Q 1. Presence of small impurity usually makes a metal quite hard because the impurities : (a) change the lattice structure of metals (b) reduce the number of slide planes (c) reduce the number of mobile electrons (d) reduce the crystal symmetry Q 2. Formation of Ni(CO)4 and its subsequent decomposition into Ni and CO (recycled) makes the basis of Mond’s process ? T1 T2 Ni 4CO Ni CO 4 Ni 4CO T1 and T2 are: (a) 100°C, 50°C (b) 50C, 100C (c) 50°C, 230°C (d) 230C, 50C Q 3. Thomas slag is: (a) calcium phosphate (b) calcium silicate (c) tricalcium phosphate and calcium silicate (d) calcium ammonium phosphate Q 4. Which of the following elements occurs free in nature? (a) Iodine (b) Sulphur (c) Phosphorus (d) Magnesium The pyrolusite ore contains: (a) Fe (b) Al (c) Mn (d) Cu Of the following reduction processes: A: Fe2O3 + C Fe B: ZnO + C Zn C : Ca3(PO4)2 + C P D: PbO + C Pb Correct processes are: (a) A, B, C and D (b) A, B, D (c) A, B, C (d) B, D Q 5. Q 6. Q 7. Q 8. Q 9. Which is not the acidic flux among the following: (a) SiO2 (b) Fe (c) CaCO3 (d) none of these The reagents added during froth floatation process act as: (a) collectors (b) activators (c) depressants (d) any of these Which of the following is used as a foaming agent in froth floatation process? (a) Pine oil (b) Amyl xanthate (c) CuSO4 (d) KCN Q 10. Witherite is an ore of : (a) Be (b) Ca (c) Mg Q 11. Metals found in free as well as combined state are: (a) sodium (b) copper (c) gold Q 12. Consider the following steps: roast in air roast without air CuS A B Which is not the correct statement ? (a) It is self-reduction (d) Ba (d) all of these (b) It involves disproportionation Cu2S Cu + CuS (c) A is a mixture of CuO and CuS and B is a mixture of Cu and SO2 (d) All are incorrect statements Q 13. Which of the following processess involves the smelting process? (a) ZnCO3 ZnO + CO2 (b) 2PbS + 3O2 2PbO + 2SO2 (c) Fe2O3 + 3C 2Fe + 3CO (d) Al2O3.2H2O Al2O3 + 2H2O Q 14. Ruffle is separated from chlorapatite by: (a) froth floatation method (c) electromagnetic separation method (b) levigation (d) electrostatic separation method Q 15. Impurities present in the ore are called: (a) flux (b) slag (c) matrix (d) any of these Q 16. Pine oil is used for theconcentration of: (a) oxide ores (b) sulphide ores (c) carbonate ores (d) sulphate ores Q 17. Match column A (process) with column B (electrolyte) A (process) B (electrolyte) I Downs cell (W) fused MgCl2 (X) fused II Dow sea water (Al2O3 + Na3AlF6) III Hall – Heroult (Y) fused KHF2 (Z) fused (40% NaCl IV Moissan + 60% CaCl2) Choose the correct alternate: I II III IV I II (a) Z W X Y (b) X Y (c) W Z X Y (d) X Z III Z W IV W Y Q 18. Metals which occur in native state in nature: (a) are very reactive (b) are noble (c) have low density (d) all of these Q 19. Which of the following oxides cannot be re4uced by carbon to give the respective metals? (a) Cu2O, SnO2 (b) Fe ZnO3 (c) CaO, K2O (d) PbO, Fe3O4 Q 20. The process of bringing the metal or its ore into solution by the action of a suitable chemical reagent followed by extraction of the metal either by electrolysis- or by a suitable precipitating agent is called: (a) electro metallurgy (b) electrorefining (c) hydrometallurgy (d) zone-refining Q 21. Van Arkel method of purification of metals involves converting the metal to a: (a) volatile stable compound (b) volatile unstable compound (c) non-volatile stable compound (d) none of the above Q 22. Match the reactions taking place in a blast furnace with temperature-range of operations: Reactions Temperature range A: Fe2O + CO CO2 + FeO (I) 1800°C B: CO C + CO2 (II) 800°C C: FeO + CO Fe + CO2 (III) 500-600°C D: CaO + SiO2 CaSiO3 (IV) 400°C Choose the correct alternate: A B C D A B C D (a) IV III II I (b) IV II III I (c) I II IV I (d) I II III IV Q 23. Which of the following processes makes the ore porous ? (a) Distillation (b) Reduction (c) Calcination (d) All of these Q 24. Commercially important ore of lead is: (a) bauxite (b) galena (d) dolomite (c) haematite Q 25. Name the metal, M which is extracted based on the following equations: 4M + 8CN- + 2H2O + O2 4 [M(CN)2]- + 4OH- 2 [M(CN)2]- + Zn [Zn (CN)2]- + 2M (a) Cu (b) Au (c) Hg (d) Ni Q 26. Extraction of silver from commercial lead is possible by: (a) Mond’s process (b) Parke’s process (c) Clarke’s process (d) Haber’s process Q 27. Match the method of concentration of the ore in column I with the ore in select the correct alternate: Column I Column II (X) Magnetic separation (A) Ag2S (Y) Froth floatation (B) FeCr2O4 (Z) Gravity separation (C) Al2 (SiO3)3 X Y Z X Y (a) A B C (b) B A (c) C A B (d) B C column 11 and Z C A Q 28. The extraction of metals from oxide involve: (a) reduction with C (b) reduction with Al (c) electrolytic reduction (d) reduction with CO32 Q 29. Pentalanbite is an ore of : (a) Cu (b) Ni (c) Mg (d) Ca Q 30. The processes by which lighter earthy particles are feed from heavier particles by using water does not include: (a) gravity separation (c) hydraulic washing (b) levigation (d) leaching Q 31. Which method of purification is represented following equations? 875 K Z r 2 I 2 ZrI 4 2075 K Z r I 4 Zr 2I 2 Tungsten filament (a) Zone refining (b) Van Arkel (c) Poling (d) Cupellation Q 32. The process of zone refining is based upon: (a) fractional crystallization (b) fractional distillation (c) magnetic properties of impurities (d) impurities are less fusible than metals Q 33. Match list I with, list II and select the correct answer using the codes given below the lists: List I List II A Van arkel method 1. Manufacture of caustic soda B Solvay process 2. Purification of titanium C Cupellation 3. Manufacture of Na2CO3 D Poling 4. Refining of silver Codes : A B C D A B C D (a) 2 1 3 4 (b) 4 3 2 5 (c) 2 3 5 4 (d) 5 1 3 4 Q 34. The metal extracted by leaching the ore with NaCN solution is: (a) Cr (b) Co (c) Ag Q 35. Silica is a/an : (a) acidic flux only acidic flux (b) gangue only (d) Cu (c) basic flux only (d) both gangue and Answers 1. 8. 15. 22. 29. b d c a b 2. 9. 16. 23. 30. c a b c d 3. 10. 17. 24. 31. c d a b b 4. 11. 18. 25. 32. b c b b d 5. 12. 19. 26. 33. c b a b c 6. 13. 20. 27. 34. a b c b c 7. 14. 21 28 35. a c a d d