SUMMARY REPORT ENERGY RECOVERY AND STORAGE: A NEW APPROACH FOR THE UK AND CHINA 18 – 22 March 2013 White Rose University Consortium With support from: British Consulate-General Shanghai, Science and Innovation Team Hosting Institutions in China: The Joint Leeds - IPE Institute in Beijing and the Joint Leeds IPE - NCIP Lab in Nanjing Funded by: Global Partnerships Programme, Department of Business, Innovation and Skills Introduction The White Rose University Consortium of Leeds, Sheffield and York, plus the University of Hull, ran two workshops on ‘Energy Recovery and Storage: A New Approach for the UK and China’, one in Beijing and again in Nanjing in March 2013. Our team of 8 UK academics had expertise in 3 key areas 1) Utilisation of Waste Heat 2) Energy from Biomass 3) Energy Storage. The aim of the workshops, run on an open-innovation model, was to present and share expertise and then to encourage joint UK-CHINA discussions in each of the key areas in order to create a number of potential project ideas for future collaborative R&D agreements. Follow up visits by the Consulate General Shanghai Science and Innovation team to our Chinese colleagues were also part of the project. In Beijing, the workshop was hosted by the Chinese Academy of Sciences at the Institute of Process Engineering. 12 Chinese academics from 9 different universities/organisations joined the workshop In Nanjing, we were hosted by the Nanjing University of Science and Technology and supported by the Joint Leeds - IPE - NCIP Lab. 15 Chinese academics from 10 different universities/organisations joined the workshop. We would like to express our thanks to the Science and Innovation Team at the British Consulate General in Shanghai for their support with this project. And also to the Joint Institutes for Process Engineering at the Chinese Academy of Sciences and the Nanjing University of Science and Technology for their generous hosting and hospitality. And finally, also to the academics from both the UK and China who participated so knowledgeably and enthusiastically during the workshops. The project was funded by the Department of Business, Innovation and Skills Global Partnership Fund Julian White, CEO of the White Rose University Consortium Claire Pickerden, Project Development Manager, White Rose University Consortium www.whiterose.ac.uk contact c.pickerden@whiterose.ac.uk CPickerden Page 2 of 10 July 2013 Workshop Themes The workshop was structured around short presentations on each theme, followed by a quickfire discussion to collect initial thoughts, issues, ideas and questions. An additional Theme on CrossCollaborative Projects steered discussion towards synergy between the themes. Small discussion groups focused on shared interests and the development of potential joint project ideas. THEME 1) Utilisation of Waste Heat Theme Lead: Professor Jim Swithenbank, University of Sheffield It is widely recognised that the efficient use of energy requires that we should recover and use the low grade heat rejected to atmosphere by power generation, in a combined heat and power (CHP) system. However, it is not so widely appreciated that the gas boilers now used to produce low grade heat for buildings or industry waste the fundamental power generation capability of high temperature flames and should be replaced by micro-generation systems. Thus the challenge is to develop and apply CHP in the urban environment in a cost efficient manner. There is an urgent need to develop new and appropriate technologies and supporting measures which are needed to enhance and exploit the large amount of unused low grade heat available from the wide range of industries (eg iron/steel industry). This low-grade heat is predominately available in the gases (eg flue gases) and liquid streams (eg cooling water). District Heating/Cooling (DHC) provided by a Combined Heat and Power (CHP) system, offers an increase in overall plant efficiency from approximately 55% for the best electricity generating plant to approximately 85% for a CHP plant, reducing CO2 emission by 30%. Furthermore, CHP can also be provided from municipal solid waste (MSW) incineration, which can represent almost 20% of the total energy needs of a city, again contributing a major reduction to net CO2 emissions. In city areas that have a heat demand during winter and a cooling demand during the summer the combination of CHP, district heating and absorption refrigeration plants can be an optimal solution for ensuring the efficient use of capital invested in production capacity. THEME 2) Energy from Biomass Theme Lead: Dr Mark Gronnow, University of York Renewable sources of energy (eg wood, agricultural crops, biofuels, forestry residues, waste) can make an important contribution to securing sustainable and diverse energy supplies and are therefore an essential element of a cost-effective climate change programme. This Theme addresses the international need to limit the emission of greenhouse gases by exploiting the energy contained in biomass/biofuels by extending state-of-the-art technologies. This is particularly timely since disappointing experience with industrial pilot-scale “energy-from-biomass” plants (e.g gasification) has emphasised the importance of first establishing the enabling scientific and engineering principles underpinning these technologies. The key areas will focus on the use of microwave heating to convert agricultural and municipal wastes to solid and liquid energy products. CPickerden Page 3 of 10 July 2013 The key to this work is energy densification through a range of means: Enhanced seed oil recovery - Through essentially a steam distillation, oil can be recovered from seed meal thereby enhancing oil value for use in bio-diesel. Pyrolysis to Liquid Fuels- The use of microwave heating to create pyrolysis of biomass and wastes at a much lower temperature to flash pyrolysis (200°C) and fractionate into liquid products such as heavy heating oils, chemicals and liquid transport fuels. Pyrolysis/Torrefaction to Solid Fuels - the microwave can be used to torrify materials and generate materials with a higher energy density weight for weight and volume for volume than native biomass or waste. These solid fuels can be used in co-firing applications. Furthermore, both pyrolysis system generate gas products, this is a relatively new area of our research. Hydrothermal Treatment to Sugar- Through the use of high water content, high pressure, relatively low temperature microwave systems, we have observed the formation of sugar from lignocellulosic materials which can subsequently be fermented to bioethanol, biobutanol etc. THEME 3) Energy storage Theme Lead: Professor Yulong Ding, University of Leeds Energy Storage is to play a key role in large scale use of renewable energy resources, distributed energy systems, and peak shaving of the power network. Integration of energy storage technologies with industrial processes is also a highly effective way to significantly increase energy efficiency. This theme will cover heat and cold storage technologies, conversion between thermal energy and electrical energy, and techno-economic analyses. We need new solutions to capture and “warehouse” green energy and allow it to be used, when required, either on grid or in a vehicle. At one end of the scale, pumped hydro is limited geograghically by requiring mountains; while, at the other end, batteries are expensive and have short lifetimes. Liquid air is an alternative to “store” energy. It is cheap, uses mature components and is highly scaleable. Additionally, the low boiling temperature of liquid air allows it to harness low grade waste heat by increasing the expansion rate from liquid back to gas by about 700 times. As with a traditional steam engine, a cryogenic engine relies on phase-change (liquid to gas) and expansion within a confined space, eg engine cylinder or turbine. Critically, the system can be scaled to 100MWs/GWhs of storage, similar to a medium scale pumped hydro. Liquid air can easily be stored in the same low pressure tanks as used by the LNG industry; it is hundreds of times more energy dense than water and the process does not need large mountains. This cycle is beginning to be exploited for large scale electricity storage in UK, China and North America for grid balancing and large scale energy storage, and in a number of novel vehicle engine designs. CPickerden Page 4 of 10 July 2013 Potential Project Collaborations – Large Scale 1) Hydrogen generation through gasification of microwave torrified biomass Joint lead: Leeds and York Biomass has been selected as a key renewable resource for a step change in the energy use for a green and sustainable future. Hydrogen is a clean energy which can be used in various applications (i.e. fuel cell). Producing hydrogen from renewable resources will be important for a sustainable and clean future, however currently there are many problems preventing the use of biomass as a feedstock for hydrogen generation. In this project, we hope to integrate the known technologies of torrefaction and gasification with an aim of demonstrating in China and Europe a complete operational system for converting biomass into hydrogen with zero by-product. The first key part of the project will be torrefaction comparing conventional and microwave generated chars and addressing some of the major issues associated with its production. The second key unit operation is the gasification process whereby biochar will be converted to gas. We anticipate the project will then iterate between gasification and torrefaction to produce optimum bio-char for the gasification process, in turn maximising hydrogen yields. Collaboration is currently being shaped with Huazhong University of Science and Technology, the Institute of Engineering Thermophysics (IET,) Chinese Academy of Science, Dalian University of Technology and Southeast University, Nanjing. 2) District energy supply and management based on trigeneration and storage technologies led by Leeds This project will choose a real world example such as an 'industrial park' as the study case. The investigation will cover the aspects of: i) supply and demand dynamic interaction ii) renewable power connection iii) storage integration. The research and demonstration of this project will show key technologies and operation of a mini 'smart grid' which enables high performances of all sectors. The UK lead is Professor Yulong Ding, working alongside the Universities of Leeds, Sheffield and Hull with Tongji University leading the Chinese team from the Peking, Sun Yat-Sen, Nanjing Science and Technology and Shanghai Jiaotong Universities. Some potential industrial partners will also be contacted and involved in both UK and China. 3) Oxygen Separation Technology led by Sheffield Due to the need for oxy-fuel or oxy-gasification technology for future power generating systems that include capture and sequestration of carbon dioxide, collaboration is being explored with Tianjin University who specialise in cryogenic separation of oxygen. The team at Sheffield has demonstrated the use of steam blowing through molten iron to separate oxygen by chemical looping with biomass/coal. CPickerden Page 5 of 10 July 2013 Potential Project Collaborations – Medium/Small Scale This list of potential shared projects is currently undergoing further refinement and discussion. 1. Influence of alkali metals on catalytic biomass gasification The influence of alkali metals released from biomass pyrolysis will be evaluated for catalytic reforming for hydrogen production (Leeds and Huazhong University of Science and Technology) 2. Food waste biorefinery Extending the refinery to generate both energy and chemical products, University of York, City University Hong Kong 3. Medicinal Plant Waste for Energy and Chemicals Generation of chemical and energy products from processed medicinal plant waste, University of York, City University Hong Kong 4. Novel recovery of metal from fly ash Microwave treatment of fly ash aluminium recovery, University of York, Huaneng Clean Energy Research Institute 5. Graphene: Development of composites based on carbonaceous mesoporous materials (Starbon) and conductive polymer for making supercapacitors, University of York, Nanjing University of Science and Technology 6. Risk Assessment Joint seminars and workshops on methodology with University of Sheffield, Tinjing University and Beijing University of Chemical Engineering Technology in September 2014. 7. Coal-fired supercritical power plants Modelling/simulation and analysis of coal-fired supercritical power plants, University of Hull with Prof Zhu from the Shanghai Electric Power University. 8. Application of Energy Storage in Power Plant with Carbon Capture Considering national grid requirements, University of Hull, working with North China Electric Power University in Beijing. 9. Hydrogen production from thermo-chemical conversion of renewable resources Mixing organic solvent (e.g. ethanol) into crude biooil will be carried out to improve the reforming process in terms of reduction of coke formation and increase of hydrogen production. 10 Biomass algae feedstock for pyrolysis/gasification Use of Sheffield’s slow pyrolysis rig to generate biochar which will be ground to powder and gasified in the gasifier. The Collaboration involves the transfer of dried material from Tsinghua. This system can also capture carbon dioxide for energy recycling. CPickerden Page 6 of 10 July 2013 Future Collaboration By late 2013, further visits by the UK academics to China will take place in order to develop the projects up to and including funding application stage. The visits will: Foster UK/China Project Team working Finalise collaboration research agreements Enable project enhancement and refinement Detailed Action planning extend the project network to include (as appropriate); other Chinese research staff; links to other HEIs; links to industry Source potential funding and discuss application process Discussion with funders at a provincial level with the aid of the Consulate Act as a model for joint UK/China research project development and operation Raise the profile of the academics involved and the benefits of UK/China collaboration Summary Both workshops were successful in the level of interaction and engagement between the academics from the two countries, the presentation of expertise and areas of interest on both sides and the identification of key areas for potential collaboration. The workshops were operational and discussion based to encourage ‘on-the-ground’ development and uptake of project ideas and were facilitated by White Rose staff. The thematic approach allowed both specialism and crosscollaborative discussion and the individual theme leaders were instrumental in presenting an overview and analysis of potential projects that could be developed. On returning to the UK, the research ideas were plentiful and work was done on refining and developing into potential projects and outline action plans. There is interest in creating an overall framework for ‘Energy Recovery and Storage’, with specialist themes, work packages and activities within it. Future visits to China by the UK academic lead to refine project plans are key to maintaining engagement and momentum. Funding sources need accessing in both UK and China by the project groups which would be enabled by further face-to-face meetings, and by utilising the commercial and investment understanding of the Consulate’s Science and Innovation Team in Shanghai. The White Rose University Consortium welcomed the opportunity to facilitate this initial activity and is enthusiastic in helping to secure and embed the potential projects and any further strategic interventions. CPickerden Page 7 of 10 July 2013 UK Delegate List University of Sheffield Professor Jim Swithenbank Dr Yajue Wu University of York Dr Mark Gronnow Dr Vitaliy Budarin University of Leeds Professor Yulong Ding Leader of Theme 1 Chairman of Sheffield University Waste Incineration Centre Department of Chemistry and Biological Engineering Lecturer, Department of Chemistry and Biological Engineering Leader of Theme 2 Process Development Unit Manager Green Chemistry Centre of Excellence Senior Researcher, Microwave technology platform Leader Green Chemistry Centre of Excellence Dr Yongliang Li Dr Chunfei Wu Leader of Theme 3 Director, Institute of Particle Science & Engineering Research Fellow, Institute of Particle Science and Engineering, Research Fellow, Energy Research Institute University of Hull Dr Meihong Wang Reader in Engineering White Rose University Consortium Dr Julian White Chief Executive Claire Pickerden Project Development Manager CPickerden Page 8 of 10 July 2013 Contributors in Beijing Chinese Academy of Sciences Professor Shimou Chen Dr Yi Jin Dr Liang Wang Dr Fengwu Bai Professor Haisheng Chen Dr Yun Huang Institute of Process Engineering Institute of Process Engineering Institute of Engineering Thermophysics Institute of Electrical Engineering Institute of Engineering Thermophysics Institute of Process Engineering Tsinghua University, Beijing Professor Qun Chen Professor Baoguo Wang Dept of Thermal Engineering Dept of Chemical Engineering University of Science and Technology Beijing Professor Hao Bai Department of Metallurgical and Ecological Engineering Professor Hongxu Li Other Institutions Professor Michael Leung Dr Xiaolong Wang Professor Xinrong Zhang Dr Dongliang Chen Professor Hongyuan (David) Wei Dr Xiyun Yang Ms Ming Liu Professor John Loughhead Dr Nicola Combe CPickerden City University of Hong Kong Huaneng Clean Energy Research Institute Peking University Beijing University of Chemical Technology School of Chemical Engineering, TianJin University. Control Science and Computer Engineering School, North China Electric Power University Head of Science & Innovation Office, British Consulate-General Guangzhou Executive Director, UK Energy Research Centre UK Energy Research Centre Page 9 of 10 July 2013 Contributors in Nanjing Mr Yangwei ZHAO British Consulate General Shanghai Mr Tim Standbrook Ms Bronte Zhang Ms Lily Zhu Ms Ying ZHANG Ms Tracy TANG Director International Cooperation Division, Department of Science and Technology, Jiangsu Province Consul of Science and Innovation, Senior Science and Innovation Officer Science and Innovation Officer Senior Trade Officer Inward Investment Officer Nanjing University of Science & Technology Professor Lianjun Wang Vice President Professor Yang Dongmei International Exchanges and Co-operation Professor Qinhua Li Deputy Dean of School of Chemical Engineering Professor Dongping Sun School of Chemical Engineering Professor Qingli Hao School of Chemical Engineering Professor Junwu Zhu School of Chemical Engineering Southeast University, Nanjing Dr Huiyan Zhang Dr Dekui Shen Energy Thermal Conversion and Control School of Energy and Environment Huazhong University of Science and Technology Professor Haiping Yang Key Laboratory of Coal Combustion Professor Hanping CHEN Deputy Director, Key Laboratory of Coal Combustion Nanjing University Of Aeronautics And Astronautics Professor Yimin Xuan School of Energy and Power Engineering Professor Bo Shi Shanghai Electric Power University Professor Weiguo PAN Professor Qunzhi ZHU Tong Ji University Professor Dong Zhang Yuefeng Li Other Institutions Dr Carol Lin Changying Zhao Dr Guanghui Leng Professor Jianzhong Sun Professor Jing Ding Dr Hui Cao Guo Hong CPickerden Vice President Associate Dean, College of Energy and Mechanical Engineering School of materials science and engineering Assistant Professor of SEE, City University Hong Kong Shanghai Jiao Tong University Institute of Process Engineering, Chinese Academy of Sciences Jiangsu University School of Engineering, Sun Yat-sen University University of Leeds Deputy Director, International Co-operation Division Page 10 of 10 July 2013