Transfer of metal(loid)s in a small vineyard catchment: contribution of dissolved and particulate fractions
in river for contrasted hydrological conditions
M. Rabiet*, M. Coquery, N. Carluer, J. Gahou, V. Gouy
Irstea, UR MALY, 5 rue de la Doua, CS70077, 69626 Villeurbanne Cedex, France
Online Resource 10: Cu, Zn and As specific fluxes to the sea (kg/km²/yr) of some large French rivers.
River
Size
watershed
(Km²)
Specific fluxes Cu (Kg/km²/yr)
Reference
Dissolved Fraction
Base flow*
Flood**
Morcille
8
0.51
0.007-0.012
0.3
Eygoutier
25
Herault
Tet
Aude
Orb
2820
1400
4830
1400
Rhone
99,000
Tet
1400
River
Size
watershed
(Km²)
Morcille
8
Eygoutier
25
Herault
Tet
Aude
Orb
2820
1400
4830
1400
Rhone
99,000
Tet
1400
0.0028 0.0109
Particulate Fraction
Base flow*
Flood**
0.0170.21
0.05
3.5
0.0360.14
3.6
3.9
2.9
2.2
3.3
0.94 (2003)-1.20 (2002)
Flood***
0.11 (2003) – 0.298 (2002)
This study
Nicolau et al. 2012
Radakovitch et al. 2008
2.38 (2001)-4.28(2002)
Flood ***
1.33 (2003)-3.5 (2002)
1.42
1.385
Ollivier et al. 2011
Dumas et al. 2015
Specific fluxes Zn (Kg/km²/yr)
Reference
Dissolved Fraction
Particulate Fraction
Base flow*
Flood**
Base flow*
Flood**
0.00050.0130.04
0.28
0.0008
0.036
1.7
16
0.02-0.06
0.14-0.64
9.6
8.3
4.2
7.9
13.1
1.04 (2003)-1.81(2002)
8.5 (2001)-17.6 (2002)
6.19
3.708
This study
Nicolau et al. 2012
Radakovitch et al. 2008
Ollivier et al. 2011
Dumas et al. 2015
River
Size
watershed
(Km²)
Specific fluxes As (Kg/km²/yr)
Reference
Dissolved Fraction
Base flow*
Flood **
Morcille
8
Garonne
Dordogne
Isle
Humber
51500
15000
6600
Rhone
99,000
0.77
0.008
0.37-1.24
0.49-0.77
0.45-0.75
0.88
0.71 (2003)– 1.08 (2002)
Flood***
0.09 (2003) – 0.37 (2002)
Particulate Fraction
Base flow*
Flood **
0.0090.15
0.024
0.60
0.69
0.33
0.22
This study
Masson et al. 2007
Neal and Davies 2003
Ollivier et al. 2011
* calculated on a 6-month period
** for one event
*** for one year
References :
Dumas C, Ludwig W, Aubert D, Eyrolle F, Raimbault P, Gueneugues A, Sotin C (2015) Riverine
transfer of anthropogenic and natural trace metals to the Gulf of Lions (NW Mediterranean
Sea). Appl Geochem 25:14–25. doi: 10.1016/j.apgeochem.2015.02.017
Masson M, Schäfer J, Blanc G, Anschutz P (2007) Seasonal variations and annual fluxes of
arsenic in the Garonne, Dordogne and Isle Rivers, France. Sci Total Environ 373:196–207.
doi:10.1016/j.scitotenv.2006.10.039
Neal C, Davies H (2003) Water quality fluxes for eastern UK rivers entering the North Sea: a
summary of information from the Land Ocean Interaction Study (LOIS). Sci Total Environ 314316:821–882. doi: 10.1016/S0048-9697(03)00086-X
Nicolau R, Lucas Y, Merdy P, Raynaud M (2012) Base flow and stormwater net fluxes of carbon
and trace metals to the Mediterranean Sea by an urbanized small river. Water Res 46(20):6625–
6637. doi: 10.1016/j.watres.2012.01.031
Ollivier P, Radakovitch O, Hamelin B (2011) Major and trace element partition and fluxes i n the
Rhône River. Chem Geol 285(1–4):15–31. doi: 10.1016/j.chemgeo.2011.02.011
Radakovitch O, Roussiez V, Ollivier P, Ludwig W, Grenz C, Probst J-L (2008) Input of particulate
heavy metals from rivers and associated sedimentary deposits on the Gulf of Li on continental
shelf. Estuar Coast Shelf Sci 77:285–295. doi: 10.1016/j.ecss.2007.09.028