Ice Cores UCAR Office of Education and Outreach Dr. Randy M. Russell Ice cores extracted from polar ice sheets and from glaciers worldwide are one type of paleoclimate proxy record - a source of data that tells us about past climates. Ice cores from glaciers and the polar ice caps are probably the most comprehensive type of proxy record of past climates. Physical and chemical analysis of ice cores provides information on temperature, precipitation, atmospheric aerosols (such as dust and volcanic ash), and even levels of solar activity. Ice cores can provide data with a resolution as fine as yearly, and some records span periods of hundreds of thousands of years. Continuous climate records embedded in ice form in areas where year-round cold temperatures prevent fresh accumulations of snowfall from melting in the summertime. The North and South Polar Ice Caps are obviously good locations for such accumulations, but high-altitude glaciers, even in low-latitude regions, can also be a source of ice cores. As layer upon layer of new snow builds up, the older layers on the bottom gradually get compressed. This compressed snow first transforms into a grainy material called "firn" that has a texture akin to granulated sugar. As the firn is buried deeper beneath subsequent layers, pressure eventually condenses it into solid ice (at a depth of about 100 meters in Antarctic samples, for instance). This ice layer can become quite deep over time; the 25 million year old East Antarctic Ice Sheet is more than 4.5 kilometers thick in places! As the firn turns to ice, the air pockets between the grains become cut off from each other and produce bubbles in the ice. The bubbles serve as miniscule air samples from past eras, which scientists can use to study the state of Earth's atmosphere in ancient times. One of the most important paleoclimate indicators in such samples is the concentration of greenhouse gases (such as carbon dioxide and methane). Picture 1: Scientists examine an ice core sample; inset shows layering Picture 2: Close-up view of layers within a different sample; (arrows indicate lighter summer layers ). Credits: Ken Abbott, Office of Public Relations, University of Colorado, Boulder (left). Anthony Gow, United States Army Corps of Engineers, Cold Regions Research and Engineering Laboratory (right). The uppermost portions of an ice core exhibit a layered structure that shows yearly variation, providing an annual resolution like that in tree rings, corals, or varved lake sediments. Extreme pressures crush the deeper ice layers together so tightly that annual variations cannot be distinguished, though climate variations with lower resolutions can still be discerned. Typically, in ice samples from polar regions (primarily Greenland and Antarctica), the upper layers of ice have alternating light and dark layers. Light bands correspond to the relatively fresh, clean snows that fall in the summer when warmer conditions bring more moisture (and thus more precipitation) to these high-latitude locales. Dark bands mark the polar winter season, when little new snow falls on these frigid deserts and blowing snow is mixed with dust carried in from afar, discoloring the white snow. In many samples, this alternating light and dark layering is visible to the naked eye; in others, the layers can only be found by looking through polarized filters or via chemical analysis. Thick summer layers can indicate periods during which precipitation was heavier than usual, while especially dark winter layers can tell the tale of dry spells with regional or global dust storms. Most ice cores are collected from the vast ice sheets covering Greenland and Antarctica, which provide records spanning the longest time periods. Scientists have drilled down through more than 3 kilometers of ice in Greenland to the bedrock beneath; the samples thus extracted represent about 130,000 years of history dating back to the last interglacial warm spell (during which Greenland was ice-free). Although deeper ice layers at a specific spot correspond to older time periods, the depth of ice at different sites doesn't always directly relate to the age of a record; different snowfall rates in different locales can lay down thicker or thinner layers over time. Although the ice in Antarctica is up to 4.5 km deep in spots, the oldest record recovered to date from Antarctica comes from a 3,270 meter deep drill hole that provides a history of climate dating back about 740,000 years. Ice from the bottom of a drill hole is much, much more compressed by pressure than is ice closer to the surface. At the South Pole firn turns to ice about 122 meters down and represents the climate of 100 years ago, while the bottom 100 meters of ice from the oldest Antarctic site represents the oldest 100,000 years of that record. What type of information is archived in ice, and what does this data tell us about past climates? As was mentioned above, gas bubbles in the ice indicate the relative abundances of various atmospheric gases. Greenhouse gases like carbon dioxide and methane give us an insight into atmospheric heating. The thickness of an ice layer provides clues about local precipitation; a thick layer corresponds to greater snowfall. Layer thickness also may tell us something about global temperatures. Higher snowfall rates in polar regions generally correspond to more moisture in the global atmosphere, which usually arises during periods when the overall global temperature is high, causing increased evaporation from the oceans. Thus, counterintuitively, more snow tends to accumulate at the poles during global warm spells. Many types of aerosols (extremely fine particles), often carried to the polar regions from afar by winds, settle upon snow and become trapped within ice. These aerosols can include soot produced by burning (forest fires, slash-andburn agriculture, industrial output from smokestacks, etc.), ash from volcanic eruptions, and dust from large-scale dust storms. Traces of unusual isotopes of certain elements also show up in ice core records. Chlorine-36 and iodine-129, produced by early atmospheric testing of nuclear weapons, have been found in ice cores from the Fremont Glacier in Wyoming. Beryllium-10 concentrations, linked to cosmic ray intensities, are an indirect indicator of solar activity. The ratio of concentrations of two isotopes of oxygen in the water molecules in ice serves as a proxy indicator of global temperatures. Oxygen has two commonly occurring natural isotopes, the usual 16O (which makes up more than 99% of naturally occurring oxygen on Earth) and the less abundant 18O. The two extra neutrons in 18O cause water molecules containing this isotope to be heavier than normal water molecules. These heavier water molecules cannot escape from ocean water to become water vapor in the atmosphere via evaporation as readily as lighter water molecules. This tendency for preferential evaporation of 18O varies, however, as a result of the ocean temperature. Through a rather complex chain of events involving the global water cycle, this disparity between concentrations of oxygen-18 and oxygen-16 shows up in the snow that falls in polar regions, and thus in the ice formed from this snow. The net result is that the ratio of 18O to 16O in ice samples provides clues about global ocean temperatures and the extent of the polar ice caps at a given time in Earth's history. Scientists must be careful in their interpretations of ice core data. For example, the gases trapped in bubbles in ice may do not have exactly the same age as the surrounding ice. For a few years after it falls, snow has air spaces between the snowflakes that are still exposed to the atmosphere, so gases can move between the snow and the atmosphere. As the deeper layers of snow are transformed into firn, the movement of air between these gaps and the atmosphere diminishes. However, this gas exchange does not cease entirely until the firn turns to ice and the pores become sealed bubbles. The gas in such bubbles therefore includes atmospheric "samples" from the years of the snowto-firn-to-ice transition period, somewhat blurring the resolution of the ice core records in terms of gas samples. The pores tend to close off at depths of 50-150 meters in the Antarctic, but at much shallower depths in cores from mountain glaciers. In polar ice samples, the difference between the "ice age" and the "gas age" can be as large as about 150 years. Ice cores are extracted using drills with ring-shaped bits on the ends of hollow tubes. Cores are typically removed in sections that are six meters long, so drilling to a depth of more than a kilometer requires many repetitions of the drilling and core removal process. Upon removal from the drilling rig, the long cores are generally cut into shorter 2meter segments and their surfaces are carefully cleaned of fluids used in the drilling process. Deep ice is especially brittle, so the cores must be handled carefully and must obviously be stored in cold conditions. The cores are kept in a deep freeze as they are transported from their collection sites to one of a handful of archival storage and research facilities around the world. One such facility, the U.S. National Ice Core Laboratory which is maintained by the USGS and NSF near Denver, Colorado, stores over 14,000 meters of ice cores from 34 drill sites in Greenland, Antarctica, and high mountain glaciers in the Western United States at a temperature of minus 35° C. The cores are split lengthwise for study in a laboratory that is kept at a temperature of minus 22° C. Data: Ice core Data-Greenland Temperature vs. O18/O16 Ratio Year 1970 1969 1968 1967 1966 1965 1964 1963 1962 1961 1960 1959 1958 1957 1956 1955 1954 1953 1952 1951 1950 1949 1948 1947 1946 1945 1944 1943 1942 1941 1940 1939 1938 1937 1936 1935 1934 1933 1932 1931 Avg. Temp -6.383333333 -5 -6.866666667 -7.65 -5.533333333 -5.083333333 -5.616666667 -4.266666667 -4.9 -7.15 -6.733333333 -6.216666667 -6.416666667 -8.133333333 -5.7 -7.116666667 -7.9 -5.15 -7.416666667 -7.2 -7.8 -10.01666667 -6.233333333 -2.766666667 -5.433333333 -8.233333333 -6.583333333 -5.9 -5.966666667 -3.633333333 -4.366666667 -7.866666667 -8.166666667 -7.733333333 -3.933333333 -5.766666667 -6.683333333 -7.683333333 -5.383333333 -7.333333333 PC1 2.277 2.928 -0.886 -0.271 1.715 3.630 2.682 3.092 0.618 2.096 4.183 1.336 -0.662 -2.041 0.643 -0.506 0.846 3.421 -1.570 0.568 -0.539 -1.425 2.647 5.455 5.387 -1.803 -0.959 -0.361 3.396 0.766 5.541 0.967 1.240 -1.732 0.788 2.675 3.906 0.482 2.819 -0.246 1930 1929 1928 1927 1926 1925 1924 1923 1922 1921 1920 1919 1918 1917 1916 1915 1914 1913 1912 1911 1910 1909 1908 1907 1906 1905 1904 1903 1902 1901 1900 1899 1898 1897 1896 1895 1894 1893 1892 1891 1890 1889 1888 1887 1886 1885 1884 1883 1882 1881 1880 1879 1878 1877 -6.433333333 -2.766666667 -5.633333333 -6.833333333 -4.9 -9.4 -5.466666667 -6.583333333 -9.216666667 -10.68333333 -8.666666667 -9.15 -10.16666667 -5.083333333 -5.3 -9.9 -10.88333333 -8.033333333 -7.116666667 -9.266666667 -10.8 -7.45 -8.566666667 -11.31666667 -10.58333333 -7.166666667 -9.216666667 -10.33333333 -7.366666667 -7.4 -7.533333333 -10.05 -11.08333333 -10.36666667 -10.91666667 -6.55 -12 -7.266666667 -8.116666667 -10.38333333 -10.26666667 -9.033333333 -6.833333333 -11.26666667 -10.1 -8.683333333 -12.76666667 -9.6 -11.6 -5.916666667 -9.8 -4.633333333 -7.7 -7.216666667 -0.388 3.827 -0.473 -2.741 1.875 -1.588 -2.249 1.420 -2.176 -2.401 -1.264 -3.102 -2.353 5.574 3.482 -3.439 -1.457 -1.973 1.850 -0.271 -2.106 2.325 -0.434 -5.378 -5.028 -2.887 -0.371 -1.585 -0.635 0.973 -4.145 -0.390 -2.485 -0.128 1.045 2.300 -1.262 1.184 0.381 -1.183 -3.772 -0.478 2.693 -0.261 -0.943 -1.642 -1.481 -2.253 -2.797 1.666 -0.357 3.038 -1.080 -0.371 1876 1875 1874 1873 1872 1871 1870 1869 1868 1867 1866 1865 1864 1863 1862 1861 1860 1859 1858 1857 1856 1855 1854 1853 1852 1851 1850 1849 1848 1847 1846 1845 1844 1843 1842 1841 1840 1839 1838 1837 1836 1835 1834 1833 1832 1831 1830 1829 -7.183333333 -6.566666667 -8.866666667 -7.883333333 -4.05 -6.733333333 -9.616666667 -9.583333333 -9.733333333 -9.166666667 -10.21666667 -7.55 -11.25 -14.13333333 -9.666666667 -9.516666667 -6.85 -9.8 -8.983333333 -7.583333333 -4.083333333 -8.233333333 -10.31666667 -6.716666667 -7.333333333 -7.15 -8.216666667 -9.966666667 -9.883333333 -2.7 -7.783333333 -8.4 -12.53333333 -7.516666667 -10.26666667 -8.85 -7.95 -10.26666667 -11.9 -11.76666667 -8.35 -11.65 -11.33333333 -11.08333333 -10.61666667 -6.9 -7.1 -5.7 Questions: 1. You will need to generate three graphs: a. temperature (dependent variable) vs. time b. PC1 (oxygen 18 isotope ratios) vs. time 2.939 1.464 -2.949 0.304 1.812 2.183 -1.419 -2.365 0.309 -0.436 -1.077 0.784 -5.969 -4.336 -0.671 -0.276 -1.009 -0.052 -0.767 -1.937 3.449 0.382 -0.554 3.191 3.038 1.697 0.373 -0.661 -1.731 3.710 -1.284 -0.707 -2.076 1.904 -1.201 1.669 -0.667 -1.963 1.857 -4.312 -1.907 -5.998 -2.981 -3.312 1.682 2.133 1.735 1.853 2. 3. 4. 5. c. Scatter plot PC1 is dependent variable and temperature is the independent variable *** be sure to include a trend line and r2 value for each graph*** Determine the relationship between temperature and PC1 (O18 ratio values). What conclusions can be made about the climate through PC1 (O18 ratios) and temperature? Use 3 pieces of evidences from your research to support your ideas. How can present day data such as this be use by paleoclimatologists to reconstruct past climates? What are the limitations of this source of information? Resources: 2 minute video about ice cores - produced by NSF - features several prominent climate scientists (Richard Alley, Michael Mann, Ellen Mosley-Thompson, and Jim White) - on Windows to the Universe "Ice Core Secrets Could Reveal Answers to Global Warming" - 5 minute video from NSF's Science Nation online magazine Graphs of temperature variation from present-day values (blue), atmospheric carbon dioxide concentration (green), and dust (red) based on data from ice cores retrieved at the Vostok drilling site in Antarctica. Credits: Petit J.R., Jouzel J., Raynaud D., Barkov N.I.,Barnola J.M., Basile I., Bender M., Chappellaz J., Davis J., Delaygue G., Delmotte M., Kotlyakov V.M., Legrand M., Lipenkov V., Lorius C., Pépin L., Ritz C., Saltzman E., Stievenard M. (1999). Climate and Atmospheric History of the Past 420,000 years from the Vostok Ice Core, Antarctica. Nature 399: 429-436.