CHE_HSD0633 Pre Purchasing Request-Checklist for Hazardous Materials Reference HS316: Purchasing Guidelines Faculty/Division: ENGINEERING Document number CHE_HSD0633 School/Unit: CHEMICAL ENGINEERING Initial Issue date 11/02/2015 Current version 3 Current Version issue date 17/06/2015 Next review date 17/06/2018 This form should be used to assess the risks of introducing new hazardous materials into the workplace. The completed form is to be emailed from supervisor to purchaser. Proposed Materials/Chemicals/Gases to be purchased: Description and quantity Supplier Catalogue/ part no. Pre-purchase Health and Safety Checks completed * 1 ☐ 2 ☐ 3 ☐ 4 ☐ 5 ☐ 6 ☐ 7 ☐ 8 ☐ Storage location other comments/indicative price(if required) Part 2: Checklist Pre-purchase Health and Safety requirements PRE PURCHASE HEALTH AND SAFETY CHECKS. Have you investigated whether safer alternatives to this chemical are available? Has a Safety Data Sheet been obtained and has the safety information been read and understood? Is the chemical already listed on SciQuest? [If not, who will add?] Is the chemical a radioactive isotope? If yes, contact the Radiation Safety Supervisor Has risk management already been completed for the task or process in which this chemical will be used? If no, the risk management form must be reviewed and revised as applicable to take account of new or modified risks. Could this chemical become unstable during storage and thus require monitoring to ensure environmental conditions are met (e.g. stored under water, stored under hydrocarbon, stored at certain temperature, stabilizers added etc)? If yes, is a system in place to monitor such conditions and dispose of the chemical by its expiry date? Does this chemical require storage in a separate segregated storage area and if yes, is one available? Is a safe method available to transport the chemical from the store (or goods received area) e.g. carrying basket, bunded trolley, gas trolley, goods lift etc. Is the substance a Prohibited or Restricted carcinogen? Check Schedule 10 of the WHS Regulation. If yes approval must be obtained from WorkCover. Are any engineering controls needed and if so are they in place (e.g. fume cupboard, biosafety cabinet, cytotoxic hood, toxic substance weighing chamber)? Is Health Surveillance required for this chemical? Refer to HS091 Air Monitoring and Health Surveillance guideline. Is the chemical a Schedule 4 or Schedule 8 Drug? Some S4s and all S8s require additional requirements. Refer to HS331 S4 and S8 Drugs procedure. Is the chemical listed a Precursor chemical of security concern? If yes, extra vigilance in terms of the use and storage of the chemical is required. Refer to the Australian Government Chemicals of Security Concern website. Is an End User Declaration required e.g. drug precursors, chemicals of security concern? Is an AQIS permit required? See Biosafety webpage. If this is a genetically modified organism (GMO) has approval been obtained from the UNSW IBC? Has the necessary PPE being obtained for use of the substance, workers trained in its use and a safe storage facility provided for such PPE? Name of Requestor Date Supervisor Date *By submitting this purchase request, I acknowledge that I have read and completed the relevant Pre Purchase Health and Safety Checks Office use only Purchaser Sciquest requisition no./Purchase order no. Purchase date document1 Work Health and Safety Regulation 2011 Current version for 24 June 2014 to date (accessed 26 November 2014 at 14:17) Schedule 10 Prohibited carcinogens and restricted carcinogens (Clauses 340 and 380–384) Note. The prohibition of the use of carcinogens listed in table 10.1, column 2 and the restriction of the use of carcinogens listed in table 10.2, column 2 apply to the pure substance and where the substance is present in a mixture at a concentration greater than 0.1%, unless otherwise specified. Table 10.1 Prohibited carcinogens Column 1 Item Column 2 Prohibited carcinogen [CAS number] 1 2 3 4 5 6 7 8 9 2-Acetylaminofluorene [53-96-3] Aflatoxins 4-Aminodiphenyl [92-67-1] Benzidine [92-87-5] and its salts (including benzidine dihydrochloride [531-85-1]) bis(Chloromethyl) ether [542-88-1] Chloromethyl methyl ether [107-30-2] (technical grade which contains bis(chloromethyl) ether) 4-Dimethylaminoazobenzene [60-11-7] (Dimethyl Yellow) 2-Naphthylamine [91-59-8] and its salts 4-Nitrodiphenyl [92-93-3] Table 10.2 Restricted carcinogens Column 1 Column 2 Item Restricted carcinogen [CAS Number] Column 3 Restricted use 1 2 Acrylonitrile [107-13-1] Benzene [71-43-2] 3 Cyclophosphamide [50-18-0] 4 5 6 7 3,3’-Dichlorobenzidine [91-94-1] and its salts (including 3,3’Dichlorobenzidine dihydrochloride [612-83-9]) Diethyl sulfate [64-67-5] Dimethyl sulfate [77-78-1] Ethylene dibromide [106-93-4] All All uses involving benzene as a feedstock containing more than 50% of benzene by volume Genuine research or analysis When used in preparation for therapeutic use in hospitals and oncological treatment facilities, and in manufacturing operations Genuine research or analysis All 8 9 10 11 7 4,4’-Methylene bis(2-chloroaniline) [101-14-4] MOCA 3-Propiolactone [57-57-8] (Beta-propiolactone) o-Toluidine [95-53-4] and o-Toluidine hydrochloride [636-21-5] Vinyl chloride monomer [75-01-4] Ethylene dibromide [106-93-4] 8 9 10 11 4,4’-Methylene bis(2-chloroaniline) [101-14-4] MOCA 3-Propiolactone [57-57-8] (Beta-propiolactone) o-Toluidine [95-53-4] and o-Toluidine hydrochloride [636-21-5] Vinyl chloride monomer [75-01-4] document1 All All When used as a fumigant Genuine research or analysis All All All All When used as a fumigant Genuine research or analysis All All All All