Caitlin Shishido SMA 521 Hydrogen Fuel Cells from Wind Energy According to the U.S. Department of Energy, production of Wind-to-Hydrogen technology will not be feasible for initial production before 2020 (DOE 2011, pg6). [BACKGROUND] Wind H2 Fuel Cells Hydrogen (H2) is produced in large quantities primarily from natural gas (California Fuel Cell Partnership) Cleaner and 2-3 times more efficient than conventional vehicles using gasoline or diesel (California Fuel Cell Partnership). But we will only lower greenhouse gas emissions (GHG) though H2 fuel cells if the H2 is derived from renewable resources such as wind. How it works (National Renewable Energy Laboratory, 2011) (Ivancic, 2010): 1. Wind turbines are linked to electrolyzers, which pass wind generated electricity through water & split into H2 and oxygen. 2. H2 is then stored for generating electricity. 3. Stored H2 is either be piped or trucked to fuel stations, where cars are refueled. 4. Cars can either use “on-board” or “off-board” fuel storage a. On-board: cars contain storage tanks that remain on the car and are refueled in place b. Off-board: empty hydrogen storage tank would be removed from the car and exchanged for a regenerated H2storage tank Pros: Generate energy with no conventional pollutants (Breakthrough Technnologies Institute) (Ivancic, 2010) FCVs emit 60% fewer greenhouse gases than conventional vehicles The replacement of fossil-fuel emitting vehicles with wind H2 fuel-cells is expected to cause a 23% reduction in the global warming impact of GHGs (Collela, 2005) Decreased national dependence on foreign energy sources Safer than gasoline: fire involving stored hydrogen produced less damage and would pose less risk to a human than a fire from gasoline (U.S. Department of Energy) Cons: Current infrastructure built around liquid fuels which are not compatible with hydrogen fuels (Univeristy of Montana Mansfield Ethics and Public Affairs Program, 2011). Requires new production, delivery, and distribution systems (Breakthrough Technnologies Institute). Environmental effects: fuel cells require metals (platinum) as a catalyst to drive the reaction to the cell. Massive initial capital and resource investment: o Wind turbine costs $1,175,000 so full capital cost of the 4 million wind turbine (to achieve a full wedge) H2 production system would be at least $4.7 trillion. (Princeton Carbon Mitigation Initiative, 2011) (Socolow, 2004) (Univeristy of Montana Mansfield Ethics and Public Affairs Program, 2011) o Copious amounts of fossil fuels, metals, and minerals are used- mostly in the initial construction of the wind turbines. (National Renewable Energy Laboratory, 2004) Difficulty in Global/National Implementation (Univeristy of Montana Mansfield Ethics and Public Affairs Program, 2011) Caitlin Shishido SMA 521 Capital intensive. o Only most developed nations will have the resources to invest in H2 programs and technologies o Initially, H2 fuel cell vehicles and their fuel will be more expensive than their gasoline counterparts which would create access problems for poor individuals. Institutional Barriers o New building, technical, and safety standards will have to be mandated and recognized at every level of government from federal to local. Political Barriers o National Academy of Engineering deems technology not yet fully optimized Informational barriers o Public perception; Consumers know little to nothing and a large education campaign would need to ensue in order to guarantee smooth transition from a gasoline economy to H2economy. Debate over cost and implications for individual transportation cost. Real life application Denmark operates a full-scale hydrogen-energy plant and testing facility. The EU’s first full-scale Hydrogen Community Demonstration facility for residential Fuel Cell Combined Heat and Power. (Renewable Energy World, 2007) Demonstrated use of compressed H2 as a replacement for gasoline or diesel (California Fuel Cell Partnership) o Ford Focus FCV: fleet evaluation vehicles delivered to U.S., Canada, Germany o Mercedes F-cell: Used as company fleet vehicles by Deutsche Telekom o Toyota FCHV-adv: 68.3mpg and 431 mile range California Fuel Cell Partnership has established about 38 independent hydrogen fuel stations. Figure 1. Diagram of Hydrogen from Wind Energy. Modified from National Renewable Energy Laboratory Caitlin Shishido SMA 521 Literature Cited Breakthrough Technnologies Institute. Questions and Answers about Hydrogen and Fuel Cells. www.fuelcells.org. California Fuel Cell Partnership. Hydrogen and Fuel Cells: It Won't Take Miracles. www.cafcp.org. Collela, W. M. (2005). Switching to a U.S. hydrogen fuel cell vehicle fleet: the resultant change in emissions, energy use, and greenhouse gases. 150 (150-181). Ivancic, T. (2010). NMR search for mobile, aluminum-bearing species during reactions of sodium alanate. Washington University in St. Louis. National Renewable Energy Laboratory. (2004). Life Cycle Assessment of Renewable Hydrogen Production via Wind/Electrolysis. National Renewable Energy Laboratory. (2011). Wind to Hydrogen Project. http://www.nrel.gov/hydrogen/proj_wind_hydrogen.html. Princeton Carbon Mitigation Initiative. (2011). The Wedge from Substituting Wind H2 Fuel Cell for Gasoline in Hybrid Car. http://cmi.princeton.edu/wedges/wind_gas.php. Renewable Energy World. (2007). First Danish Hydrogen Energy Plant is Operational. http://www.renewableenergyworld.com. Socolow, P. a. (2004). Stabilization wedges: solving the climate problem for the next 50 years with current technologies. 305 (968-972). U.S. Department of Energy. EERE News Hydrogen Safety Fact Sheet. Univeristy of Montana Mansfield Ethics and Public Affairs Program. (2011). Wind H2 in fuel-cell car for gasoline in hybrid car. http://www.umt.edu. --------------------------------------------------------------------------------------------------------------------------------------------------------- [POLICY] U.S. Federal Government Recent brief history of H2 Fuel Cells 2003: Bush proposes $1.2 billion program in State of the Union Address to fund hydrogen research 2009: $120 million in budget cuts were proposed to DOE’s Hydrogen and Fuel Cell Technologies Program. Funding was re-instated after rallying by U.S. Fuel Cell Council and industry. 2011: Obama administration is endorsing EV development focus and proposed $70 million cut on hydrogen technology spending next year. Other issues: Chicken and egg problem. Manufactures say they are ready to make H2 cars right now but that there are minimal #s fuel stations, but there are no fuel stations because no H2 cars. Congressional Action 108th Congress: 34 Bills [5 Passed House,1 Passed Both], H.R. 4818 Consolidated Appropriations Act, 2005 109th Congress: 34 Bills [7 Passed House, 2 Passed both], S.1281 National Aeronautics and Space Administration Caitlin Shishido SMA 521 Washington State Regional CA already has 23 hydrogen fueling stations in operation for 143 H2 fuel cell vehicles around Los Angeles Legislation HB 3170: 2006, Designation of I-5 as Washington Hydrogen Highway o Sights have since shifted to the “Green Highway” RCW 82.08.962: Tax Exemptions- sales of machinery and equipment used in generating electricity RCW 43.325.040: Energy freedom account-Green Incentive account- Energy recovery act HB 2994: Promoting renewable energy Other State Activity Washington State Fuel Cell Education and Demonstration Program o Partnership with WA State Dept of Community, Trade, Economic Development & Bonneville Power Administration o Trains middle & high school students and teachers about hydrogen and fuel cells o Provides college internships and education about fuel cells Pacific Northwest National Laboratory o Development of Hydrogen Safety Best Practices and Hydrogen Data Book Early Markets and Adopters o Joint base Lewis-McChord: H2 fuel cell powered fork lifts King County Fuel Cell Demonstration Project King County’s South Wastewater Treatment Plant in Renton, WA 2008: Demonstrated world’s largest demonstration of a molten carbonate hydrogen fuel cell 2011: Awarded $1 million for continued hydrogen separation and compression research, which has the potential to lead to lower cost of H2 production Seattle 2007 International Auto Show Demonstration of Hydrogen Now system o Hydrogen-on-demand system which has an internal catalyst to separate hydrogen from water to power the vehicle o Eliminates the need for a vast H2 infrastructure to be built Hydrogen Fuel Cell Companies Operating in Seattle EnerG2 and Alumi-Fuel Power, Inc. Caitlin Shishido SMA 521 University of Washington Offered Courses in H2 Fuel Cell Technology Chemical Engineering 345: Introduction to Fuel Cells Mechanical Engineering 430: Advanced Energy Conversion Systems University of Washington Mechanical Engineering 406: Corrosion and Surface Treatment of Materials Research on H2 storage using catalysts for ammonia borane, solar hydrogen production, hydrogen infrastructure with a high penetration of renewable energy. References National FreedomCAR & Fuel Partnership. 2009. Hydrogen Production Roadmap: Technology Pathways to the Future. Fuhrmans, V. 2011. Hydrogen Fuel Cells are Down, but Perhaps Not Out. Wall Street Journal. http://online.wsj.com/article/SB10001424052748703778104576286620950028178.html Llanos, M. 2003. Bush sells vision of hydrogen future. MSNBC. http://www.msnbc.msn.com/id/3339912/t/bush-sells-visionhydrogen-future/#.Tt6MHmOBqU8 National Renewable Energy Laboratory. 2011. Hydrogen and Fuel Cells Research. http://www.nrel.gov/hydrogen/ Tollefson, J. 2010. Hydrogen vehicles: Fuel of the future? Nature. 464:1262-1264 U.S. Department of Energy. 2002. National Hydrogen Energy Roadmap. U.S. Department of Energy. 2011. The Department of Energy Hydrogen and Fuel Cells Program Plan. Pg.6 U.S. Department of Energy. 2011. Hydrogen and Fuel Cells Program. http://www.hydrogen.energy.gov/fuel_cells.html Whitman, J. 2011. High Hopes- And Hurdles- For Hydrogen Cars. CNBC. http://www.cnbc.com/id/43138227/High_Hopes_And_Hurdles_For_Hydrogen_Cars State Fuel Cells 2000. 2011. State of the States: Fuel Cells in America. Pg79 Hydrogen Fuel Cars Now. 2011. Hydrogen Highway. http://www.hydrogencarsnow.com/hydrogen-highway.htm Sjoding, D. and E.Hamernyik. 2008. Overview of Hydrogen and Fuel Cells in Washington State. Washington State University Extension Energy Program. Washington State. House. Designating state route number 5 as Washington hydrogen highway. HB 3170. 2006. Washington State. House. An act relating to promoting renewable energy in Washington. HB 2994. 2008. Washington State. Exemptions- Sales of machinery and equipment used in generating electricity. RCW 82.08.962. Vowles, M. 2004. Washington State Fuel Cell Education and Demonstration Program FY 2004 Progress Report. http://www.hydrogen.energy.gov/pdfs/progress04/vii3_vowles.pdf County King County. 2009. King County Fuel Cell Demonstration Project Final Report. King County. 2011. King County fuel cell demonstration project. http://www.kingcounty.gov/environment/wastewater/EnergyRecovery/fuelcelldemonstration.aspx U.S. Department of Energy. 2011. Molten Carbonate Fuel Cell Technology. http://www.fossil.energy.gov/programs/powersystems/fuelcells/fuelcells_moltencarb.html City Hydrogen Fuel Cars Now. 2006. Hydrogen Power Inc. Displays H2 Vehicle at Seattle Auto Show. http://www.hydrogencarsnow.com/blog2/index.php/hydrogen-cars/hydrogen-power-inc-displays-h2-vehicle-at-seattle-auto-show/ Hydrogen Fuel Cars Now. 2011. Hydrogen On Demand. http://www.hydrogencarsnow.com/hydrogen-on-demand.htm Sjoding, D. and E.Hamernyik. 2008. Overview of Hydrogen and Fuel Cells in Washington State. Washington State University Extension Energy Program. UW Sjoding, D. and E.Hamernyik. 2008. Overview of Hydrogen and Fuel Cells in Washington State. Washington State University Extension Energy Program. University of Washington. 2011. University of Washington Course Descriptions. http://www.washington.edu/students/crscat/ University of Washington. 2011. Undergraduate Fuel Cell Research. http://depts.washington.edu/fuelcell/