Loch Vale Watershed Website Outline April 29, 2010 HOME The Loch Vale Watershed is located in Rocky Mountain National Park. Long-term ecological research and monitoring since 1982 addresses watershed-scale ecosystem processes, particularly as they respond to atmospheric deposition and climate variability. Monitoring of meteorological, hydrologic, and water quality parameters enable us to use long-term trends to distinguish natural from human-caused disturbances. Research into snow distribution, hydrologic flowpaths, vegetation responses to N deposition, isotopic transformations of N by forest and soil processes, trace metals, and aquatic ecological responses to disturbance enable us to understand processes that influence high elevation ecosystems. The Loch Vale Watershed long-term ecological research and monitoring project is operated by the Biological Research Division of the US Geological Survey. SITE DESCRIPTION The Loch Vale watershed is located in Rocky Mountain National Park in north-central Colorado (latitude 40.2878 / longitude –105.6628). The watershed is 660 hectares in size and ranges in elevation from 3,110 m (10,200 ft.) at The Loch outlet to 4,192 m (13,153 ft.) at Taylor Peak. There are two main subbasins in Loch Vale; Andrews Creek drains the northern subbasin, and Icy Brook drains the southern subbasin. The watershed consists of 3 lakes (The Loch, Lake of Glass and Sky Pond). The majority of Rocky Mountain National Park is underlain by igneous (granite) and metamorphic (schist and gneiss) formations. The watershed consists of 83% bare rock, boulder fields, snow and ice; 11% tundra; 5% forest; and 1% subalpine meadow (Baron, 1992). The sub-alpine forests of Loch Vale are dominated by Englemann spruce (Picea englemannii) and sub-alpine fir (Abies lasiocarpa) with average ages ~500 years. The average annual precipitation of the area is 110 cm with 65-80% originating as snow. A more detailed description of the Loch Vale watershed can be found in Baron 1992. RESEARCH Research Objectives: 1. To observe and differentiate natural biogeochemical and biological variability from humancaused disturbance in alpine and subalpine ecosystems through intensive long- term study. 2. To understand and better quantify the role of climatic variability, particularly changes in precipitation and temperature, on alpine and subalpine processes. 3. To apply new and better methods to the addressing of the role of climate on winter snow accumulation, redistribution, and melt processes. 4. Estimate potential ecosystem change induced by changes in climate due to regional land use change and/or globally-increasing greenhouse gases. Program Objectives: 1 1. To share results and information on real and potential threats to natural alpine and subalpine resources with the public, scientific community, and air, water, and land managers. 2. To apply information gained in Rocky Mountain National Park to other NPS and federallymanaged lands in Colorado, nationwide, and worldwide. 3. To offer a program of graduate education and research that develops future scientists and knowledgeable resource managers. 4. To continue the Loch Vale Watershed long-term ecological research project as a successful example of ecosystem study design, interdisciplinary collaboration, long-term continuity of quality-assured data collection, data base management, and better applied natural resource management. Include figure of biogeochemical model with links to the following text: Precipitation: The crest of the southern Rocky Mountains forms a continental-scale meteorological boundary, which influences storm trajectories and precipitation patterns. The Southern Rocky Mountains are characterized by prevailing westerly winds. The major sources of precipitation at locations west of the mountain crest are synoptic-scale frontal disturbances bearing Pacific moisture. These storms lose their moisture in decreasing amounts from west to east on successive orographic barriers in their path. This type of storm is most prevalent during the winter months, when precipitation is snow (~65-80% of LV moisture falls as snow with the average annual total ~110cm). The spring and summer moisture patterns for Loch Vale are mainly influenced by easterly upslope storm events from the Front Range. These storms are a result of local convective activity east of the Continental Divide and have been attributed to the higher N-deposition rates recorded along the eastern side of The Divide. Vegetation: Loch Vale vegetation is typical of the subalpine-alpine vegetation throughout the Rocky Mountains, from central Alberta and British Columbia to Arizona and especially in the Central Rockies. Loch Vale forests are northeast facing, old-growth closed-canopy Engelmann spruce (Picea engelmannii) and Subalpine fir (Abies lasiocarpa) stands at approximately 3200 m elevation. The forests are characterized as cool, sheltered, well drained, with relatively deep soils. Limber pine is found on open slopes and ridgetops. Patches of krummholz (dwarf forest) are found above Timberline Falls. Forest covers approximately 6% of the Loch Vale watershed. Above timberline, alpine tundra vegetation takes the form of low, mat-like plants that are able to withstand the harsh, desiccating conditions that prevent tree survival. Alpine tundra vegetation occupies about 11% of the watershed area. Wet meadows are interspersed with forests in areas of low topographic relief along streambanks and bases of slopes, and cover about 1% of the watershed area. Soils: Three soil regimes are recognized within the Loch Vale watershed: alpine ridge, forested, and alluvial/bog soils. Alpine ridge is confined to Thatchtop Mountain and the ridge above Andrew's Creek, with smaller areas above treeline in the basin that holds Sky Pond and Glass Lake. Forested soils are found in the valley floor below Timberline Falls. Alluvial and bog soils are restricted to a narrow band adjacent to Icy Brook and in one area of low relief adjacent to Andrew's Creek. Alpine ridge soils cover 11%, forested soils 5%, and alluvial/bog soils approximately 1% of the watershed. The remaining 83% of the Loch Vale basin is bare rock, boulder fields, surface water, or fields of permanent snow over boulder fields. Bedrock: The Colorado Front Range is a north-south trending massif located in the central region of Colorado. The Front Range is a Laramide structure with a core of crystalline rocks made of 2 predominantly Precambrian granite, schist, and gneiss. The core is framed by steeply dipping Paleozoic sediments. The metamorphic schist and gneiss, thought to be of sedimentary origin, are the oldest rocks in the range. Together with the Precambrian granites these rock types make up most of the terrain in Rocky Mountain National Park (Cole, 1977). About 80% of the Loch Vale watershed is dominated by bedrock. Surface Water: The surface waters of Loch Vale include lakes, streams, ponds, and temporary melt pools, although we focus our research efforts on lakes and streams only. There are three major drainage lakes within the Loch Vale Watershed (Sky Pond, Glass Lake, and The Loch). All the lakes in the basin are cirque lakes that were formed during Pinedale age advances of Taylor and Andrew's Glaciers. These lakes are all connected by Icy Brook, which originates at the base of the snowfields in the cirque above Sky Pond and leaves the watershed at The Loch outlet. For stream and lake chemistry data, please refer to the data page on this website. Biota: Subalpine and alpine lakes are generally low in phytoplankton abundance and lakes in the Front Range of the Rocky Mountains are no exception. Low nutrient levels and cold temperatures result in low productivity and biomass. Although a vast colonization pool of algae are present in the form of wind-deposited spores, only those physiologically able to withstand the low temperatures and extreme seasonality of light and hydrologic regimes are present in significant numbers. These and other physical factors exert a strong control on the composition and biomass of the phytoplankton community. In addition, ecological factors such as algal parasitism, nutrient competition, and food web interactions may influence phytoplankton populations (Canter and Lund 1968; Kalff and Knoechel 1978; Bird and Kalff 1986; Carpenter et al. 1985; Carpenter and Kitchell 1988). The most common phytoplankton in LVWS include Asterionella formosa Hass. in the spring and Oscillatoria limnetica Lemm. in the autumn. For detailed lists of Loch Vale phytoplankton and macroinvertebrate populations, go to our species lists link below. Sediments: Prior to 1980 there was no systematic collection of precipitation for chemical analysis for the southern Rocky Mountains. Thus, we use lake sediment paleolimnological techniques to reconstruct trends in deposition over time from the mid-1800s to the present (Baron et al. 1986). Lake sediments are cored and analyzed for metals and diatom community assemblages. Sequential layers from the sediment cores are radiometrically dated to reconstruct patterns of metal deposition that could be attributed to an increase in industrial emissions. Diatoms have very specific pH preferences, which are well documented, so that knowledge of diatom community changes over time can be used to interpret lake chemical composition over time (Charles and Norton 1986). DATA Hydrologic Data Units of discharge are expressed as daily averages (of midnight, noon, minimum and maximum flow) in cubic meters per second (cms). All stream discharge measurements are recorded at the Loch Outlet at an elevation of 3050m. Water Chemistry Data The Site column describes sample location and position. 3 Locations in Loch Vale Other Locations in RMNP Position The Loch Emerald Lake O = outlet Little Loch Creek Lake Haiyaha I = Inlet Andrew's Creek Lake Husted IN= Inlet North Andrew's Tarn Lake Louise IS= Inlet South Glass Lake LS=Lake Surface Sky Pond LH=Lake Hypolimnion LM=Lake Metalimnion TI =Tarn Limit “-999” refers to missing data. RMNP refers to Rocky Mountain National Park “TotalDischarge” refers to cumulative discharge from the Loch Outlet from the current sample date to the next sample date. “Temp” refers to water temperature in degrees C. “FldCond” and “LabCond” refer to field and laboratory conductivity measurements in microsiemens per centimeter (us/cm). “FldpH” and “LabpH” refer to field and laboratory pH values. “Alk” refers to alkalinity and units are expressed in microequivalents per liter (ueq/L). All major anions and cations are expressed in units of mg/L except Al, Fe, and Mn, which are expressed as micrograms per liter (ug/L). · Silica (SiO2) and dissolved organic carbon (DOC) are expressed in mg/L. “TN” refers to total nitrogen and “DON” refers to dissolved organic nitrogen. By taking TN and subtracting out inorganic nitrogen, we calculate DON for stream and precipitation samples starting in the spring of 1999. Weather Data “Water Resources Division 2m/6m (1991-2002)” refers to weather data from the USGS-WRD station at a height of 2 and 6 meters. “Biological Resources Division (1982-1992)” refers to weather data from the USGS-BRD station in Loch Vale. Common climate parameters measured for both stations are: solar radiation, 2 meter air temperature, relative humidity, 6 meter wind speed, and 6 meter wind direction. The station is located at an elevation of 3159m. Quality assurance results dictate that complete Loch Vale weather data will be filled with BRD data from September 8, 1983-December 31, 1994 and WRD data from January 1, 1995-on. WRD VARIABLES UNITS BRD VARIABLES UNITS Daily Avg. QS rad. in Langleys/hour Hourly QS rad. in Watts/m2 Daily Avg. QS rad. out Langleys/hour Daily Avg. QA rad. in Langleys/hour 4 Daily Avg. QA rad. out Langleys/hour Daily Avg. net rad. Langleys/hour Min. 6/2m air temp. oC Avg. 6/2m air temp. oC Max. 6/2m air temp. oC Min. 6/2m rel. hum. % Avg. 6/2m rel. hum. % Max. 6/2m rel. hum. % Max. 6/2m wind speed mph 6/2m EPA wind speed mph 6/2m Camp.wind speed mph 6/2mCamp.vector mag. mph 6/2m EPA UT vector dir. 360 Degrees 6/2m EPA vector dir. sd 360 Degrees 6/2m Camp. vector dir. 360 Degrees 6/2m Camp.vector dir. sd 360 Degrees 2m-air temp. oC Rel. hum. % 6m wind speed m/sec. 6m wind dir. 360 Degrees Baro. Press. Millibars Loch Vale and Fraser Soil Temperature Soil temperature data are recorded using Onset Optic StowAway temperature hobos and data are collected hourly. Temperatures are reported in degrees C. Hobos are located in the center of all control and fertilized plots and are buried at a depth of approximately 5 cm. Missing data are recorded as "-999." New probes were installed in each plot on 9/12/2003 for Loch Vale sites and 9/16/2003 for Fraser sites. Data from the new probes were appended to the existing database at these above mentioned dates due to suspect data from old probes (probes have ~5 year lifetime.) Include links to data (in .txt, .xls, or .mdb format) and websites that disseminate Loch Vale Data (i.e., USGS NWIS and NADP, maybe NRCS SNOTEL as well). Publications Advani, S. 2005. Soil respiration responses to fertilization: a comparison of two forests with different nitrogen deposition histories. M.S. Thesis, Graduate Degree Program in Ecology, Colorado State University. 40 pp. Allstott, E.J., 1995. Quality Assurance Report, Loch Vale Watershed Study, 1991-1994. Natural Resource Ecology Laboratory, Colorado State University, Fort Collins, CO. 80523. 22 pp. 5 Allstott, E.J., M.Bashkin, and J.S. Baron. 2000. Loch Vale Watershed Project Quality Assurance Report: 1995-1998: U.S. Geological Survey Open-File Report 99-111. Natural Resource Ecology Laboratory, Colorado State University, Fort Collins, CO 80523. 48 pp. Allstott, E.J., J.S. Baron, J.A. Botte. 2000. Loch Vale Watershed Project Methods Manual 2000. 70 pp. Arthur, M.A. and T.J. Fahey. 1989. Mass and nutrient content of decaying boles in an Englemann spruce subalpine fir forest, Rocky Mountain National Park. Can. J. For. Res. 20:730-737. Arthur, M.A. 1990. The effects of vegetation on watershed biogeochemistry at Loch Vale Watershed, Rocky Mountain National Park, Colorado. Ph.D. Dissertation, Cornell University, Ithaca NY. Arthur, M.A. and T.J. Fahey. 1992. Biomass and nutrients in a Picea englemannii/Abies lasiocarpa forest in north-central Colorado: pools, annual production, and nutrient cycling. Can. J. For. Res. 22:315325. Arthur, M.A. and T.J. Fahey. 1993. Controls on soil solution chemistry in a subalpine forest in northcentral Colorado. Soil Science Society of America Journal 57:1122-1130. Arthur, M.A. and T.J. Fahey. 1993. Throughfall chemistry in an Englemann spruce, subalpine fir forest in north-central Colorado. Can. J. For. Resear. 23:738-742. Bachmann, S.A. 1994. Hydrology of a subalpine wetland complex in Rocky Mountain National Park, Colorado. M.S. Thesis, Colorado State University. Back, J.A. 1992. Stable isotopes as tracers of hydrologic sources to three alpine lakes, Rocky Mountain National Park. M.S. Thesis, Colorado State University. Balk, Ben, Kelly Elder, and Jill Baron. 1998. Estimating the spatial distribution of snow water equivalence in a mountain watershed using geostatistical methods. Pp. 100-111 in: C.R. Troendle, ed. Western Snow Conference Proceedings, Snowbird, UT. April 1998. Balk, B. 1999. Statistical methods for spatial modeling of snow distirbution in a Colorado Front Range watershed M.Sc. Thesis, Department of Earth Resources, Colorado State University. 236 pp. Balk, B.C., and K. Elder. 2000. Combining binary decision tree and geostatistical methods to estimate snow distribution in a mountain watershed. Water Resources Research 36:13-26. Baron, J. 1983. Comparative water chemistry of four lakes in Rocky Mountain National Park. Wat. Res. Bull. 19:897-902. Baron, J.S. 2006. Hindcasting Nitrogen Deposition to Determine an Ecological Critical Load. Ecol. Appl. In press. Baron, J.S., K.R. Nydick, H.M. Rueth, B.M. Lafrancois, and A.P. Wolfe. 2005. High elevation ecosystem responses to atmospheric deposition of nitrogen in the Colorado Rocky Mountains, USA. Global Change and Mountain Regions: A State of Knowledge Overview. Pp. 429-436 in: Ulli M. Huber, Harald K.M. Bugmann, and M.A. Reasoner, eds. Springer, Dordrecht, The Netherlands. Baron, J. and P.M. Walthall. 1985. The nature of precipitation, soil and surface water chemistry in a subalpine ecosystem. ch. 42, pp. 497-509 in: D.E. Caldwell, J.A. Brierly and C.L. Brierly, eds. PLANETARY ECOLOGY. Van Nostrand Reinhold Company. New York. Baron, J., D.R. Beeson, S.A. Zary, P.M. Walthall, W.L. Lindsay and D.M. Swift. 1985. Long-term research into the effects of atmospheric deposition in Rocky Mountain National Park; summary report 19801984. NPS Technical Report 84-ROMO-2. 43 pp. Baron, J., S.A. Norton, D.R. Beeson and R. Herrmann. 1986. Sediment diatom and metal stratigraphy from Rocky Mountain lakes with special reference to atmospheric deposition. Can. J. Fish. Aquat. Sci. 43:1350-1362. Baron, J. and O.P. Bricker. 1987. Hydrologic and chemical flux in Loch Vale Watershed, Rocky Mountain National Park. pp. 141-156 in: R.C. Averett and D. McKnight eds. CHEMICAL QUALITY OF WATER AND THE HYDROLOGIC CYCLE. Lewis Publishers. Ann Arbor, MI. Baron, J., McKnight, D.M., and A.S. Denning. 1992. Sources of dissolved and suspended organic carbon in Loch Vale Watershed, Rocky Mountain National Park, USA. Biogeochemistry 15:89-110. 6 Baron, J. and A. S. Denning. 1993. The influence of mountain meteorology on precipitation chemistry at low and high elevations of the Colorado Front Range, USA. Atmos. Environ. 27A:2337-2349. Baron, J. 1990. Findings from ecological research program. in: Highlights of Natural Resources Management. Natural Resources Programs, Natural Resources Report NPS/NRPO/NRR-90/02. National Park Service. Baron, J.S., 1991. Surface water dynamics and biogeochemical fluxes of Loch Vale Watershed, Colorado. Ph.D. Dissertation, Department of Range Science, Colorado State University, Fort Collins, CO 122 pp. Baron, J. ed. 1992. Biogeochemistry of a subalpine ecosystem: Loch Vale Watershed. Ecological Study Series #90. Springer-Verlag, New York. Baron J., R.A. Pielke, W.J. Parton, D.S. Ojima, T.B. Kirchner, S.W. Running, and T.G.F. Kittel. 1992. Dynamic land surface/atmosphere parameterization for the South Platte River drainage. pp. 273283 in: R.Herrmann, ed.: Am. Water Resour. Assoc. Symposium Proceedings: Managing Water Resources During Global Change. Baron, J., D.S. Ojima, E.A. Holland, and W.J. Parton. 1994. Nitrogen consumption in high elevation Rocky Mountain tundra and forest and implications for aquatic systems. Biogeochemistry 27:61-82. Baron, J.S., and D.H. Campbell. 1997. Nitrogen fluxes in a high elevation Rocky Mountain basin. Hydrologic Processes 11:783-799. Baron, J.S., E.J. Allstott, and B.K. Newkirk. 1995. Analysis of long term sulfate and nitrate budgets in a Rocky Mountain basin. pp. 255-262 in: K.A. Tonnesson, M.W. Williams, and M. Tranter, eds. Biogeochemistry of seasonally snow-covered catchments. IASH Publication No 228: International Association of Hydrologic Sciences Press, Institute of Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK. Baron, Jill, Roger Pielke, Bill Parton, Larry Band, and Steve Running. 1994. Dynamic land surface/atmospheric parameterization at different spatial scales in the Colorado Rocky Mountains. pp. 34-36 in: P.H. Gleick, A. Rango, and K. Cooley, eds., Proceedings of a workshop on the use of hydrological models for evaluating the impacts of climate change in snowmelt water supply basins, Santa Fe, NM 1993. Pacific Institute for Studies in Development, Environment, and Security, Oakland, CA 94612. 54 pp. Baron, J.S., M.D. Hartman, L.E. Band, and R.L. Lammers. 1998. Sensitivity of high elevation Rocky Mountain watersheds to climate change. Pp. 269-273 in: Proceedings of the Fifth National Watershed Conference, Reno NV, May 1997. Baron, J.S., D.S. Ojima, M.D. Hartman, T.G.F. Kittel, R.B. Lammers, L.E. Band, and R.A. Pielke, Sr. 1997. The influence of land cover and temperature change on hydrological and ecosystem dynamics in the South Platte River basin. Pp. 279-286 in: J.J. Warwick, ed. Proceedings of AWRA/UCOWR Symposium on Water Resources Education, Training, and Practice: Opportunities for the Next Century. AWRA, Herndon, VA, TPS-97-1, 988 pp. Baron, J.S., M.D. Hartman, T.G.F. Kittel, L.E. Band, D.S. Ojima, and R.B. Lammers. 1998. Effects of land cover, water redistribution, and temperature on ecosystem processes in the South Platte Basin. Ecol. Appl.8:1037-1051. Baron, J., and J. Turk. 1998. Aquatic ecosystems. Pp. 4-18 in: Haddow, D., R. Musselman, T, Blett, R. Fisher, tech. Coords. Guidelines for evaluating air pollution impacts on wilderness within the Rocky Mountain Region: report of a workshop, 1990. Gen. Tech. Rep. RMRS-GTR-4. Fort Collins, CO US. Department of Agriculture, Forest Service, Rocky Mountain Research Station, 31 p. Baron, J.S., and N. Caine. 2000. The temporal coherence of two alpine lake basins of the Colorado Front Range, USA. Freshwater Biology 43: 463-476. Baron, J.S., D.M. Theobald, and D.B. Fagre. 2000. Management of land use conflicts in the United States Rocky Mountains. Mountain Research and Development 20:24-27. 7 Baron, J.S., M. Hartman, L.E. Band, and R.Lammers. 2000. Sensitivity of a high elevation Rocky Mountain watershed to altered climate and CO2. Water Resources Research, 36:89-99. Baron, J.S., and M.W. Williams. 2000. Preface to special section: recent Loch Vale Watershed research. Water Resources Research 36:11-12. Baron, J.S., Heather M. Rueth, Alexander M. Wolfe, Koren R. Nydick, Eric J. Allstott, J. Toby Minear, and Brenda Moraska.. 2000. Ecosystem Responses to Nitrogen Deposition in the Colorado Front Range. Ecosystems 3: 352-368. Baron, J.S. 2001. Lessons learned from long-term ecosystem research and monitoring in alpine and subalpine basins of the Colorado Rocky Mountains, USA.. Ekológia (Bratislava) 20, Supplement 2:2530. Baron, J.S. ed. 2002. Rocky Mountain Futures: An Ecological Perspective. Island Press, Washington. 325pp. Baron, J.S., K.R. Nydick, H.M. Rueth, B.M. Lafrancois, and A.P. Wolfe. 2003. High elevation ecosystem responses to atmospheric deposition of nitrogen in the Colorado Rocky Mountains, USA. Global Change and Mountain Regions: A State of Knowledge Overview. Ulli M. Huber, Harald K.M. Bugmann, and M.A. Reasoner, eds. Kluwer Academic Publishers, Dordrecht, The Netherlands. In press. Baron, J.S., J.A. Botte, and R. Shory, 2004. Effects of Atmospheric Nitrogen Deposition on High Elevation Colorado Forests. pp. 10-14 in: Warren R. Keammerer and Jeffrey Todd, eds. Proceedings, HIGH ALTITUDE REVEGETATION WORKSHOP NO. 16. Colorado State University, Fort Collins, Colorado, March 3-5, 2004. Baron, J.S., S. Del Grosso, D.S. Ojima, D.M. Theobald, and W.J. Parton. 2004. Nitrogen emissions along the Colorado Front Range: Response to population growth, land and water use change, and agriculture. Ecosystems and Land Use Change, Geophysical Monograph Series 153: 117-127. Bigelow, D.S., A.S. Denning, and J. Baron. 1990. Differences between Nipher and Alter-shielded Universal Belfort precipitation gages at two Colorado deposition monitoring sites. Environ. Sci. and Technol. 24:758-760. Botte, J.A., and J.S. Baron. 2004. Quality Assurance Report, Loch Vale Watershed, 1999-2002. USGS Open-File Report 2004-1306. 17 pp. Botte, J.A., and J.S. Baron. 2004. Loch Vale Watershed Project Methods Manual 2004. 79pp. Botte, J.A., and J.S. Baron. 2005. Loch Vale/Fraser Nitrogen Fertilization Experiment Methods 2005. 11pp. Brock, Cynthia L. 1997. Sulfur isotope methods as an approach to sulfur dynamics in a subalpine wetland, Loch Vale Watershed. M.S. Thesis. Department of Earth Resources, Colorado State University. 66 pp. Burkett, V.R., D.A. Wilcox, R. Stottlemyer, W. Barrow, D. Fagre, J. Baron, J. Price, J.L. Nielsen, C.Allen, D.L. Peterson, G. Ruggerone, T. Doyle. 2005. Nonlinear dynamics in ecosystem response to climatic change: Case studies and policy implications. Ecological Complexity 2:357-394. Burns, D.A. 2002. The effects of atmospheric nitrogen deposition in the Rocky Mountains of Colorado and Southern Wyoming - a synthesis and critical assessment of published results. Water-resourcesinvestigations report 02-4066, U.S. Geological Survey, Troy New York. Burns, D.A. 2003. The effects of atmospheric nitrogen depostion in the Rocky Mountains of Colorado and southern Wyoming, USA-- a critical review. Environmental Pollution 127: 257-269, U.S. Geological Survey, Troy, New York. Campbell, D.H., D.W. Clow, G.P. Ingersoll, M.A. Mast, N.E. Spahr, and J.T. Turk. 1995. Temporal variations in the chemistry of 2 snowmelt-dominated streams in the Rocky Mountains. Wat. Resour. Resear. 31:2811-2822. 8 Campbell, D.H., D.W.Clow, G.P. Ingersoll, M.A. Mast, N.E. Spahr, and J.T. Turk. 1995. Nitrogen deposition and release in alpine watersheds, Loch Vale, Colorado, USA. pp. 243-254 in: K.A. Tonnesson, M.W. Williams, and M. Tranter, eds. Biogeochemistry of seasonally snow-covered catchments. IASH Publication No 228: International Association of Hydrologic Sciences Press, Institute of Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK. Campbell, D.H., J.S. Baron, K. Tonnessen, P. Brooks, and P. Schuster. 2000. Controls on nitrogen flux in alpine/subalpine watersheds. Water Resources Research 36:37-48. Campbell, Donald H.; Kendall, Carol; Chang, Cecily C. Y.; Silva, Steven R.; Tonnessen, Kathy A.. 2002. Pathways for nitrate release from an alpine watershed: Determination using *15N and *18O. Water Resources Research 38:10.1029/2001WR000294. Chase, T.N., R.A. Pielke, Sr., T.G.F. Kittel, J. S. Baron, and T.J. Stohlgren, 1999. Potential impacts on Rocky Mountain weather and climate due to land use changes in the adjacent Great Plains. Jour. Geophys. Resear. 104, D14: 16,673-16,690. Clements, S. 2001. Spatial and temporal variations of bulk snow properties and stream water chemistry in an alpine/subalpine watershed, Rocky Mountain National Park. M.S. Thesis, Colorado State University Department of Earth Resources. 314 pp. Cline, D.W. 1994. Modeling the spatial distribution and temporal patterns of alpine and subalpine snowmelt. Proceedings of the 1993 Eastern/Western Snow Conference. Cline, D. 1995. Snow surface energy exchanges and snowmelt at a continental alpine site. Biogeochemistry of Seasonally Snow-Covered Catchments, IAHS Publ. No. 228, pp. 157-166. Cline, D.W., 1995. Studies supporting the development of spatially distributed, physically based snowmelt models for continental alpine areas. Ph.D. Dissertation, University of Colorado Department of Geography. Cline, D.W. 1997. Effect of seasonality of snow accumulation and melt on snow surface energy exchanges at a contintental alpine site. J. Appl. Meteor. 36: 32-51. Cline, D.W. 1997. Snow surface energy exchanges and snowmelt at a continental, midlatitude alpine site. Wat. Resour. Resear. 33: 689-701. Clow, D.W. 1992. Weathering rates from field and laboratory experiments on naturally-weathered soils. Ph.D. Dissertation, University of Wyoming, Laramie. Clow, D.W. and M.A. Mast. 1995. Composition of precipitation, bulk deposition, and runoff at a granitic bedrock catchment in the Loch Vale Watershed. pp. 235-242 in: K.A. Tonnesson, M.W. Williams, and M. Tranter, eds. Biogeochemistry of seasonally snow-covered catchments. IAHS Publication No 228: International Association of Hydrologic Sciences Press, Institute of Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK. Clow, D.W., and Drever, J.I., 1996, Weathering rates as a function of flow through an alpine soil, Chemical Geology, v. 132, pp. 131-141. Clow, D.W., M.A. Mast, T.D. Bullen, and J.T.Turk. 1997. Strontium 87/strontium 86 as a tracer of mineral weathering reactions and calcium sources in an alpine/subalpine watershed, Loch Vale Colorado. Wat. Resour. Resear. 33:1335-1351. Clow, D.W., and J.K. Sueker. 2000. Relations between basin characteristics and stream-water chemistry in alpine/subalpine basins in Rocky Mountain National Park, Colorado. Water Resources Research 36:49-62. Clow, D.W., J.O. Sickman, R.G. Striegl, D.B. Krabbenhoft, J.G. Elliott, M. Dornblaser, D.A. Roth, D.H. Campbell. 2003. Changes in the chemistry of lakes and precipitation in high elevation national parks in the western United States, 1985-1999. Water Resources Research 39: 6: 1171, doi, 10.1029/2002wr001533. 9 Clow, D.W., L, Schrott, R. Webb, D.H. Campbell, A. Torizzo, and M. Dornblaser. 2003. Ground water occurrence and contributions to streamflow in an alpine catchment, Colorado Front Range. Ground Water, Vol. 41, No. 7, pp. 937-950. Das, B., R. D. Vinebrooke, A. Sanchez-Azofiefa, B. Rivard, and A.P. Wolfe. 2005. Inferring sedimentary chlorophyll concentrations with reflectance spectroscopy: a novel approach to reconstructing historical changes in the trophic status of mountain lakes. Can. J. Fish. Aquat. Sci. 62:1067-1078. Denning, A.S. 1988. Quality assurance report, Loch Vale Watershed project, surface water chemistry 1982-1987. Denning, A.S. Baron, J., M.A. Mast, and M.A. Arthur. 1991. Hydrologic pathways and chemical composition of runoff during snowmelt in Loch Vale Watershed, Rocky Mountain National Park, Colorado USA. Wat. Air, Soil, Pollut. 59:107-123. Drever, J.I., and Clow, D.W., 1996, Weathering rates in catchments; IN S. Brantley, and A. White (eds.), Chemical Weathering Rates of Silicate Minerals, Mineral. Soc. Am., Rev. Mineral., v. 31, pp. 463-483. Edwards, R.L. 1991. Data Quality Report: 1989-1990, Loch Vale Watershed. Natural Resource Ecology Laboratory, Colorado State University, Fort Collins. Fenn, M.E., M. Poth, J.D. Aber, J.S. Baron, B.T. Bormann, D.W. Johnson, A.D. Lemly, S.G. McNulty, D.F. Ryan, and R. Stottlemyer. 1998. Nitrogen excess in North American ecosystems: a review of predisposing factors, geographic extent, ecosystem responses, and management strategies. Ecological Applications.8:706-733. Fenn,M.E., R. Haeuber, G.S. Tonnesen, J.S. Baron, S Grossman-Clarke, D. Hope, D.A. Jaffe, S. Copeland, L. Geiser, H. M. Rueth, AND J.O. Sickman. 2003. Nitrogen Emissions, Deposition and Monitoring in the Western United States. BioScience 53:391-403. Fenn, M.E. J.S. Baron, E.B. Allen, H. M. Rueth, K.R. Nydick, L. Geiser, W.D. Bowman, J. O. Sickman, T.Meixner, and D. W. Johnson. 2003, Ecological Effects of Nitrogen Deposition in the Western United States. BioScience 53:404-420. Gibson, J.H. and J. Baron. 1984. Acidic deposition in the Rocky Mountain region. pp. 29-42 in: T.A.Colbert and R.L. Cuany, eds. Proceedings: High-Altitude Revegetation Workshop No. 6. Information Series No. 53. Colorado Water Resources Research Institute. Colorado State University. Groffman, P.M., J.S. Baron, T. Blett, A.J. Gold, I. Goodman, L.H. Gunderson, B.M. Levinson, M.A. Palmer, H.W. Paerl, G.D. Peterson, N.L. Poff, D.W. Rajeski, J.F. Reynolds, M.G. Turner, K.C. Weathers, J. Wiens, 2006. Ecological thresholds: the key to successful environmental management, or an important concept with no practical application? Ecosystems, in press. Hartman, M.D., J. Baron, R.B. Lammers, D. Cline, L.E. Band, G.L. Liston, and C. Tague. 1999. Simulations of snow distribution and hydrology in a mountain basin. Water Resources Research 35:1587-1603. Hartman, M.D., J.S. Baron, and D.S. Ojima. 1995. Simulations of snow distribution and hydrology in a mountain basin. GPAC workshop proceedings in computer applications in water management. Hartman, M.D., J.S. Baron, D.S. Ojima. 2005. Application of a coupled ecosystem-chemical equilibrium model, DayCent-Chem, to stream and soil chemistry in an alpine watershed. Ecol. Modeling, in revision. Hauer, R., J.S. Baron, D.H. Campbell, K.D. Fausch, S.W. Hostettler, G.H. Leavesley, P.R. Leavitt, D.M. McKnight, and J.A. Stanford. 1997. Assessment of climate change and freshwater ecosystems of the Rocky Mountains, U.S. and Canada. Hydrol. Proc. 11:903-924. Heit, M., R. Klusek and J. Baron. 1984. Evidence of deposition of anthropogenic pollutants in remote Rocky Mountain lakes. Water, Air, Soil Poll. 22:403-416. Huang Jian-hui, Jill Baron, and Dan Binkley. 1996. The contribution of wetlands to stream nitrogen load in the Loch Vale Watershed, Colorado, USA. Acta Phytoecologia Sinica 20:289-302. 10 Ingersoll, G.P., D.H. Campbell, and N.E. Spahr. 1996. Snow depth variability in a small alpine watershed. Proceedings of the Western Snow Conference, 64th Annual Meeting, Bend, Oregon, April 15-18. Colorado State University. pp 159-162. Ingersoll, G.P. 1995. Estimating snowmelt contribution to the seasonal water balance in a small alpine watershed. M.S. Thesis, University of Colorado Department of Geography. Johnson, C.A., M.A. Mast, C.L. Kester. 2001. Use of 17O/16O to trace atmospherically-deposited sulfate in surface waters: a case study in alpine watersheds in the Rocky Mountains. Geophys. Resear. Let. 28:4483-4486. Kendall, C., D.H. Campbell, D.A. Burns, J.B. Shanley, S.R. Silva, and C.C.Y.Chang. 1995. Tracing sources of nitrate in snowmelt runoff using the oxygen and nitrogen isotopic compositions of nitrate. pp. 339348 in: K.A. Tonnesson, M.W. Williams, and M. Tranter, eds. Biogeochemistry of seasonally snowcovered catchments. IASH Publication No 228: International Association of Hydrologic Sciences Press, Institute of Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK. Kendall, C., Silva, S.R., Chang, C.C.Y, Burns, D.A., Campbell, D.H. and Shanley, J.B. 1995, Use of the d18O and d15N of nitrate to determine sources of nitrate in early spring runoff in forested catchments, in Isotopes in water resources management, proceedings of International Atomic Energy Agency Symposium, Vienna, Austria, March 20-24, 1995, IAEA-SM-336/29, pp.167-176. Kester, C.L., J.S. Baron, and J.T. Turk. 2003. Isotopic study of sulfate sources and residence times in a subalpine watershed. Environmental Geology 43:606-613. Klein, E.J. 1988. The variations in wet precipitation chemistry with elevation in Colorado. M.S. Thesis. Colorado State University. 112 pp. Körner, C., M. Ohsawa, E. Spehn, E. Berge, H. Bugmann, B. Groombridge, L. Hamilton, T. Hofer, J. Ives, N. Jodha, B. Messerli, J. Pratt, M. Price, M. Reasoner, A. Rodgers, J. Thonell, M. Yoshino, J. Baron, R. Barry, J. Blais, R. Bradley, R. Hofstede, V. Kapos, P. Leavitt, R. Monson, L. Nagy, D. Schindler, R. Vinebrooke, T. Watanabe. 2006. Mountain Systems. Chapter 24 in: Millennium Ecosystem Assessment. Current State and Trends: Findings of the Condition and Trends Working Group. Ecosystems and Human Well-being, vol.1., Island Press, Washington DC. Lammers, R.B., L.E. Band, and C.L. Tague. 1997. Scaling behaviour of watershed processes. in: P. van Gardingen, G. Foody, and P. Curran, eds. Scaling Up, from Cell to Landscape. Cambridge University Press, pp. 296-317. Lammers, R.B. 1998. Extending hydro-ecological simulation models from local to regional scales: Ph.D. Dissertation, University of Toronto, Toronto Ontario. Martin, Michael. 1994. Late summer, inorganic nitrogen dynamics of an alpine watershed. M.S. Thesis, Colorado State University, Fort Collins. Mast, M.A. 1989. A laboratory and field study of chemical weathering with special reference to acid deposition. Ph.D. Dissertation, University of Wyoming, Laramie. Mast, M.A., J.I. Drever, and J. Baron. 1990. Chemical weathering in The Loch Vale Watershed, Rocky Mountain National Park, Colorado. Wat. Res. Resear. 26:2871-2978. Mast, M.A., C. Kendall, D.H. Campbell, D.W. Clow, and J. Back. 1995. Determination of hydrologic pathways in an alpine-subalpine basin using isotopic and chemical tracers, Loch Vale Watershed, Colorado. pp. 263-270 in: K.A. Tonnesson, M.W. Williams, and M. Tranter, eds. Biogeochemistry of seasonally snow-covered catchments. IASH Publication No 228: International Association of Hydrologic Sciences Press, Institute of Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK. Mast, M.A., K.P. Wickland, R.T. Striegl, and D.W. Clow. 1998. Winter fluxes of CO2 and CH4 from subalpine soils in Rocky Mountain National Park, Colorado. Global Biogeochemical Cycles 12:607621. Mast, M.A., J.T. Turk, G.P. Ingersoll, D.W. Clow, and C.L. Kester. 2001. Use of stable sulfur isotopes to identify sources of sulfate in Rocky Mountain snowpacks. Atmospheric Environment 35:3303-3313. 11 Mast, M.A., D.H. Campbell, D.P. Krabbenhoft, and H.E. Taylor. 2005. Mercury transport in a highelevation watershed in Rocky Mountain National Park, Colorado. Water, Air, and Soil Pollution 161:21-42. McKnight, D., C. Miller, R. Smith, J. Baron and S. Spaulding. 1988. Phytoplankton populations in lakes in Loch Vale, Rocky Mountain National Park, Colorado: sensitivity to acidic conditions and nitrate enrichment. U.S. Geological Survey Water Resources Investigations Report 88-4115, Denver, CO. 102 pp. McKnight, D., M.V. Brenner, R. Smith and J. Baron. 1986. Seasonal changes in phytoplankton in lakes in Loch Vale, Rocky Mountain National Park. USGS Water Resources Investigations Report 86-4101. Denver, CO. 64 pp. McKnight, D.M., R.L. Smith, J.P. Bradbury, J. Baron, and S.A. Spaulding. 1990. Phytoplankton dynamics in three Rocky Mountain lakes, Colorado, USA. Arc. Alp. Resear. 22:264-274. McKnight, D.M., R. Harnish, R.L. Wershaw, J.S. Baron, and S. Schiff. 1997. Chemical characteristics of particulate, colloidal, and dissolved organic material in Loch Vale Watershed, Rocky Mountain National Park. Biogeochemistry 36:99-124. McLaughlin, P.W. 1988. The effect of storm trajectory on precipitation chemistry in Rocky Mountain National Park. M.S. Thesis. Colorado State University. 70 pp. Meixner, T., R.C. Bales, M.W. Williams, D.H. Campbell, and J.S. Baron. 2000. Stream chemistry modeling of two watersheds in the Front Range, Colorado. Water Resources Research 36: 77-88. Meixner, T., 1999. Alpine biogeochemical modeling: case studies, improvements, and parameter estimation. Ph.D. Dissertation, University of Arizona, Tucson, AZ. 246 pp. Menounos, B., 1996. A Holocene debris-flow chronology for an alpine catchment, Colorado Front Range. M.A. thesis, University of Colorado, Boulder. 160 p. Menounos, B., 1997. The Water Content of Lake Sediments and its Relationship to other Physical Parameters: an Alpine Case Study. The Holocene 7:207-212. Menounos, B., 1997. Evidence for cirque glaciation in the Colorado Front Range during the Younger Dryas chronozone. Quat. Resear. 48:38-47. Michel, R.L, D.H. Campbell, D.W. Clow, and J.T. Turk. 2000. Timescales for migration of atmosphericallyderived sulphate through an alpine watershed, Loch Vale, Colorado. Water Resources Research 36:27-36. Minear, J.T. 1998. Recent changes in water chemistry and diatom assemblages of high-altitude aquatic ecosystems in Rocky Mountain National Park, Colorado. Senior Thesis, The Colorado College, Colorado Springs, CO. Moraska Lafrançois, B. 2002. Algal and invertebrate responses to atmospheric nitrogen deposition in Rocky Mountain lakes. Ph.D. Dissertation, Colorado State University, Fort Collins, CO. Moraska Lafrançois B., K.M. Nydick, and B. Caruso. 2003. Influence of nitrogen on phytoplankton biomass and community composition in fifteen Snowy Range lakes (Wyoming, U.S.A.). Arctic, Antarctic, and Alpine Research 35:499-508. Moraska Lafrançois, B., D. M. Carlisle, K. R. Nydick, B. M. Johnson, J. S. Baron. 2003. Environmental Characteristics and Benthic Invertebrate Assemblages in Colorado Mountain Lakes. Western North American Naturalist 63:137-154. Moraska Lafrancois, B., K.R. Nydick, B.M. Johnson, and J.S. Baron. 2004. Cumulative effects of nutrients and pH on the plankton of two mountain lakes. Can. Jour. Fish. Aquat. Sciences. 61: 1153-1165. Muldoon, K. 2003. A hydrologic and nitrogen mass balance for Embryo Pond, Rocky Mountain National Park, Colorado. M.S. Thesis, Graduate Degree Program in Ecology, Colorado State University, Fort Collins, CO 80523. 53 pp. 12 Nanus, L., D.H. Campbell, G. P. Ingersoll, D.W. Clow, M.A. Mast. 2003. Atmospheric Deposition Maps for the Rocky Mountians. US Geological Survey, Denver, CO. Newkirk, B.K., 1995. Loch Vale Watershed Methods Manual. Natural Resource Ecology Laboratory. Colorado State University, Fort Collins, CO 80523. 124 pp. Nydick, K.R., 2002. Mountain lake responses to elevated nitrogen deposition. Ph.D. dissertation, Colorado State University, Fort Collins. 162 pp. Nydick, K.R., B. Moraska Lafrancois, J.S. Baron, and B.M. Johnson. 2003. Lake-specific responses to elevated atmospheric nitrogen deposition in the Colorado Rocky Mountains, USA. Hydrobiologia, 510: 103-114. Nydick, K.R., B. Moraska LaFrancois, and J.S. Baron. 2004. NO3 uptake in shallow, oligotrophic, mountain lakes: the influence of elevated NO3 concentrations. Journal of the North American Benthological Society. 23(3): 397-415. Nydick, K.R., B. Morasks LaFrancois, J.S. Baron and B.M. Johnson. 2004. Nitrogen regulation of algal biomass, productivity, and composition in shallow mountain lakes, Snowy Range, Wyoming, USA. Can. Journ. Fish. Aquat. Sciences. 61: 1256-1268. Norton, S.A., C.T. Hess, G.M. Blake, M.L. Morrison and J. Baron. 1985. Excess unsupported 210Pb in lake sediment from Rocky Mountain lakes: a groundwater effect. Can. J. Fish. Aquat. Sci. 42:1249-1254. Pielke, R.A., T.J. Lee, T.G.F. Kittel, J.M. Cram, T.N. Chase, G.A. Dalu, and J.S. Baron. 1993. The effect of mesoscale vegetation distribution on the hydrologic cycle and regional and global climate. Pages 8287, in: Preprints, Conference on Hydroclimatology: Land-Surface/Atmosphere Interactions on Global and Regional Scales, Anaheim, CA, Jan 1993. American Meteorological Society, Boston, Mass. Planert, Debra. 1997. Nitrogen fertilization influences on microbial activity. M.S. Thesis, Department of Forest Sciences, Colorado State University. Rapport, D.J., C. Gaudet, J.R. Karr, J.S. Baron, C. Bohlen, W. Jackson, B. Jones, R.J. Naiman, B. Norton, and M.M. Pollock. 1998. Evaluating landscape health: integrating societal goals and biophysical processes. Journal of Environmental Management 53:1-15. Reasoner, M.A. and Jodry, M.A. (2000). Rapid response of alpine timberline vegetation to the Younger Dryas climate oscillation in the Colorado Rocky Mountains, USA. Geology, Vol. 27, p. 51-54 Reasoner, M.A. 1996. Late Quaternary alpine and subalpine lacustrine records, Canadian and Colorado Rocky Mountains. Ph.D. Dissertation, University of Alberta Department of Earth and Atmospheric Sciences. Rueth, H.M., J.S. Baron, and E.J. Allstott. 2003. Responses of old-growth Engelmann spruce forests to nitrogen fertilization. Ecological Applications 13:664-673. Rueth, H.M., and J.S. Baron. 2002. Differences in Englemann spruce forest biogeochemistry east and west of the Continental Divide in Colorado, USA. Ecosystems 5:45-57. Rueth, H.M., and J.S. Baron. 2001. Englemann spruce nitrogen dynamics across a nitrogen deposition gradient in Colorado, USA.. Ekológia (Bratislava) 20, Supplement 2:43-49. Rueth, H.M. 2001. Englemann spruce forest responses to nitrogen deposition in northern Colorado. Ph.D. dissertation, Colorado State University Graduate Degree Program in Ecology. 105 pp. Shiller, A.M., and T.L. Hebert. 1998. Biogeochemical controls on dissolved trace elements in rivers. Mineral Mag. 62A:1391-1392. Shiller, A.M. 1999. Dissolved trace elements in a seaonally snow-covered catchment. Pp. 123-125 in: H Ármánnsson, ed. Geochemistry of the Earth’s Surface. Balkema, Rotterdam, Netherlands. Sorrano, P.A., K.E. Webster, J.L. Riera, T.K. Kratz, J.S. Baron, P. A. Bukaveckas, G.W. Kling, D.S. White, N. Caine, R.C. Lathrop, and P.R. Leavitt. 1999. Spatial variation among lakes within landscapes: ecological organization along lake chains. Ecosystems 2:395-410. Spaulding, S.A. 1992. Phytoplankton and zooplankton under ice cover in a subalpine lake, The Loch, Rocky Mountain National Park, 1987-89. U.S. Geological Survey Open-File Report 91-489.33 pp. 13 Spaulding, S.A. 1991. Phytoplankton community dynamics under ice-cover in The Loch, a lake in Rocky Mountain National Park. M.S. thesis, Colorado State University, Fort Collins. Spaulding, S.A., J. Baron, and J.V. Ward. 1993. Phytoplankton community dynamics under ice cover in The Loch, a lake in Rocky Mountain National Park. Arch. Hydrobiol. 129:179-198. Stohlgren, T.J., J. Baron, T.G.F. Kittel, and D. Binkley. 1995. Ecosystem trends in the Colorado Rockies. Pages 310-312, in: Our Living Resources: A Report to the Nation on the Distribution, Abundance, and Health of U.S. Plants, Animals, and Ecosystems. LaRoe, E.T., G.S. Farris, C.E. Puckett, P.D. Doran, and M.J. Mac, eds. Department of Interior, National Biological Service, Washington, DC. Stohlgren, T.J., J. Baron, and T.G.F. Kittel. 1993. Understanding coupled climatic, hydrological, and ecosystem response to global climate change in the Colorado Rockies Biogeographical Area. Pages 184-200, in: Partners in Stewardship: Proceedings of 7th Conference on Research and Resource Management in Parks and on Public Lands. W.E. Brown and S.D. Veirs, Jr. (eds.). The George Wright Society, Hancock, MI. Stohlgren, T.J., T.N. Chase, R.A. Pielke, Sr., T.G.F. Kittel, and J.S. Baron. 1998. Evidence that local land use practices influence regional climate, vegetation, and stream flow patterns in adjacent natural areas. Glob. Change Biology 4: 495-504. Sueker, J.K., 1995. Chemical hydrograph separation during snowmelt for three headwater basins in Rocky Mountain National Park, Colorado. pp. 271-282 in: K.A. Tonnesson, M.W. Williams, and M. Tranter, eds. Biogeochemistry of seasonally snow-covered catchments. IASH Publication No 228: International Association of Hydrologic Sciences Press, Institute of Hydrology, Wallingford, Oxfordshire, OX10 8BB, UK. Sueker, J.K., 1996. Isotopic and chemical flowpath separation of streamflow during snowmelt and hydrogeologic controls of surface water chemistry in six alpine-subalpine basins, Rocky Mountain National Park, Colorado. Ph.D. Dissertation, University of Colorado Department of Civil, Environmental, and Architectural Engineering. Sueker, J.K., J.N. Ryan, C. Kendall, and R.D. Jarrett. 2000. Determination of hydrologic pathways and sources of evapotranspiration water during snowmelt using two- and three-component hydrograph separations for six headwater basins, Rocky Mountain National Park. Water Resources Research 36: 63-76. Sullivan, T.J., B.J. Cosby, K.A. Tonnessen, and D.W. Clow. 2005. Surface water acidification responses and critical loads of sulfur and nitrogen deposition in Loch Vale watershed, Colorado. Water Resources Research 41: doi 10.1029/2004WR3414. Turk J.T., Spahr N.E., and Campbell D.H. 1993 Planning document of water, energy, and biogeochemicalbudget (WEBB) research project, Loch Vale Watershed, Rocky Mountain National Park, Colorado, U.S. Geological Survey Open-File Report 92-628, 18 p. Turk, J.T., H.E. Taylor, G.P. Ingersoll, K.A. Tonnessen, D.W. Clow, M.A. Mast, D.H. Campbell, and J.M. Melack. 2001. Major-ion chemistry of the Rocky Mountain snowpack, USA. Atmos. Environ. 25:39573966. Walko, R.L., L.E. Band, J. Baron, T.G.F. Kittel, R. Lammers, T.J. Lee, R.A. Pielke, Sr., C. Taylor, C. Tague, C.J. Tremback, and P.L. Vidale. 2000. Coupled atmosphere-terrestrial ecosystem-hydrology models for environmental modeling. Jour. Appl. Meteorol. 39:931-944. Walthall, P.M. 1985. Acidic deposition and the soil environment of Loch Vale Watershed in Rocky Mountain National Park. Ph.D. dissertation. Colorado State University. 148 pp. Wang, Y., T.G. Huntington, L.J. Osher, L.I. Wassenaar, S.E. Trumbore, R.G. Amundson, J.W. Harden, D.M. McKnight, S.L. Schiff, G.R. Aiken, W.B. Lyons, R.O. Aravena, and J.S. Baron. 1998. Carbon cycling in terrestrial environments. Pp. 577-610 in: C. Kendall and J.J. McDonnell, eds. Isotopic Tracers in Catchment Hydrology. Elsevier, New York. 14 Wickland, K.P., R.G. Striegl, S.K. Schmidt, and M.A. Mast. 1999. Methane flux in subalpine wetland and unsaturated soils in the southern Rocky Mountains. Global Biogeochemical Cycles 13:101-114. Williams, M.W., J.S. Baron, N. Caine, R. Sommerfeld, and R.L. Sanford. 1996 Nitrogen saturation in the Rocky Mountains. Environmental Science and Technology 30:640-646. Wolfe, A.P., A.C. VanGorp, J.S. Baron. 2003. Recent ecological and biogeochemical changes in alpine lakes of Rocky Mountian Naitonal Park (Colorado, USA): a response to anthropogonic nitrogen depositon. Geobiology: 1, 153-168. Wolfe, A. P., J.S. Baron, R.J. Cornett. 2001. Anthroogenic nitrogen deposition induces rapid ecological changes in alpine lakes of the Colorado Front Range (USA). Journal of Paleolimnology: 25: 1-7. Wolfe, A.P., S.S. Kaushal, J.R. Fulton, D.M. McKnight. 2002. Spectrofluorescence of Sediment Humic Stubstances and Historical Changes of Laucustrine Organic Matter Rovenance in Response to Atmospheric Nutrient Enrichment. Environmental Science Technology: 36: 3217-3223. Wolfe, A.P., J.S. Baron, and R.J. Cornett, 2001. Unprecedented changes in alpine ecosystems related to anthropogenic nitrogen deposition. J. Paleolimnology 25:1-7. EDUCATION GK12: GK12 is a National Science Foundation funded project getting graduate fellows in K- 12 classrooms. The idea is to use the graduate students as liaisons between the primary science taking place in the country’s universities and the K-12 students. The program stems from the idea that if K12 students see science as an active and hands-on approach – rather than a compendium of facts stored in textbooks, they will become more interested in science – increasing the potential for future scientists and scientific literacy in the general population. Colorado State University and the University of Northern Colorado jointly hold a GK12 grant entitled Human Impacts along the Colorado Front Range. The program funds the education of a number of graduate and undergraduate students from both institutions to work in the Poudre Valley and Weld County school district. Sanjay Advani recently finished two years of working with Northridge High School in Greeley, Colorado. Working with both the biology and chemistry classes, Advani and the Northridge teachers developed a curriculum investigating aspects of water quality in the Cache- La Poudre River watershed. Jill Oropeza has just joined the GK12 project and will be developing her particular project over time. Posters: include links to posters. REU: Research experience for undergraduates (REU) is a great opportunity for students to participate in current Loch Vale research in a hands-on work environment. We provide students with field and/or laboratory based projects to increase their understanding of ecological applications, field techniques, and laboratory methodologies. Fact Sheets: Loch Vale Watershed Long-term Ecological Research and Monitoring (conducted by US Geological Survey, National Park Service, and universities) 15 Objective: To be able to differentiate natural variability from human-caused disturbance, particularly disturbances from atmospheric deposition and climate change. Through monitoring, experiments, and modeling, we study changes in ecosystems and climate that may be affected by increasing urban, agricultural, and industrial activity. Current research in Loch Vale has three themes: 1) Long-term trends in climate and biogeochemical fluxes, 2) Ecosystem/atmospheric responses to nitrogen deposition, and 3) Effects of global change on mountain ecosystems. Fact Sheet This handout is a small primer on some of our findings, things we’d like to know if we were park visitors. We’ve been doing this work since 1983, so this is our 20th year of study. If you have questions, call, or email Jill Baron 970-491-1968, jill@nrel.colostate.edu Jorin Botte 970-491-2153 jorin@nrel.colostate.edu Our WEB address is http://www.nrel.colostate.edu/projects/lvws Loch Vale in the News: (include links to articles associated with Loch Vale) #1 The Denver Post (April 08, 2004) Pollution's long commute Air carrying mercury, pesticides to Rocky Mtn. Park, studies show #2 Rocky Mountain News (August 30, 2004) Pollutants raining down on Rockies Nitrogen buildup putting national park's ecosystem at risk - and it could get worse, research shows #3 The Daily Times-Call (March 19, 2005) RMNP begins effort to curb nitrogen levels in air #4 Coloradoan (March 19, 2005) RMNP ecosystem in danger Groups pledge to work together to solve area's air-quality problems #5 Boulder Daily Camera (March 19, 2005 ) 16 Park's nitrogen problem grows Regulators seek solution to RMNP pollution #6 The Denver Post (March 20, 2005) Long view taken on park's air: Coalition starting to address ways to clear up haze PERSONNEL Current Personnel Name Position Phone Email Jill Baron Principal Investigator (970) 491-1968 jill@nrel.colostate.edu Lindsey Christensen Research Scientist (970) 491-1609 lindsey@nrel.colostate.edu Sanjay Advani Research Associate (970) 491-3552 sanjay@nrel.colostate.edu Melannie Hartman Research Associate (970) 491-1609 melannie@nrel.colostate.edu Jill Oropeza Graduate Student (970) 491-5630 joropeza@nrel.colostate.edu Sam Prentice Graduate Student (970) 491-1604 michiko@nrel.colostate.edu Lisa Foster NPS Field Technician (970) 586-2399 lisahikes@hotmail.com Past Personnel Brett Johnson, Ph.D. Fishery and Wildlife Biology, CSU Brett.Johnson@colostate.edu Mary Arthur, Ph.D. Department of Forestry, University of Kentucky. Lexington, KY. marthur@uky.edu Jennifer Back, M.Sc. 1995 National Park Service Water Resources Division. Fort Collins, CO. jennifer_back@nps.gov Benjamin Balk, M.Sc. 1999 National Weather Sevice, NOAA. Anchorage, AK. Ben.Balk@noaa.gov 17 Cynthia Brock (Kester), M.Sc. 1997 USGS Denver, CO. ckester@usgs.gov Donald Campbell USGS Water Resources Division. Denver, CO. dhcampbe@usgs.gov Donald Cline, Ph.D. 1997 National Weather Service, NOAA. Minneapolis, MN. Donald.Cline@noaa.gov David Clow, Ph.D. USGS Water Resources Division. Denver, CO. dwclow@usgs.gov George Ingersoll USGS Water Resources Division. Denver, CO. gpingersoll@usgs.gov Toben LaFrancois, M.Sc., 1995 University of Minnesota Philosophy Department. Daniel Liptzin, Ph.D. (current). INSTAAR, University of Colorado. Boulder, CO daniel.liptzin@colorado.edu Michael Martin, M.Sc. 1994 National Park Service Water Resources Division. Fort Collins, CO. mike_martin@nps.gov Alisa Mast, Ph.D. USGS Water Resources Division. Denver, CO. mamast@usgs.gov Debbie Miller, M.Sc. 1996 National Park Sevice Air Resources Division. Debbie_Miller@nps.gov Brenda Moraska (LaFrancois), Ph.D. 2002 National Park Service, St. Croix Watershed Research Station. St. Croix, MN brenda_moraska_lafrancois@nps.gov Kathryn Muldoon, M.Sc. 2003 CSU Graduate Degree Program in Ecology. Koren Nydick, Ph.D. 2002 Mountain Studies Institute koren@mountainstudies.org 18 Heather Rueth, Ph.D. 2001 Grand Valley State University ruethh@gvsu.edu Alan Shiller, Ph.D Dept. of Marine Science, University of S. Mississippi. Stennis Space Center alan.shiller@usm.edu Julie Sueker, Ph.D Exponent Environmental Group. Boulder, CO. P. Mark Walthall, Ph.D. Current address unknown Undergraduate advisees/REU students: 1997 Julie Hawkins, Toby Minear, Matt Ridge 1998 Roger Andre, Katrina Gerkin 1999 Mary Fitzgerald, Seth Gates, Seth Martin, Andrew Ramey 2000 Hannah Afifi (Trinity College, Dublin) 2001 Bethany Caruso 2003 Stephanie Gieck PHOTOS Include pages for Scenery, Equipment, and People pictures. LINKS National Park Service - NPS United States Geological Survey - USGS Fort Collins Science Center -USGS Loch Vale WEBB Program - USGS Global Change Research in Biology - USGS Mountain Research Initiative 19 GK-12 Niwot Ridge - LTER Natural Resource Ecology Laboratory - NREL National Atmospheric Depositon Program - NADP United States Forest Service - USFS Unites States Forest Service - Rocky Mountian Research Station Consortium of Regional Ecological Observatories-COREO National Park Service - Nature and Science National Science Foundation - NSF CONTACT US Email to jill@nrel.colostate.edu 20