Element Groups and Why They Bond Notes Luster Malleable Alkali Metals Alkaline Earth Metals Transition Elements Lanthanides Actinides Name:__________________ Period: ___ Page 1 of 6 Metalloids Noble Gases Valence Electrons Ionic Bonds Covalent Bonds Formula Unit Subscript Superscript Chemical Formulas Polyatomic Ions Oxidation Numbers Polar Molecule Non-polar molecule Metals: major part of the group Most elements are metals. 88 elements found to the LEFT of the Zigzag Line Physical Properties Of Metals Luster (shininess) Good conductors of heat and electricity High density (heavy for their size) High melting point Ductile (drawn out into thin wires) Malleable (hammered into thin sheets) Chemical Properties of Metals Easily lose electrons (become positive ions CATIONS) Corrode easily React easily with other elements ALKALI METALS – GROUP 1, 1A & IA Soft metals – they can be cut with a knife Most reactive of all the metals - React rapidly with oxygen and water Do not occur in nature in their elemental form Stored under oil Will form a +1 ion by giving away their one valence electron Alkaline Earth Metals Group 2 2A & IIA Do not occur in nature in their elemental form Will form a +2 ion by giving away their two valence electrons Uses Fireworks Ca – Bones & Teeth Ba - X-Rays Transition Elements Group 3-12 These elements are most familiar to the public because they are found in nature in their elemental form Element Groups and Why They Bond Notes Name:__________________ Period: ___ Page 2 of 6 Often form colored compounds Chromium precious gems (emeralds and rubies) Cadmium yellow Cobalt blue INNER Transition Metals: Lanthanides and Actinides Lanthanides Elements 58 – 71 Elements used in motion pictures industry Produce colors you see on the TV Actinides Elements 90 – 103 All actinides are radioactive and unstable Thorium and Uranium are found in the earth’s crust Uranium – nuclear reactors NONMETALS Found to the RIGHT of the zigzag line Hydrogen is considered a nonmetal Group 18 – Noble Gasses are the only group that consists of all nonmetals Group 17 - Halogens Properties Nonmetals gain electrons to become stable – anions Most are gasses at room temp Not malleable Not ductile Poor conductors of heat and electricity No Luster – Dull Important nonmetals in Humans Carbon Hydrogen Nitrogen & Oxygen Metalloids & Synthetic Elements Metalloids conduct electricity better than nonmetals, but not as well as metals. Synthetic elements do not occur naturally (they are man-made) All elements with an atomic number higher than uranium (92) were made by scientists and most are radioactive. Electron Dot Diagrams of Selected Elements Electron Dot uses the symbol of the element and dots to illustrate the number of electrons in the outermost energy level Elements of the same group (column) have the same number of valence electrons The Story of Bending the Rules Normal atom= # Protons= # electrons Element Groups and Why They Bond Notes Name:__________________ Period: ___ Page 3 of 6 Then it’s a neutral atom *Remember that all atoms want to have orbital shells be full Full shells= 1st orbital: 2 electrons 2nd orbital: 8 electrons Trying to Get Full Example: Sodium (Na) has 11 electrons (Draw lewis dot diagram here) Wants to get rid of 1 valence electron to be full Chlorine has 7 valence electrons (Draw lewis dot diagram here) Not Your Normal Atom Na now has 10 electrons So does Ne But not normal Na atom Now Na is Na+ An ion Now orbitals are full and atom is electrically charged AND ATTRACTIVE to other elements like Cl Ions atom or molecule with missing or extra electrons Ions are charged particles (positive or negative) charge = #protons - #electrons charge given as a trailing superscript positive ions are cations X+ negative ions are anions X– Metals= + cations Non metals= - anions Chemical Bonds Bonding isn’t just for people. Why do atoms form compounds? TO BECOME STABLE!! What does stable mean to an atom? Full set of valence electrons Atoms want to have the electron configuration of a noble gas Atoms will gain, lose or share electrons in order to obtain a full set of valence electrons Combining Elements Element Groups and Why They Bond Notes Name:__________________ Period: ___ Page 4 of 6 The chemical & physical properties of the elements are different than the properties of the compound they make up Na + Cl2 → NaCl Reaction of Sodium with Chlorine & Hydrogen with Oxygen Types of Bonds Ionic Bonds Contain a metal & a nonmetal (at least 1 of each) Electrons are gained or lost Ex. Salt, NaCl Covalent Bonds Contain 2 or more nonmetals or hydrogen Electrons are shared Ex. Water, H2O Ionic Bonding In an ionic bond, one atoms gives electrons to another atom. When atoms combine this way, it is called a formula unit. Ex. NaCl is a formula unit The charge of a formula unit is always 0. The positive and negative charges must always balance each other. Formulas Chemical Formula—tells what elements a compound contains and the exact number of the atoms of each element. Ex. NaCl has 1 atom of sodium & 1 atom of chlorine Ex. H2O has 2 atoms of hydrogen and 1 atom of oxygen. A subscript (small # written below) is written after a symbol to tell how many atoms of that element are in the compound. Rules for Formulas Write the cation (metal) first. Write the anion (nonmetal) second. The net ionic charge is zero. Use subscripts to indicate multiple ions. Write the formula unit in the lowest whole number ratio. A trick for formula units Write both ions with their charges as superscripts. Cu3+ & O2 Crisscross the charges to make the subscripts in the formula Do not put + or – in the formula Cu3+ & O2Cu2O3 Silver Chloride Zinc Phosphide Aluminum Oxide Element Groups and Why They Bond Notes Name:__________________ Period: ___ Page 5 of 6 IONIC BONDS between metals & nonmetals Electrons form a give take relationship metals give e- (cation) nonmetal take e- (anion) Held together by attraction of opposite charges Polyatomic Ions Polyatomic Ions=molecule with more then one element that has a charge The prefix poly- means many in Greek. Ion consisting of a molecule with many covalently bonded atoms Act as a single unit Polyatomic ions is also referred as a radical ion Name ends in –ate & -ite -ide usually indicates binary Multiple Oxidation Numbers Some metals (other metals & transition metals) can have more than 1 oxidation number. If an element can have more than 1 oxidation number, the charge of the ion is written as a roman numeral in parentheses. Ex. Copper (I) ion is Cu1+ Copper (II) ion is Cu2+ Mistakes to Avoid Roman numerals are not written in the formula Charges are not written in the formula Don’t drop polyatomic subscripts Hydroxide, OH, needs parentheses to indicate multiples. Cu(II)O CuO +1 -1 K Br KBr CaNO2 Ca(NO3)2 CaOH2 Ca(OH)2 Rules for Naming Binary Ionic Compounds with Group A Elements Write the cation name 1st Cation name is the same as the element name Write the anion name 2nd Change the ending of the element name to –ide. Covalent Bonds Covalent bonds share electrons Composed of 2 or more nonmetals (and H) Element Groups and Why They Bond Notes Name:__________________ Period: ___ Page 6 of 6 Covalent compounds are called molecules Molecules can be polar or nonpolar Polar molecule—slightly positive and negative at parts—but overall neutral e- are unevenly shared Nonpolar molecule—electrons are shared equally—completely neutral Naming Covalent Compounds Use prefixes to tell how many of each element you have. This is done because you can have different covalent compounds containing the same elements. Change the ending of the 2nd element to -ide Ex. N2O is dinitrogen monoxide. You can leave off the prefix mono- on the first element. Ex. NO2 is nitrogen dioxide Not mononitrogen dioxide Formulas for Covalent Compounds Use the prefixes as the subscript in the formula. Ex. Phosphorus Trichloride PCl3 Dinitrogen Tetrafluoride N 2F 4