Schaub 4:00 R21 THE QUANTUM DOT SOLAR CELL: A PATH TO ETHICAL ENERGY Josh Demusz (jsd36@pitt.edu) A DILLEMA OF ETHICAL ENERGY Imagine a world 10 years in the future where I have acquired a stable, well-paid job as a materials engineer at an engineering company that focuses on developing new energy technologies. Currently, I have been working on developing improved technologies for a special type of photovoltaic cell, the quantum dot solar cell, in order to increase its efficiency, or its ability to convert sunlight to electrical power. Although my research team’s efforts to increase the efficiency of these solar cells have been extraordinary, no major breakthroughs have been reached. The efficiency levels of the solar cells remain lower than other traditional energy sources, such as nuclear energy and fossil fuel energy. This dearth of viable discoveries has led our company to consider discontinuing the research and moving the scientists and engineers working on it to a different project in its place. This project would consist of research into developing materials that would allow the conversion of petroleum to electrical energy to be more efficient. While the company does not necessarily support the usage of oil and petroleum to produce energy, they are receiving funding from many different fossil fuel companies to create these technologies. I, however, believe that this would be an ethical mistake on boundless proportions. Fossil fuel energy has demonstrated countless times that it is detrimental to both environmental and human health, whether from the emission of toxic materials or more specific examples such as oil spills [1][2]. It is not ethical to continue to support such a hazardous energy source when solar energy has the potential to support a growing nation while also remaining harmless to human and environmental health. These qualities and the high potential efficiency levels quantum dot solar cells are capable of cause me to oppose the discontinuation of quantum dot solar cell research in favor of petroleum technology research. THE SOLAR CELL: AN INTRODUCTION TO THE QUANDARY At this instant the sun is emitting about 1.8*10 11 MWs of power on the earth’s surface [3]. Although this amount is thousands of times the size of the earth’s power consumption, only an infinitesimal fraction of this energy is actually utilized due to the inefficiencies of today’s solar technology. The process of capturing solar energy occurs when photons, or particles of light, come into contact with small devices called photovoltaic cells, or solar cells, and excite the materials of which these cells are composed [3]. If the electrons of these materials become excited enough, University of Pittsburgh, Swanson School of Engineering 2013-10-29 1 they will break free and create an electric current, hereby producing electricity [3]. However, during the conversion from solar power to electrical power, energy can pass through the solar cells, be reflected by them, or be released as heat, accounting for efficiencies of only 10-15 percent [3]. Solar energy offers an unlimited supply of alternative energy, as humans can only survive if the sun does, but is not utilized since it is not as economical as petroleum or fossil fuels. However, fossil fuels are not only in limited supply, they are also detrimental to the environment due to the release of greenhouse gases during their combustion, which work to deplete the ozone layer [4]. Solar energy on the other hand does not release byproducts as it produces electrical energy, allowing it to have a neutral effect on the environment. This allows it to have a harmonious relationship with various engineering codes of ethics that is not experienced by traditional sources of energy. One reason for this is because solar energy will advance the quality of human life without threatening human and environmental health, which is a tenet found in various engineering codes of ethics [5][6]. Solar energy offers a sustainable, omnipresent, and eco-friendly energy supply that can decrease the use of or completely replace traditional energy sources, such as fossil fuels, nuclear energy, and coal, which pose threats to not only the environment but also to human welfare. These qualities allow solar energy to be a more ethical option than the detrimental energy sources listed above. Its potential to become a vital and safe energy source has been displayed by recent developing solar technologies such as quantum dot solar cells. However, solar energy’s potential to allow widespread clean and stable power can only be realized if engineers and scientists strive to produce solar cells, such as quantum dot solar cells, that are made with more efficient materials in order to be competitive on an economic spectrum. IMPROVING THE QUANTUM DOT SOLAR CELL As stated in Mishra and Mishra’s “Environmental Science and Ethics”, the three ethical recommendations to define the shape of future energy include sustainability, efficiency, and equity [7]. Sustainability concerns the quality and quantity of energy and the effect of existing energy on the environment [7]. The efficiency of energy deals with the amount of energy gained compared to the amount lost in the process of making it. Finally, equity deals with the costs of manufacturing and implementing solar materials [7]. Sustainability allows the technology to be environmentally ethical, while increased efficiency and Josh Demusz equity will allow the technology to become a practical and economical option. While solar energy is inherently sustainable, as it allows human life to be progressed while causing no harm to the environment, it is not inherently efficient or inexpensive. Improving quantum dot solar cell technology, however, could change this. With further research and development, these three tenets can be brought to life in the form of quantum dot solar cells. FOSSIL FUELS: A HAZARDOUS ENERGY SOURCE The origins of my concerns with abandoning research into quantum dot solar cell technology in favor of petroleum technology are rooted in the impending impacts that fossil fuels have on human and environmental health. TOXIC BYPRODUCTS OF FOSSIL FUEL COMBUSTION A QUANTUM ALTERNATIVE TO TRADITIONAL SOLAR CELLS In order to produce electrical energy from fossil fuels, they must be combusted. The combustion of these fuels, such as crude-oil, results in the emissions of several harmful gases, such as SO2, CO, NOX, HC, and CO2 [2]. Some of these gases, including SO2 and NOX, are responsible for acid rain that destroys vegetation and erodes buildings, statues, and other structures [2]. These gases are also responsible for urban pollution, which is caused mainly by automobile exhaust gases [2]. The more significant effect of these gases, however, is global climate change. Global climate change, which is caused primarily by CO2 emission, occurs when solar heat is trapped in the atmosphere, leading to the increased temperature of the earth [2]. This is an important issue because of what it represents for the future ecological cycles of the earth. The constantly increasing global temperature is resulting in the melting of the polar ice caps, severe droughts in countries near the equator, and even the gradual extinction of certain species of animals [2]. The scale of this issue can be demonstrated by the amount of fossil fuels that humans currently use for energy production. A study executed by the Environmental Protection Agency concluded that “the primary greenhouse gas emitted by human activities in the United States was CO2, representing approximately 83.6 percent of total greenhouse gas emissions” and that “the largest source of CO2, and of overall greenhouse gas emissions, was fossil fuel combustion” [4]. This is significant because it demonstrates that fossil fuel combustion contributes to global climate change more than any other energy source. It also demonstrates the catastrophic events that our planet could experience if fossil fuels continue to be supported. In his article on environmental ethics, Holmes Rolston from Colorado State University stated the primary causers of global warming live in a different generation from those that will experience its effects [9]. This is significant because it violates the fairness and protection of safety directives that various engineering codes of ethics share [5][6]. It is neither fair nor safe for an engineer to plant the seeds for a harsh future world by supporting the usage of fossil fuel as energy. It would, however, be both fair and safe to support the usage of solar energy for a primary power source since it will not lead to the future environmental complications that global warming will produce. Quantum mechanics is an example of technology that is within the reach of scientists and engineers, but still needs to be pursued in order to comprehend its many details. One of these “details,” or the quantum dot solar cell, has been the focus of my research for the last few years. Quantum dots, which are microscopic nanocrystals, are produced by simple chemical reactions that allow them to have low costs and uncomplicated fabrications [8]. This allows quantum dot solar cells to fulfill the equity requirement for future energy, as their manufacturing cost is relatively low when compared with other energy sources. While the QDSSC’s low cost and ability to capture sunlight are impressive, its current efficiency level forbids it from being a competitive solar technology [8]. In fact, while QDCCS’s have higher theoretical efficiency levels than any other solar cell, around 44 percent, today they have only reached 12 percent due to electron loss at the electrode interfaces [8]. However, scientists and engineers such as myself are developing new methods for allowing these solar cells to have increased efficiencies. One example of this is incorporating nanotubes in the solar cell’s structure [8]. These nanotubes improve the electron transport between the electrode interfaces, which allows for fewer electrons to be lost and more power to be generated [8]. Another possible solution to QDSSCs’ poor efficiency levels focuses on making the impact ionization process, or the process where sunlight excites electrons, faster than the cooling process in order to reduce the amount of thermal energy lost [8]. This can be accomplished by generating “hot carriers”, which transfer excess kinetic energy to a thermalized hole in the cell’s structure [8]. This allows the excess kinetic energy to be converted to electrical power, rather than lost as heat or sound. While quantum dot solar cells cannot currently fulfill the efficiency requirement of the future’s energy, breakthroughs in nanotechnology combined with the quantum dot’s high theoretical efficiency levels demonstrate that they have the potential to be adequately efficient. This potential can only be realized if engineers, including myself, continue to discover techniques to improve their efficiency. The technology to make solar energy the future’s ethical energy source is within reach; it solely needs to be pursued with greater passion. 2 Josh Demusz will shine through. This was demonstrated at the Gulf of Mexico back in 2010 and at countless other disasters where rigs and even ships have leaked crude oil into the environment. Solar energy, however, does not pose threats to human health. Since solar cells do not involve the usage or production of any toxic materials, they are not able to pose threats to human health. This allows solar energy to agree with the first canon of the NSPE’s code of ethics. Although fossil fuel energy is a relatively efficient power source, one must ask themselves this: is efficiency worth endangering the welfare of humans and nature alike when cleaner options such as solar energy are available? When writing on risk in engineering technologies, Michael S. Pritchard, an engineering pioneer from Western Michigan University, stated, “safety and risk go hand-in-hand. To set standards of safety requires a determination of acceptable risk” [11]. Based on the effects of and accidents caused by fossil fuel energy, is it acceptable to consider it safe? In order to choose an ethical energy source, or one that poses no threat to the safety of humans and the environment, engineers must stray away from fossil fuel energy. They must consider alternative energy sources, such as solar energy, which pose no threat human and environmental health. SAFETY CONCERNS OF PETROLEUM UTILIZATION Although fossil fuels are responsible for environmental damage when they are combusted since they produce toxic materials such as greenhouse gases, their retrieval and transportation can also be detrimental. An example of this is the BP oil spill in 2010, where an explosion caused 4.9 million barrels of oil to be released into the Gulf of Mexico [10]. This leakage caused health complications and in some cases death for both humans and animals in the surrounding area [10]. In high enough doses, the crude oil that leaked into the surrounding environment can cause respiratory, hepatic, renal, endocrine, neurologic, and hematologic complications as well as DNA mutations [1]. This has resulted in the sicknesses of many of the local inhabitants and 52,000 responding workers [1]. It has also resulted in the biomagnification of marine animals, which causes organisms such as fish to accumulate substances, such as crude oil, in their tissues [1]. This made it dangerous for humans and animals to consume seafood from the Gulf of Mexico. The first canon of the American Society of Civil Engineer’s Code of Ethics states that engineers should seek opportunities to work for the protection of the environment through the practice of sustainable development [5]. Methods such as fracking and drilling for oil violate this tenet because they are hazardous to environmental health. Not only does fracking and drilling for oil lead to the utilization of greenhouse gas producing fuels, but they also risk leaking toxins into the environment. The consumption and absorption of these toxins cause many of the organisms in the surrounding area to obtain various body system complications and die [1]. This has been demonstrated in the BP oil spill and countless other incidents. Since solar energy is able to advance human life without endangering the environment, it can be considered sustainable. Solar energy is therefore in agreement with this canon. Partially or completely replacing fossil fuels with solar energy could reduce or extinguish the chances that accidents such as oil spills will occur. In order to make an ethical decision concerning using fossil fuels and petroleum or solar energy as energy sources, engineers must also realize the risks, or absence of risks, that they pose to the environment. The first canon of The National Society of Professional Engineer’s Code of Ethics states that “engineers should hold paramount the safety, health, and welfare of the public” [6]. With this tenet in mind, is it just for engineers to continue to support energy sources, such as fossil fuel energy, that are perpetual threats to the safety, health, and welfare of the public? Human nature is not perfect and should not expected to be perfect. However, these imperfections, whether it be miscalculations, flawed logic, or even laziness, greatly augment the dangers of utilizing methods such as fracking. As long as these imperfections persist, as they naturally will, the instability attached with drilling for oil SUSTAINABLE SOLAR ENERGY: A VISIBLE HORIZON Although continuing research into an area such as quantum dot solar cells is not guaranteed to produce groundbreaking results, it is necessary for an engineer to continue to do so because of what he or she represents. Engineers create technologies that will propel us into a world that is more efficient, sustainable, and accommodating than it previously was. It would be more convenient for one to advocate an efficient energy source such as fossil fuels, but how would that help to change the world and create an advantageous future? Solar energy in its current state may not be able to change the world, but it does have the potential to. This potential can only be met if scientists and engineers continue to allocate funds to research new solar cell technologies, specifically solar cells incorporating nanotechnology and quantum dots. Solar energy offers clean and sustainable qualities that agree with multiple engineering codes of ethics. This is because solar energy is not only a sustainable energy source, since it advances the standard of living without destroying non-replenishable natural resources, but it is also one that protects environmental health because it does not involve the usage of any toxic materials [11]. However, these qualities can only be taken advantage of if engineers, including myself, strive to improve the efficiency of emerging solar cell technologies. Solar energy, to me, represents a clean and safe future while fossil fuel represents a putrid and hazardous one. This premonition, along with the knowledge 3 Josh Demusz of how efficient quantum dot solar cells could potentially be, causes me to unceasingly support the continuation of quantum dot solar cell research and adamantly condemn research to improve the efficiency of fossil fuel energy. ACKNOWLEDGEMENTS I extend my gratitude to the following individuals for their contributions to my paper: I would like to thank Anne Schwann from the Bevier Engineering Library for helping me locate research for this paper. Without Anne’s assistance much of the content that is crucial to my paper would have been absent. I would like to thank my father for introducing me to outdoor activities, such as hiking and camping, at an early age and insisting that I continue to participate in them even if I resisted. This gift has allowed me to truly appreciate the outdoors and yearn to protect it from pollution caused by humans. I would like to thank my mother for always pushing me to reach my academic pinnacle while also calming me if my academics had me overwhelmed. Even if I experience failure, she will always support me. REFERENCES [1] B. Goldstein, H. Osofsky, M. Lichtveld. (2011). “The Gulf Oil Spill”. The New England Journal of Medicine. (Online Article). DOI: http://dx.doi.org/10.1056/NEJMra1007197 pp. 1334-1348 [2] B. Bose. (2010). “Global Warming: Energy, Environment, and the Impact of Power Electronics.” Industrial Electronics Magazine. (Online Article). DOI: 10.1109/MIE.2010.935860 pp. 6-17 [3] S. Rompicherla. (2013). “Solar Energy: The Future.” International Journal of Engineering Trends and Technology. (Online Article). http://www.ijettjournal.org/volume-4/issue-6/IJETTV4I6P156.pdf [4] (2010). “Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2010.” Environmental Protection Agency. (Online Report). http://www.epa.gov/climatechange/Downloads/ghgemission s/US-GHG-Inventory-2012-ES.pdf [5] (2006). “American Society of Civil Engineers (ASCE) Code of Ethics.” American Society of Civil Engineers. (Online Code). http://www.asce.org/Ethics/Code-of-Ethics/ [6] (2005). “National Society of Professional Engineers (NSPE) Code of Ethics.” Encyclopedia of Sciecne, Technology, and Ethics. (Online Code). http://go.galegroup.com/ps/i.do?action=interpret&id=GALE %7CCX3434900759&v=2.1&u=upitt_main&it=r&p=GVRL &sw=w&authCount=1 [7] M. Mishra, M. Mishra. (2010). “Environmental Science & Ethics” (Online Book). http://site.ebrary.com/lib/pitt/docDetail.action?docID=10416 821 [8] Z. Yang, C. Chen, P. Roy, H. Chang. (2011). “Quantum dot-sensitized solar cells incorporating nanomaterials.” Chemical Communications. (Online Article). DOI: 10.1039/C1CC11317H. pp. 9561-9571 [9] H. Rolston. (2011). “The Future of Environmental Ethics.” Royal Institute of Philosophy. (Online Article). DOI: http://dx.doi.org/10.1017/S135824611100018X [10] R. Kurtz. (2013). “Oil Spill Causation and the Deepwater Horizon Spill.” Review of Policy Research. (Onli ne Article). DOI:10.1111/ropr.12026. pp. 366-380 [11] R. Burgess, M. Davis, M. Dyrud, J. Herkert, R. Hollander, L. Newton, M. Pritchard, P. Vesilind. (2012). “Engineering Ethics: Looking Back, Looking Forward.” Science and Engineering Ethics. (Online Article). DOI: 10.1007/s11948-012-9374-7. pp. 1395-1404 4