Name_________________________________________Date_________________Class______________Score_____ Active Chemistry 2.1 – Chemtalk Introduction In this investigation you used electricity to decompose water into two gases. You learned that the gases were different because they reacted differently to the burning and glowing splints. Since water is referred to as H2O, a first guess would be that hydrogen (H) and oxygen (O) were produced in the experiment. The test for hydrogen is a small explosion when exposed to a burning splint. The test for oxygen is the re-ignition of a glowing splint. If you look back on the results of the experiment, you find that the volume of the hydrogen gas was twice as much as the oxygen gas. There was twice as much hydrogen as oxygen; that’s where the “2” comes from in the molecular formula H2O. _________________________________________ Hydrogen and oxygen are elements. An element is any material that cannot be broken down into simpler materials by chemical means. You are probably familiar with many elements like hydrogen, oxygen, zinc, gold, or helium. Other elements like strontium and beryllium are more exotic and less likely to be familiar to you. Every kind of matter you observe in your everyday life is made up of the chemical elements. There are only a little more than a hundred different kinds of chemical elements. This is an amazing discovery of chemistry – everything you observe in the world is made of different combinations of only one hundred elements. Chemistry is the study of the properties of these elements, how these elements combine, the new properties of these combinations, and the energy changes that result from these combinations. _________________________________________ Elements are represented by symbols. The periodic table shows that the symbol used for each element is one or two letters to represent the name. It’s easier to write O than to write oxygen. It’s easier to write H than to write hydrogen. The symbols come from many different sources. However, the same symbols are used for each element in all the countries in the world. _________________________________________ When different elements combine, they form new substances called compounds. These compounds have entirely new characteristics unlike the characteristics of the elements that make them. It is like combining the letters of the alphabet to make words – twenty-six letters can be combined to make thousands of different words. Water is an example of a compound. A water molecule, H2O, is composed of two atoms of hydrogen and one atom of oxygen. In this activity, you used electricity to decompose molecules of water into the elements hydrogen and oxygen. This process is called electrolysis. You observed that oxygen gas made a glowing splint burst into flame, and that hydrogen gas was explosive. However, to extinguish a burning splint, you could use liquid water. The compound has very different characteristics from the elements from which it is made. Compounds are represented by chemical formulas. A chemical formula shows the symbols of the elements that are combined to make the compound. For example, as you discovered in this activity, the chemical formula for water is H2O, because water molecules are a combination of hydrogen and oxygen atoms. If there is more than one atom of an element in a molecule, a subscript is added after the symbol indicating how many atoms of that element there are. Two hydrogen atoms combine with one oxygen atom to produce one molecule of water, which is why there is a little 2 under the H in H2O. You could call H2O dihydrogen monoxide but you use the common name water. In chemistry, there are common names for some familiar chemical compounds. Examples of Some Chemical Formulas Compound Common Name Chemical Formula Calcium carbonate Carbon dioxide Hydrochloric acid Sodium hydrogen carbonate Chalk Dry ice Muriatic acid Baking soda CaCO3 CO2 HCl NaHCO3 Sodium chloride Sulfuric acid Table salt Battery acid NaCl H2SO4 From the table of chemical formulas, you can see that carbon dioxide (CO2) is a compound of carbon and oxygen. There are 2 atoms of oxygen for every 1 atom of carbon. Sodium hydrogen carbonate (NaHCO3) is a compound of sodium, hydrogen, carbon, and oxygen. There are three atoms of oxygen for every atom of the other elements. Also, there are a total of three atoms in the carbon dioxide formula and a total of six atoms sodium hydrogen carbonate. Also, notice that the gases are written in the elements’ diatomic form. Conservation of mass and elements states that the number of hydrogen atoms must be equal before and after the reaction. In addition, the number of oxygen atoms must be equal before and after the reaction. In the previous equation, you have one oxygen atom before the reaction and two oxygen atoms after the equation. You can fix this problem by “balancing the equation”. 2H2O(l) + energy 2H2(g) + O2(g) You now have 2 water molecules before the reaction (4 hydrogen atoms and 2 oxygen atoms). You also have 4 hydrogen atoms and 2 oxygen atoms after the reaction. You balanced the equation because you know that mass and elements must be conserved. By balancing the equation, you found that in electrolysis 2 water molecules decompose into 2 molecules of hydrogen gas and 1 molecule of oxygen gas. This is why you saw that there was twice as much hydrogen gas as oxygen gas in the two test tubes (hydrogen in one tube, oxygen in the other). _________________________________________ _________________________________________ Many elements appear as single atoms in nature. There are seven common elements that exist in diatomic (two atoms) form. They are: Hydrogen (H2), Oxygen (O2), Nitrogen (N2), Fluorine (F2), Chlorine (Cl2), Bromine (B2), and Iodine (I2). To generate the gas to fill the empty eggshell in this activity (the demonstration), zinc was placed in hydrochloric acid. Zinc is an element. Hydrochloric acid (HCl) is a compound of hydrogen and chlorine. The reaction of zinc and hydrochloric acid created a gas. Given the explosion you observed, you can guess that the gas that was produced was hydrogen. The hydrogen gas came from the hydrogen in the hydrochloric acid. You can write this reaction as an equation: For example, hydrogen may be found as a single atom in a compound like HCl and oxygen may be found as a single atom in H2O. When hydrogen is not combined with any other element, it always appears as H2, two hydrogen atoms combined together. _________________________________________ You can write an equation that summarizes the electrolysis of water: H2O(l) + energy H2(g) + O2(g) Notice that the letters “g” and “l” are used. The “g” means gaseous state and the “l” means liquid state. HCl (aq) + Zn (s) ZnCl2 (aq) + H2 (g) The sub letter “s” means that the substance is in the solid state. The sub letters “aq” stands for aqueous, meaning that the substance (HCl) is dissolved in water. The zinc combined with the chlorine and hydrogen was released. Once again, conservation of mass and elements requires you to balance the equation: 2HCl (aq) + Zn (s) ZnCl2 (aq) + H2 (g)