Elements, Compounds, and Mixtures Elements An element is a pure substance composed of a single kind of atom. An atom is the smallest particle of an element that still has all the properties of the element. Although smaller (subatomic) particles exist, once an atom is broken apart into those smaller particles, the properties of that element is lost. Gold is an element. If you slice and slice a chunk of gold until only one tiny particle is left that can’t be chopped any more without losing the properties that make gold gold, then you’ve got an atom. Atoms of an element cannot be broken apart via physical means or a chemical reaction. In other words, you cannot separate the subatomic particles (pick out the protons, neutrons, and electrons) of an atom with an ordinary chemical reaction. Only nuclear reactions, which actually involve the splitting of the atom and do not happen under ordinary circumstances, can break apart an atom. Atoms are the basic unit that form compounds. For example, when carbon reacts with oxygen to form CO2, the carbon atom does not change in any way, but only bonds the oxygen atom. For this reason, elements are considered the building block of matter. Every atom of carbon has six protons. All atoms of the same element have the same number of protons. The number of protons is also referred to as the atomic number of an element. It is the number we use to identify and classify elements, and is the organizing principle of the periodic table. Protons are subatomic particles – particles that make up an atom. They make up the nucleus of the atom (along with neutrons) and have a positive charge. The other main subatomic particles are neutrons, which also make up the nucleus and are neutral, and electrons, which orbit the nucleus and have a negative charge. Elements are represented by chemical symbols. For example, gold is represented by the symbol Au. Oxygen is represented by the symbol O. Sodium is represented by the symbol Na. 1. What is an element? 2. Define “atom”. 3. Can atoms be broken apart in a chemical reaction? What type of reaction must happen for an atom to break apart? 4. Why are atom considered the basic building block of matter? 5. Which subatomic particle is the same for every atom of an element? 6. What is another name for the number of protons in an atom? 7. How are elements represented? Compounds A compound is composed of two or more elements in a specific, fixed ratio that are held together with chemical bonds. For example, water (H2O) is a compound made up of two elements, hydrogen (H) and oxygen (O). These elements are combined in a very specific way – in a ratio of two hydrogen atoms to one oxygen atom (hence H2O). A lot of compounds contain hydrogen and oxygen, but only one has that special 2-to-1 ratio we call water. Compounds are formed during a chemical reaction, and the atoms that comprise a compound are held together with chemical bonds. The chemical bonds that hold together these atoms create a NEW substance that is completely different characteristics than the elements (atoms) that comprise it. For example, sodium is a soft, shiny metal, while chlorine is a green, poisonous gas. However, when these two elements are held together by chemical bonds, they form the compound NaCl, table salt. Because the atoms that compose compounds are held together by chemical bonds, chemists can’t easily separate the atoms of a compound. Compounds can only be broken down via a chemical reaction. Remember, elements cannot be broken down by any physical or chemical reactions. Compounds are always identified by a chemical formula. Chemical formulas tell you what types of elements make up the compound and in what ratios (or how many atoms of each element are in the compound). For example, the chemical formula for water is H2O, the chemical formula for salt is NaCl, and the chemical formula for sulfuric acid is H2SO4. The formula for sulfuric acid, H2SO4, tell you that there are two atoms of hydrogen, one atom of sulfur, and four atoms of oxygen per molecule of sulfuric acid. 1. What is a compound? 2. Do compounds retain the properties of the elements that comprise them? Why or why not? 3. How are compounds formed and broken down (i.e. what must happen for a compound to form or break apart)? 4. How do we represent compounds? 5. What information do chemical formulas convey? Mixtures Mixtures are physical combinations of pure substances (elements and/or compounds) that have no definite or constant composition (no fixed ratio) – the composition of a mixture varies according to who prepares the mixture. Suppose I ask two people to make a salad. Unless these two people used exactly the same recipe, these mixtures (salads) would vary somewhat in their relative amounts of lettuce, tomatoes, cucumbers, etc. They would have produced two slightly different mixtures. However, each component of a mixture (that is, each element and compound that makes up the mixture – in the salad example, each ingredient) retains its own set of physical and chemical characteristics because mixtures are not held together by chemical bonds but are merely physically blended. Because of this, it’s relatively easy to separate the various substances in a mixtures. Unlike compounds, which can only be separated via a chemical reaction, mixtures can be separated using physical means (i.e. chemical bonds are not broken and reformed). Mixtures can come in two different forms: Homogeneous mixtures: Sometimes called solutions, this type of mixture is relatively uniform in composition; every portion of the mixture is like every other portion. If you dissolve sugar in water and mix it really well, your mixture is basically the same no matter where you sample it. Other examples of homogeneous mixtures are air, blood, paper, and soft drinks. Heterogeneous mixtures: if you put some sugar in a jar, add some sand, and then give the jar a couple of shakes, your mixture doesn’t have the same composition throughout the jar. Because the sand is heavier, there’s probably more sand at the bottom of the jar and more sugar at the top. In this case, you have a heterogeneous mixture, a mixture whose composition varies from position to position within the sample. Other examples of heterogeneous mixtures are salads, a sandwich, and oil and water. 1. 2. 3. 4. 5. 6. What is a mixture? Do mixtures retain the original component’s properties? Why or why not? What is the fundamental difference between compounds and mixtures? What are homogeneous mixtures? What is another name for homogeneous mixtures? What are heterogeneous mixtures? Can only be separated or combined via a chemical reaction Combined and separated without breaking/forming chemical bonds New substance formed No new substance formed Can only be combined in a fixed proportion Can be combined in any proportion