C2 Important Calculations Relative molecular masses (Mr) and (Ar) – use periodic tables. It’s always the big number 1. What is the Mr of the following a. MgO b. CO2 c. ZnCl d. FeCl3 e. Al2O3 2. If a metal oxide has a Mr of 56 and a formula of XO, X being the unknown metal. What is the Ar of the unknown metal and what is its name? Ar Name: 3. If a metal chloride has a Mr of 80 and a formula of XCl2, X being the unknown metal. What is the Ar of the unknown metal and what is its name? Ar Name: Moles 1. Calculate the number of moles of the following a. 12g of C b. 12g of Mg c. 12g of Na d. 12g of Pb Percentage Composition 1. What is the percentage of a. Magnesium in MgO b. Carbon in CO2 c. Zinc in ZnCl d. Iron in FeCl3 e. Aluminium in Al2O3 Number of = moles of X Percentage composition of X = mass of X Ar or Mr of X Ar of X x 100 Mr of compound Maximum yield = (mass of X) x (Mr XY) of XY given Ar of X the mass of X Maximum (Theoretical) Yield and percentage yield Percentage = mass made x 100 1. Mg + Cl2 MgCl2 yield maximum yield a. What is the Ar of Mg? b. What is the Mr of MgCl2? c. If 24g of Mg reacted what would the maximum mass of MgCl2 be? If we only got 90g what is the percentage yield? d. If 48g of Mg reacted what would the maximum mass of MgCl2 be? If we only got 120g what would the percentage yield be? 2. O2 + 2H2 2H2O a. What is the Mr of O2? b. What is the Mr of H2O? c. If 32g of O2 reacted what would the maximum mass of H2O be? Remember there are 2H2O produced If we got 32g of water what is the percentage yield? d. If 12g of O2 reacted what would the maximum mass of H2O be? If we got 10g of water what is the percentage yield? Notes and Doodling Empirical Formula Step 1 – Calculate the number of moles of each substance Step 2 – divide each of these numbers by the smallest number to give a ratio Step 3 – Write down the numbers by elements to give a formula 1. A sample of the solvent used in one perfume contained 0.60 g of carbon, 0.15 g of hydrogen and 0.40 g of oxygen. Relative atomic masses: H = l; C = 12; O = 16. Calculate the empirical (simplest) formula of the solvent. You must show all of your working to gain full marks for this question. (4 Marks) 2. A compound is called phosgenite. Analysis of this compound shows that it contains: 76.0g lead (Pb), 13.0g chlorine (Cl), 2.2g carbon (C) and 8.8g oxygen (O) Calculate the empirical formula of this compound. To gain full marks you must show all your working. Relative atomic masses: C = 12 ; O = 16 ; Cl = 35.5 ; Pb = 207 (4 Marks) Percentage Atom Economy Percentage atom = economy Mr of useful product total Mr of all reactants x 100 1. Calcium oxide is made by the thermal decomposition of calcium carbonate This is shown in the equation below: CaCO3 CaO + CO2 a. What is the Mr of calcium carbonate (CaCO3)? b. What is the Mr of calcium oxide (CaO)? c. What is the percentage atom economy in this reaction? 2. Copper sulfate can be made in the following reaction Copper oxide + sulfuric acid CuO + H2SO4 copper sulfate + water CuSO4 + H 2O Calculate the percentage atom economy of the reaction Now look at some questions from past papers and see if you can understand everything they are asking. Try to review this work every week to make sure you still know how to calculate all the different things they may ask in the exam.