Key Terms and Concepts temperature heat thermal energy kinetic energy potential energy particle speed particle spacing phase change conduction convection radiation linear expansion specific heat capacity heat of fusion heat of vapourization coefficient of linear expansion Goals 1. Describe how adding/removing energy changes the particles of a substance. 2. Calculate how temperature changes when energy is added/removed from a sample. 3. Calculate the quantity of energy needed to be added/removed from a sample in order for a phase change to occur. 4. Calculate the change in length of a solid when energy is added/removed to change the temperature. 5. Analyze a heating/cooling graph for a sample. Equations 𝑄 = 𝑚𝑐∆𝑇 𝑄 = 𝑚𝐻𝑓 𝑄 = 𝑚𝐻𝑣 ∆𝐿 = 𝛼𝐿𝑖 ∆𝑇 1 PHYSICS 20: Heat: Heat Concepts 1. Heat Vocabulary: a. Write what you understand each of the following terms means. b. Use each term in a sentence to demonstrate its meaning. i. heat: ii. kinetic energy: iii. particles (atoms/molecules): iv. particle speed: v. particle spacing: vi. phase change: vii. temperature: viii. potential energy: Create a concept map using the terms on the preceding page. Start with two terms that you believe have a strong connection. Put each term into a bubble. Be sure to explain the connection between the terms. Continue adding terms and explanations of connections. You can use Inspiration or Cmap (free at: http://cmap.ihmc.us/) to create a digital version of your concept map. Do this on a separate page so that it can be submitted. 2 PHYSICS 20: Heat – Heating H2O Activity Purpose: to observe the behavior of water as it is heated from a solid until it is vapourized. Background: Thermometers: the graduations on the thermometer have a scale of 1°C. o Measurements where the red liquid lines up with a graduation will be recorded as ##.0°C o Measurements where the red liquid ends between graduations will be recorded as ##.5°C o ALL TEMPERATURES will be recorded to one decimal place! Procedure: Part A 1. Set up the apparatus as demonstrated by your teacher 2. Obtain a 250 ml beaker with crushed ice 3. Place the 250 ml beaker of ice in the large beaker (water bath) 4. Record the initial temperature of the ice. 5. Light the Bunsen burner and begin heating the water bath 6. Record the temperature of the ice/water in the 250 ml beaker every 30 seconds 7. Make a note of the time when the ice: a) begins melting b) is all melted 8. Once the temperature reaches 50°C turn off the Bunsen burner and stop heating. 9. Remove the 250 ml beaker from the water bath Part B: 1. Record the ‘initial’ temperature of the hot water in the water bath 2. Light the Bunsen burner and begin heating the water bath 3. Record the temperature of the water every 30 seconds 4. Make a note of the time when the water: a) Begins boiling 5. Continue to ear for 5 minutes once the water begins boiling 6. Continue to record the temperature every 30 seconds 7. After 5 minutes of boiling turn off the Bunsen burner 8. Allow the apparatus to cool and clean up 3 Data: the following is an example of the headings for a data table TIME (min) Data Set #1: Temperature (°C) Data Set #2 Temperature (°C) 0 0.5 1.5 2.0 … Analysis: Prepare a graph of Temperature vs Time using your data. Both sets of data can be plotted on the same graph. 1. Data Set #1 produces a graph with two distinct regions. What is happening to the water temperature during these two regions? 2. Data Set #2 produces a graph with two distinct regions. What is happening to the water temperature during these two regions? 3. What do you hypothesis is happening to water molecules during periods when the temperature does not change significantly? Are the molecules still gaining energy? Conclusion: use the RERUN format to assist in writing your conclusion. R: Recall what you did in the activity to obtain your data. E: Explain the purpose of the activity. R: Results – describe the graphs created from your data. Why do you suppose the graphs show this behavior for water? What connection is there between heating water molecules and the resulting temperature behavior? U: Uncertainties – describe any limitations of the procedure or apparatus. N: New Knowledge – what have you learned? How might this knowledge be used by people in the ‘real world’? 4 PHYSICS 20: Heat – Measuring Temperature A Brief History of Temperature Measurement (source: http://en.wikipedia.org/) In 1701, Ole Christensen Rømer (1644-1710) created one of the first practical thermometers. Rømer's thermometer used red wine as the temperature indicator. Rømer created a temperature scale for his thermometer with 0 representing the temperature of a salt and ice mixture (at about 259 K), 7½ representing the freezing point of water (273.15 K), and 60 representing the boiling point of water (373.15 K). (In 1676, Rømer became the first scientist to measure the speed of light.) Daniel Gabriel Fahrenheit (1686-1736) devoted most of his life to creating precision meteorological instruments. Fahrenheit invented the mercury thermometer in 1714, and later discovered the effect of pressure on the boiling point of liquids. Fahrenheit sought to create a practical temperature scale in which 0 corresponded with the coldest temperature normally encountered in Western Europe and 100 corresponded to the hottest temperature. Fahrenheit initially created a temperature scale in which 0 represented the temperature of a salt and ice mixture (at about 255 K), 30 represented the freezing point of water (273.15 K), and 90 representing the mean human body temperature (about 310 K). Fahrenheit later adjusted his temperature scale so that 32 represented the freezing point of water and 212 represented the boiling point of water (373.15 K). The Fahrenheit temperature scale is still used today in the United States and other backward places. In 1731, Réne Antoine Ferchault de Réamur (1683-1757) created a simpler temperature scale in which 0 represented the freezing point of water (273.15 K) and 80 represented the boiling point (373.15 K). The Réamur temperature scale became popular in France, but it was superseded by the centigrade temperature scale. In 1742, Anders Celsius (1701-1744) created an inverted centigrade temperature scale in which 0 represented the boiling point of water (373.15 K) and 100 represented the freezing point (273.15 K). In 1744, Carl Linnaeus (1707-1778) suggested reversing the temperature scale of Anders Celsius so that 0 represented the freezing point of water (273.15 K) and 100 represented the boiling point (373.15 K). The centigrade relative temperature scale gradually became popular throughout the world. The units of the centigrade temperature scale were designated "degree centigrade" (symbol °C). 5 In 1848, William Thomson (1824-1907) proposed a thermodynamic temperature scale which assigned 0 to thermodynamic absolute zero and used the degree centigrade as its base unit. This absolute scale was later named the Kelvin thermodynamic temperature scale (after Thomson's peer title: Lord Kelvin) and its unit designated degree Kelvin (symbol ºK). In 1859, William John Macquorn Rankine (1820-1872) proposed another thermodynamic temperature scale which also assigned 0 to thermodynamic absolute zero, but used the degree Fahrenheit as its base unit. This absolute scale was later named the Rankine thermodynamic temperature scale and its unit designated degree Rankine (symbol °R). In 1948, the Ninth General Conference on Weights and Measures changed the name "degree centigrade" to "degree Celsius" (symbol °C) in honor of Anders Celsius. In 1954, the Tenth General Conference on Weights and Measures selected the degree Kelvin as the metric unit of thermodynamic temperature. The degree Kelvin was named in honor of its creator, Sir William Thomson, Baron Kelvin of Largs, Lord Kelvin of Scotland. The conference defined the degree Kelvin by assigning the exact value 273.16°K to the triple point of water. The triple point of a substance is the thermodynamic singularity at which the gas, liquid, and solid phases may coexist in thermodynamic equilibrium. A triple point is therefore a much more accurate temperature reference than either a freezing point or a boiling point. In 1967, the Thirteenth General Conference on Weights and Measures changed the name of the thermodynamic temperature unit degree Kelvin (symbol °K) to merely kelvin (symbol K). The conference redefined Celsius temperature as the thermodynamic temperature minus 273.15 kelvin. (ºC = K – 273.15) 1. Create a timeline showing the development of measuring temperature. Be sure to use an appropriate scale for your time axis. 2. If you had a thermometer which had no markings, how would YOU add markings so that you could use the thermometer to measure air temperatures in degrees Celcius? 3. How would you add markings so that you could use the thermometer to measure air temperatures in Kelvin? 4. Why is using the boiling point and freezing point of water better than using some mixture of salt and ice and water? 6 5. Temperature Conversions: Make the following conversions between degrees Celcius and Kelvins. a. Melting temperature of H2O: ºC = K b. Boiling temperature of H2O: ºC = K c. Room temperature (make one up): ºC = K d. Outside temperature on a hot Saskatchewan summer day: ºC = K e. Outside temperature on a cold Saskatchewan winter night: ºC = K f. Temperature at which molecular motion stops (absolute zero – read the notes!) ºC = g. Temperature of liquid nitrogen: ºC = K 77 K h. Melting point of hydrogen: -259.14 ºC = K i. Melting point of mercury: -38.72 ºC = K j. Melting point of gold: ºC = 1337.73 K Use: Fundamentals of Physics: An Introductory Course – pages 196 to 198 6. What are the main points of the Kinetic-Molecular Theory? 7. According to the kinetic-molecular theory, what is the difference between a cold glass of water and a hot glass of water? 8. When we measure the temperature of a substance, what are we measuring about the particles of the substance? 9. What makes up the ‘total thermal energy’ of an object? 7 PHYSICS 20: Transferring Heat Energy – Conduction, Convection, Radiation Method of Energy Transfer CONDUCTION What It Is Examples CONVECTION RADIATION 8 PHYSICS 20: Heat – Heating Water Activity PURPOSE: To observe the temperature of a system reaching a thermal equilibrium To develop a mathematical equation to represent the temperature changes when mixing hot and cold water. THEORY: When two substances are mixed, energy is transferred from the hotter to the colder substance. This transfer of energy can occur through conduction, convection, or radiation. When the two substances are the same temperature, this is called the equilibrium temperature and there is no more transferring of energy. HYPOTHESIS: use cold water = 10ºC and hot water = 90ºC When equal quantities of hot and cold water are mixed the equilibrium temperature will be: When there is more cold water than hot water in a mixture the equilibrium temperature will be: When there is more hot water than cold water in a mixture the equilibrium temperature will be: VARIABLES: What is the independent variable for this activity? What is the dependent variable for this activity? What are some of the controlled variables for this activity? APPARATUS & PROCEDURE: Draw and label a sketch of the apparatus used and explain how it was used. DATA: use the following for headings in a data table. TRIAL Cold Cold Water Hot water Hot Water Water Initial Quantity Initial Quantity Temperature Temperature (TCi) (THi) Equilibrium Temperature (Tf) 9 OBSERVATIONS: Take note of anything you observe occurring as you prepare the mixture or while the mixture is reaching thermal equilibrium. ANALYSIS: CALCULATIONS: use the following for headings in a TRIAL Mass of Mass of Cold Hot Temperature Temperature Water Water Cold Water Hot Water 1. calculation table (m)(T) for Cold Water (m)(T) for Hot Water QUESTIONS: Cold Water: a) What happened to the temperature of the cold water? b) What change has occurred in the behavior of the cold water particles? c) How has the thermal energy of the cold water particles changed? d) Did the temperature of the cold water change by the same amount in each trial? 1. Hot Water: a) What happened to the temperature of the hot water? b) What change has occurred in the behavior of the hot water particles? c) How has the thermal energy of the hot water particles changed? d) Did the temperature of the hot water change by the same amount in each trial? 1. (m)(T) : How are the (m)(T) values similar for the cold water? How are the (m)(T) values similar for the hot water? In each trial, how does the (m)(T) product compare between the cold water and the hot water? Are they similar or very different? What does the product (m)(T) represent for each quantity of water? (Recall what happens to each quantity of water curing each trial.) 2. Which of the three methods of energy transfer (conduction, convection, radiation) was mostly likely occurring in Styrofoam-cup calorimeter? Explain. CONCLUSION: use the RERUN format to assist in writing your conclusion. RECALL: what was the purpose of the activity? EXPLAIN: what did you do to complete the activity? RESULTS: How does the initial temperature and mass of water affect the equilibrium temperature? What equation could be used to represent the effect of mass and initial temperature on the equilibrium temperature? UNCERTAINTY: what were sources of experimental ‘error’ or uncertainty? NEW: what did you learn through this activity and how could this knowledge be used or applied to real-life situations? 10 PHYSICS 20: Heat – Mixing Water Calculations When mixing quantities of hot and cold water the following equation can be used: also: 𝐦𝐜 ∆𝐓𝐜 = −𝐦𝐡 ∆𝐓𝐡 ∆𝐓 = 𝐓𝐟 − 𝐓𝐢 so: 𝐦𝐜 (𝐓𝐟 − 𝐓𝐢𝐜 ) = −𝐦𝐡 (𝐓𝐟 − 𝐓𝐢𝐡 ) 1. 400 grams of cold water at 10°C is mixed with warm water at 80°C. The final temperature of the water mixture is 30°C. Calculate the mass of the hot water. 2. 500 grams of cold water is mixed with 700 grams of warm water at 60°C. The final temperature of the water mixture is 40°C. a. Calculate the change in temperature of the cold water. b. Calculate the initial temperature of the cold water. 3. 800 grams of cold water is mixed with warm water. The cold water is initially at 15°C and the warm water is initially at 70°C. The equilibrium temperature of the mixture is 40°C. Calculate how much warm water was mixed. 4. 800 grams of cold water at 10°C is mixed with 500 grams of hot water at 75°C. Calculate the equilibrium temperature of the water mixture. 11 PHYSICS 20: Heat – Hot Metal Activity PURPOSE: To observe the temperature of a system reaching a thermal equilibrium To develop a mathematical equation to represent the temperature changes when mixing a hot metal and cold water. THEORY: When two substances are mixed, energy is transferred from the hotter to the colder substance. This transfer of energy can occur through conduction, convection, or radiation. When the two substances are the same temperature, this is called the equilibrium temperature and there is no more transferring of energy. HYPOTHESIS: use cold water = 10ºC and hot metal = 90ºC Will mixing two different substance produce an equilibrium temperature that follows the equation m1 ΔT1 = m2 ΔT2 ? VARIABLES: What is the independent variable for this activity? What is the dependent variable for this activity? What are some of the controlled variables for this activity? APPARATUS & PROCEDURE: Draw a sketch of the apparatus used and explain how it was used. DATA: TRIAL (metal) Cold Water Mass Cold Water Initial Temperature (TCi) Hot metal Mass Hot metal Initial Temperature (THi) Equilibrium Temperature (Tf) 12 OBSERVATIONS: Take note of anything you observe occurring as you prepare the mixture or while the mixture is reaching thermal equilibrium. ANALYSIS: CALCULATIONS: TRIAL Mass of (metal) Cold Temperature Water Cold Water Mass of Hot Metal Temperature Hot Metal (m)(T) for Cold Water (m)(T) for Hot Metal Class Results: Metal 1. 2. 3. 4. Hot Metal (m)(T) Cold Water (m)(T) Class Results Class Average QUESTIONS: Does the (m)(T) for cold water equal the (m)(T) for the hot metal? Do the class results and average show a pattern for each metal? What does the ratio of Hot Metal (m)(T) indicate? Cold Water (m)(T) Does the equation we develop for mixing water work with two different substances? Why might it require some changes? CONCLUSION: use the RERUN format to assist in writing your conclusion. RECALL: what was the purpose of the activity? EXPLAIN: what did you do to complete the activity? RESULTS: what did you observe about the temperature changes for the water and metal? Does your math equation still work for this equilibrium? UNCERTAINTY: what were sources of experimental ‘error’ or uncertainty? NEW: what did you learn through this activity and how could this knowledge be used or applied to real-life situations? 13 PHYSICS 20: Heat Unit – Energy Change – Practice When energy is added to a substance either the temperature changes or the phase changes. Temperature change = change in speed of particles Phase change = change in spacing of particles Temperature Change: The following equation can be used when a temperature change occurs for a substance: Q = m c ΔT Where: Q = quantity of energy transferred (gained or lost) m = mass of substance c = specific heat capacity: amount of energy (in joules) needed to change the temperature of 1 gram of a substance by 1ºC. Check table of values provided ΔT = change in temperature = Tf – Ti = final temp – initial temp Practice Questions: 1. A copper pot has a mass of 750 grams. The pot contains 1.2 kg of vegetable oil. Both pot and oil are heated from 20ºC to 150 ºC a. What is the specific heat capacity for copper? b. What is the specific heat capacity for vegetable oil? c. Calculate the amount of energy added to the copper pot to achieve the temperature change from 20ºC to 150ºC. d. Calculate the amount of energy absorbed by the vegetable oil as it is heated from 20ºC to 150ºC. Be aware of units! 2. An unknown metal object has a mass of 200 grams. The metal cools from 100ºC to 20ºC and releases 14500 J of energy. a. Calculate the specific heat capacity of the unknown metal. b. Identify the metal using its specific heat capacity. 3. An 800 gram glass bowl absorbs 21250 J of energy. a. What is the specific heat capacity of glass? b. Calculate the change in temperature of the glass bowl. 14 4. A hot brass weight is dropped into 500 grams of water. The brass cools from 120ºC to 55ºC. The water heats up from 20ºC to 55ºC. a. Calculate the amount of energy absorbed by the water. b. How much energy has the brass weight released? c. Calculate the mass of the brass weight. Phase Change: The following equations can be used when a phase change occurs for a substance Q = m Hf or Q = m Hv Where: Q = quantity of energy transferred (gained or lost) m = mass of substance Hf = Heat of Fusion: amount of energy (in joules) needed to melt or freeze each gram of a substance Hv = Heat of Vaporization: amount of energy (in joules) needed to vaporize or condense each gram of a substance Practice Questions: 1. A gold ingot is warmed to its melting temperature of 1064 °C. How much additional energy must be added to the 250 gram gold ingot in order to melt it? 2. 400 grams of water is collected from a water distiller. The distiller heats water so that it boils and then collects and cools the steam. How much energy was removed from the 100 °C steam so that it could condense to liquid water? 3. Before electricity was widely available ice was used to keep food cool in houses using ‘ice chests’. A block of ice about 20 kg was used weekly in a home ‘icebox’. The temperature of the ice was about 0C when it was delivered. As it melted, how much heat did the block of ice absorb? 15 HEAT PROPERTIES OF SUBSTANCES Material Aluminum Brass Brick Carbon Concrete Copper Glass (Crown) Glass (Pyrex) Gold Human Body Ice Iron Lead Marble Platinum Pyrex Silver Steel Wood Zinc Specific Heat Capacity Value Heats of Fusion Heats of Vapourization c Hf Hv 𝑱 ( ) 𝒈 𝑱 ( ) 𝒈 𝑱 ( ) 𝒈 °𝑪 0.903 0.376 3.00 0.710 2.90 0.385 0.664 0.78 0.130 3.47 2.16 0.460 0.130 0.87 205 5070 63 1640 334 266 20.4 6290 864 Coefficients of Linear Expansion α (𝟏⁄°𝑪) 25 x 10-6 12 x 10-6 16 x 10-6 9 x 10-6 3 x 10-6 12 x 10-6 9 x 10-6 3 x 10-6 0.235 10.4 2360 12 x 10-6 1.76 0.388 Ethyl alcohol (ethanol) Methyl alcohol (methanol) Glycerine Mercury Nitrogen (Liquid) Vegetable oil Water 2.30 2.50 2.40 0.140 0.110 2.00 4.18 Air Carbon dioxide Helium Hydrogen Oxygen Steam 0.995 0.836 5.25 14.40 0.916 2.02 Q = m c ΔT 109 99 855 878 11.5 272 2260 Q = m Hf Q = m Hv ΔL = α L ΔT 16 PHYSICS 20: HEAT – Temperature Change & Change in Length When the temperature of a substance changes it results in the change in speed of the particles of the substance. There is also a small change in the spacing of the particles. The change is not enough to cause a phase change, only a change in the length of the object. The following equation can be used to calculate the change in length of an object due to a change in temperature: ∆𝑳 = 𝜶 𝑳𝒊 ∆𝑻 Where: ΔL = change in length = final length – initial length = Lf – Li α = coefficient of Linear Expansion Li = initial length of object ΔT = change in Temperature = final temp – initial temp = Tf – Ti Practice Questions: 1. A steel cable has a length of 30 metres at a temperature of 10 °C. a) What is the change in length of the cable when the temperature changes to 30 °C? b) What is the new length of the steel cable? 2. An aluminum bar has a length of 10 metres when the temperature is 25 °C. What is the length of the aluminum bar when the temperature is -25 °C? 17 PHYSICS 20: Heat – Homework Assignment 1. 250 grams of water in a glass cup has an initial temperature of 15C. The cup and water are placed in a microwave oven and heated until the temperature of the water is 75C. a. Calculate how much energy has been added to the water to cause the temperature change. b. What form of energy transfer has occurred to add energy to the water? c. What form of energy transfer has occurred to add energy to the glass cup? 2. An aluminum roaster is used to cook a 6 kg turkey at 220C for 5 hours. The roaster has a mass of 1.5 kg. When the turkey is finished cooking the turkey is removed from the roaster and carved up. The roaster is set aside and allowed to cool to 20C. a. How much energy is released by the roaster as it cools? b. Where does the energy from the roaster go as it cools? 3. The cooling system of a car contains 20 litres of water. (1 litre of water has a mass of 1 kg). a. What is the change in temperature of the water if the engine operates until 836 KJ of energy has been absorbed by the water? b. Suppose it is winter time and the water has been replaced by 20 L of methanol (the density of methanol is 0.80 kg/L). What would be the increase in the temperature of the methanol if it absorbed the same 836 KJ of energy? c. Which is a better coolant, water or methanol? Explain why. 4. Silver is a metal used for making jewelry. It has a melting temperature of 962C. A jeweler has a 120 gram sample of silver she is going to use for casting into rings. a. If the silver starts at a room temperature of 20C, how much energy must be added to warm the silver to its melting temperature? b. How much additional energy must be added to melt the silver at its melting temperature of 962C? 18 5. Mercury has a boiling temperature of 357C. Mercury vapour is dangerous to humans because we have no way to get rid of mercury absorbed by our body. How much energy would be required to change 10 g of liquid mercury at 20C to mercury vapour at 357C? 6. A 2 kg block of ice is taken from a freezer set to -15C. The ice is placed in a pressure cooker and heated until it all changes to steam at a temperature of 120C. a. There are three different phases that the “water” occurs in. Describe the temperature change that occur to each phase of “water”. b. Calculate the energy needed to cause the temperature change of each phase of “water”. c. Describe each phase change that occurs to the “water”. d. Calculate the energy needed to cause each phase change. 7. A cup contains 300 grams of hot tea at a temperature of 85C. A person adds 30 g of creammilk (basically water) at a temperature of 4C. a. Explain what happens to the energy levels of the tea and the creammilk as they are mixed. b. Calculate the equilibrium temperature of the tea/creammilk mixture. 8. In the olden days, on a cold winter night, it was common to place a hot object in your bed to warm up the bed before you climbed in. Which would be better at warming up the bed: A 2 kg iron brick heated to 90C Or A 2 kg hot water bottle at 90C? Consider specific heat capacities when providing your answer. 9. A 500 gram piece of copper is heated to a temperature of 975C. The piece of copper is dropped into the middle of a large block of ice at 0C. a. Why does the copper cool down? b. What happens to the energy that the copper releases? c. How much energy does the copper release in cooling down to 0ºC? d. How much ice could be melted by the hot piece of copper? 19 10. A concrete bridge is measured as being 750 metres long in December when the temperature is -25C. a. What would be the length of the bridge on a warm summer day when the temperature is 25C? b. What change in length would occur if the bridge was made from steel rather than concrete? 11. A bar of an unknkown metal has a length of 0.975 m at 45C and a length of 0.972 at 23C. What is the coefficient of linear expansion for the metal? 12. Copper cable is used in power lines to carry electricity from generating stations to consumers. A cable is being strung between two power poles on a hot 30C day in Saskatchewan. The two power poles are located 100 metres from each other. What length of cable must be used so that when the temperature reaches -60C with a windchill in the middle of January the cable will still reach between the poles? Answers for Homework Assignment 1 2 3 4 5 6 7 8 9 10 a) Q=62700 J b) Radiation c) Conduction a) Q=-270900 J b) energy is transferred to surroundings (air and countertop) a) Q=26564 J b) Q=1248 J i) warming Hg: Q=472 J ii) vapourizing Hg: Q=2720 J iii) total: Q=3192 J a) & b) i) ice warms from -15°C to 0°C Q=64800 J ii) water warms from 0°C to 100°C Q=836000 J iii) steam warms from 100°C to 120°C Q=80800 J c) & d) i) Ice melts to Liquid Water Q=668000 J ii) Liquid Water vapourizes to Steam Q=4520000 J a) Tea loses energy and Creamilk gains energy b) Tf=77.6°C Pick the Hot Water Bottle: water’s higher specific heat capacity means it loses more energy than iron for every 1 degree Celsius change in temperature a) energy always travels from ‘hot’ to ‘cold’: conduction or convection b)copper loses energy to the cooler ice. This melts the ice c) Q=-187688 J d) m=562 g a) ΔL=0.45 m New Length=750.45 m b) the change in length of the steel rebar is the same as the concrete sine they have the same coefficient of linear expansion ΔL=±0.144 m Length in summer = 100.144 m 20 PHYSICS 20: Heat – Review 1. When energy is added to a substance there are two different possibilities for the change in the molecules of the substance. a. Explain the two effects that the addition of energy can have. b. How would we observe the change in the molecules? We can’t see molecules easily. 2. Sketch the graph of temperature versus time for heating ice from -20C to steam at 115C. 3. A copper bar has a mass of 1.25 kg. The bar is heated from a temperature of 20C to 220C. a. How much energy has the copper bar absorbed? b. Would a bar of aluminum with the same mass show a greater or lesser temperature change? Explain. 4. A 2.4 kg lump of iron is heated to a temperature of 240C. It is then dropped into 6 litres of water at a temperature of 20C. a. What happens to energy when the two are mixed? b. Explain the heating processes which occur when the two are mixed. c. Calculate the equilibrium temperature of the water iron mixture. 5. A 1 kg bar of gold is heated to its melting temperature and then melted. a. How much energy does it take to melt a 1 kg bar of gold once it reaches its melting temperature? b. Does your answer in part a) depend on the melting temperature of gold? Explain. 6. A copper pipe has a length of 80 metres. The pipe is used to move either water at 4C or hot water at a temperature of 95C. What change in length would occur for the copper pipe when it first is used with the cold water and then with the hot water? 7. Concrete structures like bridges are reinforced with iron rebar. Compare the coefficients of linear expansion of concrete and iron and explain why iron rather than other metals should be used to reinforce the concrete. 8. Explain why water is a better substance than oil to use in heating or cooling systems. Base your explanation on the specific heat capacity of water compared to oil. 21 # REVIEW ANSWERS 1 a) Adding energy to a substance can increase: particle speed OR particle spacing b) Δ speed = Δ temperature Δ spacing = Δ phase 2 3 4 a) Copper: Q = 96250 J b) Aluminum: temperature would be less since it has a higher specific heat capacity (c). This means it requires more energy to change each gram by 1°C. ΔT = 85.3°C a) Iron bar loses energy and water gains energy. Heat energytravels from hot to cold. b) Conduction: collisions between fast vibrating Fe atoms and slower moving water molecules. Fe atoms slow down and water molecules speed up. Convection: as water warms up it becomes less dense and rises in the container. Colder more dense water falls in the container. 5 6 7 8 c) Tf = 29.3 °C a) Q = 63000 J b) No, Q = m Hf does not require a temperature Copper: ΔL = 0.12 m Iron and concrete have the same coefficient of linear expansion (α) value. They change by the same amount for each degree temperature change. The specific heat capacity of water is 4.18 j/g C. It takes 4.18 Joules of energy to change 1 gram of water by 1 C. This is significantly higher than most other substances. Water can transport large quantities of energy because of its high heat capacity. 22