plastics, fuels and chemicals from crude oil

advertisement
PLASTICS, FUELS AND CHEMICALS FROM CRUDE OIL
Oil refineries ‘refine’ oil in massive quantities, to produce the fuels we need. These include diesel, petrol and
heating oil. However, some of the raw materials we need to manufacture plastics, are also extracted from oil at
the refinery. When crude oil is refined, four percent ends up as raw materials for the production of plastics.
Oil is used widely for the production of plastics as it is composed of carbon and hydrogen. This is why oil is
called a hydrocarbon. Oil and natural gas are the most important raw materials for plastics manufacture. To the
plastics industry, Naphtha is the most important fraction distilled from crude oil. It is used in the production of a
range of plastics.
KEVLAR® - GENERAL PRACTICAL APPLICATIONS
V. Ryan © 2011
Kevlar® is a liquid that is converted into a fibre (called aramid fibres) and then woven into a textile
material. The resulting textile material is extremely strong, lightweight, corrosion and heat
resistant. It is often used in combination with other materials, forming composites. It has a
wide range of uses. Kevlar® was developed at DuPont in the 1960s.
Kevlar® has a high tensile strength to weight ratio, far exceeding steel and even specialist
metal alloys, such as magnesium alloys, used in aerospace engineering.
For this reason it is used extensively in the manufacture of panels and wings for fighter
jets, including the Eurofighter Typhoon. During the manufacture of Formula One racing
cars, Kevlar® is used for the bodywork and petrol tank. Kevlar has many other uses.
Kevlar® is a material formed by combining para-phenylenediamine and terephthaloyl chloride. Aromatic polyamide (aramid)
threads are the result. They are further refined, by dissolving the threads and spinning them into regular fibres. When woven,
Kevlar® forms a strong and flexible material. If layers of the woven Kevlar® are combined with layers of resin, the resulting ‘rigid’
material is light and has twenty times the strength of steel. It is also superior to specialist metal alloys. However, Kevlar® is
expensive due to the demands of the manufacturing process and the need for specialist equipment
There are three main types of Kevlar®.
1. Kevlar® is used as a reinforcement material for some car tyres and bicycle tyres. It helps dramatically reduce puncture rates.
This standard of tyre is more expensive than ordinary road tyres. They are of particular use with 4 x 4 vehicles, especially when the
vehicle is being used off road and far away from recovery services.
2. Kevlar® 29 is used in the manufacture of body armour (panels) for lightweight military vehicles. A good example is the US
Army’s ‘Bradley Fighting Vehicle’. This has been used extensively in Iraq and Afghanistan. Kevlar® 29 was selected for its armour,
because it is lightweight and withstands attack from RPGs. The Kevlar® 29 panels protect the soldiers inside the vehicle.
Kevlar® 29 is ideal because it is lightweight and non-flammable and it offers protection from high temperatures (fire bombs, Molotov
cocktails etc...). Kevlar® 29 can also withstand the harsh environmental conditions, found in hot climates.
3. Kevlar® 49 is used for specialist boat hulls and in the aerospace industry. It is popular as a material for boats because it is
lightweight and can withstand a considerable amount of force (torque - twisting force), tensile stress and impact. Hulls
manufactured from traditional materials, such as fibreglass, are limited in their resistance to forces and stress. Also, a lightweight
boat is faster on the water and uses less fuel to complete distances.
Eurofighter is relatively light compared to other similar fighter jets, due to the selection of Kevlar ® 49 as a material in its
manufacture. This means that it can fly faster and further, before in-flight refuelling is needed. It is more agile than its rivals due to
excellent force (torque - twisting force) and tensile stress resistance. The plane is more likely to survive being hit by small arms fire,
compared to other fighter planes, as Kevlar ® 49 has excellent impact resistance.
FURTHER ADVANTAGES OF USING KEVLAR
Kevlar® has a range of advantages, not only its relative low weight and high strength: Laminated Kevlar® is very stable at high
temperatures and it is impact and scratch resistant. Kevlar® is often combined with other materials, to produce textiles with
enhanced properties, such as fire resistant clothing for the Fire Services.
Kevlar is used in some quality walking boots because it is waterproof (when combined with other materials as a composite) but also
breathable, ensuring comfort.
When Kevlar is used as a composite with rubber, it retains its flexibility. This composite material is used in the manufacture of
Formula One Racing Car petrol tanks. The tank holds the petrol safely, even in the event of an accident. The material cannot be
pieced by other car components, even during a high speed impact. The petrol does not escape / leak, avoiding fire and explosions.
The lightweight tank, adds to the reduced weight of the entire vehicle, leading to a faster racing car.
DISADVANTAGES OF KEVLAR
Kevlar® textiles tend to absorb moisture. It must be combined with moisture resistant materials, if there is a need for moisture
resistance as a physical property. Consequently, very few general cloths are manufactured with Kevlar®. Kevlar® reacts well under
a tensile force (stretching force) but badly under a compressive force. It is not used where compression resistance is needed, such
as bridge building or the structure of a building.It is difficult to cut and shape, unless through the use of special tools and equipment.
Laminated Kevlar® is also difficult to machine and consequently special cutters are required. Special cutting techniques were
developed to enable the manufacture of Kevlar® parts, for the Eurofighter.Kevlar® reacts badly to UV light (sunlight) unless it is
protected / hidden from direct sunlight. Kevlar® suffers some corrosion if exposed to chlorine
Download