Michael Auzenne Instructor GCM, CJC ARSON AND FIRE INVESTIGATION I. INTRODUCTION II. CHEMISTRY OF FIRE A. i. Oxidation Reaction: The complete or partial loss of electrons or gain of oxygen. i. Combustion Reaction: Oxidation reaction that involves oxygen and that releases heat and light. Heat of Combustion: Excess heat that is given off in a combustion reaction. Exothermic Reaction: Chemical reaction that releases heat. Combustion ii. iii. B. The Fire Tetrahedron Four ingredients are needed to start a fire and keep it burning: * Oxygen – a major gas in the air; important ingredient in any combustion reaction * Fuel – the material that is burning; the accelerant will burn first followed by other nearby sources that ignite and become fuel for the continuation of the fire. i. Accelerant: In fire investigation, any material used to start or sustain a fire; the most common are combustible liquids. * Heat – at or above the ignition temperature, the fuel will continue to burn even after the heat source has been removed. i. Ignition Temperature: The temperature at which fuel will react with oxygen, or burn. * Chain Reaction – The fire will usually release enough heat to keep the fire going and will continue to burn until all the oxygen or fuel is used or removed. C. Flash Point and Ignition Temperature i. ii. iii. D. Pyrolysis i. III. Hydrocarbon: Any compound consisting only of hydrogen and carbon. Vaporization: The process in which a liquid changes to a gas state. Flash Point: The lowest temperature at which heat may start burning to vaporize a liquid. Pyrolysis: Decomposition of organic matter by heat in the absence of oxygen. DIFFICULTIES IN ARSON DETECTION Arson is a difficult crime to prove because the crime is usually carefully planned, the arsonist has usually left the scene before anybody notices the fire, the fire often destroys evidence from the crime, and what evidence is left is often destroyed as firefighters extinguish the fire. i. ii. IV. Arson: The intentional and illegal burning of property. Arsonist: The person who intentionally starts an illegal fire that damages property. FUNCTION OF A FIRE INVESTIGATOR There are four categories of a fire: * Natural – A fire caused by acts of nature; a lightning strike or intense sunlight * Accidental – A fire that was unintentional and explainable; causes may include faulty wiring, malfunctioning appliances, or human carelessness. * Undetermined – The cause of the fire is unknown and cannot be identified. * Deliberate – A fire was intentionally set (not always arson; a campfire can spread out of control, for example.) V. DETERMINING CAUSE The point of origin, which can provide clues as to the origin of the fire, will be marked by a burn pattern. There is often a V-shaped burn near the point of origin. The V-shaped burn is usually present in cases of natural or accidental fires. However, in cases of arson, other patterns may be present. i. Alligatoring: A burn pattern resembling the scales of an alligator originating from the point of origin of a fire. ii. iii. iv. VI. Concrete Spalling: The breaking away of layers of concrete from the point of origin of a fire. Pools: Burn patterns resembling puddles that indicate an accelerant was poured. Streamers: Trails of accelerants often used to spread the fire. COLLECTING THE EVIDENCE Investigators often collect 3-4 L of ash and debris from the point of origin and anything that could have traces of accelerants. Investigators also take a debris sample that has not been contaminated by the accelerant. Each sample is packaged in its own container. Fire debris must be packaged in an airtight container; otherwise, vapor from accelerants might be lost. A. Collecting the Control i. B. Packing the Debris i. C. Headspace: A few inches of space left below the lid of an airtight container for the collection of vapors from fire debris samples. Finding the Igniter i. ii. VII. Substrate Control: A similar, but uncontaminated, sample; used for making comparisons. Molotov Cocktail: A homemade, firebomb made with a glass bottle, fuel, and a wick. Criminal Profile: A list of characteristics, such as age, gender, and motives, that help investigators narrow the list of suspects. LAB ANALYSIS i. ii. Direct Headspace Extraction Procedure: A method used to analyze accelerant residue from collected debris to determine exactly what accelerant was used to start a fire. Passive Headspace Extraction Procedure: A method used to analyze low concentrations of an accelerant residue from collected debris that might have been missed during the direct headspace extraction procedure. VIII. PSYCHOLOGY OF AN ARSONIST The characteristics of an arsonist include: * Less than 25 years old * Father not in the home * Domineering mother * Academically challenged * Emotionally and/or psychologically disabled * Unmarried, possibly still living at home with parents * Feelings of inadequacy and insecurity * Fascination with fire * Alcoholism * Parental neglect or abuse IX. MOTIVES FOR ARSON A. Financial Gain B. Revenge i. C. Excitement D. Vanity E. Crime Concealment F. Spite Arson: A fire started to destroy an organization or a person for the sake of a cause. i. Crime Concealment: A motive for arson sometimes used to destroy evidence of another crime. i. Vandalism: A motive for arson often used by starting fires in schools, trash cans, dumpsters, wooded areas, and abandoned buildings. Vandalism