SCH3U1 6.3 Solution Concentration What is “Solution Concentration”? Concentration = the quantity of a given solute in a solution In general, Concentration = quantity of solute quantity of solution Some Important Terms Dilute = having a relatively small quantity of solute per unit volume of solution Concentrated = having a relatively large quantity of solute per unit volume of solution Concentration Units 1. % W/V (%m/v) This concentration usually describes a solid solute dissolved in a liquid solvent. Example of a solution that uses this concentration unit: Intravenous solution is 0.90% (m/v) NaCl (this means 0.90g NaCl dissolved in 100mL of solution) Example 1 2. A box of apple juice has a fructose (sugar) concentration of 12 g/100 mL (12% W/V). What mass of fructose is present in a 175 mL glass of juice)? % W/W (%m/m) This concentration usually describes a solid solute in a solid solvent. Example of a solution that uses this concentration unit: toothpaste is 0.24% (m/m) SnF2 (this means 0.24g SnF2 dissolved in100g of solution) Example 2 A sterling silver ring has a mass of 12.0 g and contains 11.1 g of pure silver. What is the percentage weight by weight concentration of silver in the metal? SCH3U1 3. 6.3 Solution Concentration % V/V (%v/v) This concentration usually describes a liquid solute in a liquid solvent. Example of a solution that uses this concentration unit: wine is11.0% (v/v) Ethanol (this means 11.0 mL of ethanol is dissolved in 100mL of solution, ie the wine.) Example 3 4. Gasohol, which is a solution of ethanol and gasoline, is considered to be a cleaner fuel than just gasoline alone. A typical gasohol mixture available across Canada contains 4.1L of ethanol in a 55L tank of fuel. Calculate the percentage by volume concentration of ethanol. parts per million – ppm This concentration unit is for very small quantities of solute c (ppm) = amount of solute amount of solution Example of a solution that uses this concentration unit: bottled water contains 280 ppm of HCO31-, 118 ppm Ca… (this means every 1 000 000 parts of solution contain 280 parts of HCO 31- solute) *1ppm = 1 drop of water in a bathtub Units for ppm: 1ppm = 1 mg/L 1 mg/kg 1 μg/g *Choose the unit that matches the information given in the example you are calculating. Example 4: If the concentration of oxygen in water is 8 ppm, what mass of oxygen is present in 150 mL of water? SCH3U1 5. 6.3 Solution Concentration Molar Concentration - Molarity (M) This concentration unit describes the amount of solute (in moles) dissolved in 1 L of solution. Example of a solution that uses this concentration unit: Hydrochloric acid - HCl 1.25M (mol/L) (This means that 1.25 moles of HCl are dissolved in 1.00L of solution.) **Chemists use Molarity because it allows them to relate concentration to moles of a substance. Example 5: When 2.00 g of KMnO4 is dissolved into 100.0 mL of solution, what molar concentration results? Example 6: How many grams of KMnO4 are needed to make 500.0 mL of a 0.200 mol/L solution?