 → 16CO2 + 18H2O r. H2 + CO + O2 → H2CO3 s. C6H12O6 + 6O2 → 6CO2 + 6H2O t. CS2 + 2F2 → CF4 + 2S Types of Chemical Reactions Directions: Label the following reactions as synthesis (S), decomposition (D), single replacement (SR), double replacement (DR) and combustion (C). 145. NaCl → Na + Cl2 ___________ 146. Na + Cl2 → NaCl ___________ 147. C2H4 + O2 → CO2 + H2O ___________ 148. H2O → H2 + O2 ___________ 149. H2 + O2 → H2O ___________ 150. C8H18 + O2 → CO2 + H2O ___________ 151. NaOH + HCl → HOH + NaCl ___________ 152. Na + HCl → H2 + NaCl ___________ 153. K + Cl2 → KCl ___________ 154. K + AgCl → Ag + KCl ___________ 155. C6H12 + O2 → CO2 + H2O ___________ 156. Ca + S → CaS ___________ 157. KOH + HNO3 → HOH + KNO3 ___________ 158. Al + O2 → Al2O3 ___________ 159. HgO → Hg + O2 ___________ 160. 161. NaOH + H2SO4 → Na2SO4 + H2O Fe + O2 → Fe2O3 ___________ ___________ 162. C6H8 + O2 → CO2 + H2O 163. Pb(NO3)2 + K2CrO4 →PbCrO4 + KNO3 164. H2 + N2 → NH3 165. C3H5(NO3)3 → CO2 + N2 + H2O + O2 166. Fe + CuCl2 → FeCl2 + Cu ___________ 167. KClO3 → KCl + O2 ___________ 168. Mg + HCl → H2 + MgCl2 ___________ 169. C5H10 + O2 → CO2 + H2O ___________ 170. CO2 → C + O2 ___________ 171. NaCl + AgNO3 → NaNO3 + AgCl 172. S + Cl2 → SCl2 173. BaCl2 + NaOH → NaCl + Ba(OH)2 174. Zn + CuSO4 → ZnSO4 + Cu ___________ 175. CH4 → C + H2 ___________ 176. Pb(NO3)2 + Mg → Pb + Mg(NO3)2 ___________ 177. H2SO4 → H2 + S + O2 ___________ 178. C3H8 + O2 → CO2 + H2O ___________ 179. O2 + N2 → N2O4 ___________ 180. CaBr2 + 181. 2KI + Br2 → 2KBr + I2 ___________ 182. C6H12O6 → C + H2O ___________ 183. NaF → Na + F2 ___________ 184. Si + O2 → SiO2 ___________ 185. H2 + CO + O2 → H2CO3 ___________ 186. C7H14 + O2 → CO2 + H2O ___________ 187. Li3PO4 → Li + P + O2 ___________ Na3P → Ca3P2 + NaBr ___________ ___________ ___________ ___________ ___________ ___________ ___________ ___________ Classifying Chemical Reactions Part I: Matching _______ 188. A + B → AB A. combustion reaction _______ 189. A + BX → AX + B B. decomposition (analysis) reaction _______ 190. AX + BY → AY + BX C. double replacement reaction _______ 191 AB → A + B D. single replacement reaction _______ 192. hydrocarbon + O2 → CO2 + H2O E. synthesis (direct combination) reaction Part II: Classifying Classify the following reactions as synthesis (S), decomposition (D), single replacement (SR), double replacement (DR) or combustion (C). _______ 193. _______ 194. _______ 195. _______ 196. _______ 197. _______ 198. _______ 199. _______ 200. _______ 201. CO2 → C + O2 NaCl + AgNO3 → NaNO3 + AgCl S + Cl2 → SCl2 BaCl2 + NaOH → NaCl + Ba(OH)2 C5H10 + O2 → CO2 + H2O Zn + CuSO4 → ZnSO4 + Cu CH4 → C + H2 C3H8 + O2 → CO2 + H2O Pb(NO3)2 + Mg → Pb + Mg(NO3)2 Part III: Short Answer 202. Explain why hydrogen is listed in the Activity Series even though hydrogen is not a metal. __________________________________________________________________________________ __________________________________________________________________________________ Part IV: Write the complete (with state symbols) balanced equation for the following reactions and then identify the type of reaction (S, D, SR, DR, C.) 203. Magnesium metal replaces mercury in a solution of mercury (II) nitrate. 204. Bromine gas combines with gaseous nitrogen to produce gaseous nitrogen tribromide. 205. A solution of potassium sulfate reacts with a solution of lead (II) nitrate. 206. Solid potassium chlorate is heated and decomposes into oxygen gas and solid potassium chloride. 207. The gas in our gas jets is methane, CH4. Write the reaction for the combustion of methane. Equations Directions: Write, balance and identify the type for each of the following reactions. ______ 208. silver nitrate + potassium sulfate → silver sulfate + potassium nitrate ______ 209. silver cyanide + potassium → potassium cyanide + silver ______ 210. nitrogen + hydrogen → ammonia ______ 211. zinc carbonate → zinc oxide + carbon dioxide Directions: Write, balance and predict the products for each of the following reactions. 212. The double replacement rxn between sodium hydroxide and calcium nitrate: 213. The double replacement rxn between hydrogen sulfide and cadmium nitrate: 214. The decomposition of aluminum chloride: 215. The decomposition of sodium chloride: 216. The single replacement rxn between aluminum and lead (II) oxide: 217. The double replacement rxn between silver acetate and potassium chromate 218. The decomposition of water to produce gaseous products: 219. The direct combination (synthesis) of iron (III) oxide from a metal and a gas: Directions: Write, balance, identify the type, and predict the products for each of the following reactions. 220. magnesium + zinc nitrate → 221. aluminum + phosphoric acid → 222. potassium + chlorine gas → 223. chromium (III) chloride + sulfuric acid → Predicting Products Directions: Predict the product and balance each of these reactions. List the reaction type abbreviation to the left of each reaction. ________ 224. CuCl2 ________ 225. N2 + H2 ________ 226. Ca + AlCl3 ________ 227. Al(NO3)3 ________ 228. C3H6 FeCl2 + + O2 229. Aluminum sulfate reacts with barium chloride 230. Zinc reacts with copper (I) sulfate 231. Sodium chloride decomposes. 232. Calcium metal reacts with oxygen 233. Butane, C4H10, burns in air Balancing Practice Quiz Identify the type, predict the products if it occurs, and balance the following reactions: 234. _____ Ba + O2→ 235. _____ Zn + CuSO4 → 236. _____ Ag + FeSO4 → 237. _____ BaCl2 + Na3PO4 → 238. _____ C6H12O6 + O2→ 239. _____ Zn 240. _____ Cu + MgSO4 → 241. _____ KClO3 → 242. _____ C4H8 + Pb(NO3)2 → + O2→