resumen_Javier Felipe PLata

advertisement
FUEL ALCOHOL DEHYDRATION USING A SUSTAINABLE CHEMICAL PROCESS
THROUGH A POROUS MATERIAL OF IONIC LIQUID ANCHORED TO A MATRIX OF
SILICON DIOXIDE
Javier Plata / Universidad Industrial de Santander, Cr 25 Cll 9, Bucaramanga
Luz Carreño / Universidad Industrial de Santander, Cr 25 Cll 9, Bucaramanga
ABSTRACT
Functionalization of porous materials with different molecular structures allows the
probability of anchoring several functional groups for several industrial applications involving
catalytic processes. The heterogenization of catalyst offers advantages in handling,
separation and reuse processes; recently, have been designed immobilisation processes
with Ionic Liquids, allowing the possibility to extraction processes.
Ionic liquids, ILs, present such chemical versatility and environmental advantages that make
them a novel alternative in separation processes. In this work ionic liquid 1-ethyl-(3methoxysilyl) propylimidazolium chloride anchored to a matrix of silicon dioxide, were
implemented as extracting agents for obtaning anhydrous bioethanol from sugar-cane.
KEYWORDS Ionic liquids | Bioethanol | Porous Material
REFERENCES
[1] Liu, X. (2008). Rapid synthesis of highly ordered Si-MCM-41. J. Coll. Int. Sci., 319, 377.
[2] Chrobok, A. (2009). Supported hydrogensulfate ionic liquid catalysis in Baeyer?Villiger
reaction. App. Cat. A., 366, 22.
[3] Peña, D. J. (2009). Producción de Sílice Mesoporosa Empleando Monoestearato de
Glicerol como Porógeno Oleoquímico. Información Tecnológica., 20, 67.
[4] Bian, W. (2012). Room temperature ionic liquid (RTIL)-decorated mesoporous silica
SBA-15 for papain immobilization: RTIL increased the amount and activity of immobilized
enzyme. Materials Science and Engineering C., 32, 368.
[5] Pietchmann, B. (2008). Immobilization of ionic liquids within micro- and mesoporous
materials. 4th International FEZA Conference. Elsevier. 325.
[6] Zhang, X. (2009). Grafted ionic liquid: Catalyst for solventless cycloaddition of carbon
dioxide and propylene oxide. Catalysis Communications 11, 43.
Download