01/10/2014 User instruction for handling of gases and gas cylinders Background A risk assessment must be carried out for all operations where gas is handled. The requirement for this can be found in Chapter 3, Section 2a of the Work Environment Act, where the employer is obliged to regularly examine risks involved in activities and undertake action as a consequence of this. Regulations on risk assessment can be found in the Swedish Work Environment Authority's regulations on Systematic work environment management (AFS 2001:01) and Chemical work environment risks (AFS 2011:19). As regards regulations concerning gases and gas cylinders in laboratories, these rules can be found in the Swedish Work Environment Authority's regulations Gases (AFS 1997:7) and Gas cylinders (AFS 2001:04). All National Board of Occupational Safety and Health regulations are available online at www.av.se Risk assessment A form with instructions which can be found on the university's intranet is best used for carrying out a risk assessment. To be able to carry out a risk assessment, it is necessary first to identify the risk sources present. These may include hazardous substances or substances which are hazardous to health, electrical devices, pressure-bearing devices, staff hired temporarily or a lack of necessary training. It is important to assess the likelihood of the risk source being handled or working in an unwanted manner, and to try to estimate the potential consequences of a fault. Finally, an evaluation is carried out which establishes whether the risks are acceptable or whether preventive measures must be put in place, see e.g. Gases AFS 1997:7. Gases There are currently 8 gases distributed to the outlet points via central pipe systems. These are hydrogen, LPG, helium, nitrogen, argon, carbon dioxide, oxygen and compressed air. There are monitoring systems for hydrogen, LPG, helium, nitrogen, carbon dioxide, oxygen and argon which record gas consumption and monitor the consumption of hydrogen and LPG to ensure that these do not exceed the maximum permitted instantaneous flows. If this happens, or if the power to the building is cut, the distribution of hydrogen and LPG is shut off automatically. The distribution of hydrogen and LPG cannot then be resumed until staff at the chemicals store have restarted the monitoring system centrally once the cause of the problem has been located and rectified. Local key switches must then be activated in order to open the gas distribution to each individual lab. The Chemistry Building also has supplementary interlock which shuts off the distribution of hydrogen and LPG if the central ventilation fan stops. Restarting takes place in the manner described above. Besides the gases distributed centrally, there may be a requirement for other gases in order to meet special requirements. These gases must then be provided by placing a gas cylinder at or next to the point where it is required. Due to the risks involved with gas cylinders during transportation and in the event of a fire, it is extremely important to ensure that only a small number of gas cylinders is kept within the building, and that these cylinders are as small as possible. The user is responsible for acquiring product information which contains details about physical, chemical and biological data for the gas, information on the risk of fire or explosion, special properties and risks, and general instructions and material recommendations. 01/10/2014 This product information must be readily accessible and near to the gas cylinder. Information must also be provided there on the gas store in which the gas cylinder is to be stored when it is not in use. The user is responsible for the handling of the gas in question, and for ensuring that a risk assessment is carried out and documented before using the gas. Equipment For all the equipment connected together with outlet points for gas or gas cylinders, the material used must comply with the gas supplier's own material recommendations. This is particularly important to check for any part of the equipment that may be exposed to mixtures of different gases, or mixtures of gases and the ambient atmosphere. Equipment that may be subject to overpressure must be designed, installed and tested in accordance with this. If the equipment includes safety valves to protect against impermissibly high overpressure, and the gas used has particular risks or properties, it is necessary to check that the outlet line for the safety valves opens up in a location which is acceptable from a safety standpoint. If gases with different pressures are mixed in any equipment, it is necessary to protect outlet points and/or gas cylinders from overflow by fitting non-return valves in the supply lines. It is important for the equipment used to be sealed, as a leak to the atmosphere may present a risk factor and also results in an initially high-quality gas rapidly being impaired on account of atmospheric influence. Equipment which is not clean does of course also have an adverse impact on gases. Safety There must be a safe zone around outlet points for flammable gases with regard to electrical equipment not protected against explosive environments. How large this zone is is described in the general classification plans on the university's intranet in the document "Information documentation, handling of flammable products". Safety zones around outlet points for LPG and hydrogen from the central gas network are described in the general classification plans available on the university's intranet. Therefore, it is important to check whether the safety zone is sufficient before you start using new flammable gases, and that you bear in mind the fact that the safety zone starts from the nozzle of a gas outlet or safety valve. Gas cylinders must be clearly signed and secured so that there is no risk of them tipping over or being damaged by transport trolleys and suchlike. Here, it is important to bear in mind that in most instances gas cylinders are much heavier than tables, for example, so simply attaching them to a table leg is not sufficient. Instead, they must be secured to walls or other permanently mounted fittings. Gas cylinders must always be stored in a designated gas store when not in use. If there is no gas store next to the laboratory, cylinders are handed to the Chemicals Store. Always contact the Chemicals Store in the case of longer interruptions in the use of gas. It is very important to store gas cylinders in the designated store as gas cylinders heated in the event of a fire incident present such a major risk of explosion as to significantly impede the efforts of the emergency services. See also "Checklist for gas cylinders" available on the university's intranet.