P h a s e C h a n g e I n s t r uc ti o n a l C a s e : A s er i e s o f s t u de n t -c e nt er e d s c i e nc e l es s o ns Lesson 2 Effects of Temperature Change on Solids, Liquids and Gases Summary Suggested Timeline 50 minutes Materials Safety goggles for each student Station 1: Bunsen burner, bimetal strip and/or ball and ring apparatus, tongs to hold the strip, beaker of cold water for cooling (if using ball and ring apparatus) Station 2: 3 Petri dishes, one bottle of food coloring, about 300 mL of hot water, ice water (use bags of ice), room temperature water, timer Station 3: hot plate with a metal tray of water to act as a hot water bath, 250 mL Erlenmeyer flask, balloon (that fits over end of the flask), ice bucket or Styrofoam container (or refrigerator if available) Prep 1. Teacher sets up the nine setups (3 of each station). 2. Have a source of ice water and hot water for station 2 students. 3. Place a balloon over each of the three flasks for station 3 setups. Students go to three different stations to test the effect of a change in temperature on solids, liquids and gases. The solids are bimetal strips and/or a ball and ring apparatus. They observe the behavior of the strips and/or ball before and after heating over a Bunsen burner. The effect of temperature on liquids is observed in the behavior of a drop of food coloring in three Petri dishes of water: one at room temperature, one with ice water and one with hot water. The effect of temperature on gases is observed in the expansion of a balloon placed over the opening of a flask sitting in hot water, and observing what happens to the balloon when placed on ice or in a refrigerator. Objective(s) Students discover that liquids and gases move faster at higher temperatures and solids expand. They observe a demonstration that shows that there is no mass increase when temperature increases They relate their observations back to the models of molecular motion from the previous day’s probe to infer that the increase in temperature causes an increase in the motion of the particles in solids, liquids, and gases. Teacher Background Knowledge Teachers know the three states of matter and how molecular motion differs among these states. Teacher needs to know how to use a Bunsen burner. This activity investigates how change in temperature relates to molecular motion. The changes in temperature investigated are not, in this case, sufficient to induce a phase change. In a solid, the attractions between particles are so strong that the particles are essentially fixed in place and can only vibrate (definite shape and volume.) Adding heat increases the energy the particles have to vibrate. Phase Change Instructional Case Lesson 2 Page 2 of 5 Lesson 2 Effects of Temperature Change on Solids, Liquids and Gases Teacher Background Knowledge (continued) We observe this as an increase in temperature. The particles are still strongly attracted to one another, so their average position does not change, but the length of the vibration will increase, leading to a potential expansion in the solid. The particles in a liquid are still attracted to one another such that they remain in constant contact with their neighbors but can freely move around (shape of container, definite volume). The attractions between particles in a gas are negligible; they can be thought of as entirely independent from one another (shape and volume of container). As such, in the case of liquids and gases, energy added as heat will increase the kinetic energy of the particles. They will undergo the same types of motion, but move more quickly than before. For instance, this is seen in the faster dispersal of the food coloring in the hot water. Page 3 of 5 Lesson 2 Effects of Temperature Change on Solids, Liquids and Gases Standards 12 NGSS Performance Expectations: This lesson supports students in progressing toward the NGSS Performance Expectation. MS-PS 1-4: Develop a model that predicts and describes changes in particle motion, temperature, and state of a pure substance when thermal energy is added or removed. Emphasis is on qualitative molecular-level models of solids, liquids, and gases to show that adding or removing thermal energy increases or decreases kinetic energy of the particles until a change of state occurs. Examples of models could include drawings and diagrams. Examples of particles could include molecules or inert atoms. Examples of pure substances could include water, carbon dioxide, and helium. MS-PS 1-5: Develop and use a model to describe how the total number of atoms does not change in a chemical reaction and thus mass is conserved. Emphasis is on law of conservation of matter and on physical models or drawings, including digital forms that represent atoms. Assessment Boundaries: Assessment does not include the use of atomic masses, balancing symbolic equations, or intermolecular forces. In this lesson… Science and Engineering Practices Developing and Using Models: Reevaluate models (drawings) of different phases used in Lesson 1 and have students confirm or change their previous thinking of the phenomena of phase transition. Use model of food coloring to demonstrate phenomena of motion of molecules as temperature is affected. 1 Disciplinary Core Ideas PS1.A: Structure and Properties of Matter The changes of state that occur with variations in temperature or pressure can be described and predicted using these models of matter. Cross Cutting Concepts Cause and Effect Observe the changes that occur when the water is cooled and heated. Predict what will happen when water is heated and cooled. Energy and Matter Matter is conserved because atoms are conserved in physical and chemical processes. Note that the masses are the same in the demonstration when comparing ice water and room temperature water. NGSS Lead States. 2013. Next Generation Science Standards: For States, By States. Washington, D.C.: The National Academies Press. 2 National Governors Association Center for Best Practices, Council of Chief State School Officers Title: Common Core State Standards (insert specific content area if you are using only one) Publisher: National Governors Association Center for Best Practices, Council of Chief State School Officers, Washington D.C. Copyright Date: 2010 Page 4 of 5 Lesson 2 Effects of Temperature Change on Solids, Liquids and Gases In this lesson… CCSS Mathematics CCSS English-Language Arts MP.2 Reason abstractly and quantitatively. WHST 6-8 Support claim with logical reasoning and relevant, accurate data and evidence that demonstrate an understanding of phase transition. Use models to investigate ideas about increases or decreases in molecular motion. *Use credible sources. 7.EE.B.4 Use variables to construct simple inequalities to solve problems by reasoning about the quantities regarding time in seconds for the observation of food coloring. Prior Knowledge In grades K-2, students have learned that heating and cooling substances cause changes that are sometimes reversible and sometimes not. Students learned in the previous lesson that matter exists in moving particles and the freedom of movement of these particles depends on the state of matter. Lesson Station 1: 1. Using bimetal strips: Students draw the strip on a data sheet before heating. 2. Students carefully heat the strip by using the tongs to pass the metal strip slowly back and forth through the Bunsen burner flame and then make a drawing of the heated strip. 3. Have students place strip on lab bench to cool. 4. Draw the strip after cooling. OR 1. Using ball and ring apparatus: Students attempt to pass the ball through the ring and describe observations on a data sheet. 2. They heat the ball end by passing slowly back and forth through the flame and attempt to pass the ball through the ring again. Describe observations on the data sheet. 3. Cool the ball in a beaker of cold water for a few minutes. Attempt to pass the ball through the ring again. 4. Describe observations on the data sheet. Station 2: 1. Students set up 3 different Petri dishes one at a time: Cold water: ice-water from the teacher Room temperature water: from the tap Hot water: hot water from the teacher 2. As quickly as possible, add a drop of food coloring to the center of each Petri dish. Start the timer when the drop of food coloring is added. Time how long it takes for the food coloring to reach the edge of the dish for each temperature of water. 3. Observe the behavior of the food coloring, paying particular attention to any differences between the three dishes. 4. Have students draw their observations and record the times on a data sheet. Station 3: Page 5 of 5 Lesson 2 Effects of Temperature Change on Solids, Liquids and Gases 1. Make sure the flask is at room temperature. Note the placement of the balloon, and draw and describe your observations. 2. Place the flask on ice or in a refrigerator for 5 minutes. Draw and describe your observations. 3. Place the flask in the hot water bath for 5 minutes. Draw and describe your observations. Demonstration: Conservation of mass after an increase in temperature: 1. Find the mass of a container of water with ice water (with lid). Warm it to room temperature, and determine the mass again. 2. Extend: Ask students to design an experiment to demonstrate the conservation of mass when room temperature water is converted to a gas. Alternately, students can measure the mass of each phase, demonstrating conservation of mass through physical phase changes. Conclusion: 1. Refer back to the probe that you did yesterday. Which of the four models on the probe can explain the behavior of all the materials that you observed today? 2. What evidence from the activities supports your choice? 3. In what way(s) does your evidence support your choice? Potential Pitfalls Students should be taught how to use a Bunsen burner prior to performing the activity.