MSci Project Proposal Form 2009-2010 Project Code: EXSS-Chatten-1 Project title: Optimising the Luminescent Solar Concentrator Supervisor: Dr Amanda Chatten Assessor: Dr Ned Ekins-Daukes Telephone: Ex. 4 7564 Telephone: Ex. 4 6675 E-mail: a.chatten E-mail: n.ekins-daukes Research group: EXSS Research group: EXSS Project Summary: The Luminescent Solar Concentrator (LSC) is a novel approach to reducing the cost of photovoltaic electricity. LSCs have advantages over conventional geometric concentrators in that expensive solar tracking is unnecessary and both direct and diffuse radiation can be collected. However, their development has been limited by the performance of luminescent dyes, particularly their stability. The quantum photovoltaics group has pioneered the replacement of the dyes by colloidal semiconductor nanocrystals (e.g. quantum dots and nanorods). Advantages over dyes include; that the absorption threshold can be tuned by the choice of nanocrystal size, improved stability and improved solar photon harvesting owing to the broad absorption spectra of the nanocrystals. In addition high luminescence quantum efficiencies have been observed for core-shell nanocrystals. Optimising the LSC, using modelling tools which we have developed, has become one of the main objectives of the group’s research activity. This project will give two students the opportunity to make a contribution to a leading-edge research project that is collaborative with European laboratories and which is of direct relevance to the problems of developing sustainable electricity generation. The project will involve absorption, luminescence and short-circuit current measurements on concentrator samples and test devices, together with interpretation of the results using the models. The project therefore will be of interest to students with an interest in both experimental measurements and the computer modelling of the concentrator performance. The location of the project will be the Huxley Undercroft. Experimental component: 50% Computational component: 40% Theoretical component: 10% Eligible for students on the MSci Physics with Theoretical Physics Degree: NO Suggested reading: o o o A Goetzberger and W Greubel, Appl. Phys. 14, 1977, p123 K W J Barnham et al., Appl. Phys. Lett. 76, 2000, p1197 A J Chatten et al., Semiconductors, 38, 2004, p909 Imperial College of Science, Technology, and Medicine