The State of our Tap Water Monique Warren Author biography: Monique Warren is a senior at USC, and will be receiving her Bachelor of Science degree in civil engineering with an environmental emphasis in May 2014. She has taken numerous water courses at USC, of which includes: Water Chemistry, Water Treatment Design, Wastewater treatment design, and Water Supply and Sewerage System Design. She hopes to one day work in water treatment for developing countries. Writing 340 moniquew@usc.edu (626)315 -4496 12/11/2013 Abstract The average human body is made up of about 65% water. About 70% of the earth’s surface is covered with water. Water surrounds us every day, and we can’t go a day without using it somehow. Yet most people do not know the intricacy of the stringent treatment that their water goes through before it comes out of their tap. As a result, there is a stigma in our society that tap water is low quality and may even be harmful to drink. However, upon further examination one may find that the treatment process that produces our drinking water is not only thorough but trustworthy. Recommended media A form of media that could accompany this article would be a video tour of a water treatment plant. This video could highlight key points in the article, and give readers a closer look at what these treatment units look like in real life. 1|Page The State of our Tap Water Introduction Whether you turn on the shower, brush your teeth, or even do the dishes, there’s no getting around the use of tap water throughout your day. However, there seems to be a stigma surrounding the quality of water that runs from the faucet. Afraid that the water on tap is unhealthy, people seek alternatives to drinking water straight from the tap. The sale of bottled water increased by 6.7 percent in 2012, and now totals $11.8 billion [1]. People tend to turn to bottled water and home filters as opposed to drinking water straight from the tap. Is this fear of tap water justified? Well, before you can really decide that, you must take a closer look at what’s coming out of the faucet. If you do, you will find that due to extensive treatment the tap water typically received in homes around the U.S. is of high quality. Importance of drinking water treatment The water that comes out of your tap goes through long, strenuous treatment. This is due to the fact that you cannot simply pump water from a river or other water source directly into the houses of a community. Even though the water from these sources can be of high quality, this water is still are not suitable for drinking until it is treated. The water that is sent to the treatment plants to be cleaned can contain different pollutants that have to be removed before the water can be used. The treatment process generally used is known as the conventional drinking water treatment process. The process can change slightly depending on the water that the drinking water treatment plant is treating. For instance, if the source of water for a treatment plant comes from groundwater that contains an excessive amount of nitrate (an ion that can cause blue baby syndrome in infants if consumed), the conventional treatment process will need to be adjusted to treat the nitrate in the water. Thus, it is important to look at the source of the water. 2|Page The source of the drinking water being treated will depend on the area that the treatment plant is serving. For instance, a family located in Southern California may receive water originally from the Colorado River (a surface water source), or from Northern California brought to Southern California by way of the State Water Project (surface water), or from a local groundwater source. It is important to consider where the water comes from, because the treatment plant needs to know what to treat the water for before they distribute it to the public. The two most basic categories of water sources would be groundwater and surface water. Groundwater being water beneath the ground, held in rocks and porous soils, and surface water being water on the surface of the earth like rivers, lakes, and streams. Evaluating the drinking water sources Groundwater Compared to surface water, groundwater is less likely to be contaminated; however, naturally occurring inorganic chemicals (i.e. arsenic, fluoride, nitrate, etc.), human-made chemicals like pesticides or fuels, or calcium or magnesium are all contaminants that could potentially pollute groundwater sources [2]. This is due to the fact that groundwater is made up of rain water and surface water that has moved from the surface to ground. If polluted surface water infiltrates into the groundwater, then the groundwater can become polluted. For example, in Florida, the Floridian Aquifer is infiltrated by water from the Alapaha River. As seen in Figure 1, the flow from the Alapaha River flows directly into the Floridian aquifer, so that all of the contaminants and pollution in this surface water also flows into the groundwater. Figure 2, shows a diagram of groundwater from which we can also see the how the proximity of a groundwater source to a surface water source can lead to the infiltration of the groundwater 3|Page source. Groundwater can be contaminated, but it’s not exposed to as many contaminants as surface water. Figure 1: Alapaha River flowing into the Floridian Aquifer [11] Figure 2: Surface water and groundwater Modified from: [11] and [12] Surface waters On the other hand surface waters can be polluted by a number of things, because they are more exposed. Runoff containing fertilizer, untreated sewage, runoff from parking lots and other 4|Page impervious ground, and unprotected watersheds can all be potential sources of contamination [2]. These sources of contamination are of concern, because they pose the threat of the water containing pathogenic bacteria like Giardia or Cryptosporidium, which are both harmful to humans when consumed. In Figure 2, the Colorado River is shown. From this picture we can see how this river is exposed to many different elements that could provide sources of contamination; from animal waste to runoff containing pollutants from nearby areas. Contaminants in water sources Giardia and Cryptosporidium are both contaminants that can be a result of fecal contamination (animal or human). Since, surface waters are completely exposed to the elements and animals it makes sense that there is a risk of fecal contamination. If water containing Giardia were to be consumed, small intestinal problems like diarrhea could be a result. Comparably, water-containing Cryptosporidium poses the threat of fever, diarrhea, nausea, and cramping upon consumption [3]. To ensure that the water the public receives is of good quality, water treatment engineers must take it through a long, extensive process of treatment. Surface waters aren’t the only source of pollution for groundwater. Groundwater can also be polluted by seepage from landfills, uncontrolled hazardous waste, septic systems, and gas or oil storage tanks to name a few sources [14]. Each source of groundwater and surface water will be different depending on the area, and what is nearby. A treatment plant will test the source of water they intend to pull from to determine its quality and what contaminants need to be treated. Treating the contaminants – The drinking water treatment process The treatment process for drinking water contains several steps, by which different contaminant types are removed. The water first enters the plant and must go through a pretreatment process where it is screened. After the pretreatment, the water can then go through the treatment process. The water goes through coagulation, flocculation, sedimentation, 5|Page filtration, and disinfection before it is stored and then distributed to the community served. Figure 3 shows the flow of the conventional treatment process. The steps in the process are numbered in the figure based on the order they are completed, and are placed under the tank or unit where they occur. As seen in the figure, the first step in this process is the screening of the water. Figure 3: Flow chart of a conventional water treatment plant Screening Generally, the water received by the plant is first put through pretreatment where a simple screening is done so that larger materials, like sticks and other debris, don’t enter the plant with the water. These larger objects cannot enter the treatment plant, as they would damage treatment equipment. The screening process is comparable to straining pasta, in that the sizes of the holes in the strainer are small enough to allow the hot water to pass through and keep the cooked pasta in the strainer. After the water has been screened, the flow then moves to the rapid mix tank for coagulation. Coagulation and flocculation In Figure 2 flocculation is grouped with coagulation in step 2. The processes of coagulation and flocculation are typically referred to as one because they go hand in hand. In order to have flocculation, you need coagulation; and they also both occur in the rapid mix tank. 6|Page In the rapid mix tank (as shown in Figure 3), a chemical called a coagulant is added to the water and then mixed rapidly, for thirty seconds or more depending on the plant size, and then slowly mixed, for twenty minutes or more again depending on the size of the treatment plant. This process is called coagulation. Coagulation is performed in drinking water treatment, to settle out particles that won’t settle out on their own by gravity. The majority of these particles are negatively charged so that they repel each other instead of coming together to make a clump. Mixing the coagulant with the water changes the charge on some of the particles so that they no longer repel each other [4]. Once the charge on some of the particles is changed, they can clump together and form what are called flocs, which are able to settle out by gravity; this process is known as flocculation. If the water coming out of your tap were to be cloudy or murky, it would not only be aesthetically displeasing but alarming. To us, if something looks funny (especially our water) we are not going to want to consume it. This is what makes coagulation and flocculation so important. These processes settle out the particles in the water that are responsible for making it appear cloudy. The flow of the water then moves to the sedimentation tank where these flocs can settle out of the water. Figure 3: Rapid mix tank 7|Page Sedimentation The flocs that were formed by the processes of coagulation and flocculation now need to be removed from the water, and the simplest way to do that is to let them settle. Imagine dropping a golf ball into a pool, what does it do? Due to gravity, the golf ball will sink to the bottom of the pool. The same concept applies here. Before coagulation and flocculation the particles in the flow were too light to settle out of the water, but after they clumped together to form flocs they became heavy enough to be removed by sedimentation. In the sedimentation basins, the water is allowed to sit so that the flocs can sink to bottom of the tank and be removed by scrapers. Figure 5 shows a typical drawing of a sedimentation basin, that illustrates how the flocs settle to the bottom of the tank. Once these clumps gather together at the bottom of the sedimentation basin, they are then referred to as sludge. The sludge is scraped from the bottom of the tank and sent to be disposed of with other solid waste. Figure 6 shows the sedimentation basins at an actual water treatment plant. Though you cannot see the cross section of the basin, the picture does show how great masses of water are allowed to sit while the flocs settle. The cleaned effluent then leaves the sedimentation tank and moves on to filtration. Figure 5: Sedimentation basin design 8|Page Figure 6: Sedimentation basins at Bollman Water Treatment Plant [9] Filtration The process of filtration is responsible for removing non-dissolved solids from the flow of water. During filtration, the filter removes smaller particles that cause the water to be cloudy, biological contaminants like Cryptosporidium and Giardia, and inorganic chemicals like mercury and arsenic [2]. Any flocs that weren’t settled out by sedimentation will be removed here. As seen in Figure 7, the flow from the sedimentation tank comes in to the top of the filter and then flows through the layers of media in the filter. This part of the treatment process can be accomplished with by a few different kinds of filters, like a slow sand filter or granulated activated carbon filter (GAC). It all depends on what media is selected. The point of the filtration process is for the particles in the water to become trapped in the media of the filter, thus the selection of the media is important to filtration. There are a number of key elements to the selection of filter media like the durability of the filter media, length of the filter run, and ease of filter wash to remove suspended matter from the media [5]. It takes time for the water to filter and go through the different layers in the filter. The filter fun time will depend on how long it takes for a certain amount of water flow through the filter. The filters also 9|Page have to be cleaned, which is done by using some of the filtered water to backwash the filter. To back wash the filter, water is pumped up through the filter. Sand and gravel are typically the media used in the conventional filtration process. Activated carbon is another helpful media to use in filtration. Previously, activated carbon was used in filtration as merely control for the taste and odor of water; however, as technology has evolved pollutants like Disinfectant By-products (DBP), Synthetic Organic Compounds (SOC), and Endocrine Disrupting Compounds have been discovered. The presence of these compounds in water can be dangerous, so they must be regulated and treated for and activated carbon is one means of doing this [6]. Activated carbon is very porous, which means it is good at adsorbing particles and this is what allows it to be so beneficial in the filtration process. In Figure 7, once the water flows through the layers of media the water then collects at the bottom of the filter and then flows out to disinfection. Figure 7: Filtration tank [10] Disinfection The most common process used for the disinfection of water is chlorination, the addition of chlorine to the water to kill any microorganisms, pathogens, or other harmful pollutants in the 10 | P a g e water. Chlorine is effective against a variety of pathogens, so it is an ideal choice for treatment [7].When the water reaches the public obviously it is important that it is still clean, which is why some residual disinfectant must remain in the water. Before the water can come out of your tap, it has to travel through many pipes. These pipes can be dirty, have buildup, or other harmful pollutants that you don’t want to drink. This is why there must be residual disinfectant in the treated water, as it treats any bacteria that the water may come across in the pipes during the distribution process. The extra chlorine in the treated water that leaves the plant can kill any bacteria it comes across, before it reaches your faucet. All the proper precautions must be taken to ensure that the water is of the highest quality possible when it gets to the consumer. Making sure the water is clean – regulating treated water The Environmental Protection Agency (EPA) has set in place regulations to ensure that the public can trust the water they receive. The EPA gives regulations for the contamination levels of water produced by treatment plants. Since a wide range of contaminants can potentially contaminate our drinking water the EPA sets what is known as MCLs, maximum contaminant levels. An MCL is the highest level of a contaminant that is allowed in drinking water and MCLs are enforceable by law. MCLGs, maximum contaminant level goals, are also set. MCLGs give the level of contamination in water that the EPA wants treatment plants to work toward, below which there is no anticipated risk to health [8]. The water treated by a plant is bound to have a small amount of contaminant left in it, but with these sorts of regulations in place the contaminant level in the water is not at a level that should pose a threat to human health. Trustworthy tap water If you still question the water that comes out of the tap, you can purchase a water testing kit and check it yourself. If you find that there is something wrong with your water, it can be 11 | P a g e reported to your water distributer so that the problem is fixed. The conventional drinking water treatment process is widely used by treatment facilities and has many different components. The water that is distributed to households has high quality, because it is well treated, monitored, and regulated. The regulations set in place, MCLs, are enforceable by law. So, if a treatment plant were to send water out with contaminant levels higher than the set MCL they would be breaking the law. Thus, treatment plants test the water they send out to make sure that it meets the regulations set forth by the EPA. All of the effort that goes into treating the water (whether it’s from the ground or surface) is well designed, planned, monitored, and enforced. So, the water that comes out of the tap is water worth trusting. 12 | P a g e References [1] International Bottled Water Association. U.S. Consumption of bottled water shows continued growth, increasing 6.2 percent in 2012; sales up to 6.7 percent. IBWA. http://www.bottledwater.org/us-consumption-bottled-water-shows-continued-growth-increasing62-percent-2012-sales-67-percent [2] Scott G. Curry. (2003). “Drinking Water Treatment.” Water: Science and Issues. [Online] (1) pp. 257-260. Available: http://go.galegroup.com/ps/i.do?action=interpret&id=GALE%7CCX3409400087&v2.1&u=usoc al_main&it=r&p=GVRL&sw=w&authCount=1 [3] Chittaranjan Ray and Ravi Jain. Drinking Water Treatment: Focusing on Appropriate Technology and Sustainablility. Dordrecht: Springer, 2011. Print [4] “Our Water Treatment Process.” Our Treatment Process. San Diego Public Utilities, http://www.sandiego.gov/water/quality/watersources/treatmentprocess/index.shtml [5] Susan K. Burns, V. Dean Adams, and Steel B. Maloney, “Direct Filtration versus Conventional Water Treatment on the Intermountain Region,” Utah Water Research Laboratory (1984). Reports. Paper 580. http://digitalcommons.usu.edu/water_rep/580 [6] Ozgur Aktas and Ferhan Cecen. (2007, Sep.) Competitive adsorption and desorption of a bisolute mixture: effect of activated carbon type. Springer Science. [Online]. (13) 159-169. Available: http://download.springer.com/static/pdf/15/art%253A10.1007%252Fs10450-0079017-5.pdf?auth66=1383998596_9877b5f34793fd3b9103ad8a170373a8&ext=.pdf [7] Daniel Gerrity and Shane Snyder. “Wastewater and Drinking Water Treatment Technologies” in Human Pharmaceuticals in the Environment: Current and Future Perspectives Emerging Topics in Ecotoxicology 4. Springer [8] “National Primary Drinking Water Regulations.” US EPA. EPA. Web. [9] Contra Costa Water District. CCWD Photos & Maps of CCWD Facilities & People [Online]. Available: http://www.ccwater.com/photopages/index.asp [10] Michigan Environmental Education Curriculum. Drinking Water Treatment. [Online] Available: http://techalive.mtu.edu/meec/module03/Sources-Groundwater.htm [11] USGS Surface Water Information. USGS Surface Water Photo Gallery. [Online]. 13 | P a g e Available: http://water.usgs.gov/osw/images/ [12] "Aquifers." USGS Water-Science School. USGS, n.d. Web. Available: <http://ga.water.usgs.gov/edu/earthgwaquifer.html>. [13] "Potential Threats to Our Groundwater." Groundwater. The Groundwater Foundation, n.d. Web. 2013. Available: <http://www.groundwater.org/getinformed/groundwater/contamination.html>. 14 | P a g e