Name: Date: Period: Chemistry B UNIT 9-11 EXAM STUDY GUIDE STANDARDS ADDRESSED UNIT 9: REACTION RATES & EQUILIBRIUM 8a Students know the rate of reaction is the decrease in concentration of reactants or the increase in concentration of products with time. 8b Students know how reaction rates depend on such factors as concentration, temperature, and pressure. 8c Students know the role a catalyst plays in increasing the reaction rate. 9a Students know how to use Le Châtelier’s principle to predict the effect of changes in concentration, temperature, and pressure. 9b Students know equilibrium is established when forward and reverse reaction rates are equal. UNIT 10: BIOCHEMISTRY 10a Students know large molecules (polymers), such as proteins, nucleic acids, and starch, are formed by repetitive combinations of simple subunits. 10b Students know the bonding characteristics of carbon that result in the formation of a large variety of structures ranging from simple hydrocarbons to complex polymers and biological molecules. 10c Students know that amino acids are the building blocks of proteins. UNIT 11: NUCLEAR CHEMISTRY 11a Students know protons and neutrons in the nucleus are held together by nuclear forces that overcome the electromagnetic repulsion between the protons. 11c Students know some naturally occurring isotopes of elements are radioactive, as are isotopes formed in nuclear reactions. 11d Students know the three most common forms of radioactive decay (alpha, beta, and gamma) and know how the nucleus changes in each type of decay. 11e Students know alpha, beta, and gamma radiation produce different amounts and kinds of damage in matter and have different penetrations. UNIT 9: REACTION RATES & EQUILIBRIUM KEY VOCAB Reaction rate Collision theory Reaction coordinate Catalyst Activation energy Equilibrium Le Chatelier’s Principle Name: Date: Period: Chemistry B KEY POINTS Reaction rate is defined as: o the decrease in concentration of reactants over time o the increase in concentration of products over time Reactions occur when molecules collide (collision theory) A reaction coordinate graphs the energy associated with a reaction Activation energy is the amount of energy required for a reaction to go to completion A catalyst speeds up the reaction rate by lowering the activation energy: Equilibrium is established when the rate of forward reaction equals the rate of reverse reaction The concentration of reactants and products do not change during equilibrium Equilibrium is dynamic (reactions keep on going & do not stop) Le Chatelier’s Principle: if a system is at equilibrium is disturbed by a change in concentration, temperature, or pressure, the system will shift to counter this change. o Concentration the equilibrium shifts away from the side you add to and towards the side you remove from o Temperature if you increase temperature, the equilibrium shifts away from the side with heat if you decrease temperature, the equilibrium shifts towards the side with heat o Pressure If you increase the pressure, the equilibrium shifts towards the side with fewer molecules Name: Date: Period: Chemistry B If you decrease the pressure, the equilibrium shifts towards the side with more molecules PRACTICE PROBLEMS 1. As you increase temperature, the rate of reaction _______________________. 2. As you decrease concentration of reactants, the rate of reaction _______________________. 3. As you increase pressure, the rate of reaction ___________________________. 4. Draw a picture explaining what collision theory is and how it determines reaction rate. 5. Draw a reaction coordinate below and label: reactants, products, and activation energy 6. What is a catalyst? How does it affect the activation energy? Draw the effect of a catalyst on the reaction coordinate above using a dotted or dashed line. Name: Date: Period: Chemistry B 7. Use the following reaction for the next 5 questions. You can answer shift left, shift right, or no effect. UO2(s) + 4HF(g) + Energy ⇌ UF (g) + H O(g) 4 2 a. If I increase the temperature, then the reaction will _________________________ b. If the pressure is increased, then the reaction will __________________________ c. If more HF is added to the system, then the reaction will ____________________ d. If UF4 is removed, then the reaction will _________________________________ e. If H2O is added, then the reaction will ___________________________________ UNIT 10: BIOCHEMISTRY KEY VOCAB Polymer Protein Nucleic acid Starch Monomer/Subunit Amino acid Nucleotide Glucose KEY POINTS A polymer is a chemical compound consisting of repeating units called monomers (or subunits) Proteins are polymers made out of monomers called amino acids Nucleic acids are polymers made out of monomers called nucleotides Starch is a polymer made out of monomers called glucose The element carbon likes to bond with a lot of atoms because it has 4 valence electrons Carbon can make single, double, & triple bonds Most organic life is made out of carbon-containing compounds Name: Date: Period: Chemistry B PRACTICE PROBLEMS 1. Which of the above are subunits of protein? _________ 2. Which of the above are monomers of starch? __________ 3. Which of the above are subunits of nucleic acids? __________ 4. Which of the above is a hydrocarbon? __________ UNIT 11: NUCLEAR CHEMISTRY KEY VOCAB Force Gravity Electromagnetic Strong nuclear force Weak nuclear force Nuclear fusion E=mc2 Isotope Average atomic mass Radioactive decay Alpha decay Beta decay Name: Date: Period: Chemistry B Nuclear fission Gamma decay KEY POINTS A force is a push or a pull Gravity is the pull or attraction between any two objects based on their mass Electromagnetic force is the attraction between opposite charges or the repulsion between like charges The strong nuclear force holds the nucleus of an atom together o It is stronger than the electromagnetic repulsion between the protons that wants to pull the nucleus apart The weak nuclear force that makes certain elements radioactive Nuclear fusion is when two atomic nuclei combine to form one new atom Nuclear fission is when a heavy nucleus splits into smaller, more stable nuclei Einstein’s equation E=mc2 describes how a small loss in mass (m) of a nucleus is converted into large amounts of energy (E) Isotopes are atoms of the same element with different number of neutrons o Isotopes therefore have different atomic masses Radioactive decay is the spontaneous breakdown of a nucleus into a smaller nucleus and radiation The 3 forms of radioactive decay are alpha (α), beta (β), & gamma (γ) decay Alpha (α) decay releases an alpha particle (42He) as radiation o Travels a few centimeters through the air o Blocked by paper Beta (β) decay converts a neutron into a proton and an electron (beta particle). The beta particle/electron is released as radiation o Travels a few meters through the air o Blocked by metal wall Name: Date: Period: Chemistry B Gamma (γ) decay occurs when a nucleus goes from high energy to low energy and releases gamma rays o most dangerous, can cause mutations in DNA and cancer o blocked by thick walls of lead or concrete \ PRACTICE QUESTIONS 1. Rank the 4 fundamental forces from strongest to weakest. 2. Compare and contrast the strong nuclear and electromagnetic forces. Discuss why the strong nuclear force prevents the nucleus of the atom from splitting apart. 3. You have a 10 kg substance. How much energy would be produced if this mass was converted to energy? (c = 3.0 x 108) Name: Date: Period: Chemistry B 4. You produce 250,000 J of energy when you convert some mass into energy. How much mass did you begin with? (c = 3.0 x 108) 5. Three isotopes of silicon occur in nature, 92.23% is 28Si, 4.68% is 29Si, and 3.09% is 30Si. Calculate the average atomic mass of silicon. 6. Determine whether the following equations are alpha, beta, or gamma decay: a) b) 4319K 4320Ca + electron 21084Po 20682Pb + 42He 7. Write a nuclear equation for the alpha decay of 238U. 238U _________ + __________ 8. Write a nuclear equation for the beta decay of 238U. 238U _________ + __________