CHAPTER 13 LEARNING OBJECTIVES
To satisfy the minimum requirements for this course, you should master the following
learning objectives.
Understand the concept of reaction rates and be able to
• use a table of concentration versus time data to calculate an average rate of
reaction over a period of time. (pg 560) ARIS 1
• use the coefficients of a balanced reaction to express the rate of reaction in
terms of the change in concentration of a reactant or product with time.(pg 563)
ARIS 2
• determine instantaneous rates from a graph of reactant or product
concentration as a function of time.(pg 562)
Determine the rate law from initial rate data (ARIS 6-8) and be able to determine: the
order of reaction with respect to each reactant (ARIS 3), the overall order of reaction, the
rate constant with units (ARIS 5), and the initial rate for any other set of initial
concentrations. (pg 565 – 568) ARIS 4
Recognize the integrated rate laws and be able to
• use integrated first- ( pg 570 – 576) and second-order ( pg 577 – 581) rate laws
to find the value of one variable, given values of the other variables. ARIS 9-10
• explain the concept of reaction half-life and describe the relationship between
half-life and rate constant for zeroth, first, and second-order reactions.(pg 575)
ARIS 13-16
• determine the order of the reaction from plots of concentration versus time,
ln concentration versus time, and 1/concentration versus time (Figures 13.9 –
13.14) ARIS 11-12
Use the Collision Theory of Chemical Kinetics to explain how reactions occur at the
molecular level (pg 582) ARIS 21
, and
• explain the concept of activation energy and how it relates to the variation of
reaction rate with temperature. (pg 583-584)
• solve the Arrhenius equation and determine the activation energy from the
slope of the Arrhenius plot (ln k versus 1/T). (example 13.8) ARIS 17-19
Understand the relationship between a reaction mechanism, and its rate law (pg 588)
ARIS 20
and
• given a reaction mechanism, identify the reaction intermediates and catalysts,
write the overall reaction, and determine the molecularity of each step.(pg 590591) ARIS 24
• derive a rate law for a reaction that has a rate-determining step, given the
elementary steps and their relative speeds.(pg 589) ARIS 22
• choose a plausible mechanism for a reaction given the rate law. (example
13.10)
Define a catalyst and be able to
• describe the effect of a catalyst on the energy requirements for a reaction. (pg
595)
• explain the differences between homogeneous (pg 598) and heterogeneous (pg
595) catalysts.
• sketch a potential energy profile showing the activation energies for the
forward and reverse reactions and show how they are affected by the
addition of a catalyst. (Figure 13.23) ARIS 23
• explain how enzymes act as biological catalysts and how they interact with
specific substrate molecules.(pg 599-601)
Understand the meaning of the Key Words on page 602.