Session B11 Paper 6100 Disclaimer — This paper partially fulfills a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering. This paper is a student, not a professional, paper. This paper is based on publicly available information and may not be provide complete analyses of all relevant data. If this paper is used for any purpose other than these authors’ partial fulfillment of a writing requirement for first year (freshman) engineering students at the University of Pittsburgh Swanson School of Engineering, the user does so at his or her own risk. SOLID-OXIDE FUEL CELLS POWERED BY NATURAL GAS AS THE SOLUTION FOR CLEAN CONSUMER ENERGY Luke Barone, LJB59@pitt.edu, Sanchez 10:00, Zane Kharitonov, ZVK2@pitt.edu, Lora 4:00, Nicholas Roth, ROTH.NJ@pitt.edu, Sanchez 10:00 Revised Proposal — Electricity has been a vital part of life ever since the late 1800’s when it was first developed. In 1882, the first coal fired power plant was implemented by Thomas Edison. It has now been over one hundred and thirty years since then and the United Stated still primarily uses the burning of coal for the majority of its power needs. As questions about the environment and coal dependence rise while the industrial world continues to advance, it is time for a clean energy that can power the world. Therefore, we believe the future for global consumer power needs is in the use of the clean fuel, natural gas. More specifically, the consumer power industry needs to turn to the new technology of solid-oxide fuel cells powered by natural gas as a replacement for the current, outdated system that requires the burning of fossil fuels for power. The solid-oxide fuel cell is an innovative way to harness the power of methane (CH4), the main component of natural gas. Rather than burning the natural gas to create steam that is then used to operate a turbine, a solid-oxide fuel cell relies on the electrochemical process of oxidation to create power. The solid-oxide fuel cell works more like a battery, relying on the transfer of electrons during a chemical reaction to create the power. As of now, solid-oxide fuel cells have been primarily used in small scale laboratory testing and by Bloom Energy in production of individual solid-oxide fuel cells that can be used in a per household or building setup[1]. The challenge with this system is the high cost per unit, making this configuration not viable for the replacement of the current setup. The real advantages from solid-oxide fuel cells only come when the process is scaled. Therefore, GE is researching the idea of using solid-oxide fuel cells that could create up to 10 megawatts of electric output [2]. This is roughly the same output as a nuclear power plant. The advantage with this setup is the cost-benefit gains from scaling the operation. If perfected, this power creation method could easily be integrated into the current power grid system, also saving on infrastructure costs. The importance of this new technology could be grand as it has the ability to solve the expected energy crisis. Studies show that this process is extremely efficient and it is University of Pittsburgh Swanson School of Engineering 1 2016/1/29 predicted to have an energy recovery of up to 95%. In addition to that, the process can reduce the greenhouse gasses produced from energy production since the CO2 byproduct forms in a pure state, allowing it to be isolated and stored underground in a process called carbon capture and sequestration (CCS). These positive externalities from this innovative method of consumer power production have the potential to outweigh the costs of implication, making it beneficial to switch to this method for consumer power needs. As we prepare research and ultimately an academic article on this topic, we are consulting research currently being done on the topic in the academia world at universities like Massachusetts Institute of Technology and in the corporate world by corporations like Bloom Energy and GE. In addition to this, we are using professional online articles on the topic found through engineering databases to put forth a detailed academic article that encompasses how this process works and its potential benefits to society. REFERENCES [1] (2015) “Solid Oxide Fuel Cells.” Bloom Energy. (Internet Webpage). http://www.bloomenergy.com/fuel-cell/solidoxide/ [2] T. Kellner. (2014, July 22) “The New Power Generation: This Fuel Cell Startup Could Spark a Revolution.” GE Reports. (Internet Webpage). http://www.gereports.com/post/92454271755/the-newpower-generation-this-fuel-cell-startup/ ANNOTATED BIBLIOGRAPHY T. A. Adams II, P. I. Barton. (2010, April). “High-efficiency power production from natural gas with carbon capture.” Journal of Power Sources. (online article). DOI: 10.1016/j.jpowsour.2009.10.046 This article from a journal specializing in Power Sources highlights the process of using solid-oxide fuel cells powered by natural gas. The article goes into deep technical Luke Barone Zane Kharitonov Nicholas Roth detail about the science behind the process, explaining what solid-oxide fuel cells are and how they work. This article is going to be a valuable source for describing in the technology in detail. article, the author analyzes the process by which solid-oxide fuel cells provide energy. Additionally, he explains how General Electric is discovering breakthroughs with this energy source. These factors will be useful in our paper by providing an example of how the fuel cells work and to show how they are being innovated in the industry. (2010, March) “Can natural gas--SOFC combo be cheapest route to cleaner electricity?” American Ceramic Society Bulletin. (Internet Periodical). http://web.b.ebscohost.com/ehost/pdfviewer/pdfviewer?sid= e96674ac-8694-4150-8f5d7ea44ef2ce46%40sessionmgr110&vid=30&hid=115 This source is a periodical published by the American Ceramic Society Bulletin. The author discusses how two researchers at MIT argue that solar oxide fuel cells paired with natural gas is the most cost effective and clean solution for future energy. In our paper, this article will be utilized to show how some of the world's most credible researchers have been pursuing solid-oxide fuel cell research, which in turn shows its potential. V. Meshcheryakov, V. Kirillov, V. Sobyanin. (2006, January). “Thermodynamic analysis of a solid oxide fuel cell power system with external natural gas reforming.” Theoretical Foundations of Chemical Engineering. (online article). DOI: 10.1134/S0040579506010088 This article from the Russian Academy of Sciences provides a more technical explanation on how solid-oxide fuel cells work. The authors, all experts in the field of thermodynamics, use their knowledge to explain chemically the process of how solid-oxide fuel cells work. This article will help guide us by providing detail on the mathematical and chemical processes that solid-oxide-fuel cells go through while generating electrical energy. D. Chandler (2009, December 3) “A greener way to get electricity from natural gas.” MIT News. (Internet Webpage). http://news.mit.edu/2009/natural-gas This article from Massachusetts Institute of Technology’s online webpage about ongoing research at the university highlights the possibility of implementing solidoxide fuel cells as an alternative method for providing consumer power. The article highlights the efficiency and cleanliness that was observer in their small scale testing. It also goes into a cost-benefit analysis of the technology. Information from this article will be useful when evaluating the viability of implementing this technology on a large scale. C. Ni, Z. Yuan, S. Wang, et al. (2015, December). “Study on an integrated natural gas fuel processor for 2-kW solid-oxide fuel cell.” International Journal of Hydrogen Energy. (online article). DOI: 10.1016/j.ijhydene.2015.09.067 This article from a journal on Hydrogen energy focuses on a small scale 2-kW solid-oxide fuel cell that has been created. This article has operating information on this small scale fuel cell that includes testing to find the most efficient setup. We will be able to take this collated data from the small scale operation and be able to relate it to a sizable operation that would be useful for the consumer power industry. P. IIora, M.A.A. Tasher, P. Chiesa, et al. (2010, November). “A novel system for the production of pure hydrogen from natural gas based on solid oxide fuel cell–solid oxide electrolyzer.” International Journal of Hydrogen Energy. (online article). DOI: 10.1016/j.ijhydene.2010.07.078 This article from a journal on hydrogen energy explain how the fuel for solid-oxide fuel cells, pure hydrogen, is derived from natural gases. With this method, the fossil fuels are not being burned but rater being used in a much cleaner way than the current processes of combustion. The conversion of natural gas into hydrogen is the first step in the process of recovering electrical energy from solid-oxide fuel cells. This article will be used provide the detail on the important conversion step in the process. A. Rismanchian, J. Mirzababaei, S. Chuang. (2015, May). “Electroless plated Cu–Ni anode catalyst for natural gas solid oxide fuel cells.” Catalysis Today. (online article). DOI: 10.1016/j.cattod.2014.05.012 This article from a professional journal specializing in catalytic reactions highlights the testing of a specific anode used in solid-oxide fuel cells. The article details the efficiency of using an anode plated in copper and nickel. If viable, a plated anode would be more cost effective than traditional anodes made from precious meatal like platinum. This article will be useful in comparing the effectiveness of different anodes to help determine which material will be most efficient to use, economically and scientifically. T. Kellner. (2014, July 22) “The New Power Generation: This Fuel Cell Startup Could Spark a Revolution.” GE Reports. (Internet Webpage). http://www.gereports.com/post/92454271755/the-newpower-generation-this-fuel-cell-startup/ This source is an online article published by GE Reports, an online news site affiliated with General Electric. In this (2015) “Solid Oxide Fuel Cells.” Bloom Energy. (Internet Webpage). http://www.bloomenergy.com/fuel-cell/solidoxide/ This webpage is from a company that is currently producing solid-oxide fuel cells and have made engineering breakthroughs that have developed solid-oxide fuel cells into much cleaner solution to the energy crisis. This webpage 2 Luke Barone Zane Kharitonov Nicholas Roth describes some of the hardships that were experienced while developing consumer solid-oxide fuel cells and also tells the process of how they operate. This webpage will greatly benefit us in our research to understanding how solid-oxide fuel cells can be implemented into real world applications. J. Thijssen. (2009, March 9). “Natural Gas-Fueled Distributed Generation Solid Oxide Fuel Cell Systems.” US Department of Energy. (online article).https://www.netl.doe.gov/File%20Library/research/c oal/energy%20systems/fuel%20cells/Natural-Gas-DG-FCpaper-update-090330a.pdf This source is an informational article produced by J. Thijissen LLC. The main focus of the article is outlining both the cost and performance analysis of solid-oxide fuel cell systems powered by natural gas. However, this article also provides environmental and technical overviews. This article will be incredibly useful in our paper by providing information regarding the cost, efficiency, and environmental impact of the innovation. 3